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Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation
Abstract
Divalent samarium and europium complexes with bulky 3-coordinate bis(tris- tert -butoxysilyl)amides are synthesized through oxidative transmetallation.
- Authors:
- Department of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, USA
- Department of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, USA, Nuclear and Radiological Engineering Program
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1573858
- Grant/Contract Number:
- SC0019385
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Dalton Transactions
- Additional Journal Information:
- Journal Name: Dalton Transactions Journal Volume: 48 Journal Issue: 45; Journal ID: ISSN 1477-9226
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Gompa, Thaige P., Jiang, Ningxin, Bacsa, John, and La Pierre, Henry S. Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9DT04230J.
Gompa, Thaige P., Jiang, Ningxin, Bacsa, John, & La Pierre, Henry S. Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation. United Kingdom. doi:10.1039/C9DT04230J.
Gompa, Thaige P., Jiang, Ningxin, Bacsa, John, and La Pierre, Henry S. Tue .
"Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation". United Kingdom. doi:10.1039/C9DT04230J.
@article{osti_1573858,
title = {Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation},
author = {Gompa, Thaige P. and Jiang, Ningxin and Bacsa, John and La Pierre, Henry S.},
abstractNote = {Divalent samarium and europium complexes with bulky 3-coordinate bis(tris- tert -butoxysilyl)amides are synthesized through oxidative transmetallation.},
doi = {10.1039/C9DT04230J},
journal = {Dalton Transactions},
number = 45,
volume = 48,
place = {United Kingdom},
year = {2019},
month = {11}
}
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DOI: 10.1039/C9DT04230J
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Works referenced in this record:
Lanthanidocenes: Synthesis, Structure, and Bonding of Linear Sandwich Complexes of Lanthanides
journal, October 2018
- Xémard, Mathieu; Zimmer, Sébastien; Cordier, Marie
- Journal of the American Chemical Society, Vol. 140, Issue 43
Divalent Thulium Crown Ether Complexes with Field-Induced Slow Magnetic Relaxation
journal, February 2019
- Xémard, Mathieu; Cordier, Marie; Molton, Florian
- Inorganic Chemistry, Vol. 58, Issue 4
The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet
journal, January 2015
- Chilton, Nicholas F.; Goodwin, Conrad A. P.; Mills, David P.
- Chemical Communications, Vol. 51, Issue 1
The organometallic Chemistry of the lanthanide elements in low oxidation states
journal, January 1987
- Evans, William J.
- Polyhedron, Vol. 6, Issue 5
Pentavalent uranium trans-dihalides and -pseudohalides
journal, January 2012
- Lewis, Andrew J.; Nakamaru-Ogiso, Eiko; Kikkawa, James M.
- Chemical Communications, Vol. 48, Issue 41
A Dysprosium Metallocene Single-Molecule Magnet Functioning at the Axial Limit
journal, July 2017
- Guo, Fu-Sheng; Day, Benjamin M.; Chen, Yan-Cong
- Angewandte Chemie International Edition, Vol. 56, Issue 38
Design, Isolation, and Spectroscopic Analysis of a Tetravalent Terbium Complex
journal, July 2019
- Rice, Natalie T.; Popov, Ivan A.; Russo, Dominic R.
- Journal of the American Chemical Society, Vol. 141, Issue 33
Pentavalent uranium chemistry—synthetic pursuit of a rare oxidation state
journal, January 2009
- Graves, Christopher R.; Kiplinger, Jaqueline L.
- Chemical Communications, Issue 26
Exploiting single-ion anisotropy in the design of f-element single-molecule magnets
journal, January 2011
- Rinehart, Jeffrey D.; Long, Jeffrey R.
- Chemical Science, Vol. 2, Issue 11
ORGANOMETALLIC COMPOUNDS OF TITANIUM, ZIRCONIUM, AND LANTHANUM 1
journal, November 1945
- Gilman, Henry; Jones, R. G.
- The Journal of Organic Chemistry, Vol. 10, Issue 6
Homoleptic Trigonal Planar Lanthanide Complexes Stabilized by Superbulky Silylamide Ligands
journal, November 2014
- Goodwin, Conrad A. P.; Joslin, Kristian C.; Lockyer, Selena J.
- Organometallics, Vol. 34, Issue 11
Molecular magnetic hysteresis at 60 kelvin in dysprosocenium
journal, August 2017
- Goodwin, Conrad A. P.; Ortu, Fabrizio; Reta, Daniel
- Nature, Vol. 548, Issue 7668
Synthesis and Magnetism of Neutral, Linear Metallocene Complexes of Terbium(II) and Dysprosium(II)
journal, August 2019
- Gould, Colin A.; McClain, K. Randall; Yu, Jason M.
