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Title: Smectic and nematic phase modulations and transitions under electron beam in Tb 2 Cu 0.83 Pd 0.17 O 4

Abstract

Understanding the structural origin of the functionality in cuprates has attracted tremendous attention over several decades. In particular, probing distortions in the Cu- O bonding is of great importance for exploring the coupling between the charge and the lattice, a key mechanism for superconductivity and other functionality in correlated materials. Here we study a superlattice modulation in the Tb 2Cu 0.83Pd 0.17O 4 “214” material, which possesses no superconductivity itself but has the parent structure of the R 2CuO 4 (R = a rare earth element) superconducting cuprate group. Using transmission electron microscopy (TEM), we find that this superlattice modulation is formed by Cu ion displacements in a direction perpendicular to the Cu-O planes. The superlattice modulation undergoes a reversible electronic smectic-nematic phase transition under electron-beam illumination. With the help of in situ TEM results, our findings imply that the superlattice modulation in this material arises from spatially modulated charge ordering at the Cu sites.

Authors:
 [1];  [2];  [3];  [3];  [4];  [4];  [5]; ORCiD logo [4]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States); Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Chinese Academy of Sciences (CAS), Beijing (China)
  2. Univ. of Michigan, Ann Arbor, MI (United States)
  3. Princeton Univ., NJ (United States)
  4. Brookhaven National Lab. (BNL), Upton, NY (United States)
  5. Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Chinese Academy of Sciences (CAS), Beijing (China)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1573476
Report Number(s):
BNL-212306-2019-JAAM
Journal ID: ISSN 2475-9953; PRMHAR
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review Materials
Additional Journal Information:
Journal Volume: 3; Journal Issue: 9; Journal ID: ISSN 2475-9953
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats

Wang, Wei, Sun, Kai, Oey, Yuzki M., Cava, Robert J., Wu, Lijun, Zhu, Yimei, Yu, Richeng, and Tao, Jing. Smectic and nematic phase modulations and transitions under electron beam in Tb2Cu0.83Pd0.17O4. United States: N. p., 2019. Web. doi:10.1103/PhysRevMaterials.3.093601.
Wang, Wei, Sun, Kai, Oey, Yuzki M., Cava, Robert J., Wu, Lijun, Zhu, Yimei, Yu, Richeng, & Tao, Jing. Smectic and nematic phase modulations and transitions under electron beam in Tb2Cu0.83Pd0.17O4. United States. doi:10.1103/PhysRevMaterials.3.093601.
Wang, Wei, Sun, Kai, Oey, Yuzki M., Cava, Robert J., Wu, Lijun, Zhu, Yimei, Yu, Richeng, and Tao, Jing. Thu . "Smectic and nematic phase modulations and transitions under electron beam in Tb2Cu0.83Pd0.17O4". United States. doi:10.1103/PhysRevMaterials.3.093601.
@article{osti_1573476,
title = {Smectic and nematic phase modulations and transitions under electron beam in Tb2Cu0.83Pd0.17O4},
author = {Wang, Wei and Sun, Kai and Oey, Yuzki M. and Cava, Robert J. and Wu, Lijun and Zhu, Yimei and Yu, Richeng and Tao, Jing},
abstractNote = {Understanding the structural origin of the functionality in cuprates has attracted tremendous attention over several decades. In particular, probing distortions in the Cu- O bonding is of great importance for exploring the coupling between the charge and the lattice, a key mechanism for superconductivity and other functionality in correlated materials. Here we study a superlattice modulation in the Tb2Cu0.83Pd0.17O4 “214” material, which possesses no superconductivity itself but has the parent structure of the R2CuO4 (R = a rare earth element) superconducting cuprate group. Using transmission electron microscopy (TEM), we find that this superlattice modulation is formed by Cu ion displacements in a direction perpendicular to the Cu-O planes. The superlattice modulation undergoes a reversible electronic smectic-nematic phase transition under electron-beam illumination. With the help of in situ TEM results, our findings imply that the superlattice modulation in this material arises from spatially modulated charge ordering at the Cu sites.},
doi = {10.1103/PhysRevMaterials.3.093601},
journal = {Physical Review Materials},
number = 9,
volume = 3,
place = {United States},
year = {2019},
month = {9}
}

Journal Article:
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Works referenced in this record:

The Resonating Valence Bond State in La2CuO4 and Superconductivity
journal, March 1987


Electron-Doped High T c Superconductors
journal, June 1990


Electron–phonon coupling reflecting dynamic charge inhomogeneity in copper oxide superconductors
journal, April 2006


Extended Superconducting Concentration Range Observed in Pr 2 x Ce x CuO 4 δ
journal, June 1995


Incommensurate Spin Fluctuations in High-Transition Temperature Superconductors
journal, August 1997


Neutron-scattering study of spin-density wave order in the superconducting state of excess-oxygen-doped La 2 CuO 4 + y
journal, August 1999


Superconductivity phase diagrams for the electron-doped cuprates R 2 x Ce x Cu O 4 ( R = La , Pr, Nd, Sm, and Eu)
journal, February 2008


Different roles of cerium substitution and oxygen reduction in transport in Pr 2 x Ce x CuO 4 thin films
journal, January 2007


Synthesis and properties of superconducting T R 2 CuO 4 ( R = Pr , Nd, Sm, Eu, Gd)
journal, March 2009


