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Title: Bimetallic Mo-Co/ZSM-5 and Mo-Ni/ZSM-5 catalysts for methane dehydroaromatization: A study of the effect of pretreatment and metal loadings on the catalytic behavior

Authors:
; ; ORCiD logo; ; ; ORCiD logo
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1573860
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Applied Catalysis. A, General
Additional Journal Information:
Journal Name: Applied Catalysis. A, General Journal Volume: 589 Journal Issue: C; Journal ID: ISSN 0926-860X
Publisher:
Elsevier
Country of Publication:
Netherlands
Language:
English

Citation Formats

Sridhar, Apoorva, Rahman, Mustafizur, Infantes-Molina, Antonia, Wylie, Benjamin J., Borcik, Collin G., and Khatib, Sheima J. Bimetallic Mo-Co/ZSM-5 and Mo-Ni/ZSM-5 catalysts for methane dehydroaromatization: A study of the effect of pretreatment and metal loadings on the catalytic behavior. Netherlands: N. p., 2020. Web. doi:10.1016/j.apcata.2019.117247.
Sridhar, Apoorva, Rahman, Mustafizur, Infantes-Molina, Antonia, Wylie, Benjamin J., Borcik, Collin G., & Khatib, Sheima J. Bimetallic Mo-Co/ZSM-5 and Mo-Ni/ZSM-5 catalysts for methane dehydroaromatization: A study of the effect of pretreatment and metal loadings on the catalytic behavior. Netherlands. https://doi.org/10.1016/j.apcata.2019.117247
Sridhar, Apoorva, Rahman, Mustafizur, Infantes-Molina, Antonia, Wylie, Benjamin J., Borcik, Collin G., and Khatib, Sheima J. Wed . "Bimetallic Mo-Co/ZSM-5 and Mo-Ni/ZSM-5 catalysts for methane dehydroaromatization: A study of the effect of pretreatment and metal loadings on the catalytic behavior". Netherlands. https://doi.org/10.1016/j.apcata.2019.117247.
@article{osti_1573860,
title = {Bimetallic Mo-Co/ZSM-5 and Mo-Ni/ZSM-5 catalysts for methane dehydroaromatization: A study of the effect of pretreatment and metal loadings on the catalytic behavior},
author = {Sridhar, Apoorva and Rahman, Mustafizur and Infantes-Molina, Antonia and Wylie, Benjamin J. and Borcik, Collin G. and Khatib, Sheima J.},
abstractNote = {},
doi = {10.1016/j.apcata.2019.117247},
journal = {Applied Catalysis. A, General},
number = C,
volume = 589,
place = {Netherlands},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
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https://doi.org/10.1016/j.apcata.2019.117247

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Cited by: 4 works
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Works referenced in this record:

Effect of addition of a second metal in Mo/ZSM-5 catalyst for methane aromatization reaction under elevated pressures
journal, November 2015


Temperature-programed reduction of molybdenum(VI) oxide and molybdenum(IV) oxide
journal, October 1985

  • Arnoldy, P.; De Jonge, J. C. M.; Moulijn, J. A.
  • The Journal of Physical Chemistry, Vol. 89, Issue 21
  • DOI: 10.1021/j100267a021

Methane dehydro-aromatization on Mo/ZSM-5: About the hidden role of Brønsted acid sites
journal, March 2008

  • Tessonnier, Jean-Philippe; Louis, Benoît; Rigolet, Séverinne
  • Applied Catalysis A: General, Vol. 336, Issue 1-2
  • DOI: 10.1016/j.apcata.2007.08.026

Structure and acidity of Mo/ZSM-5 synthesized by solid state reaction for methane dehydrogenation and aromatization
journal, January 2006


Evolution of isomorphously substituted iron zeolites during activation: comparison of Fe-beta and Fe-ZSM-5
journal, June 2005


A Radical Twist to the Versatile Behavior of Iron in Selective Methane Activation
journal, September 2014

  • Ruitenbeek, Matthijs; Weckhuysen, Bert M.
  • Angewandte Chemie International Edition, Vol. 53, Issue 42
  • DOI: 10.1002/anie.201407109

Increasing the catalytic stability by optimizing the formation of zeolite-supported Mo carbide species ex situ for methane dehydroaromatization
journal, July 2019


