Progress in development of electrolytes for magnesium batteries

Deivanayagam, Ramasubramonian; Ingram, Brian J.; Shahbazian-Yassar, Reza

doi:10.1016/j.ensm.2019.05.028

Title: Progress in development of electrolytes for magnesium batteries

Journal Article · 21 May 2019 · Energy Storage Materials

DOI: https://doi.org/10.1016/j.ensm.2019.05.028 · OSTI ID:1572939

Deivanayagam, Ramasubramonian ^[1]; Ingram, Brian J. ^[2]; Shahbazian-Yassar, Reza ^[1]

Univ. of Illinois at Chicago, Chicago, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)

Over the last few years, there has been an increased interest in developing safe, next-generation battery systems that offer energy densities higher than those of lithium-based batteries. In this context, batteries based on multivalent-ions (Mg²⁺, Zn²⁺, Ca²⁺, and Al³⁺) have developed their own niche with their capability to achieve at least twice the energy density of monovalent-ion systems such as Li-ion and Na-ion batteries. Among the multivalent-ion battery candidates, magnesium (Mg) batteries appear to be the most viable choice to eventually replace the Li-ion technology because of the high electrode potential, superior safety, and high abundance of Mg-metal. However, the limited development in electrolytes and cathodes has prevented their commercialization to date. There is a lack of suitable electrolytes that can be used at high voltages required for Mg²⁺ insertion into cathode hosts. The limited compatibility of organic electrolytes with Mg-metal anode is also a challenge, which requires extensive studies of the metal/electrolyte interactions. Such studies over the last two decades were critical in developing state-of-the-art Mg electrolytes that possess voltage windows of >4.0 V and simultaneously be compatible with Mg-metal anodes. Here, we present a review on the development of Mg battery electrolytes, challenges that impede their performance, and promising strategies that have been adopted to address them. As a result, we believe that this comprehensive review covering all three categories of Mg electrolytes (liquids, polymers, and solids) would enable researchers to get a quick grasp of the prevailing challenges, and consequently motivate them to develop novel electrolyte candidates.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Joint Center for Energy Storage Research (JCESR)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1572939

Journal Information:: Energy Storage Materials, Journal Name: Energy Storage Materials Journal Issue: C Vol. 21; ISSN 2405-8297

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (132)

Quest for Nonaqueous Multivalent Secondary Batteries: Magnesium and Beyond Muldoon, John; Bucur, Claudiu B.; Gregory, Thomas Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500049y	journal	October 2014
Polymerâceramic composite electrolytes: conductivity and thermal history effects Kumar, B. Solid State Ionics, Vol. 124, Issue 3-4 https://doi.org/10.1016/S0167-2738(99)00148-4	journal	September 1999
A novel type of magnesium ion conducting polymer electrolyte Liebenow, C. Electrochimica Acta, Vol. 43, Issue 10-11 https://doi.org/10.1016/S0013-4686(97)10026-3	journal	April 1998
Mg rechargeable batteries: an on-going challenge Yoo, Hyun Deog; Shterenberg, Ivgeni; Gofer, Yosef Energy & Environmental Science, Vol. 6, Issue 8, p. 2265-2279 https://doi.org/10.1039/c3ee40871j	journal	January 2013
High temperature 31P NMR study on Mg2+ ion conductors Kawamura, Junichi; Morota, Kai; Kuwata, Naoaki Solid State Communications, Vol. 120, Issue 7-8 https://doi.org/10.1016/S0038-1098(01)00386-6	journal	October 2001
Framework Structure, Phase Transition, and Transport Properties in M ^II Zr ₄ (PO ₄ ) ₆ Compounds (M ^II = Mg, Ca, Sr, Ba, Mn, Co, Ni, Zn, Cd, and Pb) Nomura, Katsuhiro; Ikeda, Shoichiro; Ito, Kaname Bulletin of the Chemical Society of Japan, Vol. 65, Issue 12 https://doi.org/10.1246/bcsj.65.3221	journal	December 1992
A novel inorganic solid state ion conductor for rechargeable Mg batteries Higashi, Shougo; Miwa, Kazutoshi; Aoki, Masakazu Chem. Commun., Vol. 50, Issue 11 https://doi.org/10.1039/C3CC47097K	journal	January 2014
