Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation

doi:10.1039/C9DT04230J

This content will become publicly available on November 5, 2020

Title: Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation

Abstract

Divalent samarium and europium complexes with bulky 3-coordinate bis(tris- tert -butoxysilyl)amides are synthesized through oxidative transmetallation.

Authors:

^[1];

^[2]

Department of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, USA
Department of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, USA, Nuclear and Radiological Engineering Program

Publication Date:: 2019-11-19

Sponsoring Org.:: USDOE

OSTI Identifier:: 1573858

Grant/Contract Number:: SC0019385

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Dalton Transactions

Additional Journal Information:: Journal Name: Dalton Transactions Journal Volume: 48 Journal Issue: 45; Journal ID: ISSN 1477-9226

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Gompa, Thaige P., Jiang, Ningxin, Bacsa, John, and La Pierre, Henry S. Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation.  United Kingdom: N. p., 2019. 
        Web.  doi:10.1039/C9DT04230J.

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                    Gompa, Thaige P., Jiang, Ningxin, Bacsa, John, & La Pierre, Henry S. Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation.  United Kingdom.  doi:10.1039/C9DT04230J.

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                    Gompa, Thaige P., Jiang, Ningxin, Bacsa, John, and La Pierre, Henry S. Tue .  
        "Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation".  United Kingdom.  doi:10.1039/C9DT04230J.

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@article{osti_1573858,

  title        = {Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation},

  author       = {Gompa, Thaige P. and Jiang, Ningxin and Bacsa, John and La Pierre, Henry S.},

  abstractNote = {Divalent samarium and europium complexes with bulky 3-coordinate bis(tris- tert -butoxysilyl)amides are synthesized through oxidative transmetallation.},

  doi          = {10.1039/C9DT04230J},

  journal      = {Dalton Transactions},

  number       = 45,

  volume       = 48,

  place        = {United Kingdom},

  year         = {2019},

  month        = {11}

}

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DOI: 10.1039/C9DT04230J

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Similar Records

This content will become publicly available on November 5, 2020

Title: Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation

Abstract

Citation Formats

Lanthanidocenes: Synthesis, Structure, and Bonding of Linear Sandwich Complexes of Lanthanides journal, October 2018

Divalent Thulium Crown Ether Complexes with Field-Induced Slow Magnetic Relaxation journal, February 2019

The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet journal, January 2015

The organometallic Chemistry of the lanthanide elements in low oxidation states journal, January 1987

Pentavalent uranium trans-dihalides and -pseudohalides journal, January 2012

A Dysprosium Metallocene Single-Molecule Magnet Functioning at the Axial Limit journal, July 2017

Design, Isolation, and Spectroscopic Analysis of a Tetravalent Terbium Complex journal, July 2019

Pentavalent uranium chemistry—synthetic pursuit of a rare oxidation state journal, January 2009

Exploiting single-ion anisotropy in the design of f-element single-molecule magnets journal, January 2011

ORGANOMETALLIC COMPOUNDS OF TITANIUM, ZIRCONIUM, AND LANTHANUM 1 journal, November 1945

Homoleptic Trigonal Planar Lanthanide Complexes Stabilized by Superbulky Silylamide Ligands journal, November 2014

Molecular magnetic hysteresis at 60 kelvin in dysprosocenium journal, August 2017

Synthesis and Magnetism of Neutral, Linear Metallocene Complexes of Terbium(II) and Dysprosium(II) journal, August 2019

Synthesis and Electronic Structures of Heavy Lanthanide Metallocenium Cations journal, December 2017

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Physicochemical Properties of Near-Linear Lanthanide(II) Bis(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb) journal, May 2016

Phosphorescence and Structure of a Tetrameric Copper(I)−Amide Cluster journal, July 1998

Bis(pentafluorophenyl)mercury—a versatile synthon in organo-, organooxo-, and organoamido-lanthanoid chemistry journal, March 2002

