Quantum liquid with strong orbital fluctuations: the case of the pyroxene family

Feiguin, A E.; Tsvelik, Alexei M.; Yin, Weiguo; Bozin, E. S.

doi:10.1103/PhysRevLett.123.237204

Title: Quantum liquid with strong orbital fluctuations: the case of the pyroxene family

Abstract

We discuss quasi one-dimensional magnetic Mott insulators from the pyroxene family where spin and orbital degrees of freedom remain tightly bound. Here, we analyze their excitation spectrum and outline the conditions under which the orbital degrees of freedom become liberated so that the corresponding excitations become dispersive and the spectral weight shifts to energies much smaller than the exchange integral.

Authors:

Feiguin, A E. ^[1];

^[2]; Yin, Weiguo ^[2]; Bozin, E. S. ^[2]

Northeastern Univ., Boston, MA (United States). Dept. of Physics
Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Div.

Publication Date:: 2019-11-15

Research Org.:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1574428

Report Number(s):: BNL-212346-2019-JAAM
Journal ID: ISSN 0031-9007; PRLTAO; TRN: US2100171

Grant/Contract Number:: SC0012704

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review Letters

Additional Journal Information:: Journal Volume: 123; Journal Issue: 23; Journal ID: ISSN 0031-9007

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Feiguin, A E., Tsvelik, Alexei M., Yin, Weiguo, and Bozin, E. S. Quantum liquid with strong orbital fluctuations: the case of the pyroxene family.  United States: N. p., 2019. 
Web.  doi:10.1103/PhysRevLett.123.237204.

Copy to clipboard


                    Feiguin, A E., Tsvelik, Alexei M., Yin, Weiguo, & Bozin, E. S. Quantum liquid with strong orbital fluctuations: the case of the pyroxene family.  United States.  https://doi.org/10.1103/PhysRevLett.123.237204

Copy to clipboard


                    Feiguin, A E., Tsvelik, Alexei M., Yin, Weiguo, and Bozin, E. S. Fri .  
"Quantum liquid with strong orbital fluctuations: the case of the pyroxene family".  United States.  https://doi.org/10.1103/PhysRevLett.123.237204.  https://www.osti.gov/servlets/purl/1574428.

Copy to clipboard


                    
@article{osti_1574428,

  title        = {Quantum liquid with strong orbital fluctuations: the case of the pyroxene family},

  author       = {Feiguin, A E. and Tsvelik, Alexei M. and Yin, Weiguo and Bozin, E. S.},

  abstractNote = {We discuss quasi one-dimensional magnetic Mott insulators from the pyroxene family where spin and orbital degrees of freedom remain tightly bound. Here, we analyze their excitation spectrum and outline the conditions under which the orbital degrees of freedom become liberated so that the corresponding excitations become dispersive and the spectral weight shifts to energies much smaller than the exchange integral.},

  doi          = {10.1103/PhysRevLett.123.237204},

  journal      = {Physical Review Letters},

  number       = 23,

  volume       = 123,

  place        = {United States},

  year         = {2019},

  month        = {11}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1103/PhysRevLett.123.237204

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 1 work

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
DOI: 10.1103/PhysRevLett.77.3865

Real-Time Evolution Using the Density Matrix Renormalization Group
journal, August 2004

White, Steven R.; Feiguin, Adrian E.
Physical Review Letters, Vol. 93, Issue 7
DOI: 10.1103/PhysRevLett.93.076401

Coexistence of Gapless Excitations and Commensurate Charge-Density Wave in the $2 H$ Transition Metal Dichalcogenides
journal, January 2006

Barnett, Ryan L.; Polkovnikov, Anatoli; Demler, Eugene
Physical Review Letters, Vol. 96, Issue 2
DOI: 10.1103/PhysRevLett.96.026406

Orbital dimerization in ${NaTiSi}_{2} O_{6} :$ An orbital analogue of the spin-Peierls phase transition
journal, January 2004

Konstantinović, M. J.; van den Brink, J.; Popović, Z. V.
Physical Review B, Vol. 69, Issue 2
DOI: 10.1103/PhysRevB.69.020409

