Reversible MOF-Based Sensors for the Electrical Detection of Iodine Gas
Abstract
Iodine detection is crucial for nuclear waste clean-up and first responder activities. For ease of use and durability of response, robust active materials that enable the direct electrical detection of I2 are needed. Herein, a large reversible electrical response is demonstrated as I2 is controllably and repeatedly adsorbed and desorbed from a series of metal–organic frameworks (MOFs) MFM-300(X), each possessing a different metal center (X = Al, Fe, In, or Sc) bridged by biphenyl-3,3',5,5'-tetracarboxylate linkers. Impedance spectroscopy is used to evaluate how the different metal centers influence the electrical response upon cycling of I2 gas, ranging from 10× to 106× decrease in resistance upon I2 adsorption in air. This large variation in electrical response is attributed not only to the differing structural characteristics of the MOFs but also to the differing MOF morphologies and how this influences the degree of reversibility of I2 adsorption. Interestingly, MFM-300(Al) and MFM-300(In) displayed the largest changes in resistance (up to 106×) yet lost much of their adsorption capacity after five I2 adsorption cycles in air. On the other hand, MFM-300(Fe) and MFM-300(Sc) revealed more moderate changes in resistance (10–100×), maintaining most of their original adsorption capacity after five cycles. This work demonstrates how changesmore »
- Authors:
-
[1];
[2];
[3];
[3];
[1]
- Sandia National Laboratories, Albuquerque 87185, New Mexico, United States
- Department of Chemistry, Stony Brook University, 100 Nicolls Road, New York 11794, United States
- School of Chemistry, University of Manchester, Manchester M13 9PL, United Kingdom
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1571695
- Alternate Identifier(s):
- OSTI ID: 1574480
- Report Number(s):
- SAND-2019-13634J
Journal ID: ISSN 1944-8244
- Grant/Contract Number:
- AC02-06CH11357; AC04-94AL85000; NA0003525
- Resource Type:
- Published Article
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Name: ACS Applied Materials and Interfaces Journal Volume: 11 Journal Issue: 31; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 47 OTHER INSTRUMENTATION; metal−organic framework; MOF; iodine; nanoporous; impedance spectroscopy; sensor
Citation Formats
Small, Leo J., Hill, Ryan C., Krumhansl, James L., Schindelholz, Mara E., Chen, Zhihengyu, Chapman, Karena W., Zhang, Xinran, Yang, Sihai, Schröder, Martin, and Nenoff, Tina M. Reversible MOF-Based Sensors for the Electrical Detection of Iodine Gas. United States: N. p., 2019.
Web. doi:10.1021/acsami.9b09938.
Small, Leo J., Hill, Ryan C., Krumhansl, James L., Schindelholz, Mara E., Chen, Zhihengyu, Chapman, Karena W., Zhang, Xinran, Yang, Sihai, Schröder, Martin, & Nenoff, Tina M. Reversible MOF-Based Sensors for the Electrical Detection of Iodine Gas. United States. https://doi.org/10.1021/acsami.9b09938
Small, Leo J., Hill, Ryan C., Krumhansl, James L., Schindelholz, Mara E., Chen, Zhihengyu, Chapman, Karena W., Zhang, Xinran, Yang, Sihai, Schröder, Martin, and Nenoff, Tina M. Wed .
"Reversible MOF-Based Sensors for the Electrical Detection of Iodine Gas". United States. https://doi.org/10.1021/acsami.9b09938.