Ionic Liquid as an Effective Additive for Rechargeable Magnesium Batteries Pan, Baofei; Lau, Ka-Cheong; Vaughey, John T. Journal of The Electrochemical Society, Vol. 164, Issue 4 https://doi.org/10.1149/2.1551704jes	journal	January 2017
Magnesium(II) Bis(trifluoromethane sulfonyl) Imide-Based Electrolytes with Wide Electrochemical Windows for Rechargeable Magnesium Batteries Ha, Se-Young; Lee, Yong-Won; Woo, Sang Won ACS Applied Materials & Interfaces, Vol. 6, Issue 6, p. 4063-4073 https://doi.org/10.1021/am405619v	journal	March 2014
On the strange case of divalent ions intercalation in V2O5 Verrelli, R.; Black, A. P.; Pattanathummasid, C. Journal of Power Sources, Vol. 407 https://doi.org/10.1016/j.jpowsour.2018.08.024	journal	December 2018
Influence of PEG-Borate Ester as a Lewis Acid on Ionic Conductivity of Polymer Electrolyte Containing Mg-Salt Saito, Morihiro; Ikuta, Hiromasa; Uchimoto, Yoshiharu Journal of The Electrochemical Society, Vol. 150, Issue 4 https://doi.org/10.1149/1.1559066	journal	January 2003
Secondary batteries with multivalent ions for energy storage Xu, Chengjun; Chen, Yanyi; Shi, Shan Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep14120	journal	September 2015
Na-Ion Batteries for Large Scale Applications: A Review on Anode Materials and Solid Electrolyte Interphase Formation Muñoz-Márquez, Miguel Ángel; Saurel, Damien; Gómez-Cámer, Juan Luis Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201700463	journal	July 2017
Recent advances in air-battery chemistries Chawla, N. Materials Today Chemistry, Vol. 12 https://doi.org/10.1016/j.mtchem.2019.03.006	journal	June 2019
Electrical and electrochemical properties of magnesium ion conducting composite gel polymer electrolytes Pandey, G. P.; Agrawal, R. C.; Hashmi, S. A. Journal of Physics D: Applied Physics, Vol. 43, Issue 25 https://doi.org/10.1088/0022-3727/43/25/255501	journal	June 2010
Solid-State Rechargeable Magnesium Batteries Chusid, O.; Gofer, Y.; Gizbar, H. Advanced Materials, Vol. 15, Issue 78, p. 627-630 https://doi.org/10.1002/adma.200304415	journal	April 2003
A review on the problems of the solid state ions diffusion in cathodes for rechargeable Mg batteries Levi, E.; Levi, M. D.; Chasid, O. Journal of Electroceramics, Vol. 22, Issue 1-3 https://doi.org/10.1007/s10832-007-9370-5	journal	December 2007
The Role of MgCl ₂ as a Lewis Base in ROMgCl-MgCl ₂ Electrolytes for Magnesium-Ion Batteries Pan, Baofei; Huang, Jinhua; He, Meinan ChemSusChem, Vol. 9, Issue 6 https://doi.org/10.1002/cssc.201501557	journal	February 2016
A critical review of cathodes for rechargeable Mg batteries Mao, Minglei; Gao, Tao; Hou, Singyuk Chemical Society Reviews, Vol. 47, Issue 23 https://doi.org/10.1039/C8CS00319J	journal	January 2018
Novel solid state polymeric batteries Patrick, A.; Glasse, M.; Latham, R. Solid State Ionics, Vol. 18-19 https://doi.org/10.1016/0167-2738(86)90309-7	journal	January 1986
A novel polymeric gel electrolyte systems containing magnesium salt with ionic liquid Yoshimoto, Nobuko; Shirai, Takahiro; Morita, Masayuki Electrochimica Acta, Vol. 50, Issue 19, p. 3866-3871 https://doi.org/10.1016/j.electacta.2005.02.036	journal	June 2005
Prototype rechargeable magnesium batteries using ionic liquid electrolytes Gao, Xinpei; Mariani, Alessandro; Jeong, Sangsik Journal of Power Sources, Vol. 423 https://doi.org/10.1016/j.jpowsour.2019.03.049	journal	May 2019
Electrochemical and structural investigations on solutions of organomagnesium bromide in polymeric ether Liebenow, C. Solid State Ionics, Vol. 136-137, Issue 1-2 https://doi.org/10.1016/S0167-2738(00)00586-5	journal	November 2000
MgCl ₂ : The Key Ingredient to Improve Chloride Containing Electrolytes for Rechargeable Magnesium-Ion Batteries Pan, Baofei; Huang, Jinhua; Sa, Niya Journal of The Electrochemical Society, Vol. 163, Issue 8 https://doi.org/10.1149/2.0821608jes	journal	January 2016
Magnesium ion-conducting gel polymer electrolytes dispersed with fumed silica for rechargeable magnesium battery application Pandey, G. P.; Agrawal, R. C.; Hashmi, S. A. Journal of Solid State Electrochemistry, Vol. 15, Issue 10 https://doi.org/10.1007/s10008-010-1240-4	journal	November 2010
Nonaqueous magnesium electrochemistry and its application in secondary batteries Aurbach, Doron; Weissman, Idit; Gofer, Yosef The Chemical Record, Vol. 3, Issue 1, p. 61-73 https://doi.org/10.1002/tcr.10051	journal	January 2003