Phase Transitions in Spin-orbital Coupled Model for Pyroxene Titanium Oxides
journal, January 2005

Hikihara, Toshiya; Motome, Yukitoshi
Journal of the Physical Society of Japan, Vol. 74, Issue Suppl
DOI: 10.1143/JPSJS.74S.212

Exact Results for a Quantum Many-Body Problem in One Dimension. II
journal, March 1972

Sutherland, Bill
Physical Review A, Vol. 5, Issue 3
DOI: 10.1103/PhysRevA.5.1372

Electronic structure and magnetic properties of pyroxenes $(Li, Na) TM {(Si, Ge)}_{2} O_{6}$ : Low-dimensional magnets with 90° bonds
journal, February 2008

Streltsov, S. V.; Khomskii, D. I.
Physical Review B, Vol. 77, Issue 6
DOI: 10.1103/PhysRevB.77.064405

Novel Phase Transition in Spin-1/2 Linear Chain Systems: NaTiSi ₂ O ₆ and LiTiSi ₂ O ₆
journal, June 2002

Isobe, Masahiko; Ninomiya, Emi; N. Vasil'ev, Alexander
Journal of the Physical Society of Japan, Vol. 71, Issue 6
DOI: 10.1143/JPSJ.71.1423

SU $(N)$ magnetism in chains of ultracold alkaline-earth-metal atoms: Mott transitions and quantum correlations
journal, October 2011

Manmana, Salvatore R.; Hazzard, Kaden R. A.; Chen, Gang
Physical Review A, Vol. 84, Issue 4
DOI: 10.1103/PhysRevA.84.043601

Tuning the in-plane electron behavior in high- $T_{c}$ cuprate superconductors via apical atoms: A first-principles Wannier-states analysis
journal, June 2009

Yin, Wei-Guo; Ku, Wei
Physical Review B, Vol. 79, Issue 21
DOI: 10.1103/PhysRevB.79.214512

Direct measurement of the spin gap in a quasi-one-dimensional clinopyroxene: ${NaTiSi}_{2} O_{6}$
journal, October 2014

Silverstein, Harlyn J.; Smith, Alison E.; Mauws, Cole
Physical Review B, Vol. 90, Issue 14
DOI: 10.1103/PhysRevB.90.140402

Insulating Ferromagnetism in ${L a}_{4} {B a}_{2} {C u}_{2} O_{10}$ : An Ab Initio Wannier Function Analysis
journal, September 2002

Ku, Wei; Rosner, H.; Pickett, W. E.
Physical Review Letters, Vol. 89, Issue 16
DOI: 10.1103/PhysRevLett.89.167204

Comment on “Sodium Pyroxene ${NaTiSi}_{2} O_{6}$ : Possible Haldane Spin-1 Chain System”
journal, June 2006

Streltsov, S. V.; Popova, O. A.; Khomskii, D. I.
Physical Review Letters, Vol. 96, Issue 24
DOI: 10.1103/PhysRevLett.96.249701

Spectral function for the $S = 1$ Heisenberg antiferromagetic chain
journal, April 2008

White, Steven R.; Affleck, Ian
Physical Review B, Vol. 77, Issue 13
DOI: 10.1103/PhysRevB.77.134437

Orbital Ordering in ${LaMnO}_{3}$ : Electron-Electron versus Electron-Lattice Interactions
journal, March 2006

Yin, Wei-Guo; Volja, Dmitri; Ku, Wei
Physical Review Letters, Vol. 96, Issue 11
DOI: 10.1103/PhysRevLett.96.116405

Mott Insulators in the Strong Spin-Orbit Coupling Limit: From Heisenberg to a Quantum Compass and Kitaev Models
journal, January 2009

Jackeli, G.; Khaliullin, G.
Physical Review Letters, Vol. 102, Issue 1
DOI: 10.1103/PhysRevLett.102.017205

On the origin of biquadratic exchange in spin 1 chains
journal, June 2000

Mila, F.; Zhang, Fu-Chun
The European Physical Journal B, Vol. 16, Issue 1
DOI: 10.1007/s100510070242

