Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes

doi:10.1039/C9CC08006F

This content will become publicly available on November 1, 2020

Title: Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes

Abstract

The diverse gas-phase reactivity of [LnO ₂ (NO ₃ ) ₂ ] ⁻ complexes with water (Ln = Ce, Pr, Nd), examined in a quadrupole ion trap and complemented by ab initio computations, illuminates the chemical stability of Pr in the unusual +5 oxidation state.

Authors:

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^[3];

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Centro de Ciências e Tecnologias Nucleares and Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, 2695-066 Bobadela, Portugal
BioISI and Centro de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, 1749-016 Lisboa, Portugal
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA

Publication Date:: 2019-11-21

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI Identifier:: 1573425

Grant/Contract Number:: AC02-05CH1123

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Name: ChemComm Journal Volume: 55 Journal Issue: 94; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Monteiro, Bernardo, Bandeira, Nuno A. G., Lourenço, Célia, Lucena, Ana F., Carretas, José M., Gibson, John K., and Marçalo, Joaquim. Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes.  United Kingdom: N. p., 2019. 
        Web.  doi:10.1039/C9CC08006F.

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                    Monteiro, Bernardo, Bandeira, Nuno A. G., Lourenço, Célia, Lucena, Ana F., Carretas, José M., Gibson, John K., & Marçalo, Joaquim. Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes.  United Kingdom.  doi:10.1039/C9CC08006F.

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                    Monteiro, Bernardo, Bandeira, Nuno A. G., Lourenço, Célia, Lucena, Ana F., Carretas, José M., Gibson, John K., and Marçalo, Joaquim. Thu .  
        "Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes".  United Kingdom.  doi:10.1039/C9CC08006F.

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@article{osti_1573425,

  title        = {Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes},

  author       = {Monteiro, Bernardo and Bandeira, Nuno A. G. and Lourenço, Célia and Lucena, Ana F. and Carretas, José M. and Gibson, John K. and Marçalo, Joaquim},

  abstractNote = {The diverse gas-phase reactivity of [LnO 2 (NO 3 ) 2 ] − complexes with water (Ln = Ce, Pr, Nd), examined in a quadrupole ion trap and complemented by ab initio computations, illuminates the chemical stability of Pr in the unusual +5 oxidation state.},

  doi          = {10.1039/C9CC08006F},

  journal      = {ChemComm},

  number       = 94,

  volume       = 55,

  place        = {United Kingdom},

  year         = {2019},

  month        = {11}

}

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Similar Records

This content will become publicly available on November 1, 2020

Title: Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes

Abstract

Citation Formats

The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis journal, February 2014

The CeO 2 + Cation: Gas-Phase Reactivity and Electronic Structure journal, January 1996

On the Upper Limits of Oxidation States in Chemistry journal, February 2018

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Nitrogen dioxide reactions with atomic lanthanide cations and their monoxides: gas-phase kinetics at room temperature journal, January 2010

Sparse maps—A systematic infrastructure for reduced-scaling electronic structure methods. II. Linear scaling domain based pair natural orbital coupled cluster theory journal, January 2016

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The difficult search for organocerium( iv ) compounds journal, January 2017

The 3D quadrupole ion trap mass spectrometer as a complete chemical laboratory for fundamental gas-phase studies of metal mediated chemistry journal, January 2006

Synthesis and hydrolysis of gas-phase lanthanide and actinide oxide nitrate complexes: a correspondence to trivalent metal ion redox potentials and ionization energies journal, January 2015

Oxidation State 10 Exists journal, June 2016

Pentavalent lanthanide nitride-oxides: NPrO and NPrO − complexes with NPr triple bonds journal, January 2017

Pentavalent Lanthanide Compounds: Formation and Characterization of Praseodymium(V) Oxides journal, April 2016

Identification of an iridium-containing compound with a formal oxidation state of IX journal, October 2014

Molecular Complex of Tb in the +4 Oxidation State journal, June 2019

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Recent advances in the coordination chemistry of cerium(IV) complexes journal, June 2017

An efficient and near linear scaling pair natural orbital based local coupled cluster method journal, January 2013

Thermal genesis course and characterization of praseodymium oxide from praseodymium nitrate hydrate journal, March 2001

The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis
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The CeO ₂ ⁺ Cation: Gas-Phase Reactivity and Electronic Structure
journal, January 1996

On the Upper Limits of Oxidation States in Chemistry
journal, February 2018

Remarkably High Stability of Late Actinide Dioxide Cations: Extending Chemistry to Pentavalent Berkelium and Californium
journal, November 2017

Nitrogen dioxide reactions with atomic lanthanide cations and their monoxides: gas-phase kinetics at room temperature
journal, January 2010

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journal, January 2016

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journal, July 2018

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journal, January 2017

The 3D quadrupole ion trap mass spectrometer as a complete chemical laboratory for fundamental gas-phase studies of metal mediated chemistry
journal, January 2006

Synthesis and hydrolysis of gas-phase lanthanide and actinide oxide nitrate complexes: a correspondence to trivalent metal ion redox potentials and ionization energies
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Pentavalent lanthanide nitride-oxides: NPrO and NPrO ⁻ complexes with NPr triple bonds
journal, January 2017

Pentavalent Lanthanide Compounds: Formation and Characterization of Praseodymium(V) Oxides
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