An Efficient Halogen-Free Electrolyte for Use in Rechargeable Magnesium Batteries Tutusaus, Oscar; Mohtadi, Rana; Arthur, Timothy S. Angewandte Chemie International Edition, Vol. 54, Issue 27 https://doi.org/10.1002/anie.201412202	journal	May 2015
Multivalent Cationic Conduction in Crystalline Solids Köhler, Joachim; Imanaka, Nobuhito; Adachi, Gin-ya Chemistry of Materials, Vol. 10, Issue 12 https://doi.org/10.1021/cm980473t	journal	December 1998
Preparation of magnesium ion conducting MgS–P2S5–MgI2 glasses by a mechanochemical technique Yamanaka, Tomohiro; Hayashi, Akitoshi; Yamauchi, Akihiro Solid State Ionics, Vol. 262 https://doi.org/10.1016/j.ssi.2013.10.037	journal	September 2014
Confession of a Magnesium Battery Bucur, Claudiu B.; Gregory, Thomas; Oliver, Allen G. The Journal of Physical Chemistry Letters, Vol. 6, Issue 18 https://doi.org/10.1021/acs.jpclett.5b01219	journal	August 2015
Evaluation of (CF ₃ SO ₂ ) ₂ N ⁻ (TFSI) Based Electrolyte Solutions for Mg Batteries Shterenberg, Ivgeni; Salama, Michael; Yoo, Hyun Deog Journal of The Electrochemical Society, Vol. 162, Issue 13 https://doi.org/10.1149/2.0161513jes	journal	January 2015
First-principles evaluation of multi-valent cation insertion into orthorhombic V ₂ O ₅ Gautam, Gopalakrishnan Sai; Canepa, Pieremanuele; Malik, Rahul Chemical Communications, Vol. 51, Issue 71 https://doi.org/10.1039/C5CC04947D	journal	January 2015
A concept of dual-salt polyvalent-metal storage battery Yagi, Shunsuke; Ichitsubo, Tetsu; Shirai, Yoshimasa J. Mater. Chem. A, Vol. 2, Issue 4 https://doi.org/10.1039/C3TA13668J	journal	January 2014
Mapping the Challenges of Magnesium Battery Song, Jaehee; Sahadeo, Emily; Noked, Malachi The Journal of Physical Chemistry Letters, Vol. 7, Issue 9 https://doi.org/10.1021/acs.jpclett.6b00384	journal	April 2016
Transition-Metal-Free Magnesium-Based Batteries Activated by Anionic Insertion into Fluorinated Graphene Nanosheets Xie, Junjie; Li, Chilin; Cui, Zhonghui Advanced Functional Materials, Vol. 25, Issue 41 https://doi.org/10.1002/adfm.201503010	journal	September 2015
Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries Doe, Robert E.; Han, Ruoban; Hwang, Jaehee Chemical Communications, Vol. 50, Issue 2, p. 243-245 https://doi.org/10.1039/C3CC47896C	journal	January 2014
Communication—A Composite Polymer Electrolyte for Safer Mg Batteries Song, Shufeng; Kotobuki, Masashi; Zheng, Feng Journal of The Electrochemical Society, Vol. 164, Issue 4 https://doi.org/10.1149/2.1171704jes	journal	January 2017
A novel electrolytic complex based on δ-MgCl2 and poly(ethylene glycol) 400 Noto, V. Di; Lavina, S.; Longo, D. Electrochimica Acta, Vol. 43, Issue 10-11 https://doi.org/10.1016/S0013-4686(97)10023-8	journal	April 1998
Spinel compounds as multivalent battery cathodes: a systematic evaluation based on ab initio calculations Liu, Miao; Rong, Ziqin; Malik, Rahul Energy & Environmental Science, Vol. 8, Issue 3 https://doi.org/10.1039/C4EE03389B	journal	January 2015
Promise and reality of post-lithium-ion batteries with high energy densities Choi, Jang Wook; Aurbach, Doron Nature Reviews Materials, Vol. 1, Issue 4 https://doi.org/10.1038/natrevmats.2016.13	journal	March 2016
The electrodeposition of magnesium using solutions of organomagnesium halides, amidomagnesium halides and magnesium organoborates Liebenow, C.; Yang, Z.; Lobitz, P. Electrochemistry Communications, Vol. 2, Issue 9 https://doi.org/10.1016/S1388-2481(00)00094-1	journal	September 2000
Magnesium Borohydride-Based Electrolytes Containing 1-butyl-1-methylpiperidinium bis(trifluoromethyl sulfonyl)imide Ionic Liquid for Rechargeable Magnesium Batteries Su, Shuojian; NuLi, Yanna; Wang, Nan Journal of The Electrochemical Society, Vol. 163, Issue 13 https://doi.org/10.1149/2.0631613jes	journal	January 2016
Cathode materials for magnesium and magnesium-ion based batteries Huie, Matthew M.; Bock, David C.; Takeuchi, Esther S. Coordination Chemistry Reviews, Vol. 287 https://doi.org/10.1016/j.ccr.2014.11.005	journal	March 2015
Understanding the Initial Stages of Reversible Mg Deposition and Stripping in Inorganic Nonaqueous Electrolytes Canepa, Pieremanuele; Gautam, Gopalakrishnan Sai; Malik, Rahul Chemistry of Materials, Vol. 27, Issue 9 https://doi.org/10.1021/acs.chemmater.5b00389	journal	April 2015
