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Title: Self-Assembled Chromophore–Catalyst Bilayer for Water Oxidation in a Dye-Sensitized Photoelectrosynthesis Cell

Authors:
 [1];  [2]; ORCiD logo [1]; ORCiD logo [3]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [4]
  1. Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, United States
  2. Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, New York 11794, United States
  3. Department of Chemistry and Biochemistry, Florida International University, 11200 SW 8th Street, Miami, Florida 33199, United States
  4. Chemistry Division, Brookhaven National Laboratory, Upton, New York 11973, United States
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Alliance for Molecular PhotoElectrode Design for Solar Fuels (AMPED); Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division
OSTI Identifier:
1573856
Alternate Identifier(s):
OSTI ID: 1580034; OSTI ID: 1593250
Report Number(s):
BNL-213642-2020-JAAM; BNL-213568-2020-JAAM
Journal ID: ISSN 1932-7447
Grant/Contract Number:  
SC0001011; SC0012704
Resource Type:
Published Article
Journal Name:
Journal of Physical Chemistry. C
Additional Journal Information:
Journal Name: Journal of Physical Chemistry. C Journal Volume: 123 Journal Issue: 50; Journal ID: ISSN 1932-7447
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY

Citation Formats

Wang, Degao, Wang, Lei, Brady, Matthew D., Dares, Christopher J., Meyer, Gerald J., Meyer, Thomas J., and Concepcion, Javier J. Self-Assembled Chromophore–Catalyst Bilayer for Water Oxidation in a Dye-Sensitized Photoelectrosynthesis Cell. United States: N. p., 2019. Web. https://doi.org/10.1021/acs.jpcc.9b07125.
Wang, Degao, Wang, Lei, Brady, Matthew D., Dares, Christopher J., Meyer, Gerald J., Meyer, Thomas J., & Concepcion, Javier J. Self-Assembled Chromophore–Catalyst Bilayer for Water Oxidation in a Dye-Sensitized Photoelectrosynthesis Cell. United States. https://doi.org/10.1021/acs.jpcc.9b07125
Wang, Degao, Wang, Lei, Brady, Matthew D., Dares, Christopher J., Meyer, Gerald J., Meyer, Thomas J., and Concepcion, Javier J. Wed . "Self-Assembled Chromophore–Catalyst Bilayer for Water Oxidation in a Dye-Sensitized Photoelectrosynthesis Cell". United States. https://doi.org/10.1021/acs.jpcc.9b07125.
@article{osti_1573856,
title = {Self-Assembled Chromophore–Catalyst Bilayer for Water Oxidation in a Dye-Sensitized Photoelectrosynthesis Cell},
author = {Wang, Degao and Wang, Lei and Brady, Matthew D. and Dares, Christopher J. and Meyer, Gerald J. and Meyer, Thomas J. and Concepcion, Javier J.},
abstractNote = {},
doi = {10.1021/acs.jpcc.9b07125},
journal = {Journal of Physical Chemistry. C},
number = 50,
volume = 123,
place = {United States},
year = {2019},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acs.jpcc.9b07125

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Cited by: 3 works
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Works referenced in this record:

Inverse Opal CuCrO 2 Photocathodes for H 2 Production Using Organic Dyes and a Molecular Ni Catalyst
journal, September 2019

  • Creissen, Charles E.; Warnan, Julien; Antón-García, Daniel
  • ACS Catalysis, Vol. 9, Issue 10
  • DOI: 10.1021/acscatal.9b02984

Accumulation of Multiple Oxidative Equivalents at a Single Site by Cross-Surface Electron Transfer on TiO 2
journal, July 2013

  • Song, Wenjing; Ito, Akitaka; Binstead, Robert A.
  • Journal of the American Chemical Society, Vol. 135, Issue 31
  • DOI: 10.1021/ja4032538

Interfacial Electron Transfer Dynamics for [Ru(bpy) 2 ((4,4′-PO 3 H 2 ) 2 bpy)] 2+ Sensitized TiO 2 in a Dye-Sensitized Photoelectrosynthesis Cell: Factors Influencing Efficiency and Dynamics
journal, March 2011

  • Song, Wenjing; Brennaman, M. Kyle; Concepcion, Javier J.
  • The Journal of Physical Chemistry C, Vol. 115, Issue 14
  • DOI: 10.1021/jp200124k

Visible light-driven water oxidation using a covalently-linked molecular catalyst–sensitizer dyad assembled on a TiO 2 electrode
journal, January 2016

  • Yamamoto, Masanori; Wang, Lei; Li, Fusheng
  • Chemical Science, Vol. 7, Issue 2
  • DOI: 10.1039/c5sc03669k

Light-Driven Water Splitting with a Molecular Electroassembly-Based Core/Shell Photoanode
journal, July 2015

