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Triple hydrogen atom abstraction from Mn–NH 3 complexes results in cyclophosphazenium cations
Abstract
All three H atoms of the NH 3 ligand of [Mn(depe) 2 (CO)(NH 3 )] + are abstracted by an organic radical, giving a rare cyclophosphazenium cation; computations suggest that insertion of NH x into a Mn–P bond provides a strong thermodynamic driving force.
- Authors:
-
[1];
[2];
[1]
- Center for Molecular Electrocatalysis, Pacific Northwest National Laboratory P.O. Box 999, Richland, USA
- Department of Chemistry, University of Washington, Seattle, USA
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- OSTI Identifier:
- 1573275
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Name: ChemComm Journal Volume: 55 Journal Issue: 93; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Cook, Brian J., Johnson, Samantha I., Chambers, Geoffrey M., Kaminsky, Werner, and Bullock, R. Morris. Triple hydrogen atom abstraction from Mn–NH 3 complexes results in cyclophosphazenium cations. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9CC06915A.
Cook, Brian J., Johnson, Samantha I., Chambers, Geoffrey M., Kaminsky, Werner, & Bullock, R. Morris. Triple hydrogen atom abstraction from Mn–NH 3 complexes results in cyclophosphazenium cations. United Kingdom. doi:10.1039/C9CC06915A.
Cook, Brian J., Johnson, Samantha I., Chambers, Geoffrey M., Kaminsky, Werner, and Bullock, R. Morris. Tue .
"Triple hydrogen atom abstraction from Mn–NH 3 complexes results in cyclophosphazenium cations". United Kingdom. doi:10.1039/C9CC06915A.
@article{osti_1573275,
title = {Triple hydrogen atom abstraction from Mn–NH 3 complexes results in cyclophosphazenium cations},
author = {Cook, Brian J. and Johnson, Samantha I. and Chambers, Geoffrey M. and Kaminsky, Werner and Bullock, R. Morris},
abstractNote = {All three H atoms of the NH 3 ligand of [Mn(depe) 2 (CO)(NH 3 )] + are abstracted by an organic radical, giving a rare cyclophosphazenium cation; computations suggest that insertion of NH x into a Mn–P bond provides a strong thermodynamic driving force.},
doi = {10.1039/C9CC06915A},
journal = {ChemComm},
number = 93,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {11}
}
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DOI: 10.1039/C9CC06915A
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