High pressure synthesis and structural study of R2CuO4 compounds with R = Y, Tb, Dy, Ho, Er, Tm
journal, April 1992

  • Bordet, P.; Capponi, J. J.; Chaillout, C.
  • Physica C: Superconductivity and its Applications, Vol. 193, Issue 1-2
  • DOI: 10.1016/0921-4534(92)90885-G

Weak ferromagnetism and spin‐glass‐like behavior in Tb 2 CuO 4
journal, November 1991

  • Tovar, M.; Obradors, X.; Pérez, F.
  • Journal of Applied Physics, Vol. 70, Issue 10
  • DOI: 10.1063/1.350057

Weak ferromagnetism and spin-glass-like behavior in the rare-earth cuprates R 2 CuO 4 ( R =Tb, Dy, Ho, Er, Tm, and Y)
journal, March 1992


Relaxation of dc magnetization in Gd2CuO4
journal, September 1994


A superconducting copper oxide compound with electrons as the charge carriers
journal, January 1989

  • Tokura, Y.; Takagi, H.; Uchida, S.
  • Nature, Vol. 337, Issue 6205
  • DOI: 10.1038/337345a0

Structural stability and doping in R2CuO4 (R = rare-earth)
journal, February 1990


Crystal structure and high-field magnetism of La 2 Cu O 4
journal, April 2006


Unusually simple crystal structure of an Nd–Ce–Sr–Cu–O superconductor
journal, January 1989

  • Sawa, Hiroshi; Suzuki, Seiichiro; Watanabe, Masaru
  • Nature, Vol. 337, Issue 6205
  • DOI: 10.1038/337347a0

Correlation between weak ferromagnetism and crystal symmetry in Gd 2 CuO 4 -type cuprates
journal, November 1999


Direct role of structural dynamics in electron-lattice coupling of superconducting cuprates
journal, December 2008

  • Carbone, F.; Yang, D. -S.; Giannini, E.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 51
  • DOI: 10.1073/pnas.0811335106

Interplay of electron–lattice interactions and superconductivity in Bi2Sr2CaCu2O8+δ
journal, August 2006


Electron-phonon coupling and d -wave superconductivity in the cuprates
journal, February 1995


High pressure synthesis and structural study of R2CUO4 compounds with R=Y,TB,DY,HO,ER,TM
journal, December 1991


Stabilizing the Tb-based 214 cuprate by partial Pd substitution
journal, May 2018

  • Oey, Yuzki M.; Park, James Eujin; Tao, Jing
  • Journal of Materials Research, Vol. 33, Issue 11
  • DOI: 10.1557/jmr.2018.102

Neutron and electron diffraction study of the electron-doped superconductor Nd1.845Ce0.155CuO4 − y
journal, May 1989


Superlattice modulation and superconductivity in the electron-doped Nd2CuO4−xFx and Nd2−xCexCuO4 systems
journal, September 1989


Probing optically silent superfluid stripes in cuprates
journal, February 2018


Evidence for stripe correlations of spins and holes in copper oxide superconductors
journal, June 1995

  • Tranquada, J. M.; Sternlieb, B. J.; Axe, J. D.
  • Nature, Vol. 375, Issue 6532
  • DOI: 10.1038/375561a0

Bond-Stretching-Phonon Anomalies in Stripe-Ordered La 1.69 Sr 0.31 NiO 4
journal, January 2002


Direct observation of electronic-liquid-crystal phase transitions and their microscopic origin in La1/3Ca2/3MnO3
journal, November 2016

  • Tao, J.; Sun, K.; Yin, W. -G.
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep37624

Electronic Liquid Crystal State in the High-Temperature Superconductor YBa2Cu3O6.45
journal, January 2008


Electrical Resistivity Anisotropy from Self-Organized One Dimensionality in High-Temperature Superconductors
journal, March 2002


Topological Defects Coupling Smectic Modulations to Intra-Unit-Cell Nematicity in Cuprates
journal, July 2011


Mixed Lattice and Electronic States in High-Temperature Superconductors
journal, July 2001


Electron-Phonon Renormalization in Cuprate Superconductors
journal, February 2007


Interplay of electron-phonon interaction and electron correlation in high-temperature superconductivity
journal, April 2004


Strong Coupling of a Spin Ensemble to a Superconducting Resonator
journal, September 2010


Effective ionic radii in oxides and fluorides
journal, May 1969

  • Shannon, R. D.; Prewitt, C. T.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 25, Issue 5
  • DOI: 10.1107/S0567740869003220

Orbital character of states at the Fermi level in La 2 x Sr x CuO 4 and R 2 x Ce x CuO 4 ( R =Nd,Sm)
journal, February 1993


Control of radiation damage in the TEM
journal, April 2013


Radiation damage in the TEM and SEM
journal, August 2004


Reversible structure manipulation by tuning carrier concentration in metastable Cu 2 S
journal, August 2017

  • Tao, Jing; Chen, Jingyi; Li, Jun
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 37
  • DOI: 10.1073/pnas.1709163114

Quenched disorder and vestigial nematicity in the pseudogap regime of the cuprates
journal, May 2014

  • Nie, L.; Tarjus, G.; Kivelson, S. A.
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 22
  • DOI: 10.1073/pnas.1406019111