Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes

Monteiro, Bernardo; Bandeira, Nuno A. G.; Lourenço, Célia; Lucena, Ana F.; Carretas, José M.; Gibson, John K.; Marçalo, Joaquim

doi:10.1039/C9CC08006F

Title: Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes

Abstract

The diverse gas-phase reactivity of [LnO ₂ (NO ₃ ) ₂ ] ⁻ complexes with water (Ln = Ce, Pr, Nd), examined in a quadrupole ion trap and complemented by ab initio computations, illuminates the chemical stability of Pr in the unusual +5 oxidation state.

Authors:

^[1];

^[2];

^[1];

^[3];

^[1]

Centro de Ciências e Tecnologias Nucleares and Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, 2695-066 Bobadela, Portugal
BioISI and Centro de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, 1749-016 Lisboa, Portugal
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA

Publication Date:: 2019-11-21

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1573425

Grant/Contract Number:: AC02-05CH1123

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Name: ChemComm Journal Volume: 55 Journal Issue: 94; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Monteiro, Bernardo, Bandeira, Nuno A. G., Lourenço, Célia, Lucena, Ana F., Carretas, José M., Gibson, John K., and Marçalo, Joaquim. Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C9CC08006F.

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                    Monteiro, Bernardo, Bandeira, Nuno A. G., Lourenço, Célia, Lucena, Ana F., Carretas, José M., Gibson, John K., & Marçalo, Joaquim. Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes.  United Kingdom.  https://doi.org/10.1039/C9CC08006F

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                    Monteiro, Bernardo, Bandeira, Nuno A. G., Lourenço, Célia, Lucena, Ana F., Carretas, José M., Gibson, John K., and Marçalo, Joaquim. Thu .  
"Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes".  United Kingdom.  https://doi.org/10.1039/C9CC08006F.

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@article{osti_1573425,

  title        = {Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes},

  author       = {Monteiro, Bernardo and Bandeira, Nuno A. G. and Lourenço, Célia and Lucena, Ana F. and Carretas, José M. and Gibson, John K. and Marçalo, Joaquim},

  abstractNote = {The diverse gas-phase reactivity of [LnO 2 (NO 3 ) 2 ] − complexes with water (Ln = Ce, Pr, Nd), examined in a quadrupole ion trap and complemented by ab initio computations, illuminates the chemical stability of Pr in the unusual +5 oxidation state.},

  doi          = {10.1039/C9CC08006F},

  journal      = {ChemComm},

  number       = 94,

  volume       = 55,

  place        = {United Kingdom},

  year         = {2019},

  month        = {11}

}

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Works referenced in this record:

The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis
journal, February 2014

Piro, Nicholas A.; Robinson, Jerome R.; Walsh, Patrick J.
Coordination Chemistry Reviews, Vol. 260
DOI: 10.1016/j.ccr.2013.08.034

The CeO ₂ ⁺ Cation: Gas-Phase Reactivity and Electronic Structure
journal, January 1996

Heinemann, Christoph; Cornehl, Hans H.; Schröder, Detlef
Inorganic Chemistry, Vol. 35, Issue 9
DOI: 10.1021/ic951322k

On the Upper Limits of Oxidation States in Chemistry
journal, February 2018

Hu, Shu-Xian; Li, Wan-Lu; Lu, Jun-Bo
Angewandte Chemie International Edition, Vol. 57, Issue 12
DOI: 10.1002/anie.201711450

Remarkably High Stability of Late Actinide Dioxide Cations: Extending Chemistry to Pentavalent Berkelium and Californium
journal, November 2017

Dau, Phuong D.; Vasiliu, Monica; Peterson, Kirk A.
Chemistry - A European Journal, Vol. 23, Issue 68
DOI: 10.1002/chem.201704193

Nitrogen dioxide reactions with atomic lanthanide cations and their monoxides: gas-phase kinetics at room temperature
journal, January 2010

Jarvis, Michael J. Y.; Blagojevic, Voislav; Koyanagi, Gregory K.
Physical Chemistry Chemical Physics, Vol. 12, Issue 18
DOI: 10.1039/b925576a

Sparse maps—A systematic infrastructure for reduced-scaling electronic structure methods. II. Linear scaling domain based pair natural orbital coupled cluster theory
journal, January 2016

