Interface Engineered Room‐Temperature Ferromagnetic Insulating State in Ultrathin Manganite Films

doi:10.1002/advs.201901606

Title: Interface Engineered Room‐Temperature Ferromagnetic Insulating State in Ultrathin Manganite Films

Authors:

^[1]; Zhu, Bonan ^[1]; He, Qian ^[2]; Borisevich, Albina Y. ^[3]; Yun, Chao ^[1]; Wu, Rui ^[1]; Lu, Ping ^[4]; Qi, Zhimin ^[5]; Wang, Qiang ^[6]; Chen, Aiping ^[7]; Wang, Haiyan ^[5]; Cavill, Stuart A. ^[8]; Zhang, Kelvin H. L. ^[9]; MacManus‐Driscoll, Judith L. ^[1]

Department of Materials Science and MetallurgyUniversity of Cambridge 27 Charles Babbage Road Cambridge CB3 0FS UK
Cardiff Catalysis InstituteSchool of ChemistryCardiff University Main Building, Park Place Cardiff CF10 3AT UK
Center for Nanophase Materials SciencesOak Ridge National Laboratory Oak Ridge TN 37831 USA
Sandia National Laboratory Albuquerque NM 87185 USA
School of Materials EngineeringPurdue University West Lafayette IN 47907 USA
Department of Physics and AstronomyWest Virginia University Morgantown WV 26506 USA
Center for Integrated NanotechnologiesLos Alamos National Laboratory Los Alamos NM 87545 USA
Department of PhysicsUniversity of York York YO10 5DD UK, Diamond Light Source Didcot OX11 0DE UK
State Key Laboratory of Physical Chemistry of Solid SurfacesCollege of Chemistry and Chemical EngineeringXiamen University Xiamen 361005 China

Publication Date:: 2019-11-11

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI Identifier:: 1573844

Alternate Identifier(s):: OSTI ID: 1573845

Grant/Contract Number:: DE‐NA0003525; 89233218CNA000001

Resource Type:: Published Article

Journal Name:: Advanced Science

Additional Journal Information:: Journal Name: Advanced Science; Journal ID: ISSN 2198-3844

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Li, Weiwei, Zhu, Bonan, He, Qian, Borisevich, Albina Y., Yun, Chao, Wu, Rui, Lu, Ping, Qi, Zhimin, Wang, Qiang, Chen, Aiping, Wang, Haiyan, Cavill, Stuart A., Zhang, Kelvin H. L., and MacManus‐Driscoll, Judith L. Interface Engineered Room‐Temperature Ferromagnetic Insulating State in Ultrathin Manganite Films.  Germany: N. p., 2019. 
        Web.  doi:10.1002/advs.201901606.

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                    Li, Weiwei, Zhu, Bonan, He, Qian, Borisevich, Albina Y., Yun, Chao, Wu, Rui, Lu, Ping, Qi, Zhimin, Wang, Qiang, Chen, Aiping, Wang, Haiyan, Cavill, Stuart A., Zhang, Kelvin H. L., & MacManus‐Driscoll, Judith L. Interface Engineered Room‐Temperature Ferromagnetic Insulating State in Ultrathin Manganite Films.  Germany.  doi:10.1002/advs.201901606.

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                    Li, Weiwei, Zhu, Bonan, He, Qian, Borisevich, Albina Y., Yun, Chao, Wu, Rui, Lu, Ping, Qi, Zhimin, Wang, Qiang, Chen, Aiping, Wang, Haiyan, Cavill, Stuart A., Zhang, Kelvin H. L., and MacManus‐Driscoll, Judith L. Mon .  
        "Interface Engineered Room‐Temperature Ferromagnetic Insulating State in Ultrathin Manganite Films".  Germany.  doi:10.1002/advs.201901606.

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@article{osti_1573844,

  title        = {Interface Engineered Room‐Temperature Ferromagnetic Insulating State in Ultrathin Manganite Films},

  author       = {Li, Weiwei and Zhu, Bonan and He, Qian and Borisevich, Albina Y. and Yun, Chao and Wu, Rui and Lu, Ping and Qi, Zhimin and Wang, Qiang and Chen, Aiping and Wang, Haiyan and Cavill, Stuart A. and Zhang, Kelvin H. L. and MacManus‐Driscoll, Judith L.},

  abstractNote = {},

  doi          = {10.1002/advs.201901606},

  journal      = {Advanced Science},

  number       = ,

  volume       = ,

  place        = {Germany},

  year         = {2019},

  month        = {11}

}

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Title: Interface Engineered Room‐Temperature Ferromagnetic Insulating State in Ultrathin Manganite Films