Sodium Pyroxene ${N a T i S i}_{2} O_{6}$ : Possible Haldane Spin-1 Chain System
journal, July 2004

Popović, Zoran S.; Šljivančanin, Željko V.; Vukajlović, Filip R.
Physical Review Letters, Vol. 93, Issue 3
DOI: 10.1103/PhysRevLett.93.036401

Orbital-assisted Peierls state in NaTiSi ₂ O ₆
journal, September 2006

Wezel, J. van; Brink, J. van den
Europhysics Letters (EPL), Vol. 75, Issue 6
DOI: 10.1209/epl/i2006-10197-2

Electronic structure calculations of solids using the WIEN2k package for material sciences
journal, August 2002

Schwarz, K.; Blaha, P.; Madsen, G. K. H.
Computer Physics Communications, Vol. 147, Issue 1-2
DOI: 10.1016/S0010-4655(02)00206-0

Orbital dimerization in NaTiSi2O6. An orbital analogue of the spin-Peierls phase transition
journal, May 2004

Konstantinović, M. J.; van den Brink, J.; Popović, Z. V.
Journal of Magnetism and Magnetic Materials, Vol. 272-276
DOI: 10.1016/j.jmmm.2003.11.328

Electronic structure and magnetic properties of pyroxenes (Li,Na)TM(Si,Ge)2O6: novel low-dimensional magnets with 90 bonds
text, January 2007

Streltsov, S. V.; Khomskii, D. I.
arXiv
DOI: 10.48550/arxiv.0710.5351

Spectral Function for the S=1 Heisenberg Antiferromagetic Chain
text, January 2007

White, Steven R.; Affleck, Ian
arXiv
DOI: 10.48550/arxiv.0712.3785

Real time evolution using the density matrix renormalization group
text, January 2004

White, Steven R.; Feiguin, Adrian E.
arXiv
DOI: 10.48550/arxiv.cond-mat/0403310

Similar Records in DOE PAGES and OSTI.GOV collections:

Ultrafast dynamics of spin and orbital correlations in quantum materials: an energy- and momentum-resolved perspective

Journal Article Cao, Y. ; Mazzone, D. G. ; Meyers, D. ; ... - Philosophical Transactions of the Royal Society. A, Mathematical, Physical and Engineering Sciences

Many remarkable properties of quantum materials emerge from states with intricate coupling between the charge, spin and orbital degrees of freedom. Ultrafast photo-excitations of these materials hold great promise for understanding and controlling the properties of these states. Here we introduce time-resolved resonant inelastic X-ray scattering (tr-RIXS) as a means of measuring the charge, spin and orbital excitations out of equilibrium. These excitations encode the correlations and interactions that determine the detailed properties of the states generated. After outlining the basic principles and instrumentation of tr-RIXS, we review our first observations of transient antiferromagnetic correlations in quasi two dimensions inmore »« less
Cited by 3
https://doi.org/10.1098/rsta.2017.0480

Full Text Available
Designing Quantum Spin-Orbital Liquids in Artificial Mott Insulators

Journal Article Dou, Xu ; Kotov, Valeri N. ; Uchoa, Bruno - Scientific Reports

Quantum spin-orbital liquids are elusive strongly correlated states of matter that emerge from quantum frustration between spin and orbital degrees of freedom. A promising route towards the observation of those states is the creation of artificial Mott insulators where antiferromagnetic correlations between spins and orbitals can be designed. We show that Coulomb impurity lattices on the surface of gapped honeycomb substrates, such as graphene on SiC, can be used to simulate SU(4) symmetric spin-orbital lattice models. We exploit the property that massive Dirac fermions form mid-gap bound states with spin and valley degeneracies in the vicinity of a Coulomb impurity.more »« less
https://doi.org/10.1038/srep31737

Full Text Available
Hundness versus Mottness in a three-band Hubbard–Hund model: On the origin of strong correlations in Hund metals☆

Journal Article Stadler, K.M., E-mail: Katharina.M.Stadler@physik.uni-muenchen.de ; Kotliar, G., E-mail: kotliar@physics.rutgers.edu ; Weichselbaum, A., E-mail: weichselbaum@bnl.gov ; ... - Annals of Physics (New York)