Riplinger, Christoph; Pinski, Peter; Becker, Ute
The Journal of Chemical Physics, Vol. 144, Issue 2
DOI: 10.1063/1.4939030

Pentavalent Curium, Berkelium, and Californium in Nitrate Complexes: Extending Actinide Chemistry and Oxidation States
journal, July 2018

Kovács, Attila; Dau, Phuong D.; Marçalo, Joaquim
Inorganic Chemistry, Vol. 57, Issue 15
DOI: 10.1021/acs.inorgchem.8b01450

The difficult search for organocerium( iv ) compounds
journal, January 2017

Anwander, Reiner; Dolg, Michael; Edelmann, Frank T.
Chemical Society Reviews, Vol. 46, Issue 22
DOI: 10.1039/C7CS00147A

The 3D quadrupole ion trap mass spectrometer as a complete chemical laboratory for fundamental gas-phase studies of metal mediated chemistry
journal, January 2006

O'Hair, Richard A. J.
Chemical Communications, Issue 14
DOI: 10.1039/b516348j

Synthesis and hydrolysis of gas-phase lanthanide and actinide oxide nitrate complexes: a correspondence to trivalent metal ion redox potentials and ionization energies
journal, January 2015

Lucena, Ana F.; Lourenço, Célia; Michelini, Maria C.
Physical Chemistry Chemical Physics, Vol. 17, Issue 15
DOI: 10.1039/C5CP00515A

Oxidation State 10 Exists
journal, June 2016

Yu, Haoyu S.; Truhlar, Donald G.
Angewandte Chemie International Edition, Vol. 55, Issue 31
DOI: 10.1002/anie.201604670

Pentavalent lanthanide nitride-oxides: NPrO and NPrO ⁻ complexes with NPr triple bonds
journal, January 2017

Hu, Shu-Xian; Jian, Jiwen; Su, Jing
Chemical Science, Vol. 8, Issue 5
DOI: 10.1039/C7SC00710H

Pentavalent Lanthanide Compounds: Formation and Characterization of Praseodymium(V) Oxides
journal, April 2016

Zhang, Qingnan; Hu, Shu-Xian; Qu, Hui
Angewandte Chemie International Edition, Vol. 55, Issue 24
DOI: 10.1002/anie.201602196

Identification of an iridium-containing compound with a formal oxidation state of IX
journal, October 2014

Wang, Guanjun; Zhou, Mingfei; Goettel, James T.
Nature, Vol. 514, Issue 7523
DOI: 10.1038/nature13795

Molecular Complex of Tb in the +4 Oxidation State
journal, June 2019

Palumbo, Chad T.; Zivkovic, Ivica; Scopelliti, Rosario
Journal of the American Chemical Society, Vol. 141, Issue 25
DOI: 10.1021/jacs.9b05337

Design, Isolation, and Spectroscopic Analysis of a Tetravalent Terbium Complex
journal, July 2019

Rice, Natalie T.; Popov, Ivan A.; Russo, Dominic R.
Journal of the American Chemical Society, Vol. 141, Issue 33
DOI: 10.1021/jacs.9b06622

Managing the Computational Chemistry Big Data Problem: The ioChem-BD Platform
journal, December 2014

Álvarez-Moreno, M.; de Graaf, C.; López, N.
Journal of Chemical Information and Modeling, Vol. 55, Issue 1
DOI: 10.1021/ci500593j

Recent advances in the coordination chemistry of cerium(IV) complexes
journal, June 2017

So, Yat-Ming; Leung, Wa-Hung
Coordination Chemistry Reviews, Vol. 340
DOI: 10.1016/j.ccr.2016.12.009

An efficient and near linear scaling pair natural orbital based local coupled cluster method
journal, January 2013

Riplinger, Christoph; Neese, Frank
The Journal of Chemical Physics, Vol. 138, Issue 3
DOI: 10.1063/1.4773581

Thermal genesis course and characterization of praseodymium oxide from praseodymium nitrate hydrate
journal, March 2001

Hussein, G. A. M.; Balboul, B. A. A.; A-Warith, M. A.
Thermochimica Acta, Vol. 369, Issue 1-2
DOI: 10.1016/S0040-6031(00)00727-9

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Title: Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes

Abstract

Citation Formats

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