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Title: Selective Catalytic Chemistry at Rhodium(II) Nodes in Bimetallic Metal–Organic Frameworks

Authors:
 [1];  [1];  [2];  [3];  [1];  [1];  [1];  [4];  [5];  [3];  [6];  [6];  [2];  [1]; ORCiD logo [1]
  1. Department of Chemistry and Biochemistry University of South Carolina Columbia SC 29208 USA
  2. Department of Chemistry University of Tennessee Knoxville TN 37996 USA
  3. Chemistry Division Brookhaven National Laboratory Upton NY 11973 USA
  4. Department of Materials Science and Chemical Engineering Stony Brook University Stony Brook NY 11794 USA
  5. Chemistry Division Brookhaven National Laboratory Upton NY 11973 USA, Department of Materials Science and Chemical Engineering Stony Brook University Stony Brook NY 11794 USA
  6. Department of Chemical Engineering University of South Carolina Columbia SC 29208 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1573065
Grant/Contract Number:  
SC0019360
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 131 Journal Issue: 46; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Shakya, Deependra M., Ejegbavwo, Otega A., Rajeshkumar, Thayalan, Senanayake, Sanjaya D., Brandt, Amy J., Farzandh, Sharfa, Acharya, Narayan, Ebrahim, Amani M., Frenkel, Anatoly I., Rui, Ning, Tate, Gregory L., Monnier, John R., Vogiatzis, Konstantinos D., Shustova, Natalia B., and Chen, Donna A. Selective Catalytic Chemistry at Rhodium(II) Nodes in Bimetallic Metal–Organic Frameworks. Germany: N. p., 2019. Web. doi:10.1002/ange.201908761.
Shakya, Deependra M., Ejegbavwo, Otega A., Rajeshkumar, Thayalan, Senanayake, Sanjaya D., Brandt, Amy J., Farzandh, Sharfa, Acharya, Narayan, Ebrahim, Amani M., Frenkel, Anatoly I., Rui, Ning, Tate, Gregory L., Monnier, John R., Vogiatzis, Konstantinos D., Shustova, Natalia B., & Chen, Donna A. Selective Catalytic Chemistry at Rhodium(II) Nodes in Bimetallic Metal–Organic Frameworks. Germany. https://doi.org/10.1002/ange.201908761
Shakya, Deependra M., Ejegbavwo, Otega A., Rajeshkumar, Thayalan, Senanayake, Sanjaya D., Brandt, Amy J., Farzandh, Sharfa, Acharya, Narayan, Ebrahim, Amani M., Frenkel, Anatoly I., Rui, Ning, Tate, Gregory L., Monnier, John R., Vogiatzis, Konstantinos D., Shustova, Natalia B., and Chen, Donna A. Tue . "Selective Catalytic Chemistry at Rhodium(II) Nodes in Bimetallic Metal–Organic Frameworks". Germany. https://doi.org/10.1002/ange.201908761.
@article{osti_1573065,
title = {Selective Catalytic Chemistry at Rhodium(II) Nodes in Bimetallic Metal–Organic Frameworks},
author = {Shakya, Deependra M. and Ejegbavwo, Otega A. and Rajeshkumar, Thayalan and Senanayake, Sanjaya D. and Brandt, Amy J. and Farzandh, Sharfa and Acharya, Narayan and Ebrahim, Amani M. and Frenkel, Anatoly I. and Rui, Ning and Tate, Gregory L. and Monnier, John R. and Vogiatzis, Konstantinos D. and Shustova, Natalia B. and Chen, Donna A.},
abstractNote = {},
doi = {10.1002/ange.201908761},
journal = {Angewandte Chemie},
number = 46,
volume = 131,
place = {Germany},
year = {2019},
month = {9}
}

Works referenced in this record:

Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy
journal, January 2005

  • Weigend, Florian; Ahlrichs, Reinhart
  • Physical Chemistry Chemical Physics, Vol. 7, Issue 18, p. 3297-3305
  • DOI: 10.1039/b508541a

Dehydrogenation and oxydehydrogenation of paraffins to olefins
journal, November 2001