  • Sherman, Benjamin D.; Ashford, Dennis L.; Lapides, Alexander M.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 16
  • DOI: 10.1021/acs.jpclett.5b01370

Inner Layer Control of Performance in a Dye-Sensitized Photoelectrosynthesis Cell
journal, March 2017

  • Wang, Degao; Farnum, Byron H.; Sheridan, Matthew V.
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 39
  • DOI: 10.1021/acsami.7b00225

Photoinduced electron transfer from rylenediimide radical anions and dianions to Re(bpy)(CO) 3 using red and near-infrared light
journal, January 2017

  • La Porte, Nathan T.; Martinez, Jose F.; Hedström, Svante
  • Chemical Science, Vol. 8, Issue 5
  • DOI: 10.1039/c6sc05103k

Supramolecular Cobaloxime Assemblies for H 2 Photocatalysis: An Initial Solution State Structure−Function Analysis
journal, November 2010

  • Mulfort, Karen L.; Tiede, David M.
  • The Journal of Physical Chemistry B, Vol. 114, Issue 45
  • DOI: 10.1021/jp1023636

Visible Photoelectrochemical Water Splitting Based on a Ru(II) Polypyridyl Chromophore and Iridium Oxide Nanoparticle Catalyst
journal, July 2015

  • Michaux, Katherine E.; Gambardella, Alessa A.; Alibabaei, Leila
  • The Journal of Physical Chemistry C, Vol. 119, Issue 29
  • DOI: 10.1021/acs.jpcc.5b05711

Light-Driven Water Splitting by a Covalently Linked Ruthenium-Based Chromophore–Catalyst Assembly
journal, December 2016


Ultrafast Photodriven Intramolecular Electron Transfer from a Zinc Porphyrin to a Readily Reduced Diiron Hydrogenase Model Complex
journal, July 2010

  • Samuel, Amanda P. S.; Co, Dick T.; Stern, Charlotte L.
  • Journal of the American Chemical Society, Vol. 132, Issue 26
  • DOI: 10.1021/ja100016v

Making solar fuels by artificial photosynthesis
journal, March 2011

  • Song, Wenjing; Chen, Zuofeng; Brennaman, M. Kyle
  • Pure and Applied Chemistry, Vol. 83, Issue 4
  • DOI: 10.1351/pac-con-10-11-09

Earth-Abundant Molecular Z-Scheme Photoelectrochemical Cell for Overall Water-Splitting
journal, April 2019

  • Windle, Christopher D.; Kumagai, Hiromu; Higashi, Masanobu
  • Journal of the American Chemical Society, Vol. 141, Issue 24
  • DOI: 10.1021/jacs.9b02521

Evaluation of Chromophore and Assembly Design in Light-Driven Water Splitting with a Molecular Water Oxidation Catalyst
journal, June 2016


WO 3 /Conducting Polymer Heterojunction Photoanodes for Efficient and Stable Photoelectrochemical Water Splitting
journal, February 2018

  • Jeon, Dasom; Kim, Nayeong; Bae, Sanghyun
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 9
  • DOI: 10.1021/acsami.7b19203

Polypyrrole-Ru(2,2′-bipyridine) 3 2+ /MoS x Structured Composite Film As a Photocathode for the Hydrogen Evolution Reaction
journal, February 2015

  • Lattach, Youssef; Fortage, Jérôme; Deronzier, Alain
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 8
  • DOI: 10.1021/acsami.5b00401

Interrogating the photogenerated Ir(iv) state of a water oxidation catalyst using ultrafast optical and X-ray absorption spectroscopy
journal, January 2013

  • Vagnini, Michael T.; Mara, Michael W.; Harpham, Michael R.
  • Chemical Science, Vol. 4, Issue 10
  • DOI: 10.1039/c3sc51511g

Evidence for an Electronic State at the Interface between the SnO 2 Core and the TiO 2 Shell in Mesoporous SnO 2 /TiO 2 Thin Films
journal, February 2018

  • James, Erica M.; Barr, Timothy J.; Meyer, Gerald J.
  • ACS Applied Energy Materials, Vol. 1, Issue 2
  • DOI: 10.1021/acsaem.7b00274

Electro-assembly of a Chromophore-Catalyst Bilayer for Water Oxidation and Photocatalytic Water Splitting
journal, February 2015

  • Ashford, Dennis L.; Sherman, Benjamin D.; Binstead, Robert A.
  • Angewandte Chemie International Edition, Vol. 54, Issue 16
  • DOI: 10.1002/anie.201410944

Organic Dye-Sensitized Tandem Photoelectrochemical Cell for Light Driven Total Water Splitting
journal, July 2015