- Journal of the American Chemical Society, Vol. 141, Issue 33
Synthesis and Electronic Structures of Heavy Lanthanide Metallocenium Cations
journal, December 2017
- Goodwin, Conrad A. P.; Reta, Daniel; Ortu, Fabrizio
- Journal of the American Chemical Society, Vol. 139, Issue 51
The Second Quantum Revolution: Role and Challenges of Molecular Chemistry
journal, June 2019
- Atzori, Matteo; Sessoli, Roberta
- Journal of the American Chemical Society, Vol. 141, Issue 29
Facile Access to Pentavalent Uranium Organometallics: One-Electron Oxidation of Uranium(IV) Imido Complexes with Copper(I) Salts
journal, October 2007
- Graves, Christopher R.; Scott, Brian L.; Morris, David E.
- Journal of the American Chemical Society, Vol. 129, Issue 39
Physicochemical Properties of Near-Linear Lanthanide(II) Bis(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb)
journal, May 2016
- Goodwin, Conrad A. P.; Chilton, Nicholas F.; Vettese, Gianni F.
- Inorganic Chemistry, Vol. 55, Issue 20
Phosphorescence and Structure of a Tetrameric Copper(I)−Amide Cluster
journal, July 1998
- James, Alicia M.; Laxman, Ravi K.; Fronczek, Frank R.
- Inorganic Chemistry, Vol. 37, Issue 15
Bis(pentafluorophenyl)mercury—a versatile synthon in organo-, organooxo-, and organoamido-lanthanoid chemistry
journal, March 2002
- Deacon, Glen B.; Forsyth, Craig M.; Nickel, Siegbert
- Journal of Organometallic Chemistry, Vol. 647, Issue 1-2
Homoleptic Imidophosphorane Stabilization of Tetravalent Cerium
journal, March 2019
- Rice, Natalie T.; Su, Jing; Gompa, Thaige P.
- Inorganic Chemistry, Vol. 58, Issue 8
Structural variation in copper( i ) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, τ 4
journal, January 2007
- Yang, Lei; Powell, Douglas R.; Houser, Robert P.
- Dalton Trans., Issue 9
Progress towards creating optically addressable molecular qubits
journal, January 2018
- Fataftah, Majed S.; Freedman, Danna E.
- Chemical Communications, Vol. 54, Issue 98
Carbon dioxide reduction by dinuclear Yb( ii ) and Sm( ii ) complexes supported by siloxide ligands
journal, January 2019
- Willauer, Aurélien R.; Toniolo, Davide; Fadaei-Tirani, Farzaneh
- Dalton Transactions, Vol. 48, Issue 18
Rare-Earth Metalation of Calix[4]pyrrole/Calix[4]arene Free of Alkali-Metal Companions
journal, May 2012
- Deacon, Glen B.; Gardiner, Michael G.; Junk, Peter C.
- Organometallics, Vol. 31, Issue 10
Metal–metal and metal–halogen bond cleavage by lanthanide and related metals
journal, January 1973
- Crease, Allan E.; Legzdins, Peter
- J. Chem. Soc., Chem. Commun., Issue 20
Metal–ligand pair anisotropy in a series of mononuclear Er–COT complexes
journal, January 2018
- Hilgar, J. D.; Bernbeck, M. G.; Flores, B. S.
- Chemical Science, Vol. 9, Issue 36
Syntheses and Crystal Structures of Cuprate Complexes of Europium and Ytterbium, {[(PhC⋮C) 3 Cu][Eu(Py)(THF) 2 ]} 2 and {[(PhC⋮C) 3 Cu][Yb(THF) 2 ]} 2
journal, February 1997
- Bochkarev, Leonid N.; Druzhkova, Olga N.; Zhiltsov, Sergey F.
- Organometallics, Vol. 16, Issue 4
Record High Single-Ion Magnetic Moments Through 4f n 5d 1 Electron Configurations in the Divalent Lanthanide Complexes [(C 5 H 4 SiMe 3 ) 3 Ln] −
journal, July 2015
- Meihaus, Katie R.; Fieser, Megan E.; Corbey, Jordan F.
- Journal of the American Chemical Society, Vol. 137, Issue 31
Synthesis and structure of metal carbonyl derivatives of lanthanium, samarium and ytterbium
journal, January 1986
- Beletskaya, I. P.; Suleimanov, G. Z.; Shifrina, R. R.
- Journal of Organometallic Chemistry, Vol. 299, Issue 2