Thermally Driven Structure and Performance Evolution of Atomically Dispersed FeN 4 Sites for Oxygen Reduction
- Authors:
-
- Department MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage School of Chemistry and Chemical Engineering Harbin Institute of Technology Harbin 150001 China, Department of Chemical and Biological Engineering University at Buffalo The State University of New York Buffalo NY 14260 USA
- Department of Chemical and Biological Engineering University at Buffalo The State University of New York Buffalo NY 14260 USA
- School of Chemical Biological, and Environmental Engineering Oregon State University Corvallis OR 97331 USA
- Department of Mechanical Engineering and Materials Science University of Pittsburgh Pittsburgh PA 15261 USA
- Center for Nanophase Materials Sciences Oak Ridge National Laboratory Oak Ridge TN 37831 USA
- Department of Chemical Engineering University of South Carolina Columbia SC 29208 USA
- Department MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage School of Chemistry and Chemical Engineering Harbin Institute of Technology Harbin 150001 China
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1573874
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 131 Journal Issue: 52; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Li, Jiazhan, Zhang, Hanguang, Samarakoon, Widitha, Shan, Weitao, Cullen, David A., Karakalos, Stavros, Chen, Mengjie, Gu, Daming, More, Karren L., Wang, Guofeng, Feng, Zhenxing, Wang, Zhenbo, and Wu, Gang. Thermally Driven Structure and Performance Evolution of Atomically Dispersed FeN 4 Sites for Oxygen Reduction. Germany: N. p., 2019.
Web. doi:10.1002/ange.201909312.
Li, Jiazhan, Zhang, Hanguang, Samarakoon, Widitha, Shan, Weitao, Cullen, David A., Karakalos, Stavros, Chen, Mengjie, Gu, Daming, More, Karren L., Wang, Guofeng, Feng, Zhenxing, Wang, Zhenbo, & Wu, Gang. Thermally Driven Structure and Performance Evolution of Atomically Dispersed FeN 4 Sites for Oxygen Reduction. Germany. https://doi.org/10.1002/ange.201909312
Li, Jiazhan, Zhang, Hanguang, Samarakoon, Widitha, Shan, Weitao, Cullen, David A., Karakalos, Stavros, Chen, Mengjie, Gu, Daming, More, Karren L., Wang, Guofeng, Feng, Zhenxing, Wang, Zhenbo, and Wu, Gang. Mon .
"Thermally Driven Structure and Performance Evolution of Atomically Dispersed FeN 4 Sites for Oxygen Reduction". Germany. https://doi.org/10.1002/ange.201909312.
@article{osti_1573874,
title = {Thermally Driven Structure and Performance Evolution of Atomically Dispersed FeN 4 Sites for Oxygen Reduction},
author = {Li, Jiazhan and Zhang, Hanguang and Samarakoon, Widitha and Shan, Weitao and Cullen, David A. and Karakalos, Stavros and Chen, Mengjie and Gu, Daming and More, Karren L. and Wang, Guofeng and Feng, Zhenxing and Wang, Zhenbo and Wu, Gang},
abstractNote = {},
doi = {10.1002/ange.201909312},
journal = {Angewandte Chemie},
number = 52,
volume = 131,
place = {Germany},
year = {2019},
month = {11}
}
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Works referenced in this record:
Heat-treated polyacrylonitrile-based catalysts for oxygen electroreduction
journal, January 1989
- Gupta, S.; Tryk, D.; Bae, I.
- Journal of Applied Electrochemistry, Vol. 19, Issue 1, p. 19-27
Stability of Fe-N-C Catalysts in Acidic Medium Studied by Operando Spectroscopy
journal, August 2015
- Choi, Chang Hyuck; Baldizzone, Claudio; Grote, Jan-Philipp
- Angewandte Chemie, Vol. 127, Issue 43
Degradation of Fe/N/C catalysts upon high polarization in acid medium
journal, January 2014
- Goellner, Vincent; Baldizzone, Claudio; Schuppert, Anna
- Phys. Chem. Chem. Phys., Vol. 16, Issue 34
Negative Thermal Expansion Coefficient of Graphene Measured by Raman Spectroscopy
journal, August 2011
- Yoon, Duhee; Son, Young-Woo; Cheong, Hyeonsik
- Nano Letters, Vol. 11, Issue 8
Controlled ripple texturing of suspended graphene and ultrathin graphite membranes
journal, July 2009
- Bao, Wenzhong; Miao, Feng; Chen, Zhen
- Nature Nanotechnology, Vol. 4, Issue 9
Minimizing Operando Demetallation of Fe-N-C Electrocatalysts in Acidic Medium
journal, April 2016
- Choi, Chang Hyuck; Baldizzone, Claudio; Polymeros, George
- ACS Catalysis, Vol. 6, Issue 5
Multitechnique Characterization of a Polyaniline–Iron–Carbon Oxygen Reduction Catalyst
journal, July 2012
- Ferrandon, Magali; Kropf, A. Jeremy; Myers, Deborah J.