  • Li, Fusheng; Fan, Ke; Xu, Bo
  • Journal of the American Chemical Society, Vol. 137, Issue 28
  • DOI: 10.1021/jacs.5b04856

Interfacial Deposition of Ru(II) Bipyridine-Dicarboxylate Complexes by Ligand Substitution for Applications in Water Oxidation Catalysis
journal, January 2018

  • Wang, Degao; Marquard, Seth L.; Troian-Gautier, Ludovic
  • Journal of the American Chemical Society, Vol. 140, Issue 2
  • DOI: 10.1021/jacs.7b10809

A Co( ii )–Ru( ii ) dyad relevant to light-driven water oxidation catalysis
journal, January 2014

  • López, Alejandro Montellano; Natali, Mirco; Pizzolato, Erica
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 24
  • DOI: 10.1039/c3cp55369h

Layer-by-Layer Molecular Assemblies for Dye-Sensitized Photoelectrosynthesis Cells Prepared by Atomic Layer Deposition
journal, August 2017

  • Wang, Degao; Sheridan, Matthew V.; Shan, Bing
  • Journal of the American Chemical Society, Vol. 139, Issue 41
  • DOI: 10.1021/jacs.7b07216

Visible Light-Driven Water Splitting in Photoelectrochemical Cells with Supramolecular Catalysts on Photoanodes
journal, May 2014

  • Ding, Xin; Gao, Yan; Zhang, Linlin
  • ACS Catalysis, Vol. 4, Issue 7
  • DOI: 10.1021/cs500518k

Self-Assembled Bilayers as an Anchoring Strategy: Catalysts, Chromophores, and Chromophore-Catalyst Assemblies
journal, May 2019

  • Wang, Lei; Polyansky, Dmitry E.; Concepcion, Javier J.
  • Journal of the American Chemical Society
  • DOI: 10.1021/jacs.9b01044

Photovoltage Effects of Sintered IrO 2 Nanoparticle Catalysts in Water-Splitting Dye-Sensitized Photoelectrochemical Cells
journal, April 2014

  • Swierk, John R.; McCool, Nicholas S.; Saunders, Timothy P.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 30
  • DOI: 10.1021/jp500589n

Effect of Perylene Photosensitizer Attachment to [Pd(triphosphine)L] 2+ on CO 2 Electrocatalysis
journal, November 2016


Dynamics of Electron Recombination and Transport in Water-Splitting Dye-Sensitized Photoanodes
journal, June 2015

  • Swierk, John R.; McCool, Nicholas S.; Mallouk, Thomas E.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 24
  • DOI: 10.1021/acs.jpcc.5b01442

A Sensitized Nb 2 O 5 Photoanode for Hydrogen Production in a Dye-Sensitized Photoelectrosynthesis Cell
journal, December 2012

  • Luo, Hanlin; Song, Wenjing; Hoertz, Paul G.
  • Chemistry of Materials, Vol. 25, Issue 2
  • DOI: 10.1021/cm3027972

Finding the Way to Solar Fuels with Dye-Sensitized Photoelectrosynthesis Cells
journal, September 2016

  • Brennaman, M. Kyle; Dillon, Robert J.; Alibabaei, Leila
  • Journal of the American Chemical Society, Vol. 138, Issue 40
  • DOI: 10.1021/jacs.6b06466

Recent advances in dye-sensitized photoelectrochemical cells for solar hydrogen production based on molecular components
journal, January 2015

  • Yu, Ze; Li, Fei; Sun, Licheng
  • Energy & Environmental Science, Vol. 8, Issue 3
  • DOI: 10.1039/c4ee03565h

A robust ruthenium complex with nonyl-substituted bpy ligand for dye-sensitized photoelectrochemical cell application
journal, February 2018


Photoassisted Overall Water Splitting in a Visible Light-Absorbing Dye-Sensitized Photoelectrochemical Cell
journal, January 2009

  • Youngblood, W. Justin; Lee, Seung-Hyun Anna; Kobayashi, Yoji
  • Journal of the American Chemical Society, Vol. 131, Issue 3, p. 926-927
  • DOI: 10.1021/ja809108y

Immobilizing Ru(bda) Catalyst on a Photoanode via Electrochemical Polymerization for Light-Driven Water Splitting
journal, May 2015

  • Li, Fusheng; Fan, Ke; Wang, Lei
  • ACS Catalysis, Vol. 5, Issue 6
  • DOI: 10.1021/cs502115f

Dyad Sensitizer of Chlorophyll with Indoline Dye for Panchromatic Photocatalytic Hydrogen Evolution
journal, May 2018

  • Sun, Yuan; Sun, Yuliang; Dall’Agnese, Chunxiang
  • ACS Applied Energy Materials, Vol. 1, Issue 6
  • DOI: 10.1021/acsaem.8b00380

