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Title: Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes

Abstract

The diverse gas-phase reactivity of [LnO 2 (NO 3 ) 2 ] complexes with water (Ln = Ce, Pr, Nd), examined in a quadrupole ion trap and complemented by ab initio computations, illuminates the chemical stability of Pr in the unusual +5 oxidation state.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [3]; ORCiD logo [1]
  1. Centro de Ciências e Tecnologias Nucleares and Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, 2695-066 Bobadela, Portugal
  2. BioISI and Centro de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, 1749-016 Lisboa, Portugal
  3. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1573425
Grant/Contract Number:  
AC02-05CH1123
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 55 Journal Issue: 94; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Monteiro, Bernardo, Bandeira, Nuno A. G., Lourenço, Célia, Lucena, Ana F., Carretas, José M., Gibson, John K., and Marçalo, Joaquim. Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes. United Kingdom: N. p., 2019. Web. doi:10.1039/C9CC08006F.
Monteiro, Bernardo, Bandeira, Nuno A. G., Lourenço, Célia, Lucena, Ana F., Carretas, José M., Gibson, John K., & Marçalo, Joaquim. Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes. United Kingdom. doi:10.1039/C9CC08006F.
Monteiro, Bernardo, Bandeira, Nuno A. G., Lourenço, Célia, Lucena, Ana F., Carretas, José M., Gibson, John K., and Marçalo, Joaquim. Thu . "Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes". United Kingdom. doi:10.1039/C9CC08006F.
@article{osti_1573425,
title = {Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes},
author = {Monteiro, Bernardo and Bandeira, Nuno A. G. and Lourenço, Célia and Lucena, Ana F. and Carretas, José M. and Gibson, John K. and Marçalo, Joaquim},
abstractNote = {The diverse gas-phase reactivity of [LnO 2 (NO 3 ) 2 ] − complexes with water (Ln = Ce, Pr, Nd), examined in a quadrupole ion trap and complemented by ab initio computations, illuminates the chemical stability of Pr in the unusual +5 oxidation state.},
doi = {10.1039/C9CC08006F},
journal = {ChemComm},
number = 94,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {11}
}

Journal Article:
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