Hund metals are multi-orbital systems with moderate Coulomb interaction, U, among charges and sizeable Hund’s rule coupling, J(
https://doi.org/10.1016/J.AOP.2018.10.017
Mott transition controlled by lattice-orbital coupling in $3 d$ -metal-doped double-layer ruthenates

Journal Article Peng, J. ; Gu, M. Q. ; Gu, X. M. ; ... - Physical Review B

We have investigated unusual phase transitions that were triggered by chemical doping in Ca₃Ru₂O₇. Our experiments showed that doping with a few percent of Mn (>4%) can change the quasi-two-dimensional metallic state of Ca₃Ru₂O₇ into a Mott insulating state with a G-type antiferromagnetic order, but this Mott state cannot be induced by Fe doping. By combining these results with first-principles calculations, we show that lattice-orbital coupling (LOC) plays an important role in the Mott transition. Interestingly, the transition temperature T_MIT is found to be predetermined by a structural parameter denoted by c/√ab at temperatures far above Néel temperature T_N. Thismore »« less
Cited by 4
https://doi.org/10.1103/physrevb.96.205105

Full Text Available
Realization of the orbital-selective Mott state at the molecular level in ${Ba}_{3} {LaRu}_{2} O_{9}$

Journal Article Chen, Q. ; Verrier, A. ; Ziat, D. ; ... - Physical Review Materials

Molecular magnets based on heavy transition metals have recently attracted significant interest in the quest for novel magnetic properties. For systems with an odd number of valence electrons per molecule, high or low molecular spin states are typically expected in the double exchange or quasi-molecular orbital limits respectively. In this work, we use bulk characterization, muon spin relaxation, neutron diffraction, and inelastic neutron scattering to identify a rare intermediate spin-3/2 per dimer state in the 6H-perovskite Ba3LaRu2O9 that cannot be understood in a double exchange or quasi-molecular orbital picture and instead arises from orbital-selective Mott insulating behavior at the molecularmore »« less
https://doi.org/10.1103/PhysRevMaterials.4.064409

Full Text Available

Similar Records

Title: Quantum liquid with strong orbital fluctuations: the case of the pyroxene family

Abstract

Citation Formats

Generalized Gradient Approximation Made Simple journal, October 1996

Real-Time Evolution Using the Density Matrix Renormalization Group journal, August 2004

Coexistence of Gapless Excitations and Commensurate Charge-Density Wave in the 2 H Transition Metal Dichalcogenides journal, January 2006

Orbital dimerization in NaTiSi 2 O 6 : An orbital analogue of the spin-Peierls phase transition journal, January 2004

Phase Transitions in Spin-orbital Coupled Model for Pyroxene Titanium Oxides journal, January 2005

Exact Results for a Quantum Many-Body Problem in One Dimension. II journal, March 1972

Electronic structure and magnetic properties of pyroxenes ( Li , Na ) TM ( Si , Ge ) 2 O 6 : Low-dimensional magnets with 90° bonds journal, February 2008

Novel Phase Transition in Spin-1/2 Linear Chain Systems: NaTiSi 2 O 6 and LiTiSi 2 O 6 journal, June 2002

SU ( N ) magnetism in chains of ultracold alkaline-earth-metal atoms: Mott transitions and quantum correlations journal, October 2011

Tuning the in-plane electron behavior in high- T c cuprate superconductors via apical atoms: A first-principles Wannier-states analysis journal, June 2009

Direct measurement of the spin gap in a quasi-one-dimensional clinopyroxene: NaTiSi 2 O 6 journal, October 2014

Insulating Ferromagnetism in L a 4 B a 2 C u 2 O 10 : An Ab Initio Wannier Function Analysis journal, September 2002

Comment on “Sodium Pyroxene NaTiSi 2 O 6 : Possible Haldane Spin-1 Chain System” journal, June 2006

Spectral function for the S = 1 Heisenberg antiferromagetic chain journal, April 2008