Methane aromatization using Mo-based catalysts prepared by microwave heating
journal, December 2004


H2-TPR Study on Mo/HZSM-5 Catalyst for CH4 Dehydroaromatization
journal, April 2006


The effect of water on the reduction of nickel/alumina catalysts
journal, December 1992


Dehydrogenation and aromatization of methane under non-oxidizing conditions
journal, January 1993

  • Wang, Linsheng; Tao, Longxiang; Xie, Maosong
  • Catalysis Letters, Vol. 21, Issue 1-2
  • DOI: 10.1007/BF00767368

Dehydro-oligomerization of Methane to Ethylene and Aromatics over Molybdenum/HZSM-5 Catalyst
journal, November 1995


Impact of the presence of Mo carbide species prepared ex situ in Mo/HZSM-5 on the catalytic properties in methane aromatization
journal, May 2018


Non-oxidative conversion of methane to aromatics over modified Mo/HZSM5 catalysts
journal, March 2001


Structure and Density of Mo and Acid Sites in Mo-Exchanged H-ZSM5 Catalysts for Nonoxidative Methane Conversion
journal, July 1999

  • Borry, Richard W.; Kim, Young Ho; Huffsmith, Anne
  • The Journal of Physical Chemistry B, Vol. 103, Issue 28
  • DOI: 10.1021/jp990866v

Recent progress in methane dehydroaromatization: From laboratory curiosities to promising technology
journal, January 2013


Effect of Cr Addition on the Methane Aromatization Performance of the Mo/HZSM-5 Catalyst
journal, January 2002

  • Zhang, Y.; Wang, D.; Fei, J.
  • Australian Journal of Chemistry, Vol. 55, Issue 8
  • DOI: 10.1071/CH01170

Improvement of catalyst stability during methane dehydroaromatization (MDA) on Mo/HZSM-5 comprising intracrystalline mesopores
journal, July 2011


Confined Carbon Mediating Dehydroaromatization of Methane over Mo/ZSM-5
journal, December 2017

  • Kosinov, Nikolay; Wijpkema, Alexandra S. G.; Uslamin, Evgeny
  • Angewandte Chemie International Edition, Vol. 57, Issue 4
  • DOI: 10.1002/anie.201711098

Direct conversion of methane on Mo/ZSM-5 catalysts to produce benzene and hydrogen: achievements and perspectives
journal, January 2008

  • Ismagilov, Zinfer R.; Matus, Ekaterina V.; Tsikoza, Lidia T.
  • Energy & Environmental Science, Vol. 1, Issue 5
  • DOI: 10.1039/b810981h

XPS, XAES, and TG/DTA characterization of deposited carbon in methane dehydroaromatization over Ga–Mo/ZSM-5 catalyst
journal, March 2007


Determination of Molybdenum Species Evolution during Non‐Oxidative Dehydroaromatization of Methane and its Implications for Catalytic Performance
journal, October 2018

  • Agote‐Arán, Miren; Kroner, Anna B.; Islam, Husn U.
  • ChemCatChem, Vol. 11, Issue 1
  • DOI: 10.1002/cctc.201801299

Aromatization of Methane over Supported and Unsupported Mo-Based Catalysts
journal, January 1997


Silica-Alumina-Supported Acidic Molybdenum Catalysts - TPR and XRD Characterization
journal, June 1994

  • Rajagopal, S.; Marini, H. J.; Marzari, J. A.
  • Journal of Catalysis, Vol. 147, Issue 2
  • DOI: 10.1006/jcat.1994.1159

Characterization of a Mo/ZSM-5 Catalyst for the Conversion of Methane to Benzene
journal, July 1997

  • Wang, Dingjun; Lunsford, Jack H.; Rosynek, Michael P.
  • Journal of Catalysis, Vol. 169, Issue 1
  • DOI: 10.1006/jcat.1997.1712

Methane activation without using oxidants over Mo/HZSM-5 zeolite catalysts
journal, January 1995

  • Xu, Yide; Liu, Shetian; Guo, Xiexian
  • Catalysis Letters, Vol. 30, Issue 1-4
  • DOI: 10.1007/BF00813680