Study of Electrochemical Phenomena Observed at the Mg Metal/Electrolyte Interface Tutusaus, Oscar; Mohtadi, Rana; Singh, Nikhilendra ACS Energy Letters, Vol. 2, Issue 1 https://doi.org/10.1021/acsenergylett.6b00549	journal	December 2016
Ionic liquid hybrids: Progress toward non-corrosive electrolytes with high-voltage oxidation stability for magnesium-ion based batteries Huie, Matthew M.; Cama, Christina A.; Smith, Paul F. Electrochimica Acta, Vol. 219 https://doi.org/10.1016/j.electacta.2016.09.107	journal	November 2016
Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges Canepa, Pieremanuele; Sai Gautam, Gopalakrishnan; Hannah, Daniel C. Chemical Reviews, Vol. 117, Issue 5 https://doi.org/10.1021/acs.chemrev.6b00614	journal	February 2017
Improving a Mg/S Battery with YCl ₃ Additive and Magnesium Polysulfide Xu, Yan; Zhou, Guangmin; Zhao, Shuyang Advanced Science https://doi.org/10.1002/advs.201800981	journal	December 2018
Materials Design Rules for Multivalent Ion Mobility in Intercalation Structures Rong, Ziqin; Malik, Rahul; Canepa, Pieremanuele Chemistry of Materials, Vol. 27, Issue 17 https://doi.org/10.1021/acs.chemmater.5b02342	journal	August 2015
Studies of some poly(vinylidene fluoride) electrolytes Jiang, Z.; Carroll, B.; Abraham, K. M. Electrochimica Acta, Vol. 42, Issue 17 https://doi.org/10.1016/S0013-4686(97)00005-4	journal	January 1997
Practical Stability Limits of Magnesium Electrolytes Lipson, Albert L.; Han, Sang-Don; Pan, Baofei Journal of The Electrochemical Society, Vol. 163, Issue 10 https://doi.org/10.1149/2.0451610jes	journal	January 2016
A Solid Lithium Electrolyte via Addition of Lithium Isopropoxide to a Metal–Organic Framework with Open Metal Sites Wiers, Brian M.; Foo, Maw-Lin; Balsara, Nitash P. Journal of the American Chemical Society, Vol. 133, Issue 37 https://doi.org/10.1021/ja205827z	journal	September 2011
Studies on the Electrodeposition of Magnesium in Ionic Liquids Cheek, G. T.; O’Grady, W. E.; El Abedin, S. Zein Journal of The Electrochemical Society, Vol. 155, Issue 1 https://doi.org/10.1149/1.2804763	journal	January 2008
Factors affecting the conductivity of divalent polymeric electrolytes Martins, M. A. G.; Sequeira, C. A. C. Journal of Power Sources, Vol. 32, Issue 2 https://doi.org/10.1016/S0378-7753(12)80001-2	journal	August 1990
Electrolyte Solutions for Rechargeable Magnesium Batteries Based on Organomagnesium Chloroaluminate Complexes Aurbach, Doron; Gizbar, Haim; Schechter, Alex Journal of The Electrochemical Society, Vol. 149, Issue 2, p. A115-A121 https://doi.org/10.1149/1.1429925	journal	January 2002
Sodium-Ion Batteries Slater, Michael D.; Kim, Donghan; Lee, Eungje Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958 https://doi.org/10.1002/adfm.201200691	journal	May 2012
A Lewis acid-free and phenolate-based magnesium electrolyte for rechargeable magnesium batteries Pan, Baofei; Zhang, Junjie; Huang, Jinhua Chemical Communications, Vol. 51, Issue 28 https://doi.org/10.1039/C5CC01225B	journal	January 2015
Synthesis and characterization of [PEG400-alt-DEOS]/(δ-MgCl2)0.2597 complex Di Noto, Vito; Vittadello, Michele; Pace, Giuseppe Macromolecular Chemistry and Physics, Vol. 203, Issue 9 https://doi.org/10.1002/1521-3935(200206)203:9<1201::AID-MACP1201>3.0.CO;2-1	journal	June 2002
Ionic liquid electrolytes for reversible magnesium electrochemistry Kar, Mega; Ma, Zheng; Azofra, Luis Miguel Chemical Communications, Vol. 52, Issue 21 https://doi.org/10.1039/C5CC09324D	journal	January 2016
Divalent Magnesium Ionic Conduction in the Magnesium Phosphate Based Composites Imanaka, Nobuhito; Okazaki, Yusuke; Adachi, Gin-ya Chemistry Letters, Vol. 28, Issue 9 https://doi.org/10.1246/cl.1999.939	journal	September 1999
MgCl ₂ /AlCl ₃ electrolytes for reversible Mg deposition/stripping: electrochemical conditioning or not? He, Shuijian; Luo, Jian; Liu, T. Leo Journal of Materials Chemistry A, Vol. 5, Issue 25 https://doi.org/10.1039/C7TA01769C	journal	January 2017
Bisamide based non-nucleophilic electrolytes for rechargeable magnesium batteries Zhao-Karger, Zhirong; Zhao, Xiangyu; Fuhr, Olaf RSC Advances, Vol. 3, Issue 37 https://doi.org/10.1039/c3ra43206h	journal	January 2013
