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Title: Supermetal: SbF 5 -mediated methane oxidation occurs by C–H activation and isobutane oxidation occurs by hydride transfer

Abstract

Sb V F 5 is generally assumed to oxidize methane through a methanium-to-methyl cation mechanism.

Authors:
 [1];  [1];  [1];  [1];  [1];  [2];  [3]; ORCiD logo [1]
  1. Department of Chemistry and Biochemistry, Brigham Young University, Provo, USA
  2. Hyconix, Inc., Warrenville, USA
  3. Department of Chemistry, The Scripps Research Institute, Jupiter, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1573289
Grant/Contract Number:  
SC0018329
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 48 Journal Issue: 45; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

King, Clinton R., Holdaway, Ashley, Durrant, George, Wheeler, Josh, Suaava, Lorna, Konnick, Michael M., Periana, Roy A., and Ess, Daniel H. Supermetal: SbF 5 -mediated methane oxidation occurs by C–H activation and isobutane oxidation occurs by hydride transfer. United Kingdom: N. p., 2019. Web. doi:10.1039/C9DT03564H.
King, Clinton R., Holdaway, Ashley, Durrant, George, Wheeler, Josh, Suaava, Lorna, Konnick, Michael M., Periana, Roy A., & Ess, Daniel H. Supermetal: SbF 5 -mediated methane oxidation occurs by C–H activation and isobutane oxidation occurs by hydride transfer. United Kingdom. doi:10.1039/C9DT03564H.
King, Clinton R., Holdaway, Ashley, Durrant, George, Wheeler, Josh, Suaava, Lorna, Konnick, Michael M., Periana, Roy A., and Ess, Daniel H. Tue . "Supermetal: SbF 5 -mediated methane oxidation occurs by C–H activation and isobutane oxidation occurs by hydride transfer". United Kingdom. doi:10.1039/C9DT03564H.
@article{osti_1573289,
title = {Supermetal: SbF 5 -mediated methane oxidation occurs by C–H activation and isobutane oxidation occurs by hydride transfer},
author = {King, Clinton R. and Holdaway, Ashley and Durrant, George and Wheeler, Josh and Suaava, Lorna and Konnick, Michael M. and Periana, Roy A. and Ess, Daniel H.},
abstractNote = {Sb V F 5 is generally assumed to oxidize methane through a methanium-to-methyl cation mechanism.},
doi = {10.1039/C9DT03564H},
journal = {Dalton Transactions},
number = 45,
volume = 48,
place = {United Kingdom},
year = {2019},
month = {11}
}

Journal Article:
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Works referenced in this record:

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