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Title: Triple hydrogen atom abstraction from Mn–NH 3 complexes results in cyclophosphazenium cations

Abstract

All three H atoms of the NH 3 ligand of [Mn(depe) 2 (CO)(NH 3 )] + are abstracted by an organic radical, giving a rare cyclophosphazenium cation; computations suggest that insertion of NH x into a Mn–P bond provides a strong thermodynamic driving force.

Authors:
 [1]; ORCiD logo [1];  [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Center for Molecular Electrocatalysis, Pacific Northwest National Laboratory P.O. Box 999, Richland, USA
  2. Department of Chemistry, University of Washington, Seattle, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1573275
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 55 Journal Issue: 93; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Cook, Brian J., Johnson, Samantha I., Chambers, Geoffrey M., Kaminsky, Werner, and Bullock, R. Morris. Triple hydrogen atom abstraction from Mn–NH 3 complexes results in cyclophosphazenium cations. United Kingdom: N. p., 2019. Web. doi:10.1039/C9CC06915A.
Cook, Brian J., Johnson, Samantha I., Chambers, Geoffrey M., Kaminsky, Werner, & Bullock, R. Morris. Triple hydrogen atom abstraction from Mn–NH 3 complexes results in cyclophosphazenium cations. United Kingdom. doi:10.1039/C9CC06915A.
Cook, Brian J., Johnson, Samantha I., Chambers, Geoffrey M., Kaminsky, Werner, and Bullock, R. Morris. Tue . "Triple hydrogen atom abstraction from Mn–NH 3 complexes results in cyclophosphazenium cations". United Kingdom. doi:10.1039/C9CC06915A.
@article{osti_1573275,
title = {Triple hydrogen atom abstraction from Mn–NH 3 complexes results in cyclophosphazenium cations},
author = {Cook, Brian J. and Johnson, Samantha I. and Chambers, Geoffrey M. and Kaminsky, Werner and Bullock, R. Morris},
abstractNote = {All three H atoms of the NH 3 ligand of [Mn(depe) 2 (CO)(NH 3 )] + are abstracted by an organic radical, giving a rare cyclophosphazenium cation; computations suggest that insertion of NH x into a Mn–P bond provides a strong thermodynamic driving force.},
doi = {10.1039/C9CC06915A},
journal = {ChemComm},
number = 93,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {11}
}

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