Metal–organic frameworks as solid magnesium electrolytes Aubrey, M. L.; Ameloot, R.; Wiers, B. M. Energy & Environmental Science, Vol. 7, Issue 2 https://doi.org/10.1039/c3ee43143f	journal	January 2014
Prototype systems for rechargeable magnesium batteries Aurbach, D.; Lu, Z.; Schechter, A. Nature, Vol. 407, Issue 6805, p. 724-727 https://doi.org/10.1038/35037553	journal	October 2000
Mixed electrolyte consisting of ethylmagnesiumbromide with ionic liquid for rechargeable magnesium electrode Yoshimoto, Nobuko; Matsumoto, Mami; Egashia, Minato Journal of Power Sources, Vol. 195, Issue 7 https://doi.org/10.1016/j.jpowsour.2009.10.073	journal	April 2010
A short review on the comparison between Li battery systems and rechargeable magnesium battery technology Aurbach, D.; Gofer, Y.; Lu, Z. Journal of Power Sources, Vol. 97-98 https://doi.org/10.1016/S0378-7753(01)00585-7	journal	July 2001
Unravelling the Surface Structure of MgMn ₂ O ₄ Cathode Materials for Rechargeable Magnesium-Ion Battery Truong, Quang Duc; Kempaiah Devaraju, Murukanahally; Tran, Phong D. Chemistry of Materials, Vol. 29, Issue 15 https://doi.org/10.1021/acs.chemmater.7b01252	journal	July 2017
Interaction between the Lewis Acid Group of a Borate Ester and Various Anion Species in a Polymer Electrolyte Containing Mg Salt Saito, Morihiro; Ikuta, Hiromasa; Uchimoto, Yoshiharu The Journal of Physical Chemistry B, Vol. 107, Issue 42 https://doi.org/10.1021/jp034040b	journal	October 2003
Thermal and electrical properties of solid polymer electrolyte PEO9 Mg(ClO4)2 incorporating nano-porous Al2O3 filler Dissanayake, M. A. K. L.; Bandara, L. R. A. K.; Karaliyadda, L. H. Solid State Ionics, Vol. 177, Issue 3-4 https://doi.org/10.1016/j.ssi.2005.10.031	journal	January 2006
Mixed ionic liquids as electrolyte for reversible deposition and dissolution of magnesium Wang, Pu; NuLi, Yanna; Yang, Jun Surface and Coatings Technology, Vol. 201, Issue 6 https://doi.org/10.1016/j.surfcoat.2006.03.020	journal	December 2006
Electrical Spectroscopy Studies of Lithium and Magnesium Polymer Electrolytes Based on PEG400 Di Noto, Vito The Journal of Physical Chemistry B, Vol. 106, Issue 43 https://doi.org/10.1021/jp020771k	journal	October 2002
Characterization of magnesium-intercalated V2O5/carbon composites Imamura, D. Solid State Ionics, Vol. 161, Issue 1-2 https://doi.org/10.1016/S0167-2738(03)00267-4	journal	July 2003
Optimization of cation structure of imidazolium-based ionic liquids as ionic solvents for rechargeable magnesium batteries Kakibe, Takeshi; Yoshimoto, Nobuko; Egashira, Minato Electrochemistry Communications, Vol. 12, Issue 11 https://doi.org/10.1016/j.elecom.2010.09.012	journal	November 2010
High-Capacity Anode Materials for Sodium-Ion Batteries Kim, Youngjin; Ha, Kwang-Ho; Oh, Seung M. Chemistry - A European Journal, Vol. 20, Issue 38 https://doi.org/10.1002/chem.201402511	journal	August 2014
Reversible deposition and dissolution of magnesium from BMIMBF4 ionic liquid NuLi, Yanna; Yang, Jun; Wu, Rong Electrochemistry Communications, Vol. 7, Issue 11 https://doi.org/10.1016/j.elecom.2005.07.013	journal	November 2005
Mg Desolvation and Intercalation Mechanism at the Mo ₆ S ₈ Chevrel Phase Surface Wan, Liwen F.; Perdue, Brian R.; Apblett, Christopher A. Chemistry of Materials, Vol. 27, Issue 17 https://doi.org/10.1021/acs.chemmater.5b01907	journal	August 2015
Solvation structure and energetics of electrolytes for multivalent energy storage Lapidus, Saul H.; Rajput, Nav Nidhi; Qu, Xiaohui Phys. Chem. Chem. Phys., Vol. 16, Issue 40 https://doi.org/10.1039/C4CP03015J	journal	January 2014
The Coupling between Stability and Ion Pair Formation in Magnesium Electrolytes from First-Principles Quantum Mechanics and Classical Molecular Dynamics Rajput, Nav Nidhi; Qu, Xiaohui; Sa, Niya Journal of the American Chemical Society, Vol. 137, Issue 9, p. 3411-3420 https://doi.org/10.1021/jacs.5b01004	journal	February 2015
High magnesium mobility in ternary spinel chalcogenides Canepa, Pieremanuele; Bo, Shou-Hang; Sai Gautam, Gopalakrishnan Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01772-1	journal	November 2017
Ionic Conductivity in Complexes of Poly(ethylene oxide) and MgCl2 Yang, L. L.; McGhie, A. R.; Farrington, G. C. Journal of The Electrochemical Society, Vol. 133, Issue 7 https://doi.org/10.1149/1.2108891	journal	July 1986