Homoleptic Imidophosphorane Stabilization of Tetravalent Cerium journal, March 2019

Structural variation in copper( i ) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, τ 4 journal, January 2007

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Carbon dioxide reduction by dinuclear Yb( ii ) and Sm( ii ) complexes supported by siloxide ligands journal, January 2019

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Metal–metal and metal–halogen bond cleavage by lanthanide and related metals journal, January 1973

Metal–ligand pair anisotropy in a series of mononuclear Er–COT complexes journal, January 2018

Syntheses and Crystal Structures of Cuprate Complexes of Europium and Ytterbium, {[(PhC⋮C) 3 Cu][Eu(Py)(THF) 2 ]} 2 and {[(PhC⋮C) 3 Cu][Yb(THF) 2 ]} 2 journal, February 1997

Record High Single-Ion Magnetic Moments Through 4f n 5d 1 Electron Configurations in the Divalent Lanthanide Complexes [(C 5 H 4 SiMe 3 ) 3 Ln] − journal, July 2015

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Lanthanidocenes: Synthesis, Structure, and Bonding of Linear Sandwich Complexes of Lanthanides
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Divalent Thulium Crown Ether Complexes with Field-Induced Slow Magnetic Relaxation
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The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet
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The organometallic Chemistry of the lanthanide elements in low oxidation states
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Pentavalent uranium trans-dihalides and -pseudohalides
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A Dysprosium Metallocene Single-Molecule Magnet Functioning at the Axial Limit
journal, July 2017

Design, Isolation, and Spectroscopic Analysis of a Tetravalent Terbium Complex
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Pentavalent uranium chemistry—synthetic pursuit of a rare oxidation state
journal, January 2009

Exploiting single-ion anisotropy in the design of f-element single-molecule magnets
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Homoleptic Trigonal Planar Lanthanide Complexes Stabilized by Superbulky Silylamide Ligands
journal, November 2014

Molecular magnetic hysteresis at 60 kelvin in dysprosocenium
journal, August 2017

Synthesis and Magnetism of Neutral, Linear Metallocene Complexes of Terbium(II) and Dysprosium(II)
journal, August 2019

Synthesis and Electronic Structures of Heavy Lanthanide Metallocenium Cations
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The Second Quantum Revolution: Role and Challenges of Molecular Chemistry
journal, June 2019

Facile Access to Pentavalent Uranium Organometallics: One-Electron Oxidation of Uranium(IV) Imido Complexes with Copper(I) Salts
journal, October 2007

Physicochemical Properties of Near-Linear Lanthanide(II) Bis(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb)
journal, May 2016

Phosphorescence and Structure of a Tetrameric Copper(I)−Amide Cluster
journal, July 1998

Bis(pentafluorophenyl)mercury—a versatile synthon in organo-, organooxo-, and organoamido-lanthanoid chemistry
journal, March 2002

Homoleptic Imidophosphorane Stabilization of Tetravalent Cerium
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journal, January 2018

Carbon dioxide reduction by dinuclear Yb( ii ) and Sm( ii ) complexes supported by siloxide ligands
journal, January 2019

Rare-Earth Metalation of Calix[4]pyrrole/Calix[4]arene Free of Alkali-Metal Companions
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Metal–metal and metal–halogen bond cleavage by lanthanide and related metals
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journal, January 2018

Syntheses and Crystal Structures of Cuprate Complexes of Europium and Ytterbium, {[(PhC⋮C) ₃ Cu][Eu(Py)(THF) ₂ ]} ₂ and {[(PhC⋮C) ₃ Cu][Yb(THF) ₂ ]} ₂
journal, February 1997

Record High Single-Ion Magnetic Moments Through 4f ⁿ 5d ¹ Electron Configurations in the Divalent Lanthanide Complexes [(C ₅ H ₄ SiMe ₃ ) ₃ Ln] ⁻
journal, July 2015

Synthesis and structure of metal carbonyl derivatives of lanthanium, samarium and ytterbium
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