Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes

doi:10.1039/C9CC08006F

Title: Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes

Abstract

The diverse gas-phase reactivity of [LnO ₂ (NO ₃ ) ₂ ] ⁻ complexes with water (Ln = Ce, Pr, Nd), examined in a quadrupole ion trap and complemented by ab initio computations, illuminates the chemical stability of Pr in the unusual +5 oxidation state.

Authors:

^[1];

^[2];

^[1];

^[3];

^[1]

Centro de Ciências e Tecnologias Nucleares and Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, 2695-066 Bobadela, Portugal
BioISI and Centro de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, 1749-016 Lisboa, Portugal
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA

Publication Date:: 2019-11-21

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1573425

Grant/Contract Number:: AC02-05CH1123

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Name: ChemComm Journal Volume: 55 Journal Issue: 94; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Monteiro, Bernardo, Bandeira, Nuno A. G., Lourenço, Célia, Lucena, Ana F., Carretas, José M., Gibson, John K., and Marçalo, Joaquim. Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes.  United Kingdom: N. p., 2019. 
        Web.  doi:10.1039/C9CC08006F.

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                    Monteiro, Bernardo, Bandeira, Nuno A. G., Lourenço, Célia, Lucena, Ana F., Carretas, José M., Gibson, John K., & Marçalo, Joaquim. Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes.  United Kingdom.  doi:10.1039/C9CC08006F.

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                    Monteiro, Bernardo, Bandeira, Nuno A. G., Lourenço, Célia, Lucena, Ana F., Carretas, José M., Gibson, John K., and Marçalo, Joaquim. Thu .  
        "Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes".  United Kingdom.  doi:10.1039/C9CC08006F.

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@article{osti_1573425,

  title        = {Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes},

  author       = {Monteiro, Bernardo and Bandeira, Nuno A. G. and Lourenço, Célia and Lucena, Ana F. and Carretas, José M. and Gibson, John K. and Marçalo, Joaquim},

  abstractNote = {The diverse gas-phase reactivity of [LnO 2 (NO 3 ) 2 ] − complexes with water (Ln = Ce, Pr, Nd), examined in a quadrupole ion trap and complemented by ab initio computations, illuminates the chemical stability of Pr in the unusual +5 oxidation state.},

  doi          = {10.1039/C9CC08006F},

  journal      = {ChemComm},

  number       = 94,

  volume       = 55,

  place        = {United Kingdom},

  year         = {2019},

  month        = {11}

}

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DOI: 10.1039/C9CC08006F

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Similar Records

Title: Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes

Abstract

Citation Formats

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