- The Journal of Physical Chemistry C, Vol. 116, Issue 30
PGM‐Free Cathode Catalysts for PEM Fuel Cells: A Mini‐Review on Stability Challenges
journal, December 2018
- Shao, Yuyan; Dodelet, Jean‐Pol; Wu, Gang
- Advanced Materials, Vol. 31, Issue 31
Carbon nanocomposite catalysts for oxygen reduction and evolution reactions: From nitrogen doping to transition-metal addition
journal, November 2016
- Wu, Gang; Santandreu, Ana; Kellogg, William
- Nano Energy, Vol. 29
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction
journal, April 2017
- Chen, Yuanjun; Ji, Shufang; Wang, Yanggang
- Angewandte Chemie International Edition, Vol. 56, Issue 24
Mn- and N- doped carbon as promising catalysts for oxygen reduction reaction: Theoretical prediction and experimental validation
journal, April 2019
- Liu, Kexi; Qiao, Zhi; Hwang, Sooyeon
- Applied Catalysis B: Environmental, Vol. 243
On the Role of Metals in Nitrogen-Doped Carbon Electrocatalysts for Oxygen Reduction
journal, July 2015
- Masa, Justus; Xia, Wei; Muhler, Martin
- Angewandte Chemie International Edition, Vol. 54, Issue 35
Fe-N-C Oxygen Reduction Fuel Cell Catalyst Derived from Carbendazim: Synthesis, Structure, and Reactivity
journal, March 2014
- Serov, Alexey; Artyushkova, Kateryna; Atanassov, Plamen
- Advanced Energy Materials, Vol. 4, Issue 10
Platinum group metal-free catalysts boost cost competitiveness of fuel cell vehicles
journal, July 2019
- Thompson, Simon T.; Papageorgopoulos, Dimitrios
- Nature Catalysis, Vol. 2, Issue 7
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt
journal, April 2011
- Wu, G.; More, K. L.; Johnston, C. M.
- Science, Vol. 332, Issue 6028, p. 443-447
Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction
journal, January 2018
- Weng, Zhe; Wu, Yueshen; Wang, Maoyu
- Nature Communications, Vol. 9, Issue 1
Understanding the High Activity of Fe–N–C Electrocatalysts in Oxygen Reduction: Fe/Fe 3 C Nanoparticles Boost the Activity of Fe–N x
journal, March 2016
- Jiang, Wen-Jie; Gu, Lin; Li, Li
- Journal of the American Chemical Society, Vol. 138, Issue 10
Surface functionalization of ZIF-8 with ammonium ferric citrate toward high exposure of Fe-N active sites for efficient oxygen and carbon dioxide electroreduction
journal, August 2017
- Ye, Yifan; Cai, Fan; Li, Haobo
- Nano Energy, Vol. 38
Atomically dispersed manganese catalysts for oxygen reduction in proton-exchange membrane fuel cells
journal, October 2018
- Li, Jiazhan; Chen, Mengjie; Cullen, David A.
- Nature Catalysis, Vol. 1, Issue 12
Fe–N–C electrocatalyst with dense active sites and efficient mass transport for high-performance proton exchange membrane fuel cells
journal, March 2019
- Wan, Xin; Liu, Xiaofang; Li, Yongcheng
- Nature Catalysis, Vol. 2, Issue 3
Synthesis of nitrogen-doped onion-like carbon and its use in carbon-based CoFe binary non-precious-metal catalysts for oxygen-reduction
journal, October 2011
- Wu, Gang; Nelson, Mark; Ma, Shuguo
- Carbon, Vol. 49, Issue 12
3D polymer hydrogel for high-performance atomic iron-rich catalysts for oxygen reduction in acidic media
journal, December 2017
- Qiao, Zhi; Zhang, Hanguang; Karakalos, Stavros
- Applied Catalysis B: Environmental, Vol. 219
Synthesis of highly-active Fe–N–C catalysts for PEMFC with carbide-derived carbons
journal, January 2018
- Ratso, Sander; Ranjbar Sahraie, Nastaran; Sougrati, Moulay Tahar
- Journal of Materials Chemistry A, Vol. 6, Issue 30
Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts
journal, April 2010
- Strasser, Peter; Koh, Shirlaine; Anniyev, Toyli
- Nature Chemistry, Vol. 2, Issue 6
FeN 4 Sites Embedded into Carbon Nanofiber Integrated with Electrochemically Exfoliated Graphene for Oxygen Evolution in Acidic Medium
journal, August 2018
- Lei, Chaojun; Chen, Hengquan; Cao, Junhui
- Advanced Energy Materials, Vol. 8, Issue 26
High performance platinum single atom electrocatalyst for oxygen reduction reaction
journal, July 2017
- Liu, Jing; Jiao, Menggai; Lu, Lanlu
- Nature Communications, Vol. 8, Issue 1
High-performance fuel cell cathodes exclusively containing atomically dispersed iron active sites
journal, January 2019
- Zhang, Hanguang; Chung, Hoon T.; Cullen, David A.
