Niobium-substituted octahedral molecular sieve (OMS-2) materials in selective oxidation of methanol to dimethoxymethane
Abstract
The prepared bifunctional Nb-OMS-2 catalysts are promising candidate in partial oxidation of methanol into dimethoxymethane at a lower temperature suggesting that there is an important temperature regime when forming active sites for DMM production.
- Authors:
- Department of Chemistry, University of Connecticut, Storrs, USA
- Corporate Strategic Research, ExxonMobil Research and Engineering Company, Annandale, USA
- Institute of Material Science, University of Connecticut, Storrs, USA
- Department of Chemistry, University of Connecticut, Storrs, USA, Institute of Material Science
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1574081
- Grant/Contract Number:
- FG02-86ER13622.A000
- Resource Type:
- Published Article
- Journal Name:
- RSC Advances
- Additional Journal Information:
- Journal Name: RSC Advances Journal Volume: 9 Journal Issue: 56; Journal ID: ISSN 2046-2069
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Wasalathanthri, Niluka D., Guild, Curtis, Nizami, Quddus A., Dissanayake, Shanka L., He, Junkai, Kerns, Peter, Fee, Jared, Achola, Laura, Rathnayake, Dinithi, Weerakkody, Chandima, Suib, Steven L., and Nandi, Partha. Niobium-substituted octahedral molecular sieve (OMS-2) materials in selective oxidation of methanol to dimethoxymethane. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9RA04804A.
Wasalathanthri, Niluka D., Guild, Curtis, Nizami, Quddus A., Dissanayake, Shanka L., He, Junkai, Kerns, Peter, Fee, Jared, Achola, Laura, Rathnayake, Dinithi, Weerakkody, Chandima, Suib, Steven L., & Nandi, Partha. Niobium-substituted octahedral molecular sieve (OMS-2) materials in selective oxidation of methanol to dimethoxymethane. United Kingdom. doi:10.1039/C9RA04804A.
Wasalathanthri, Niluka D., Guild, Curtis, Nizami, Quddus A., Dissanayake, Shanka L., He, Junkai, Kerns, Peter, Fee, Jared, Achola, Laura, Rathnayake, Dinithi, Weerakkody, Chandima, Suib, Steven L., and Nandi, Partha. Mon .
"Niobium-substituted octahedral molecular sieve (OMS-2) materials in selective oxidation of methanol to dimethoxymethane". United Kingdom. doi:10.1039/C9RA04804A.
@article{osti_1574081,
title = {Niobium-substituted octahedral molecular sieve (OMS-2) materials in selective oxidation of methanol to dimethoxymethane},
author = {Wasalathanthri, Niluka D. and Guild, Curtis and Nizami, Quddus A. and Dissanayake, Shanka L. and He, Junkai and Kerns, Peter and Fee, Jared and Achola, Laura and Rathnayake, Dinithi and Weerakkody, Chandima and Suib, Steven L. and Nandi, Partha},
abstractNote = {The prepared bifunctional Nb-OMS-2 catalysts are promising candidate in partial oxidation of methanol into dimethoxymethane at a lower temperature suggesting that there is an important temperature regime when forming active sites for DMM production.},
doi = {10.1039/C9RA04804A},
journal = {RSC Advances},
number = 56,
volume = 9,
place = {United Kingdom},
year = {2019},
month = {10}
}
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9RA04804A
DOI: 10.1039/C9RA04804A
Other availability
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Selective oxidation of methanol to dimethoxymethane under mild conditions over V2O5/TiO2 with enhanced surface acidity
journal, January 2007
- Fu, Yuchuan; Shen, Jianyi
- Chemical Communications, Issue 21
Manganese Oxide-catalyzed Additive- and Solvent-free Aerobic Oxidative Synthesis of Primary Amides from Primary Amines
journal, June 2012
- Yamaguchi, Kazuya; Wang, Ye; Mizuno, Noritaka
- Chemistry Letters, Vol. 41, Issue 6
Structure, stability and photocatalytic H 2 production by Cr-, Mn-, Fe-, Co-, and Ni-substituted decaniobate clusters
journal, January 2014
- Son, Jung-Ho; Wang, Jiarui; Casey, William H.
