In‐Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO 2 Reduction to Ethylene
- Authors:
-
[1];
[1];
[1];
[1]
- Joint Center for Artificial Photosynthesis and Division of Chemistry and Chemical EngineeringCalifornia Institute of Technology Pasadena, California 91125 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1573863
- Grant/Contract Number:
- SC0004993
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 131 Journal Issue: 47; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Thevenon, Arnaud, Rosas‐Hernández, Alonso, Peters, Jonas C., and Agapie, Theodor. In‐Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO 2 Reduction to Ethylene. Germany: N. p., 2019.
Web. doi:10.1002/ange.201907935.
Thevenon, Arnaud, Rosas‐Hernández, Alonso, Peters, Jonas C., & Agapie, Theodor. In‐Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO 2 Reduction to Ethylene. Germany. doi:10.1002/ange.201907935.
Thevenon, Arnaud, Rosas‐Hernández, Alonso, Peters, Jonas C., and Agapie, Theodor. Mon .
"In‐Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO 2 Reduction to Ethylene". Germany. doi:10.1002/ange.201907935.
@article{osti_1573863,
title = {In‐Situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO 2 Reduction to Ethylene},
author = {Thevenon, Arnaud and Rosas‐Hernández, Alonso and Peters, Jonas C. and Agapie, Theodor},
abstractNote = {},
doi = {10.1002/ange.201907935},
journal = {Angewandte Chemie},
number = 47,
volume = 131,
place = {Germany},
year = {2019},
month = {11}
}
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DOI: 10.1002/ange.201907935
DOI: 10.1002/ange.201907935
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Works referenced in this record:
CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films
journal, April 2012
- Li, Christina W.; Kanan, Matthew W.
- Journal of the American Chemical Society, Vol. 134, Issue 17, p. 7231-7234
Mesostructure-Induced Selectivity in CO 2 Reduction Catalysis
journal, November 2015
- Hall, Anthony Shoji; Yoon, Youngmin; Wuttig, Anna
- Journal of the American Chemical Society, Vol. 137, Issue 47
Chelating N-Heterocyclic Carbene Ligands Enable Tuning of Electrocatalytic CO 2 Reduction to Formate and Carbon Monoxide: Surface Organometallic Chemistry
journal, March 2018
- Cao, Zhi; Derrick, Jeffrey S.; Xu, Jun
- Angewandte Chemie, Vol. 130, Issue 18
Nanostrukturierte Materialien für die elektrokatalytische CO 2 -Reduktion und ihre Reaktionsmechanismen
journal, July 2017
- Zhang, Lei; Zhao, Zhi-Jian; Gong, Jinlong
- Angewandte Chemie, Vol. 129, Issue 38
Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO 2 over Cu Nanowire Arrays
journal, April 2016
- Ma, Ming; Djanashvili, Kristina; Smith, Wilson A.
- Angewandte Chemie, Vol. 128, Issue 23
X-ray Photoelectron Spectroscopy of Pyridinium-Based Ionic Liquids: Comparison to Imidazolium- and Pyrrolidinium-Based Analogues
journal, May 2015
- Men, Shuang; Mitchell, Daniel S.; Lovelock, Kevin R. J.
- ChemPhysChem, Vol. 16, Issue 10
Electrochemical CO2 Reduction on Metal Electrodes
book, January 2008
- Hori, Y.; Vayenas, Constantinos G.; White, Ralph E.
- Modern Aspects of Electrochemistry, p. 89-189
Selective Electroreduction of CO 2 toward Ethylene on Nano Dendritic Copper Catalysts at High Current Density
journal, January 2017
- Reller, Christian; Krause, Ralf; Volkova, Elena
- Advanced Energy Materials, Vol. 7, Issue 12
Eine Brücke zwischen industriellen und wohldefinierten Trägerkatalysatoren
journal, March 2018
- Copéret, Christophe; Allouche, Florian; Chan, Ka Wing
- Angewandte Chemie, Vol. 130, Issue 22
Insight into Electrochemical CO 2 Reduction on Surface-Molecule-Mediated Ag Nanoparticles
journal, December 2016
- Kim, Cheonghee; Eom, Taedaehyeong; Jee, Michael Shincheon
- ACS Catalysis, Vol. 7, Issue 1
Dynamic Changes in the Structure, Chemical State and Catalytic Selectivity of Cu Nanocubes during CO 2 Electroreduction: Size and Support Effects
journal, April 2018
- Grosse, Philipp; Gao, Dunfeng; Scholten, Fabian
- Angewandte Chemie International Edition, Vol. 57, Issue 21
Prism-Shaped Cu Nanocatalysts for Electrochemical CO 2 Reduction to Ethylene
journal, December 2017
- Jeon, Hyo Sang; Kunze, Sebastian; Scholten, Fabian
- ACS Catalysis, Vol. 8, Issue 1
Engineering Cu surfaces for the electrocatalytic conversion of CO 2 : Controlling selectivity toward oxygenates and hydrocarbons
journal, May 2017
- Hahn, Christopher; Hatsukade, Toru; Kim, Youn-Geun
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 23
Using a Two-Step Hydride Transfer To Achieve 1,4-Reduction in the Catalytic Hydrogenation of an Acyl Pyridinium Cation
journal, December 2008
- Shaw, Anthony P.; Ryland, Bradford L.; Franklin, Mary J.