Using phosphorus doping of MoO3/ZSM-5 to modify performance in methane dehydroaromatisation
journal, February 2006


On the Mechanism Underlying the Direct Conversion of Methane to Methanol by Copper Hosted in Zeolites; Braiding Cu K-Edge XANES and Reactivity Studies
journal, July 2018

  • Newton, Mark A.; Knorpp, Amy J.; Pinar, Ana B.
  • Journal of the American Chemical Society, Vol. 140, Issue 32
  • DOI: 10.1021/jacs.8b05139

Nonoxidative conversion of methane into aromatic hydrocarbons on Ni-Mo/ZSM-5 catalysts
journal, September 2009

  • Vosmerikov, A. V.; Zaikovskii, V. I.; Korobitsyna, L. L.
  • Kinetics and Catalysis, Vol. 50, Issue 5
  • DOI: 10.1134/S0023158409050140

Conversion of Methane to Benzene over Transition Metal Ion ZSM-5 Zeolites
journal, April 1998

  • Weckhuysen, Bert M.; Wang, Dingjun; Rosynek, Michael P.
  • Journal of Catalysis, Vol. 175, Issue 2
  • DOI: 10.1006/jcat.1998.2010

Methane decomposition into hydrogen and carbon nanofibers over supported Pd–Ni catalysts
journal, December 2003


The effects of boron and silver on the oxygen-free conversion of methane over Mo/H-ZSM-5 catalysts
journal, June 2009

  • Ngobeni, M. W.; Carley, A. F.; Scurrell, M. S.
  • Journal of Molecular Catalysis A: Chemical, Vol. 305, Issue 1-2
  • DOI: 10.1016/j.molcata.2008.10.047

Thermodynamic Analysis of Nonoxidative Dehydroaromatization of Methane
journal, June 2012

  • Moghimpour Bijani, P.; Sohrabi, M.; Sahebdelfar, S.
  • Chemical Engineering & Technology, Vol. 35, Issue 10
  • DOI: 10.1002/ceat.201100436

Carbon capacious Ni-Cu-Al2O3 catalysts for high-temperature methane decomposition
journal, July 2003

  • Reshetenko, Tatyana V.; Avdeeva, Lyudmila B.; Ismagilov, Zinfer R.
  • Applied Catalysis A: General, Vol. 247, Issue 1
  • DOI: 10.1016/S0926-860X(03)00080-2

Mass production of high-quality multi-walled carbon nanotube bundles on a Ni/Mo/MgO catalyst
journal, January 2005


Remarkable non-oxidative conversion of methane to naphthalene and benzene on Co and Fe modified Mo/HZSM-5 catalysts
journal, January 1997

  • Liu, Shetian; Dong, Qun; Ohnishi, Ryuichiro
  • Chemical Communications, Issue 15
  • DOI: 10.1039/a702731a

Dehydroaromatization of methane over doped Pt/Mo/H-ZSM-5 zeolite catalysts: The promotional effect of tin
journal, September 2014


The effect of dopants on the activity of MoO3/ZSM-5 catalysts for the dehydroaromatisation of methane
journal, May 2006


Quantitative Measurement of the Brönsted Acid Sites in Solid Acids:  Toward a Single-Site Design of Mo-Modified ZSM-5 Zeolite
journal, June 2006

  • Tessonnier, Jean-Philippe; Louis, Benoît; Walspurger, Stephane
  • The Journal of Physical Chemistry B, Vol. 110, Issue 21
  • DOI: 10.1021/jp0602629

Understanding and Breaking Scaling Relations in Single-Site Catalysis: Methane to Methanol Conversion by Fe IV ═O
journal, January 2018


Realumination of dealuminated HZSM-5 zeolites by acid treatment: a reexamination
journal, August 2001


Molybdenum Speciation and its Impact on Catalytic Activity during Methane Dehydroaromatization in Zeolite ZSM-5 as Revealed by Operando X-Ray Methods
journal, March 2016

  • Lezcano-González, Inés; Oord, Ramon; Rovezzi, Mauro
  • Angewandte Chemie International Edition, Vol. 55, Issue 17
  • DOI: 10.1002/anie.201601357