- Dalton Trans., Vol. 43, Issue 48
Characterization of Manganese Oxide Octahedral Molecular Sieve (M−OMS-2) Materials with Different Metal Cation Dopants
journal, February 2002
- Chen, Xiao; Shen, Yan-Fei; Suib, Steven L.
- Chemistry of Materials, Vol. 14, Issue 2
Selective oxidation of methanol to dimethoxymethane over bifunctional VOx/TS-1 catalysts
journal, January 2011
- Chen, Shuang; Wang, Shengping; Ma, Xinbin
- Chemical Communications, Vol. 47, Issue 33
Manganese Oxide Octahedral Molecular Sieves (OMS-2) Multiple Framework Substitutions: A New Route to OMS-2 Particle Size and Morphology Control
journal, November 2010
- King’ondu, Cecil K.; Opembe, Naftali; Chen, Chun-hu
- Advanced Functional Materials, Vol. 21, Issue 2
Study of the Partial Oxidation of Methanol to Formaldehyde on a Polycrystalline Ag Foil
journal, June 2001
- Beuhler, R. J.; Rao, R. M.; Hrbek, J.
- The Journal of Physical Chemistry B, Vol. 105, Issue 25
Characterization of the Fe-Doped Mixed-Valent Tunnel Structure Manganese Oxide KOMS-2
journal, October 2011
- Shen, Xiongfei; Morey, Aimee M.; Liu, Jia
- The Journal of Physical Chemistry C, Vol. 115, Issue 44
Mesoporous manganese oxides for NO2 assisted catalytic soot oxidation
journal, February 2017
- Wasalathanthri, Niluka D.; SantaMaria, Thomas M.; Kriz, David A.
- Applied Catalysis B: Environmental, Vol. 201
A decatungstate-type polyoxoniobate with centered manganese: [H2MnIVNb10O32]8− as a soluble tetramethylammonium salt
journal, January 2013
- Son, Jung-Ho; Casey, William H.
- Dalton Transactions, Vol. 42, Issue 37
Dimethoxymethane as a Cleaner Synthetic Fuel: Synthetic Methods, Catalysts, and Reaction Mechanism
journal, January 2019
- Sun, Ruiyan; Delidovich, Irina; Palkovits, Regina
- ACS Catalysis, Vol. 9, Issue 2
Mechanistic Aspects of Methanol Partial Oxidation over Supported Iron Oxide Aerogels
journal, September 2001
- Wang, Chien-Tsung; Willey, Ronald J.
- Journal of Catalysis, Vol. 202, Issue 2
Selective Oxidation of Methanol to Dimethoxymethane at Low Temperatures through Size-controlled VTiO x Nanoparticles
journal, April 2017
- Sima, Rui; Liu, Guojuan; Wang, Qiyan
- ChemCatChem, Vol. 9, Issue 10
Enhancement of Catalytic Activities of Octahedral Molecular Sieve Manganese Oxide for Total and Preferential CO Oxidation through Vanadium Ion Framework Substitution
journal, April 2013
- Genuino, Homer C.; Meng, Yongtao; Horvath, Dayton T.