Role of the ceramic fillers in enhancing the transport properties of composite polymer electrolytes Croce, F.; Persi, L.; Scrosati, B. Electrochimica Acta, Vol. 46, Issue 16 https://doi.org/10.1016/S0013-4686(01)00458-3	journal	May 2001
Hexafluorophosphate-Based Solutions for Mg Batteries and the Importance of Chlorides Shterenberg, Ivgeni; Salama, Michael; Gofer, Yosef Langmuir, Vol. 33, Issue 37 https://doi.org/10.1021/acs.langmuir.7b01609	journal	July 2017
Effect of 1-allyl-1-methylpyrrolidinium chloride addition to ethylmagnesium bromide electrolyte on a rechargeable magnesium battery Cho, Jae-Hyun; Ha, Jung Hoon; Lee, Sang-Hoon Electrochimica Acta, Vol. 231 https://doi.org/10.1016/j.electacta.2017.02.062	journal	March 2017
Solid electrolytes with multivalent cation conduction (2) zinc ion conduction in Zn$z.sbnd;Zr$z.sbnd;PO4 system Ikeda, S. Solid State Ionics, Vol. 40-41 https://doi.org/10.1016/0167-2738(90)90291-X	journal	August 1990
A lithium superionic conductor Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro Nature Materials, Vol. 10, Issue 9, p. 682-686 https://doi.org/10.1038/nmat3066	journal	July 2011
Solid state cathode materials for secondary magnesium-ion batteries that are compatible with magnesium metal anodes in water-free electrolyte Crowe, Adam J.; Bartlett, Bart M. Journal of Solid State Chemistry, Vol. 242 https://doi.org/10.1016/j.jssc.2016.04.011	journal	October 2016
Beyond Li-ion: electrode materials for sodium- and magnesium-ion batteries Massé, Robert C.; Uchaker, Evan; Cao, Guozhong Science China Materials, Vol. 58, Issue 9 https://doi.org/10.1007/s40843-015-0084-8	journal	September 2015
Beyond Intercalation Chemistry for Rechargeable Mg Batteries: A Short Review and Perspective Zhao-Karger, Zhirong; Fichtner, Maximilian Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00656	journal	January 2019
Ionic conductance behavior of polymeric electrolytes containing magnesium salts and their application to rechargeable batteries Yoshimoto, N. Solid State Ionics, Vol. 152-153 https://doi.org/10.1016/S0167-2738(02)00308-9	journal	December 2002
Electrochemical measurement of transference numbers in polymer electrolytes Evans, James; Vincent, Colin A.; Bruce, Peter G. Polymer, Vol. 28, Issue 13 https://doi.org/10.1016/0032-3861(87)90394-6	journal	December 1987
The rechargeable revolution: A better battery Van Noorden, Richard Nature, Vol. 507, Issue 7490 https://doi.org/10.1038/507026a	journal	March 2014
Nonaqueous Electrochemistry of Magnesium Gregory, Thomas D.; Hoffman, Ronald J.; Winterton, Richard C. Journal of The Electrochemical Society, Vol. 137, Issue 3, p. 775-780 https://doi.org/10.1149/1.2086553	journal	January 1990
MgSc ₂ Se ₄ —A Magnesium Solid Ionic Conductor for All‐Solid‐State Mg Batteries? Wang, Li‐Ping; Zhao‐Karger, Zhirong; Klein, Franziska ChemSusChem, Vol. 12, Issue 10 https://doi.org/10.1002/cssc.201900225	journal	April 2019
A solid future for battery development Janek, Jürgen; Zeier, Wolfgang G. Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.141	journal	September 2016
Ionic conductivity of a gel polymer electrolyte based on Mg(ClO4)2 and polyacrylonitrile (PAN) Perera, Kumudu; Dissanayake, M. A. K. L.; Bandaranayake, P. W. S. K. Materials Research Bulletin, Vol. 39, Issue 11 https://doi.org/10.1016/j.materresbull.2004.03.027	journal	September 2004
A gel polymer electrolyte of magnesium triflate Kumar, G. Solid State Ionics, Vol. 128, Issue 1-4 https://doi.org/10.1016/S0167-2738(00)00276-9	journal	February 2000
Nanocomposite polymer electrolyte for rechargeable magnesium batteries Shao, Yuyan; Rajput, Nav Nidhi; Hu, Jianzhi Nano Energy, Vol. 12 https://doi.org/10.1016/j.nanoen.2014.12.028	journal	March 2015
Impact of intermediate sites on bulk diffusion barriers: Mg intercalation in Mg ₂ Mo ₃ O ₈ Gautam, Gopalakrishnan Sai; Sun, Xiaoqi; Duffort, Victor Journal of Materials Chemistry A, Vol. 4, Issue 45 https://doi.org/10.1039/C6TA07804D	journal	January 2016
Constitution of Grignard Reagent RMgCl in Tetrahydrofuran Sakamoto, Shigeru; Imamoto, Tsuneo; Yamaguchi, Kentaro Organic Letters, Vol. 3, Issue 12 https://doi.org/10.1021/ol010048x	journal	June 2001
