In-Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO 2 Reduction to Ethylene

doi:10.1002/anie.201907935

This content will become publicly available on October 7, 2020

Title: In-Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO ₂ Reduction to Ethylene

Authors:

^[1];

^[1]

Joint Center for Artificial Photosynthesis and Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125 USA

Publication Date:: 2019-10-08

Sponsoring Org.:: USDOE

OSTI Identifier:: 1573870

Grant/Contract Number:: SC0004993; H2020-MSCA-IF-2017 (793471)

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Angewandte Chemie (International Edition)

Additional Journal Information:: Journal Name: Angewandte Chemie (International Edition) Journal Volume: 58 Journal Issue: 47; Journal ID: ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Thevenon, Arnaud, Rosas-Hernández, Alonso, Peters, Jonas C., and Agapie, Theodor. In-Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO 2 Reduction to Ethylene.  Germany: N. p., 2019. 
        Web.  doi:10.1002/anie.201907935.

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                    Thevenon, Arnaud, Rosas-Hernández, Alonso, Peters, Jonas C., & Agapie, Theodor. In-Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO 2 Reduction to Ethylene.  Germany.  doi:10.1002/anie.201907935.

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                    Thevenon, Arnaud, Rosas-Hernández, Alonso, Peters, Jonas C., and Agapie, Theodor. Tue .  
        "In-Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO 2 Reduction to Ethylene".  Germany.  doi:10.1002/anie.201907935.

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@article{osti_1573870,

  title        = {In-Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO 2 Reduction to Ethylene},

  author       = {Thevenon, Arnaud and Rosas-Hernández, Alonso and Peters, Jonas C. and Agapie, Theodor},

  abstractNote = {},

  doi          = {10.1002/anie.201907935},

  journal      = {Angewandte Chemie (International Edition)},

  number       = 47,

  volume       = 58,

  place        = {Germany},

  year         = {2019},

  month        = {10}

}

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This content will become publicly available on October 7, 2020

Title: In-Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO 2 Reduction to Ethylene

Citation Formats

CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films journal, April 2012

Mesostructure-Induced Selectivity in CO 2 Reduction Catalysis journal, November 2015

Chelating N-Heterocyclic Carbene Ligands Enable Tuning of Electrocatalytic CO 2 Reduction to Formate and Carbon Monoxide: Surface Organometallic Chemistry journal, March 2018

Nanostrukturierte Materialien für die elektrokatalytische CO 2 -Reduktion und ihre Reaktionsmechanismen journal, July 2017

Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO 2 over Cu Nanowire Arrays journal, April 2016

X-ray Photoelectron Spectroscopy of Pyridinium-Based Ionic Liquids: Comparison to Imidazolium- and Pyrrolidinium-Based Analogues journal, May 2015

Electrochemical CO2 Reduction on Metal Electrodes book, January 2008

Selective Electroreduction of CO 2 toward Ethylene on Nano Dendritic Copper Catalysts at High Current Density journal, January 2017

Eine Brücke zwischen industriellen und wohldefinierten Trägerkatalysatoren journal, March 2018

Insight into Electrochemical CO 2 Reduction on Surface-Molecule-Mediated Ag Nanoparticles journal, December 2016

Dynamic Changes in the Structure, Chemical State and Catalytic Selectivity of Cu Nanocubes during CO 2 Electroreduction: Size and Support Effects journal, April 2018

Prism-Shaped Cu Nanocatalysts for Electrochemical CO 2 Reduction to Ethylene journal, December 2017

Engineering Cu surfaces for the electrocatalytic conversion of CO 2 : Controlling selectivity toward oxygenates and hydrocarbons journal, May 2017

Using a Two-Step Hydride Transfer To Achieve 1,4-Reduction in the Catalytic Hydrogenation of an Acyl Pyridinium Cation journal, December 2008

Nanoscale corrosion behavior of polycrystalline copper fine wires in dilute NaCl solution investigated by in-situ atomic force microscopy journal, April 2016

CO 2 Reduction Selective for C ≥2 Products on Polycrystalline Copper with N-Substituted Pyridinium Additives journal, July 2017

Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO 2 over Cu Nanowire Arrays journal, April 2016

Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts journal, March 2016

Homogene und heterogene Katalyse – Brückenschlag durch Oberflächen-Organometallchemie journal, January 2003

Copper nanoparticle ensembles for selective electroreduction of CO 2 to C 2 –C 3 products journal, September 2017

Homogeneous and Heterogeneous Catalysis: Bridging the Gap through Surface Organometallic Chemistry journal, January 2003

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Nanostructured electrocatalysts with tunable activity and selectivity journal, March 2016

Dynamic Changes in the Structure, Chemical State and Catalytic Selectivity of Cu Nanocubes during CO 2 Electroreduction: Size and Support Effects journal, April 2018

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Chelating N-Heterocyclic Carbene Ligands Enable Tuning of Electrocatalytic CO 2 Reduction to Formate and Carbon Monoxide: Surface Organometallic Chemistry journal, March 2018

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Title: In-Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO ₂ Reduction to Ethylene

CO₂ Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu₂O Films
journal, April 2012

Mesostructure-Induced Selectivity in CO ₂ Reduction Catalysis
journal, November 2015

Chelating N-Heterocyclic Carbene Ligands Enable Tuning of Electrocatalytic CO ₂ Reduction to Formate and Carbon Monoxide: Surface Organometallic Chemistry
journal, March 2018