- ChemCatChem, Vol. 5, Issue 8
Selective oxidation of methanol to dimethoxymethane on V2O5–MoO3/γ-Al2O3 catalysts
journal, November 2014
- Meng, Yali; Wang, Tuo; Chen, Shuang
- Applied Catalysis B: Environmental, Vol. 160-161
Direct conversion of methanol into 1,1-dimethoxymethane: remarkably high productivity over an FeMo catalyst placed under unusual conditions
journal, January 2010
- Gornay, Julien; Sécordel, Xavier; Tesquet, Guillaume
- Green Chemistry, Vol. 12, Issue 10
Manganese oxide-catalyzed transformation of primary amines to primary amides through the sequence of oxidative dehydrogenation and successive hydration
journal, January 2012
- Wang, Ye; Kobayashi, Hiroaki; Yamaguchi, Kazuya
- Chemical Communications, Vol. 48, Issue 20
Practical methods for measuring the tortuosity of porous materials from binary or gray-tone tomographic reconstructions
journal, August 2009
- Gommes, Cedric J.; Bons, Anton-Jan; Blacher, Silvia
- AIChE Journal, Vol. 55, Issue 8
Heterogeneously Catalyzed Synthesis of Primary Amides Directly from Primary Alcohols and Aqueous Ammonia
journal, November 2011
- Yamaguchi, Kazuya; Kobayashi, Hiroaki; Oishi, Takamichi
- Angewandte Chemie International Edition, Vol. 51, Issue 2
Aqueous-phase hydrodeoxygenation of sorbitol with Pt/SiO2–Al2O3: Identification of reaction intermediates
journal, March 2010
- Li, Ning; Huber, George W.
- Journal of Catalysis, Vol. 270, Issue 1
Highly productive iron molybdate mixed oxides and their relevant catalytic properties for direct synthesis of 1,1-dimethoxymethane from methanol
journal, February 2014
- Thavornprasert, Kaew-arpha; Capron, Mickaël; Jalowiecki-Duhamel, Louise
- Applied Catalysis B: Environmental, Vol. 145
Potential of oxymethylenether-diesel blends for ultra-low emission engines
journal, December 2017
- Omari, Ahmad; Heuser, Benedikt; Pischinger, Stefan
- Fuel, Vol. 209
Selective One-Step Synthesis of Dimethoxymethane via Methanol or Dimethyl Ether Oxidation on H 3+ n V n Mo 12- n PO 40 Keggin Structures
journal, October 2003
- Liu, Haichao; Iglesia, Enrique
- The Journal of Physical Chemistry B, Vol. 107, Issue 39
Green oxidative synthesis of primary amides from primary alcohols or aldehydes catalyzed by a cryptomelane-type manganese oxide-based octahedral molecular sieve, OMS-2
journal, January 2013
- Yamaguchi, Kazuya; Kobayashi, Hiroaki; Wang, Ye
- Catal. Sci. Technol., Vol. 3, Issue 2
The Role of Additives for Diesel and Diesel Blended (Ethanol or Biodiesel) Fuels: A Review
journal, July 2007
- Ribeiro, Núbia M.; Pinto, Angelo C.; Quintella, Cristina M.
- Energy & Fuels, Vol. 21, Issue 4
Structural Distortion of Molybdenum-Doped Manganese Oxide Octahedral Molecular Sieves for Enhanced Catalytic Performance
journal, October 2015
- Chen, Chun-Hu; Njagi, Eric C.; Chen, Sheng-Yu
- Inorganic Chemistry, Vol. 54, Issue 21
VOx molecular level grafted g-C3N4 for highly selective oxidation of methanol to dimethoxymethane
journal, May 2019
- Ma, Hongrui; Wang, Hongxia; Lu, Bin
- Molecular Catalysis, Vol. 469
Synthesis, Characterization, and Rietveld Refinement of Tungsten-Framework-Doped Porous Manganese Oxide (K-OMS-2) Material
journal, October 2008
- Calvert, Craig; Joesten, Raymond; Ngala, Katana
- Chemistry of Materials, Vol. 20, Issue 20
High-Performance Catalytic CH 4 Oxidation at Low Temperatures: Inverse Micelle Synthesis of Amorphous Mesoporous Manganese Oxides and Mild Transformation to K 2– x Mn 8 O 16 and ϵ-MnO 2
journal, January 2015
- Wasalathanthri, Niluka D.; Poyraz, Altug S.; Biswas, Sourav
- The Journal of Physical Chemistry C, Vol. 119, Issue 3