Citation Formats

Generalized Gradient Approximation Made Simple journal, October 1996

Experimental Confirmation of the X-Ray Magnetic Circular Dichroism Sum Rules for Iron and Cobalt journal, July 1995

Control of octahedral rotations in (LaNiO 3 ) n /(SrMnO 3 ) m superlattices journal, April 2011

Structure and Properties of Functional Oxide Thin Films: Insights From Electronic-Structure Calculations journal, July 2011

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Surface symmetry-breaking and strain effects on orbital occupancy in transition metal perovskite epitaxial films journal, January 2012

Controlled-valence properties of La 1 − x Sr x FeO 3 and La 1 − x Sr x MnO 3 studied by soft-x-ray absorption spectroscopy journal, August 1992

Suppression of Octahedral Tilts and Associated Changes in Electronic Properties at Epitaxial Oxide Heterostructure Interfaces journal, August 2010

Controlled lateral anisotropy in correlated manganite heterostructures by interface-engineered oxygen octahedral coupling journal, March 2016

AiiDA: automated interactive infrastructure and database for computational science journal, January 2016

Strain effect and the phase diagram of La 1 − x Ba x MnO 3 thin films journal, October 2001

Tunnel junctions with multiferroic barriers journal, March 2007

Strain-induced high-temperature perovskite ferromagnetic insulator journal, March 2018

Density-functional theory and strong interactions: Orbital ordering in Mott-Hubbard insulators journal, August 1995

Spectral and Fermi surface properties from Wannier interpolation journal, May 2007

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Orbital Reconstruction and Covalent Bonding at an Oxide Interface journal, November 2007

Enhancement of Ferroelectricity in Strained BaTiO3 Thin Films journal, November 2004

Electron Accumulation and Emergent Magnetism in LaMnO 3 / SrTiO 3 Heterostructures journal, October 2017

High-Temperature Magnetic Insulating Phase in Ultrathin La 0.67 Sr 0.33 MnO 3 Films journal, October 2012

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In Vivo Biomolecule Corona around Blood-Circulating, Clinically Used and Antibody-Targeted Lipid Bilayer Nanoscale Vesicles journal, July 2015

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Spin filtering through ferrimagnetic NiFe2O4 tunnel barriers journal, February 2006

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Tuning Perpendicular Magnetic Anisotropy by Oxygen Octahedral Rotations in ( La 1 − x Sr x MnO 3 ) / ( SrIrO 3 ) Superlattices journal, August 2017

Titanium dx y ferromagnetism at the LaAlO3/SrTiO3 interface journal, June 2013

Magnetoresistance in Double Spin Filter Tunnel Junctions with Nonmagnetic Electrodes and its Unconventional Bias Dependence journal, February 2009

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Oxygen octahedron reconstruction in the SrTiO 3 / LaAlO 3 heterointerfaces investigated using aberration-corrected ultrahigh-resolution transmission electron microscopy journal, February 2009

Electronic band redistribution probed by oxygen absorption spectra of (SrMnO 3 ) n (LaMnO 3 ) 2 n superlattices journal, March 2012

Persistent optically induced magnetism in oxygen-deficient strontium titanate journal, March 2014

Oxygen-Vacancy-Induced Antiferromagnetism to Ferromagnetism Transformation in Eu0.5Ba0.5TiO3−δ Multiferroic Thin Films journal, September 2013

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Localized Control of Curie Temperature in Perovskite Oxide Film by Capping-Layer-Induced Octahedral Distortion journal, October 2017

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Origin of Interface Magnetism in BiMnO 3 / SrTiO 3 and LaAlO 3 / SrTiO 3 Heterostructures journal, August 2013

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Electron-Spin Polarization in Tunnel Junctions in Zero Applied Field with Ferromagnetic EuS Barriers journal, August 1988

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Electronic and Magnetic Reconstructions in La 0.7 Sr 0.3 MnO 3 / SrTiO 3 Heterostructures: A Case of Enhanced Interlayer Coupling Controlled by the Interface journal, April 2011

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Erratum: Evidence of Orbital Reconstruction at Interfaces in Ultrathin La 0.67 Sr 0.33 MnO 3 Films [Phys. Rev. Lett. 100 , 137401 (2008)] journal, August 2009

A high-mobility electron gas at the LaAlO3/SrTiO3 heterointerface journal, January 2004

Control of Octahedral Tilts and Magnetic Properties of Perovskite Oxide Heterostructures by Substrate Symmetry journal, November 2010

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Spatial control of functional properties via octahedral modulations in complex oxide superlattices journal, December 2014