Stability and deactivation of Fe-ZSM-5 zeolite catalyst for catalytic wet peroxide oxidation of phenol in a membrane reactor
journal, January 2015

  • Jiang, Songshan; Zhang, Huiping; Yan, Ying
  • RSC Advances, Vol. 5, Issue 51
  • DOI: 10.1039/C5RA05039A

A corrected procedure and consistent interpretation for temperature programmed reduction of supported MoO3
journal, January 1994

  • Regalbuto, John R.; Ha, Jin -Wook
  • Catalysis Letters, Vol. 29, Issue 1-2
  • DOI: 10.1007/BF00814265

Catalytic aromatization of methane
journal, January 2014

  • Spivey, James J.; Hutchings, Graham
  • Chem. Soc. Rev., Vol. 43, Issue 3
  • DOI: 10.1039/C3CS60259A

On the dynamic nature of Mo sites for methane dehydroaromatization
journal, January 2018

  • Vollmer, Ina; van der Linden, Bart; Ould-Chikh, Samy
  • Chemical Science, Vol. 9, Issue 21
  • DOI: 10.1039/C8SC01263F

Enhancement of Molybdenum/ZSM-5 Catalysts in Methane Aromatization by the Addition of Iron Promoters and by Reduction/Carburization Pretreatment
journal, May 2018

  • Sridhar, Apoorva; Rahman, Mustafizur; Khatib, Sheima J.
  • ChemCatChem, Vol. 10, Issue 12
  • DOI: 10.1002/cctc.201800002

Genesis of methane activation sites in Mo-exchanged H–ZSM-5 catalysts
journal, April 2000


Methane Dehydroaromatization by Mo/HZSM-5: Mono- or Bifunctional Catalysis?
journal, December 2016

  • Kosinov, Nikolay; Coumans, Ferdy J. A. G.; Uslamin, Evgeny A.
  • ACS Catalysis, Vol. 7, Issue 1
  • DOI: 10.1021/acscatal.6b02497

Incorporation of molybdenum into Pd and Pt catalysts supported on commercial silica for hydrodeoxygenation reaction of dibenzofuran
journal, October 2017

  • Ballesteros-Plata, D.; Infantes-Molina, A.; Rodríguez-Cuadrado, M.
  • Applied Catalysis A: General, Vol. 547
  • DOI: 10.1016/j.apcata.2017.08.034

Aluminum siting in mordenite and dealumination mechanism
journal, October 1986

  • Bodart, Philippe; Nagy, Janos B.; Debras, Guy
  • The Journal of Physical Chemistry, Vol. 90, Issue 21
  • DOI: 10.1021/j100412a058

Effect of Pd or Ir on the catalytic performance of Mo/H-ZSM-5 during the non-oxidative conversion of natural gas to petrochemicals
journal, December 2008

  • Aboul-Gheit, Ahmed K.; Awadallah, Ahmed E.; El-Kossy, Salah M.
  • Journal of Natural Gas Chemistry, Vol. 17, Issue 4
  • DOI: 10.1016/S1003-9953(09)60005-0

Stable Mo/HZSM-5 methane dehydroaromatization catalysts optimized for high-temperature calcination-regeneration
journal, February 2017


Non-oxidative dehydroaromatization of methane over Ga-promoted Mo/HZSM-5-based catalysts
journal, June 2001


Methane Conversion to Aromatics on Mo/H-ZSM5:  Structure of Molybdenum Species in Working Catalysts
journal, January 2001

  • Ding, Weiping; Li, Senzi; D. Meitzner, George
  • The Journal of Physical Chemistry B, Vol. 105, Issue 2
  • DOI: 10.1021/jp0030692

The function of Cu(II) ions in the Mo/CuH-ZSM-5 catalyst for methane conversion under non-oxidative condition
journal, October 1999


Identification of molybdenum oxide nanostructures on zeolites for natural gas conversion
journal, April 2015


A hollow Mo/HZSM-5 zeolite capsule catalyst: preparation and enhanced catalytic properties in methane dehydroaromatization
journal, January 2017

  • Zhu, Pengfei; Yang, Guohui; Sun, Jian
  • Journal of Materials Chemistry A, Vol. 5, Issue 18
  • DOI: 10.1039/C7TA02345F