Interlayer-Expanded Molybdenum Disulfide Nanocomposites for Electrochemical Magnesium Storage Liang, Yanliang; Yoo, Hyun Deog; Li, Yifei Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/acs.nanolett.5b00388	journal	February 2015
Thermodynamics and Kinetics of Sulfur Cathode during Discharge in MgTFSI ₂ -DME Electrolyte Gao, Tao; Ji, Xiao; Hou, Singyuk Advanced Materials, Vol. 30, Issue 3 https://doi.org/10.1002/adma.201704313	journal	November 2017
Boron Clusters as Highly Stable Magnesium-Battery Electrolytes Carter, Tyler J.; Mohtadi, Rana; Arthur, Timothy S. Angewandte Chemie International Edition, Vol. 53, Issue 12 https://doi.org/10.1002/anie.201310317	journal	February 2014
High-Capacity Mg–Organic Batteries Based on Nanostructured Rhodizonate Salts Activated by Mg–Li Dual-Salt Electrolyte Tian, Jing; Cao, Dunping; Zhou, Xuejun ACS Nano, Vol. 12, Issue 4 https://doi.org/10.1021/acsnano.7b09177	journal	March 2018
Theoretical Analysis on De-Solvation of Lithium, Sodium, and Magnesium Cations to Organic Electrolyte Solvents Okoshi, Masaki; Yamada, Yuki; Yamada, Atsuo Journal of The Electrochemical Society, Vol. 160, Issue 11 https://doi.org/10.1149/2.074311jes	journal	January 2013
Nanocomposite polymer electrolytes for lithium batteries Croce, F.; Appetecchi, G. B.; Persi, L. Nature, Vol. 394, Issue 6692 https://doi.org/10.1038/28818	journal	July 1998
Fervent Hype behind Magnesium Batteries: An Open Call to Synthetic Chemists-Electrolytes and Cathodes Needed Muldoon, John; Bucur, Claudiu B.; Gregory, Thomas Angewandte Chemie International Edition, Vol. 56, Issue 40 https://doi.org/10.1002/anie.201700673	journal	August 2017
Ionic Conductivity in the Metal-Organic Framework UiO-66 by Dehydration and Insertion of Lithium tert -Butoxide Ameloot, Rob; Aubrey, Michael; Wiers, Brian M. Chemistry - A European Journal, Vol. 19, Issue 18 https://doi.org/10.1002/chem.201300326	journal	March 2013
Divalent magnesium ion conducting characteristics in phosphate based solid electrolyte composites Imanaka, Nobuhito; Okazaki, Yusuke; Adachi, Gin-ya Journal of Materials Chemistry, Vol. 10, Issue 6 https://doi.org/10.1039/a909599c	journal	January 2000
Magnesium Borohydride: From Hydrogen Storage to Magnesium Battery Mohtadi, Rana; Matsui, Masaki; Arthur, Timothy S. Angewandte Chemie International Edition, Vol. 51, Issue 39, p. 9780-9783 https://doi.org/10.1002/anie.201204913	journal	August 2012
Novel Sol–Gel Synthesis of MgZr ₄ P ₆ O ₂₄ Composite Solid Electrolyte and Newer Insight into the Mg ²⁺ -Ion Conducting Properties Using Impedance Spectroscopy Adamu, Mohammed; Kale, Girish M. The Journal of Physical Chemistry C, Vol. 120, Issue 32 https://doi.org/10.1021/acs.jpcc.6b05036	journal	August 2016
Rechargeable magnesium batteries with polymeric gel electrolytes containing magnesium salts Yoshimoto, Nobuko; Yakushiji, Shin; Ishikawa, Masashi Electrochimica Acta, Vol. 48, Issue 14-16, p. 2317-2322 https://doi.org/10.1016/S0013-4686(03)00221-4	journal	June 2003
Structure and compatibility of a magnesium electrolyte with a sulphur cathode Kim, Hee Soo; Arthur, Timothy S.; Allred, Gary D. Nature Communications, Vol. 2, Article No. 427 https://doi.org/10.1038/ncomms1435	journal	August 2011
Magnesium ion conducting polymeric electrolytes Chen, Kaimin; Shriver, D. F. Chemistry of Materials, Vol. 3, Issue 5 https://doi.org/10.1021/cm00017a003	journal	September 1991
Dual-Salt Mg-Based Batteries with Conversion Cathodes Zhang, Ye; Xie, Junjie; Han, Yanlin Advanced Functional Materials, Vol. 25, Issue 47 https://doi.org/10.1002/adfm.201503639	journal	November 2015
Electrochemistry of Magnesium Electrolytes in Ionic Liquids for Secondary Batteries Vardar, Gulin; Sleightholme, Alice E. S.; Naruse, Junichi ACS Applied Materials & Interfaces, Vol. 6, Issue 20 https://doi.org/10.1021/am5049064	journal	October 2014
Investigation of the Effect of Lewis Acid on Ionic Conductivity of Polymer Electrolyte Containing Mg Salt Saito, Morihiro; Ikuta, Hiromasa; Uchimoto, Yoshiharu Journal of The Electrochemical Society, Vol. 150, Issue 6 https://doi.org/10.1149/1.1572151	journal	January 2003
A new class of non-corrosive, highly efficient electrolytes for rechargeable magnesium batteries Zhao-Karger, Zhirong; Gil Bardaji, Maria Elisa; Fuhr, Olaf Journal of Materials Chemistry A, Vol. 5, Issue 22 https://doi.org/10.1039/C7TA02237A	journal	January 2017