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Orbital Reconstruction and Covalent Bonding at an Oxide Interface
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Enhancement of Ferroelectricity in Strained BaTiO₃ Thin Films
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Electron Accumulation and Emergent Magnetism in ${LaMnO}_{3} / {SrTiO}_{3}$ Heterostructures
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High-Temperature Magnetic Insulating Phase in Ultrathin ${La}_{0.67} {Sr}_{0.33} {MnO}_{3}$ Films
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Magnetic Properties at Surface Boundary of a Half-Metallic Ferromagnet ${La}_{0.7} {Sr}_{0.3} {MnO}_{3}$
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Room-temperature ferroelectricity in strained SrTiO₃
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Spin filtering through ferrimagnetic NiFe2O4 tunnel barriers
journal, February 2006

Thickness-dependent structural phase transition of strained SrRuO $_{3}$ ultrathin films: The role of octahedral tilt
journal, September 2011

Tuning Perpendicular Magnetic Anisotropy by Oxygen Octahedral Rotations in $({La}_{1 - x} {Sr}_{x} {MnO}_{3}) / ({SrIrO}_{3})$ Superlattices
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Titanium dx y ferromagnetism at the LaAlO3/SrTiO3 interface
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Magnetoresistance in Double Spin Filter Tunnel Junctions with Nonmagnetic Electrodes and its Unconventional Bias Dependence
journal, February 2009

Electronic structure of ${La}_{1 - x}$ ${Sr}_{x}$ ${MnO}_{3}$ studied by photoemission and x-ray-absorption spectroscopy
journal, May 1995

Oxygen octahedron reconstruction in the ${SrTiO}_{3} / {LaAlO}_{3}$ heterointerfaces investigated using aberration-corrected ultrahigh-resolution transmission electron microscopy
journal, February 2009

Electronic band redistribution probed by oxygen absorption spectra of (SrMnO $_{3}$ ) $_{n}$ (LaMnO $_{3}$ ) $_{2 n}$ superlattices
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Persistent optically induced magnetism in oxygen-deficient strontium titanate
journal, March 2014

Oxygen-Vacancy-Induced Antiferromagnetism to Ferromagnetism Transformation in Eu0.5Ba0.5TiO3−δ Multiferroic Thin Films
journal, September 2013

Large magnetoresistance using hybrid spin filter devices
journal, January 2002

Localized Control of Curie Temperature in Perovskite Oxide Film by Capping-Layer-Induced Octahedral Distortion
journal, October 2017

The magnetic, optical, and transport properties of representatives of a class of magnetic semiconductors: The europium chalcogenides
journal, August 1986

Origin of Interface Magnetism in ${BiMnO}_{3} / {SrTiO}_{3}$ and ${LaAlO}_{3} / {SrTiO}_{3}$ Heterostructures
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Tuning the Structure of Nickelates to Achieve Two-Dimensional Electron Conduction
journal, February 2014

Electron-Spin Polarization in Tunnel Junctions in Zero Applied Field with Ferromagnetic EuS Barriers
journal, August 1988

OptaDOS: A tool for obtaining density of states, core-level and optical spectra from electronic structure codes
journal, May 2014

The physics of manganites: Structure and transport
journal, August 2001

Synthesis and properties of the vacancy-free ${La}_{1 - x} {Ba}_{x} {MnO}_{3}$
journal, August 1998

Electronic and Magnetic Reconstructions in ${La}_{0.7} {Sr}_{0.3} {MnO}_{3} / {SrTiO}_{3}$ Heterostructures: A Case of Enhanced Interlayer Coupling Controlled by the Interface
journal, April 2011

The classification of tilted octahedra in perovskites
journal, November 1972

Erratum: Evidence of Orbital Reconstruction at Interfaces in Ultrathin ${La}_{0.67} {Sr}_{0.33} {MnO}_{3}$ Films [Phys. Rev. Lett. 100 , 137401 (2008)]
journal, August 2009

A high-mobility electron gas at the LaAlO3/SrTiO3 heterointerface
journal, January 2004

Control of Octahedral Tilts and Magnetic Properties of Perovskite Oxide Heterostructures by Substrate Symmetry
journal, November 2010

Competing Pathways for Nucleation of the Double Perovskite Structure in the Epitaxial Synthesis of La ₂ MnNiO ₆
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First principles methods using CASTEP
journal, January 2005

Spatial control of functional properties via octahedral modulations in complex oxide superlattices
journal, December 2014

Dimensionality-Driven Metal-Insulator Transition in Spin-Orbit-Coupled ${SrIrO}_{3}$
journal, December 2017

Dimensional-Crossover-Driven Metal-Insulator Transition in ${SrVO}_{3}$ Ultrathin Films
journal, April 2010