- The Journal of Organic Chemistry, Vol. 73, Issue 24
Nanoscale corrosion behavior of polycrystalline copper fine wires in dilute NaCl solution investigated by in-situ atomic force microscopy
journal, April 2016
- Ogata, Shoichiro; Kobayashi, Naritaka; Kitagawa, Takuya
- Corrosion Science, Vol. 105
CO 2 Reduction Selective for C ≥2 Products on Polycrystalline Copper with N-Substituted Pyridinium Additives
journal, July 2017
- Han, Zhiji; Kortlever, Ruud; Chen, Hsiang-Yun
- ACS Central Science, Vol. 3, Issue 8
Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO 2 over Cu Nanowire Arrays
journal, April 2016
- Ma, Ming; Djanashvili, Kristina; Smith, Wilson A.
- Angewandte Chemie International Edition, Vol. 55, Issue 23
Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts
journal, March 2016
- Pelletier, Jérémie D. A.; Basset, Jean-Marie
- Accounts of Chemical Research, Vol. 49, Issue 4
Homogene und heterogene Katalyse – Brückenschlag durch Oberflächen-Organometallchemie
journal, January 2003
- Copéret, Christophe; Chabanas, Mathieu; Petroff Saint-Arroman, Romain
- Angewandte Chemie, Vol. 115, Issue 2
Copper nanoparticle ensembles for selective electroreduction of CO 2 to C 2 –C 3 products
journal, September 2017
- Kim, Dohyung; Kley, Christopher S.; Li, Yifan
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 40
Homogeneous and Heterogeneous Catalysis: Bridging the Gap through Surface Organometallic Chemistry
journal, January 2003
- Copéret, Christophe; Chabanas, Mathieu; Petroff Saint-Arroman, Romain
- Angewandte Chemie International Edition, Vol. 42, Issue 2, p. 156-181
Nitrogen-containing polymers as a platform for CO2 electroreduction
journal, June 2017
- Ponnurangam, Sathish; Chernyshova, Irina V.; Somasundaran, Ponisseril
- Advances in Colloid and Interface Science, Vol. 244
Bridging the Gap between Industrial and Well-Defined Supported Catalysts
journal, March 2018
- Copéret, Christophe; Allouche, Florian; Chan, Ka Wing
- Angewandte Chemie International Edition, Vol. 57, Issue 22
Improved CO 2 Electroreduction Performance on Plasma-Activated Cu Catalysts via Electrolyte Design: Halide Effect
journal, July 2017
- Gao, Dunfeng; Scholten, Fabian; Roldan Cuenya, Beatriz
- ACS Catalysis, Vol. 7, Issue 8
High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015
- Roberts, F. Sloan; Kuhl, Kendra P.; Nilsson, Anders
- Angewandte Chemie International Edition, Vol. 54, Issue 17
Bridging homogeneous and heterogeneous catalysis by heterogeneous single-metal-site catalysts
journal, June 2018
- Cui, Xinjiang; Li, Wu; Ryabchuk, Pavel
- Nature Catalysis, Vol. 1, Issue 6
Electrochemical specific adsorption of halides on Cu 111 , 100 , and 211 : A Density Functional Theory study
journal, August 2015
- McCrum, Ian T.; Akhade, Sneha A.; Janik, Michael J.
- Electrochimica Acta, Vol. 173
Nanostructured electrocatalysts with tunable activity and selectivity
journal, March 2016
- Mistry, Hemma; Varela, Ana Sofia; Kühl, Stefanie
- Nature Reviews Materials, Vol. 1, Issue 4
Dynamic Changes in the Structure, Chemical State and Catalytic Selectivity of Cu Nanocubes during CO 2 Electroreduction: Size and Support Effects
journal, April 2018
- Grosse, Philipp; Gao, Dunfeng; Scholten, Fabian
- Angewandte Chemie, Vol. 130, Issue 21
Effects of temperature and gas–liquid mass transfer on the operation of small electrochemical cells for the quantitative evaluation of CO 2 reduction electrocatalysts
journal, January 2016
- Lobaccaro, Peter; Singh, Meenesh R.; Clark, Ezra Lee
- Physical Chemistry Chemical Physics, Vol. 18, Issue 38
Structure- and Electrolyte-Sensitivity in CO 2 Electroreduction
journal, October 2018
- Arán-Ais, Rosa M.; Gao, Dunfeng; Roldan Cuenya, Beatriz
- Accounts of Chemical Research, Vol. 51, Issue 11
Plasma-Activated Copper Nanocube Catalysts for Efficient Carbon Dioxide Electroreduction to Hydrocarbons and Alcohols
journal, April 2017
- Gao, Dunfeng; Zegkinoglou, Ioannis; Divins, Nuria J.
