Pressure-induced semiconductor-to-metal phase transition of a charge-ordered indium halide perovskite
Abstract
Phase transitions in halide perovskites triggered by external stimuli generate significantly different material properties, providing a great opportunity for broad applications. Here, we demonstrate an In-based, charge-ordered (In+/In3+) inorganic halide perovskite with the composition of Cs2In(I)In(III)Cl6in which a pressure-driven semiconductor-to-metal phase transition exists. The single crystals, synthesized via a solid-state reaction method, crystallize in a distorted perovskite structure with space groupI4/mwitha= 17.2604(12) Å,c= 11.0113(16) Å if both the strong reflections and superstructures are considered. The supercell was further confirmed by rotation electron diffraction measurement. The pressure-induced semiconductor-to-metal phase transition was demonstrated by high-pressure Raman and absorbance spectroscopies and was consistent with theoretical modeling. This type of charge-ordered inorganic halide perovskite with a pressure-induced semiconductor-to-metal phase transition may inspire a range of potential applications.
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1573106
- Alternate Identifier(s):
- OSTI ID: 1597526; OSTI ID: 1599818
- Grant/Contract Number:
- AC02-05CH11231; AC02-76SF00515
- Resource Type:
- Published Article
- Journal Name:
- Proceedings of the National Academy of Sciences of the United States of America
- Additional Journal Information:
- Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 116 Journal Issue: 47; Journal ID: ISSN 0027-8424
- Publisher:
- National Academy of Sciences
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; charge ordered; inorganic; halide perovskite; phase transition; high pressure
Citation Formats
Lin, Jia, Chen, Hong, Gao, Yang, Cai, Yao, Jin, Jianbo, Etman, Ahmed S., Kang, Joohoon, Lei, Teng, Lin, Zhenni, Folgueras, Maria C., Quan, Li Na, Kong, Qiao, Sherburne, Matthew, Asta, Mark, Sun, Junliang, Toney, Michael F., Wu, Junqiao, and Yang, Peidong. Pressure-induced semiconductor-to-metal phase transition of a charge-ordered indium halide perovskite. United States: N. p., 2019.
Web. doi:10.1073/pnas.1907576116.
Lin, Jia, Chen, Hong, Gao, Yang, Cai, Yao, Jin, Jianbo, Etman, Ahmed S., Kang, Joohoon, Lei, Teng, Lin, Zhenni, Folgueras, Maria C., Quan, Li Na, Kong, Qiao, Sherburne, Matthew, Asta, Mark, Sun, Junliang, Toney, Michael F., Wu, Junqiao, & Yang, Peidong. Pressure-induced semiconductor-to-metal phase transition of a charge-ordered indium halide perovskite. United States. https://doi.org/10.1073/pnas.1907576116
Lin, Jia, Chen, Hong, Gao, Yang, Cai, Yao, Jin, Jianbo, Etman, Ahmed S., Kang, Joohoon, Lei, Teng, Lin, Zhenni, Folgueras, Maria C., Quan, Li Na, Kong, Qiao, Sherburne, Matthew, Asta, Mark, Sun, Junliang, Toney, Michael F., Wu, Junqiao, and Yang, Peidong. Mon .
"Pressure-induced semiconductor-to-metal phase transition of a charge-ordered indium halide perovskite". United States. https://doi.org/10.1073/pnas.1907576116.
@article{osti_1573106,
title = {Pressure-induced semiconductor-to-metal phase transition of a charge-ordered indium halide perovskite},
author = {Lin, Jia and Chen, Hong and Gao, Yang and Cai, Yao and Jin, Jianbo and Etman, Ahmed S. and Kang, Joohoon and Lei, Teng and Lin, Zhenni and Folgueras, Maria C. and Quan, Li Na and Kong, Qiao and Sherburne, Matthew and Asta, Mark and Sun, Junliang and Toney, Michael F. and Wu, Junqiao and Yang, Peidong},
abstractNote = {Phase transitions in halide perovskites triggered by external stimuli generate significantly different material properties, providing a great opportunity for broad applications. Here, we demonstrate an In-based, charge-ordered (In+/In3+) inorganic halide perovskite with the composition of Cs2In(I)In(III)Cl6in which a pressure-driven semiconductor-to-metal phase transition exists. The single crystals, synthesized via a solid-state reaction method, crystallize in a distorted perovskite structure with space groupI4/mwitha= 17.2604(12) Å,c= 11.0113(16) Å if both the strong reflections and superstructures are considered. The supercell was further confirmed by rotation electron diffraction measurement. The pressure-induced semiconductor-to-metal phase transition was demonstrated by high-pressure Raman and absorbance spectroscopies and was consistent with theoretical modeling. This type of charge-ordered inorganic halide perovskite with a pressure-induced semiconductor-to-metal phase transition may inspire a range of potential applications.},
doi = {10.1073/pnas.1907576116},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 47,
volume = 116,
place = {United States},
year = {Mon Nov 04 00:00:00 EST 2019},
month = {Mon Nov 04 00:00:00 EST 2019}
}
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https://doi.org/10.1073/pnas.1907576116
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