@article{osti_1571695,
title = {Reversible MOF-Based Sensors for the Electrical Detection of Iodine Gas},
author = {Small, Leo J. and Hill, Ryan C. and Krumhansl, James L. and Schindelholz, Mara E. and Chen, Zhihengyu and Chapman, Karena W. and Zhang, Xinran and Yang, Sihai and Schröder, Martin and Nenoff, Tina M.},
abstractNote = {Iodine detection is crucial for nuclear waste clean-up and first responder activities. For ease of use and durability of response, robust active materials that enable the direct electrical detection of I2 are needed. Herein, a large reversible electrical response is demonstrated as I2 is controllably and repeatedly adsorbed and desorbed from a series of metal–organic frameworks (MOFs) MFM-300(X), each possessing a different metal center (X = Al, Fe, In, or Sc) bridged by biphenyl-3,3',5,5'-tetracarboxylate linkers. Impedance spectroscopy is used to evaluate how the different metal centers influence the electrical response upon cycling of I2 gas, ranging from 10× to 106× decrease in resistance upon I2 adsorption in air. This large variation in electrical response is attributed not only to the differing structural characteristics of the MOFs but also to the differing MOF morphologies and how this influences the degree of reversibility of I2 adsorption. Interestingly, MFM-300(Al) and MFM-300(In) displayed the largest changes in resistance (up to 106×) yet lost much of their adsorption capacity after five I2 adsorption cycles in air. On the other hand, MFM-300(Fe) and MFM-300(Sc) revealed more moderate changes in resistance (10–100×), maintaining most of their original adsorption capacity after five cycles. This work demonstrates how changes in MOFs can profoundly affect the magnitude and reversibility of the electrical response of sensor materials. Tuning both the intrinsic (resistivity and adsorption capacity) and extrinsic (surface area and particle morphology) properties is necessary to develop highly reversible, large signal-generating MOF materials for direct electrical readout for I2 sensing.},
doi = {10.1021/acsami.9b09938},
journal = {ACS Applied Materials and Interfaces},
number = 31,
volume = 11,
place = {United States},
year = {Wed Jul 17 00:00:00 EDT 2019},
month = {Wed Jul 17 00:00:00 EDT 2019}
}
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https://doi.org/10.1021/acsami.9b09938
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Works referenced in this record:
Competitive I 2 Sorption by Cu-BTC from Humid Gas Streams
journal, June 2013
- Sava, Dorina F.; Chapman, Karena W.; Rodriguez, Mark A.
- Chemistry of Materials, Vol. 25, Issue 13
Iodine Adsorption in Metal Organic Frameworks in the Presence of Humidity
journal, March 2018
- Banerjee, Debasis; Chen, Xianyin; Lobanov, Sergey S.
- ACS Applied Materials & Interfaces, Vol. 10, Issue 13
Determination of effective capacitance and film thickness from constant-phase-element parameters
journal, August 2010
- Hirschorn, Bryan; Orazem, Mark E.; Tribollet, Bernard
- Electrochimica Acta, Vol. 55, Issue 21
Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material
journal, August 2016
- Savage, Mathew; Cheng, Yongqiang; Easun, Timothy L.
- Advanced Materials, Vol. 28, Issue 39
Highly porous and robust scandium-based metal–organic frameworks for hydrogen storage
journal, January 2011
- Ibarra, Ilich A.; Yang, Sihai; Lin, Xiang
- Chemical Communications, Vol. 47, Issue 29
Highly selective carbon dioxide adsorption in a water-stable indium–organic framework material
journal, January 2012
- Qian, Jinjie; Jiang, Feilong; Yuan, Daqiang
- Chemical Communications, Vol. 48, Issue 78
Determination of Parameters of Electron Transport in Dye-Sensitized Solar Cells Using Electrochemical Impedance Spectroscopy
journal, July 2006
- Adachi, Motonari; Sakamoto, Masaru; Jiu, Jinting
- The Journal of Physical Chemistry B, Vol. 110, Issue 28
Increased Electric Conductivity upon I 2 Uptake and Gas Sorption in a Pillar-Layered Metal-Organic Framework
journal, April 2017
- Li, Gao-Peng; Zhang, Kun; Zhao, Hai-Yan
- ChemPlusChem, Vol. 82, Issue 5
Selectivity and direct visualization of carbon dioxide and sulfur dioxide in a decorated porous host
journal, September 2012
- Yang, Sihai; Sun, Junliang; Ramirez-Cuesta, Anibal J.
- Nature Chemistry, Vol. 4, Issue 11
Radioactive Iodine and Krypton Control for Nuclear Fuel Reprocessing Facilities
journal, January 2013
- Soelberg, Nick R.; Garn, Troy G.; Greenhalgh, Mitchell R.
- Science and Technology of Nuclear Installations, Vol. 2013
Thermochemical Evidence for Strong Iodine Chemisorption by ZIF-8
journal, October 2013
- Hughes, James T.; Sava, Dorina F.; Nenoff, Tina M.
- Journal of the American Chemical Society, Vol. 135, Issue 44
Materials and processes for the effective capture and immobilization of radioiodine: A review
journal, March 2016
- Riley, Brian J.; Vienna, John D.; Strachan, Denis M.