- ACS Nano, Vol. 11, Issue 5
Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials
journal, September 2011
- Rosen, B. A.; Salehi-Khojin, A.; Thorson, M. R.
- Science, Vol. 334, Issue 6056, p. 643-644
Catalyst electro-redeposition controls morphology and oxidation state for selective carbon dioxide reduction
journal, January 2018
- De Luna, Phil; Quintero-Bermudez, Rafael; Dinh, Cao-Thang
- Nature Catalysis, Vol. 1, Issue 2
Nanostructured Materials for Heterogeneous Electrocatalytic CO 2 Reduction and their Related Reaction Mechanisms
journal, July 2017
- Zhang, Lei; Zhao, Zhi-Jian; Gong, Jinlong
- Angewandte Chemie International Edition, Vol. 56, Issue 38
Evaluation of the Impact of Surface Reconstruction on Rough Electrodeposited Copper-Based Catalysts for Carbon Dioxide Electroreduction
journal, December 2016
- Karaiskakis, Alexandros N.; Biddinger, Elizabeth J.
- Energy Technology, Vol. 5, Issue 6
High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015
- Roberts, F. Sloan; Kuhl, Kendra P.; Nilsson, Anders
- Angewandte Chemie, Vol. 127, Issue 17
Structure-Sensitive CO 2 Electroreduction to Hydrocarbons on Ultrathin 5-fold Twinned Copper Nanowires
journal, January 2017
- Li, Yifan; Cui, Fan; Ross, Michael B.
- Nano Letters, Vol. 17, Issue 2
Chelating N-Heterocyclic Carbene Ligands Enable Tuning of Electrocatalytic CO 2 Reduction to Formate and Carbon Monoxide: Surface Organometallic Chemistry
journal, March 2018
- Cao, Zhi; Derrick, Jeffrey S.; Xu, Jun
- Angewandte Chemie International Edition, Vol. 57, Issue 18
New Insights Into the Role of Imidazolium-Based Promoters for the Electroreduction of CO 2 on a Silver Electrode
journal, June 2016
- Lau, Genevieve P. S.; Schreier, Marcel; Vasilyev, Dmitry
- Journal of the American Chemical Society, Vol. 138, Issue 25
Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
journal, June 2016
- Mistry, Hemma; Varela, Ana Sofia; Bonifacio, Cecile S.
- Nature Communications, Vol. 7, Issue 1
Impurity Ion Complexation Enhances Carbon Dioxide Reduction Catalysis
journal, June 2015
- Wuttig, Anna; Surendranath, Yogesh
- ACS Catalysis, Vol. 5, Issue 7
Microporous carbonaceous adsorbents for CO 2 separation via selective adsorption
journal, January 2015
- Zhao, Yunfeng; Liu, Xin; Han, Yu
- RSC Advances, Vol. 5, Issue 38
Supramolecular Porphyrin Cages Assembled at Molecular–Materials Interfaces for Electrocatalytic CO Reduction
journal, September 2017
- Gong, Ming; Cao, Zhi; Liu, Wei
- ACS Central Science, Vol. 3, Issue 9
CO 2 Electroreduction with Enhanced Ethylene and Ethanol Selectivity by Nanostructuring Polycrystalline Copper
journal, April 2016
- Kwon, Youngkook; Lum, Yanwei; Clark, Ezra L.
- ChemElectroChem, Vol. 3, Issue 6
High-Density Nanosharp Microstructures Enable Efficient CO 2 Electroreduction
journal, October 2016
- Saberi Safaei, Tina; Mepham, Adam; Zheng, Xueli
- Nano Letters, Vol. 16, Issue 11
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012
- Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N.
- Energy & Environmental Science, Vol. 5, Issue 5
Achieving Selective and Efficient Electrocatalytic Activity for CO 2 Reduction Using Immobilized Silver Nanoparticles
journal, October 2015
- Kim, Cheonghee; Jeon, Hyo Sang; Eom, Taedaehyeong
- Journal of the American Chemical Society, Vol. 137, Issue 43
Tuning the Catalytic Activity and Selectivity of Cu for CO 2 Electroreduction in the Presence of Halides
journal, February 2016
- Varela, Ana Sofia; Ju, Wen; Reier, Tobias
- ACS Catalysis, Vol. 6, Issue 4