A Cr3+ luminescence study of natural topaz Al2SiO4(F,OH)2 up to 60 GPa
Topaz [Al2SiO4(F,OH)2] is a subduction-related mineral that is found in metasediments and has a large pressure and temperature stability field. Here, we use luminescence spectroscopy of Cr3+ to probe the Al site in topaz at pressures up to ~60 GPa, which corresponds to a depth of ~1400 km in the Earth. This technique allows us to probe all three unique Al environments (i.e., [AlO4(OH)2]7–, [AlO4(F)2]7–, and [AlO4OH,F]7–) simultaneously under high pressure. We find that the R-line luminescence from all three Al environments shift linearly to longer wavelength to ~40 GPa. Above ~40 GPa, they shift nonlinearly and begin to flatten out at ~48 GPa, with a pressure shift of ~0 cm–1/GPa from ~48–55 GPa. Our results, combined with previous high-pressure single-crystal X-ray diffraction studies to ~45 GPa, strongly indicate that there is a change in the compression mechanism in topaz above ~40 GPa. Furthermore, our high-pressure room-temperature results show that the metastable persistence of topaz on compression represents one of the most extreme cases among tetrahedrally coordinated silicates.
- Research Organization:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- Sponsoring Organization:
- USDOE National Nuclear Security Administration (NNSA)
- Grant/Contract Number:
- AC52-07NA27344
- OSTI ID:
- 1573158
- Report Number(s):
- LLNL-JRNL--772914; 963785
- Journal Information:
- American Mineralogist, Journal Name: American Mineralogist Journal Issue: 11 Vol. 104; ISSN 0003-004X
- Publisher:
- Mineralogical Society of AmericaCopyright Statement
- Country of Publication:
- United States
- Language:
- English
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