- Journal of Nuclear Materials, Vol. 470
Electrochemical impedance spectroscopy in interfacial studies
journal, February 2017
- Pajkossy, Tamás; Jurczakowski, Rafal
- Current Opinion in Electrochemistry, Vol. 1, Issue 1
MOF-Sensitized Solar Cells Enabled by a Pillared Porphyrin Framework
journal, February 2017
- Spoerke, Erik D.; Small, Leo J.; Foster, Michael E.
- The Journal of Physical Chemistry C, Vol. 121, Issue 9
Silver-mordenite for radiologic gas capture from complex streams: Dual catalytic CH3I decomposition and I confinement
journal, December 2014
- Nenoff, Tina M.; Rodriguez, Mark A.; Soelberg, Nick R.
- Microporous and Mesoporous Materials, Vol. 200
Influence of Analysis Method on the Experimentally Observed Capacitance at the Gold-Ionic Liquid Interface
journal, January 2014
- Small, L. J.; Wheeler, D. R.
- Journal of The Electrochemical Society, Vol. 161, Issue 4
Ball-Milling-Induced Amorphization of Zeolitic Imidazolate Frameworks (ZIFs) for the Irreversible Trapping of Iodine
journal, April 2013
- Bennett, Thomas D.; Saines, Paul J.; Keen, David A.
- Chemistry - A European Journal, Vol. 19, Issue 22
Direct Electrical Detection of Iodine Gas by a Novel Metal–Organic-Framework-Based Sensor
journal, December 2017
- Small, Leo J.; Nenoff, Tina M.
- ACS Applied Materials & Interfaces, Vol. 9, Issue 51
The effect of cobalt content in Zn/Co-ZIF-8 on iodine capping properties
journal, June 2019
- Butova, Vera V.; Bulanova, Elena A.; Polyakov, Vladimir A.
- Inorganica Chimica Acta, Vol. 492
Iodine detection in Ag-mordenite based sensors: Charge conduction pathway determinations
journal, May 2019
- Small, Leo J.; Krumhansl, James L.; Rademacher, David X.
- Microporous and Mesoporous Materials, Vol. 280
Electroceramics: Characterization by Impedance Spectroscopy
journal, March 1990
- Irvine, John T. S.; Sinclair, Derek C.; West, Anthony R.
- Advanced Materials, Vol. 2, Issue 3
Confinement of Iodine Molecules into Triple-Helical Chains within Robust Metal–Organic Frameworks
journal, November 2017
- Zhang, Xinran; da Silva, Ivan; Godfrey, Harry G. W.
- Journal of the American Chemical Society, Vol. 139, Issue 45
Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009
- Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
Direct Observation of Confined I − ⋅⋅⋅I 2 ⋅⋅⋅I − Interactions in a Metal-Organic Framework: Iodine Capture and Sensing
journal, May 2017
- Hu, Yue-Qiao; Li, Mu-Qing; Wang, Yanyan
- Chemistry - A European Journal, Vol. 23, Issue 35
Capture of Volatile Iodine, a Gaseous Fission Product, by Zeolitic Imidazolate Framework-8
journal, August 2011
- Sava, Dorina F.; Rodriguez, Mark A.; Chapman, Karena W.
- Journal of the American Chemical Society, Vol. 133, Issue 32
Stereoselective Halogenation of Integral Unsaturated C-C Bonds in Chemically and Mechanically Robust Zr and Hf MOFs
journal, February 2016
- Marshall, Ross J.; Griffin, Sarah L.; Wilson, Claire
- Chemistry - A European Journal, Vol. 22, Issue 14
Rigid Pillars and Double Walls in a Porous Metal-Organic Framework: Single-Crystal to Single-Crystal, Controlled Uptake and Release of Iodine and Electrical Conductivity
journal, March 2010
- Zeng, Ming-Hua; Wang, Qiang-Xin; Tan, Yan-Xi
- Journal of the American Chemical Society, Vol. 132, Issue 8
Radioactive Iodine Capture in Silver-Containing Mordenites through Nanoscale Silver Iodide Formation
journal, July 2010
- Chapman, Karena W.; Chupas, Peter J.; Nenoff, Tina M.
- Journal of the American Chemical Society, Vol. 132, Issue 26