Magnesium ion-conducting gel polymer electrolytes dispersed with nanosized magnesium oxide Pandey, G. P.; Agrawal, R. C.; Hashmi, S. A. Journal of Power Sources, Vol. 190, Issue 2, p. 563-572 https://doi.org/10.1016/j.jpowsour.2009.01.057	journal	May 2009
Experimental investigations of an ionic-liquid-based, magnesium ion conducting, polymer gel electrolyte Pandey, G. P.; Hashmi, S. A. Journal of Power Sources, Vol. 187, Issue 2 https://doi.org/10.1016/j.jpowsour.2008.10.112	journal	February 2009
Reversibility of Mg/Mg2+ couple in a gel polymer electrolyte Kumar, G. Girish; Munichandraiah, N. Electrochimica Acta, Vol. 44, Issue 15 https://doi.org/10.1016/S0013-4686(98)00388-0	journal	January 1999
Electrochemical Intercalation of Mg ²⁺ into Anhydrous and Hydrated Crystalline Tungsten Oxides Wang, Ruocun; Chung, Ching-Chang; Liu, Yang Langmuir, Vol. 33, Issue 37 https://doi.org/10.1021/acs.langmuir.7b00705	journal	July 2017
Rechargeable magnesium battery: Current status and key challenges for the future Saha, Partha; Datta, Moni Kanchan; Velikokhatnyi, Oleg I. Progress in Materials Science, Vol. 66 https://doi.org/10.1016/j.pmatsci.2014.04.001	journal	October 2014
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Enhanced Stability of the Carba- closo -dodecaborate Anion for High-Voltage Battery Electrolytes through Rational Design Hahn, Nathan T.; Seguin, Trevor J.; Lau, Ka-Cheong Journal of the American Chemical Society, Vol. 140, Issue 35 https://doi.org/10.1021/jacs.8b05967	journal	July 2018
Ionic conductance behavior of polymeric gel electrolyte containing ionic liquid mixed with magnesium salt Morita, Masayuki; Shirai, Takahiro; Yoshimoto, Nobuko Journal of Power Sources, Vol. 139, Issue 1-2 https://doi.org/10.1016/j.jpowsour.2004.07.028	journal	January 2005
Mg(PF ₆ ) ₂ -Based Electrolyte Systems: Understanding Electrolyte–Electrode Interactions for the Development of Mg-Ion Batteries Keyzer, Evan N.; Glass, Hugh F. J.; Liu, Zigeng Journal of the American Chemical Society, Vol. 138, Issue 28 https://doi.org/10.1021/jacs.6b04319	journal	July 2016
Solid electrolytes with multivalent cation conduction. 1. Conducting species in MgZrPO4 system Ikeda, S.; Takahashi, M.; Ishikawa, J. Solid State Ionics, Vol. 23, Issue 1-2 https://doi.org/10.1016/0167-2738(87)90091-9	journal	March 1987
Novel Design Concepts of Efficient Mg-Ion Electrolytes toward High-Performance Magnesium-Selenium and Magnesium-Sulfur Batteries Zhang, Zhonghua; Cui, Zili; Qiao, Lixin Advanced Energy Materials, Vol. 7, Issue 11 https://doi.org/10.1002/aenm.201602055	journal	January 2017
Ionic liquid mediated magnesium ion conduction in poly(ethylene oxide) based polymer electrolyte Kumar, Yogesh; Hashmi, S. A.; Pandey, G. P. Electrochimica Acta, Vol. 56, Issue 11 https://doi.org/10.1016/j.electacta.2011.02.035	journal	April 2011
Degradation Mechanisms of Magnesium Metal Anodes in Electrolytes Based on (CF ₃ SO ₂ ) ₂ N ^– at High Current Densities Yoo, Hyun Deog; Han, Sang-Don; Bolotin, Igor L. Langmuir, Vol. 33, Issue 37 https://doi.org/10.1021/acs.langmuir.7b01051	journal	July 2017
Preparation and characterization of gel polymer electrolytes for solid state magnesium batteries Oh, Ji-Sun; Ko, Jang-Myoun; Kim, Dong-Won Electrochimica Acta, Vol. 50, Issue 2-3 https://doi.org/10.1016/j.electacta.2004.01.099	journal	November 2004
Binary ionic liquid electrolytes containing organo-magnesium complex for rechargeable magnesium batteries Kakibe, Takeshi; Hishii, Jun-ya; Yoshimoto, Nobuko Journal of Power Sources, Vol. 203 https://doi.org/10.1016/j.jpowsour.2011.10.127	journal	April 2012

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A high-voltage concept with sodium-ion conducting β-alumina for magnesium-sodium dual-ion batteries Kravchyk, Kostiantyn V.; Walter, Marc; Kovalenko, Maksym V. Communications Chemistry, Vol. 2, Issue 1 https://doi.org/10.1038/s42004-019-0186-4	journal	July 2019
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A high-voltage concept with sodium-ion conducting β-alumina for magnesium-sodium dual-ion batteries Kravchyk, Kostiantyn V.; Walter, Marc; Kovalenko, Maksym V. ETH Zurich https://doi.org/10.3929/ethz-b-000361670	text	January 2019
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