- Energy & Environmental Science, Vol. 12, Issue 8
Analyzing Structural Changes of Fe–N–C Cathode Catalysts in PEM Fuel Cell by Mößbauer Spectroscopy of Complete Membrane Electrode Assemblies
journal, October 2014
- Kramm, Ulrike I.; Lefèvre, Michel; Bogdanoff, Peter
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 21
Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials
journal, August 2015
- Zitolo, Andrea; Goellner, Vincent; Armel, Vanessa
- Nature Materials, Vol. 14, Issue 9
Achievements, challenges and perspectives on cathode catalysts in proton exchange membrane fuel cells for transportation
journal, July 2019
- Wang, Xiao Xia; Swihart, Mark T.; Wu, Gang
- Nature Catalysis, Vol. 2, Issue 7
Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis
journal, December 2016
- Bu, Lingzheng; Zhang, Nan; Guo, Shaojun
- Science, Vol. 354, Issue 6318
Single Atomic Iron Catalysts for Oxygen Reduction in Acidic Media: Particle Size Control and Thermal Activation
journal, September 2017
- Zhang, Hanguang; Hwang, Sooyeon; Wang, Maoyu
- Journal of the American Chemical Society, Vol. 139, Issue 40
First-principles determination of the structural, vibrational and thermodynamic properties of diamond, graphite, and derivatives
journal, May 2005
- Mounet, Nicolas; Marzari, Nicola
- Physical Review B, Vol. 71, Issue 20
Thermal Expansion of Supported and Freestanding Graphene: Lattice Constant versus Interatomic Distance
journal, March 2011
- Pozzo, Monica; Alfè, Dario; Lacovig, Paolo
- Physical Review Letters, Vol. 106, Issue 13
Role of Local Carbon Structure Surrounding FeN 4 Sites in Boosting the Catalytic Activity for Oxygen Reduction
journal, May 2017
- Liu, Kexi; Wu, Gang; Wang, Guofeng
- The Journal of Physical Chemistry C, Vol. 121, Issue 21
Atomic-scale cation dynamics in a monolayer VO X /α-Fe 2 O 3 catalyst
journal, January 2015
- Feng, Z.; Ma, Q.; Lu, J.
- RSC Advances, Vol. 5, Issue 126
Unravelling the electrochemical mechanisms for nitrogen fixation on single transition metal atoms embedded in defective graphitic carbon nitride
journal, January 2018
- Chen, Xingzhu; Zhao, Xiujian; Kong, Zhouzhou
- Journal of Materials Chemistry A, Vol. 6, Issue 44
Facile Metal Coordination of Active Site Imprinted Nitrogen Doped Carbons for the Conservative Preparation of Non-Noble Metal Oxygen Reduction Electrocatalysts
journal, December 2017
- Mehmood, Asad; Pampel, Jonas; Ali, Ghulam
- Advanced Energy Materials, Vol. 8, Issue 9
Highly active atomically dispersed CoN 4 fuel cell cathode catalysts derived from surfactant-assisted MOFs: carbon-shell confinement strategy
journal, January 2019
- He, Yanghua; Hwang, Sooyeon; Cullen, David A.
- Energy & Environmental Science, Vol. 12, Issue 1
In Situ X-ray Absorption Spectroscopy Studies of Nanoscale Electrocatalysts
journal, June 2019
- Wang, Maoyu; Árnadóttir, Líney; Xu, Zhichuan J.