Orbital Ordering in LaMnO 3 : Electron-Electron versus Electron-Lattice Interactions journal, March 2006

Mott Insulators in the Strong Spin-Orbit Coupling Limit: From Heisenberg to a Quantum Compass and Kitaev Models journal, January 2009

On the origin of biquadratic exchange in spin 1 chains journal, June 2000

Sodium Pyroxene N a T i S i 2 O 6 : Possible Haldane Spin-1 Chain System journal, July 2004

Orbital-assisted Peierls state in NaTiSi 2 O 6 journal, September 2006

Electronic structure calculations of solids using the WIEN2k package for material sciences journal, August 2002

Orbital dimerization in NaTiSi2O6. An orbital analogue of the spin-Peierls phase transition journal, May 2004

Electronic structure and magnetic properties of pyroxenes (Li,Na)TM(Si,Ge)2O6: novel low-dimensional magnets with 90 bonds text, January 2007

Spectral Function for the S=1 Heisenberg Antiferromagetic Chain text, January 2007

Real time evolution using the density matrix renormalization group text, January 2004

Generalized Gradient Approximation Made Simple
journal, October 1996

Real-Time Evolution Using the Density Matrix Renormalization Group
journal, August 2004

Coexistence of Gapless Excitations and Commensurate Charge-Density Wave in the $2 H$ Transition Metal Dichalcogenides
journal, January 2006

Orbital dimerization in ${NaTiSi}_{2} O_{6} :$ An orbital analogue of the spin-Peierls phase transition
journal, January 2004

Phase Transitions in Spin-orbital Coupled Model for Pyroxene Titanium Oxides
journal, January 2005

Exact Results for a Quantum Many-Body Problem in One Dimension. II
journal, March 1972

Electronic structure and magnetic properties of pyroxenes $(Li, Na) TM {(Si, Ge)}_{2} O_{6}$ : Low-dimensional magnets with 90° bonds
journal, February 2008

Novel Phase Transition in Spin-1/2 Linear Chain Systems: NaTiSi ₂ O ₆ and LiTiSi ₂ O ₆
journal, June 2002

SU $(N)$ magnetism in chains of ultracold alkaline-earth-metal atoms: Mott transitions and quantum correlations
journal, October 2011

Tuning the in-plane electron behavior in high- $T_{c}$ cuprate superconductors via apical atoms: A first-principles Wannier-states analysis
journal, June 2009

Direct measurement of the spin gap in a quasi-one-dimensional clinopyroxene: ${NaTiSi}_{2} O_{6}$
journal, October 2014

Insulating Ferromagnetism in ${L a}_{4} {B a}_{2} {C u}_{2} O_{10}$ : An Ab Initio Wannier Function Analysis
journal, September 2002

Comment on “Sodium Pyroxene ${NaTiSi}_{2} O_{6}$ : Possible Haldane Spin-1 Chain System”
journal, June 2006

Spectral function for the $S = 1$ Heisenberg antiferromagetic chain
journal, April 2008

Orbital Ordering in ${LaMnO}_{3}$ : Electron-Electron versus Electron-Lattice Interactions
journal, March 2006

Mott Insulators in the Strong Spin-Orbit Coupling Limit: From Heisenberg to a Quantum Compass and Kitaev Models
journal, January 2009

On the origin of biquadratic exchange in spin 1 chains
journal, June 2000

Sodium Pyroxene ${N a T i S i}_{2} O_{6}$ : Possible Haldane Spin-1 Chain System
journal, July 2004

Orbital-assisted Peierls state in NaTiSi ₂ O ₆
journal, September 2006

Electronic structure calculations of solids using the WIEN2k package for material sciences
journal, August 2002

Orbital dimerization in NaTiSi2O6. An orbital analogue of the spin-Peierls phase transition
journal, May 2004

Electronic structure and magnetic properties of pyroxenes (Li,Na)TM(Si,Ge)2O6: novel low-dimensional magnets with 90 bonds
text, January 2007

Spectral Function for the S=1 Heisenberg Antiferromagetic Chain
text, January 2007

Real time evolution using the density matrix renormalization group
text, January 2004