Nanostrukturierte Materialien für die elektrokatalytische CO ₂ -Reduktion und ihre Reaktionsmechanismen
journal, July 2017

Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO ₂ over Cu Nanowire Arrays
journal, April 2016

X-ray Photoelectron Spectroscopy of Pyridinium-Based Ionic Liquids: Comparison to Imidazolium- and Pyrrolidinium-Based Analogues
journal, May 2015

Electrochemical CO₂ Reduction on Metal Electrodes
book, January 2008

Selective Electroreduction of CO ₂ toward Ethylene on Nano Dendritic Copper Catalysts at High Current Density
journal, January 2017

Eine Brücke zwischen industriellen und wohldefinierten Trägerkatalysatoren
journal, March 2018

Insight into Electrochemical CO ₂ Reduction on Surface-Molecule-Mediated Ag Nanoparticles
journal, December 2016

Dynamic Changes in the Structure, Chemical State and Catalytic Selectivity of Cu Nanocubes during CO ₂ Electroreduction: Size and Support Effects
journal, April 2018

Prism-Shaped Cu Nanocatalysts for Electrochemical CO ₂ Reduction to Ethylene
journal, December 2017

Engineering Cu surfaces for the electrocatalytic conversion of CO ₂ : Controlling selectivity toward oxygenates and hydrocarbons
journal, May 2017

Using a Two-Step Hydride Transfer To Achieve 1,4-Reduction in the Catalytic Hydrogenation of an Acyl Pyridinium Cation
journal, December 2008

Nanoscale corrosion behavior of polycrystalline copper fine wires in dilute NaCl solution investigated by in-situ atomic force microscopy
journal, April 2016

CO ₂ Reduction Selective for C _≥2 Products on Polycrystalline Copper with N-Substituted Pyridinium Additives
journal, July 2017

Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO ₂ over Cu Nanowire Arrays
journal, April 2016

Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts
journal, March 2016

Homogene und heterogene Katalyse – Brückenschlag durch Oberflächen-Organometallchemie
journal, January 2003

Copper nanoparticle ensembles for selective electroreduction of CO ₂ to C ₂ –C ₃ products
journal, September 2017

Homogeneous and Heterogeneous Catalysis: Bridging the Gap through Surface Organometallic Chemistry
journal, January 2003

Nitrogen-containing polymers as a platform for CO2 electroreduction
journal, June 2017

Bridging the Gap between Industrial and Well-Defined Supported Catalysts
journal, March 2018

Improved CO ₂ Electroreduction Performance on Plasma-Activated Cu Catalysts via Electrolyte Design: Halide Effect
journal, July 2017

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015

Bridging homogeneous and heterogeneous catalysis by heterogeneous single-metal-site catalysts
journal, June 2018

Electrochemical specific adsorption of halides on Cu 111 , 100 , and 211 : A Density Functional Theory study
journal, August 2015

Nanostructured electrocatalysts with tunable activity and selectivity
journal, March 2016

Dynamic Changes in the Structure, Chemical State and Catalytic Selectivity of Cu Nanocubes during CO ₂ Electroreduction: Size and Support Effects
journal, April 2018

Effects of temperature and gas–liquid mass transfer on the operation of small electrochemical cells for the quantitative evaluation of CO ₂ reduction electrocatalysts
journal, January 2016

Structure- and Electrolyte-Sensitivity in CO ₂ Electroreduction
journal, October 2018

Plasma-Activated Copper Nanocube Catalysts for Efficient Carbon Dioxide Electroreduction to Hydrocarbons and Alcohols
journal, April 2017

Ionic Liquid-Mediated Selective Conversion of CO₂ to CO at Low Overpotentials
journal, September 2011

Catalyst electro-redeposition controls morphology and oxidation state for selective carbon dioxide reduction
journal, January 2018

Nanostructured Materials for Heterogeneous Electrocatalytic CO ₂ Reduction and their Related Reaction Mechanisms
journal, July 2017

Evaluation of the Impact of Surface Reconstruction on Rough Electrodeposited Copper-Based Catalysts for Carbon Dioxide Electroreduction
journal, December 2016

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015

Structure-Sensitive CO ₂ Electroreduction to Hydrocarbons on Ultrathin 5-fold Twinned Copper Nanowires
journal, January 2017

Chelating N-Heterocyclic Carbene Ligands Enable Tuning of Electrocatalytic CO ₂ Reduction to Formate and Carbon Monoxide: Surface Organometallic Chemistry
journal, March 2018

New Insights Into the Role of Imidazolium-Based Promoters for the Electroreduction of CO ₂ on a Silver Electrode
journal, June 2016

Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
journal, June 2016

Impurity Ion Complexation Enhances Carbon Dioxide Reduction Catalysis
journal, June 2015

Microporous carbonaceous adsorbents for CO ₂ separation via selective adsorption
journal, January 2015

Supramolecular Porphyrin Cages Assembled at Molecular–Materials Interfaces for Electrocatalytic CO Reduction
journal, September 2017

CO ₂ Electroreduction with Enhanced Ethylene and Ethanol Selectivity by Nanostructuring Polycrystalline Copper
journal, April 2016

High-Density Nanosharp Microstructures Enable Efficient CO ₂ Electroreduction
journal, October 2016

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012

Achieving Selective and Efficient Electrocatalytic Activity for CO ₂ Reduction Using Immobilized Silver Nanoparticles
journal, October 2015

Tuning the Catalytic Activity and Selectivity of Cu for CO ₂ Electroreduction in the Presence of Halides
journal, February 2016