Hydroformylation of Olefins by a Rhodium Single-Atom Catalyst with Activity Comparable to RhCl(PPh 3 ) 3
journal, November 2016

  • Lang, Rui; Li, Tianbo; Matsumura, Daiju
  • Angewandte Chemie International Edition, Vol. 55, Issue 52
  • DOI: 10.1002/anie.201607885

Sintering-Resistant Single-Site Nickel Catalyst Supported by Metal–Organic Framework
journal, February 2016

  • Li, Zhanyong; Schweitzer, Neil M.; League, Aaron B.
  • Journal of the American Chemical Society, Vol. 138, Issue 6
  • DOI: 10.1021/jacs.5b12515

Active Sites in Copper-Based Metal–Organic Frameworks: Understanding Substrate Dynamics, Redox Processes, and Valence-Band Structure
journal, November 2015

  • Duke, Audrey S.; Dolgopolova, Ekaterina A.; Galhenage, Randima P.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 49
  • DOI: 10.1021/acs.jpcc.5b08053

Postsynthetic Tuning of Metal–Organic Frameworks for Targeted Applications
journal, February 2017


Unraveling reaction networks behind the catalytic oxidation of methane with H 2 O 2 over a mixed-metal MIL-53(Al,Fe) MOF catalyst
journal, January 2018

  • Szécsényi, Ágnes; Li, Guanna; Gascon, Jorge
  • Chemical Science, Vol. 9, Issue 33
  • DOI: 10.1039/C8SC02376J

Self-Assembly of a Rh(I) Complex on Au(111) Surfaces and Its Electrocatalytic Activity toward the Hydrogen Evolution Reaction
journal, June 2007

  • Zhou, Xiao-Shun; Dong, Zhen-Rong; Zhang, Hai-Ming
  • Langmuir, Vol. 23, Issue 12
  • DOI: 10.1021/la062949q

Metal–organic frameworks as selectivity regulators for hydrogenation reactions
journal, October 2016


Hydroformylation of Olefins by a Rhodium Single-Atom Catalyst with Activity Comparable to RhCl(PPh 3 ) 3
journal, November 2016


Activation of hydrogen by bridged transition metal carboxylates. Rhodium(II) acetate catalyzed hydrogenation of olefins
journal, April 1973

  • Hui, B. C. Y.; Teo, W. K.; Rempel, G. L.
  • Inorganic Chemistry, Vol. 12, Issue 4
  • DOI: 10.1021/ic50122a010

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

Site Isolation in Metal–Organic Frameworks Enables Novel Transition Metal Catalysis
journal, August 2018


Metal–Organic Frameworks as A Tunable Platform for Designing Functional Molecular Materials
journal, August 2013

  • Wang, Cheng; Liu, Demin; Lin, Wenbin
  • Journal of the American Chemical Society, Vol. 135, Issue 36
  • DOI: 10.1021/ja308229p

Single-Atom-Based Vanadium Oxide Catalysts Supported on Metal–Organic Frameworks: Selective Alcohol Oxidation and Structure–Activity Relationship
journal, June 2018

  • Otake, Ken-ichi; Cui, Yuexing; Buru, Cassandra T.
  • Journal of the American Chemical Society, Vol. 140, Issue 28
  • DOI: 10.1021/jacs.8b05107

Non-local Effects on Oxygen-Induced Surface Core Level Shifts of Re(0001)
journal, October 2012

  • Miniussi, E.; Hernández, E. R.; Pozzo, M.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 44
  • DOI: 10.1021/jp304838g

A catalytically active porous coordination polymer based on a dinuclear rhodium paddle-wheel unit
journal, January 2014

  • Nickerl, Georg; Stoeck, Ulrich; Burkhardt, Ulrich
  • J. Mater. Chem. A, Vol. 2, Issue 1
  • DOI: 10.1039/C3TA12795H

Aerobic Epoxidation of Olefins Catalyzed by the Cobalt-Based Metal-Organic Framework STA-12(Co)
journal, December 2011

  • Beier, Matthias J.; Kleist, Wolfgang; Wharmby, Michael T.
  • Chemistry - A European Journal, Vol. 18, Issue 3
  • DOI: 10.1002/chem.201101223