Two Electrode Collector–Generator Method for the Detection of Electrochemically or Photoelectrochemically Produced O 2
journal, July 2016

  • Sherman, Benjamin D.; Sheridan, Matthew V.; Dares, Christopher J.
  • Analytical Chemistry, Vol. 88, Issue 14
  • DOI: 10.1021/acs.analchem.6b00738

Chromophore-Catalyst Assembly for Water Oxidation Prepared by Atomic Layer Deposition
journal, October 2017

  • Alibabaei, Leila; Dillon, Robert J.; Reilly, Caroline E.
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 44
  • DOI: 10.1021/acsami.7b11905

A Dye-Sensitized Photoelectrochemical Tandem Cell for Light Driven Hydrogen Production from Water
journal, December 2016

  • Sherman, Benjamin D.; Sheridan, Matthew V.; Wee, Kyung-Ryang
  • Journal of the American Chemical Society, Vol. 138, Issue 51
  • DOI: 10.1021/jacs.6b10699

Platinum Terpyridine Metallopolymer Electrode as Cost-Effective Replacement for Bulk Platinum Catalysts in Oxygen Reduction Reaction and Hydrogen Evolution Reaction
journal, October 2017

  • Elmas, Sait; Beelders, Wesley; Bradley, Siobhan J.
  • ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 11
  • DOI: 10.1021/acssuschemeng.7b02198

Catalytic and Surface-Electrocatalytic Water Oxidation by Redox Mediator-Catalyst Assemblies
journal, November 2009

  • Concepcion, Javier J.; Jurss, Jonah W.; Hoertz, Paul G.
  • Angewandte Chemie International Edition, Vol. 48, Issue 50
  • DOI: 10.1002/anie.200901279

Electron Transfer Mediator Effects in Water Oxidation Catalysis by Solution and Surface-Bound Ruthenium Bpy-Dicarboxylate Complexes
journal, October 2015

  • Sheridan, Matthew V.; Sherman, Benjamin D.; Marquard, Seth L.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 45
  • DOI: 10.1021/acs.jpcc.5b08326

Visible Light Driven Water Splitting in a Molecular Device with Unprecedentedly High Photocurrent Density
journal, March 2013

  • Gao, Yan; Ding, Xin; Liu, Jianhui
  • Journal of the American Chemical Society, Vol. 135, Issue 11
  • DOI: 10.1021/ja400402d

Detection of a charge-separated catalyst precursor state in a linked photosensitizer-catalyst assembly
journal, January 2013

  • Mukherjee, Anusree; Kokhan, Oleksandr; Huang, Jier
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 48
  • DOI: 10.1039/c3cp54420f

Visible-Light-Driven Photocatalytic Water Oxidation by a π-Conjugated Donor–Acceptor–Donor Chromophore/Catalyst Assembly
journal, August 2018


Photocatalytic Hydrogen Production Using a Red-Absorbing Ir(III)–Co(III) Dyad
journal, May 2017


Ultrafast photodriven intramolecular electron transfer from an iridium-based water-oxidation catalyst to perylene diimide derivatives
journal, May 2012

  • Vagnini, M. T.; Smeigh, A. L.; Blakemore, J. D.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 39
  • DOI: 10.1073/pnas.1202075109

Fluorinated Zn II Porphyrins for Dye-Sensitized Aqueous Photoelectrosynthetic Cells
journal, August 2019

  • Orbelli Biroli, Alessio; Tessore, Francesca; Di Carlo, Gabriele
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 36
  • DOI: 10.1021/acsami.9b08042

Bias-free photoelectrochemical water splitting with photosystem II on a dye-sensitized photoanode wired to hydrogenase
journal, September 2018


Solar H 2 generation in water with a CuCrO 2 photocathode modified with an organic dye and molecular Ni catalyst
journal, January 2018

  • Creissen, Charles E.; Warnan, Julien; Reisner, Erwin
  • Chemical Science, Vol. 9, Issue 6
  • DOI: 10.1039/c7sc04476c

Visible photoelectrochemical water splitting into H 2 and O 2 in a dye-sensitized photoelectrosynthesis cell
journal, April 2015

  • Alibabaei, Leila; Sherman, Benjamin D.; Norris, Michael R.
  • Proceedings of the National Academy of Sciences, Vol. 112, Issue 19
  • DOI: 10.1073/pnas.1506111112

Photo-driven electron transfer from the highly reducing excited state of naphthalene diimide radical anion to a CO 2 reduction catalyst within a molecular triad
journal, January 2017

  • Martinez, Jose F.; La Porte, Nathan T.; Mauck, Catherine M.
  • Faraday Discussions, Vol. 198
  • DOI: 10.1039/c6fd00219f