- Nano-Micro Letters, Vol. 11, Issue 1
Reaction Pathway for Oxygen Reduction on FeN 4 Embedded Graphene
journal, January 2014
- Kattel, Shyam; Wang, Guofeng
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 3
Nanostructured Nonprecious Metal Catalysts for Oxygen Reduction Reaction
journal, April 2013
- Wu, Gang; Zelenay, Piotr
- Accounts of Chemical Research, Vol. 46, Issue 8
Metal-Nitrogen-Carbon Catalysts for Oxygen Reduction in PEM Fuel Cells: Self-Template Synthesis Approach to Enhancing Catalytic Activity and Stability
journal, March 2019
- He, Yanghua; Tan, Qiang; Lu, Leilei
- Electrochemical Energy Reviews, Vol. 2, Issue 2
Stability of Fe-N-C Catalysts in Acidic Medium Studied by Operando Spectroscopy
journal, August 2015
- Choi, Chang Hyuck; Baldizzone, Claudio; Grote, Jan-Philipp
- Angewandte Chemie International Edition, Vol. 54, Issue 43
Atomically Dispersed Iron Cathode Catalysts Derived from Binary Ligand-Based Zeolitic Imidazolate Frameworks with Enhanced Stability for PEM Fuel Cells
journal, January 2019
- Zhang, Hanguang; Ding, Shuo; Hwang, Sooyeon
- Journal of The Electrochemical Society, Vol. 166, Issue 7
Boosting Oxygen Reduction Catalysis with Fe–N 4 Sites Decorated Porous Carbons toward Fuel Cells
journal, January 2019
- Yang, Zhengkun; Wang, Yu; Zhu, Mengzhao
- ACS Catalysis, Vol. 9, Issue 3
Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells
journal, January 2018
- Wang, Xiao Xia; Cullen, David A.; Pan, Yung-Tin
- Advanced Materials, Vol. 30, Issue 11
A specific demetalation of Fe–N 4 catalytic sites in the micropores of NC_Ar + NH 3 is at the origin of the initial activity loss of the highly active Fe/N/C catalyst used for the reduction of oxygen in PEM fuel cells
journal, January 2018
- Chenitz, Régis; Kramm, Ulrike I.; Lefèvre, Michel
- Energy & Environmental Science, Vol. 11, Issue 2
Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells
journal, April 2009
- Lefèvre, Michel; Proietti, Eric; Jaouen, Frédéric
- Science, Vol. 324, Issue 5923, p. 71-74
Development of high performance carbon composite catalyst for oxygen reduction reaction in PEM Proton Exchange Membrane fuel cells
journal, August 2008
- Nallathambi, Vijayadurga; Lee, Jong-Won; Kumaraguru, Swaminatha P.
- Journal of Power Sources, Vol. 183, Issue 1, p. 34-42
g-C 3 N 4 promoted MOF derived hollow carbon nanopolyhedra doped with high density/fraction of single Fe atoms as an ultra-high performance non-precious catalyst towards acidic ORR and PEM fuel cells
journal, January 2019
- Deng, Yijie; Chi, Bin; Tian, Xinlong
- Journal of Materials Chemistry A, Vol. 7, Issue 9
Engineering nanostructures of PGM-free oxygen-reduction catalysts using metal-organic frameworks
journal, January 2017
- Zhang, Hanguang; Osgood, Hannah; Xie, Xiaohong
- Nano Energy, Vol. 31
Directly converting Fe-doped metal–organic frameworks into highly active and stable Fe-N-C catalysts for oxygen reduction in acid
journal, July 2016
- Wang, Xiaojuan; Zhang, Hanguang; Lin, Honghong
- Nano Energy, Vol. 25
Über die Rolle von Metallen in Elektrokatalysatoren auf Basis von stickstoffdotiertem Kohlenstoff für die Sauerstoffreduktion
journal, July 2015
- Masa, Justus; Xia, Wei; Muhler, Martin
- Angewandte Chemie, Vol. 127, Issue 35
A Combined Probe-Molecule, Mössbauer, Nuclear Resonance Vibrational Spectroscopy, and Density Functional Theory Approach for Evaluation of Potential Iron Active Sites in an Oxygen Reduction Reaction Catalyst
journal, July 2017
- Kneebone, Jared L.; Daifuku, Stephanie L.; Kehl, Jeffrey A.
- The Journal of Physical Chemistry C, Vol. 121, Issue 30
Iron‐Free Cathode Catalysts for Proton‐Exchange‐Membrane Fuel Cells: Cobalt Catalysts and the Peroxide Mitigation Approach
journal, December 2018
- Wang, Xiao Xia; Prabhakaran, Venkateshkumar; He, Yanghua
- Advanced Materials, Vol. 31, Issue 31