skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Chemical self-assembly strategies for designing molecular electronic circuits

Abstract

Design principles are demonstrated for fabricating molecular electronic circuits using the inherently self-limiting growth of molecular wires between gold nanoparticles from the oligomerization of 1,4-phenylene diisocyanide.

Authors:
 [1];  [1]; ORCiD logo [1]
  1. Department of Chemistry and Biochemistry and Laboratory for Surface Studies, University of Wisconsin-Milwaukee, Milwaukee, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1572730
Grant/Contract Number:  
SC0012704.
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 55 Journal Issue: 92; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Olson, Dustin, Boscoboinik, Alejandro, and Tysoe, Wilfred T. Chemical self-assembly strategies for designing molecular electronic circuits. United Kingdom: N. p., 2019. Web. https://doi.org/10.1039/C9CC07200D.
Olson, Dustin, Boscoboinik, Alejandro, & Tysoe, Wilfred T. Chemical self-assembly strategies for designing molecular electronic circuits. United Kingdom. https://doi.org/10.1039/C9CC07200D
Olson, Dustin, Boscoboinik, Alejandro, and Tysoe, Wilfred T. Thu . "Chemical self-assembly strategies for designing molecular electronic circuits". United Kingdom. https://doi.org/10.1039/C9CC07200D.
@article{osti_1572730,
title = {Chemical self-assembly strategies for designing molecular electronic circuits},
author = {Olson, Dustin and Boscoboinik, Alejandro and Tysoe, Wilfred T.},
abstractNote = {Design principles are demonstrated for fabricating molecular electronic circuits using the inherently self-limiting growth of molecular wires between gold nanoparticles from the oligomerization of 1,4-phenylene diisocyanide.},
doi = {10.1039/C9CC07200D},
journal = {ChemComm},
number = 92,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C9CC07200D

Citation Metrics:
Cited by: 1 work
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Creation of Low-Coordination Gold Sites on Au(111) Surface by 1,4-phenylene Diisocyanide Adsorption
journal, January 2011


Adsorption of Aryl and Alkyl Isocyanides on Powdered Gold
journal, May 1994

  • Robertson, Mitchell J.; Angelici, Robert J.
  • Langmuir, Vol. 10, Issue 5
  • DOI: 10.1021/la00017a028

Quantum chemistry calculations for molecules coupled to reservoirs: Formalism, implementation, and application to benzenedithiol
journal, May 2007

  • Arnold, A.; Weigend, F.; Evers, F.
  • The Journal of Chemical Physics, Vol. 126, Issue 17
  • DOI: 10.1063/1.2716664

Correlation between HOMO Alignment and Contact Resistance in Molecular Junctions:  Aromatic Thiols versus Aromatic Isocyanides
journal, April 2006

  • Kim, ; Beebe, Jeremy M.; Jun, Yongseok
  • Journal of the American Chemical Society, Vol. 128, Issue 15
  • DOI: 10.1021/ja0607990

Electron transmission characteristics of Au/1,4-benzenedithiol/Au junctions
journal, December 2008


Benzenedithiol: A Broad-Range Single-Channel Molecular Conductor
journal, September 2011

  • Kim, Youngsang; Pietsch, Torsten; Erbe, Artur
  • Nano Letters, Vol. 11, Issue 9
  • DOI: 10.1021/nl201777m

Self-Assembled Oligomeric Structures from 1,4-Benzenedithiol on Au(111) and the Formation of Conductive Linkers between Gold Nanoparticles
journal, September 2015

  • Kestell, John; Abuflaha, Rasha; Garvey, Michael
  • The Journal of Physical Chemistry C, Vol. 119, Issue 40
  • DOI: 10.1021/acs.jpcc.5b07343

Conductance of Molecular Wires:  Influence of Molecule−Electrode Binding
journal, April 1999

  • Yaliraki, S. N.; Kemp, M.; Ratner, Mark A.
  • Journal of the American Chemical Society, Vol. 121, Issue 14
  • DOI: 10.1021/ja982918k

Reproducible Measurement of Single-Molecule Conductivity
journal, October 2001


Length-Dependent Conductance of Conjugated Molecular Wires Synthesized by Stepwise “Click” Chemistry
journal, July 2010

  • Luo, Liang; Frisbie, C. Daniel
  • Journal of the American Chemical Society, Vol. 132, Issue 26
  • DOI: 10.1021/ja103239b

Molecular Electronics
journal, October 1992


Hopping Conductivity in Granular Metals
journal, July 1973


Equilibrium and Saturation Coverage Studies of Alkyl and Aryl Isocyanides on Powdered Gold
journal, July 1995


Substrate dependent structure of adsorbed aryl isocyanides studied by sum frequency generation (SFG) spectroscopy
journal, January 2010

  • Ito, Mikio; Noguchi, Hidenori; Ikeda, Katsuyoshi
  • Physical Chemistry Chemical Physics, Vol. 12, Issue 13
  • DOI: 10.1039/b920411c

Length Dependence of Conductance in Aromatic Single-Molecule Junctions
journal, November 2009

  • Quek, Su Ying; Choi, Hyoung Joon; Louie, Steven G.
  • Nano Letters, Vol. 9, Issue 11
  • DOI: 10.1021/nl9021336

Microscopic Characterization of the Interface between Aromatic Isocyanides and Au(111):  A First-Principles Investigation
journal, April 2008

  • Li, Yan; Lu, Deyu; Swanson, Sally A.
  • The Journal of Physical Chemistry C, Vol. 112, Issue 16
  • DOI: 10.1021/jp7111044

Measurement of Single Molecule Conductance:  Benzenedithiol and Benzenedimethanethiol
journal, February 2004


Electronic transport through metal–1,4-phenylene diisocyanide–metal junctions
journal, November 1999


Conductance of a Molecular Junction
journal, October 1997


Linking gold nanoparticles with conductive 1,4-phenylene diisocyanide–gold oligomers
journal, January 2013

  • Kestell, John; Abuflaha, Rasha; Boscoboinik, J. Anibal
  • Chemical Communications, Vol. 49, Issue 14
  • DOI: 10.1039/c2cc38389f

Influence of Conformation on Conductance of Biphenyl-Dithiol Single-Molecule Contacts
journal, January 2010

  • Mishchenko, Artem; Vonlanthen, David; Meded, Velimir
  • Nano Letters, Vol. 10, Issue 1
  • DOI: 10.1021/nl903084b

Determination of Adsorbate Structures from 1,4-Phenylene Diisocyanide on Gold
journal, September 2014

  • Kestell, John; Abuflaha, Rasha; Boscoboinik, J. Anibal
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 20
  • DOI: 10.1021/jz501761u

Transport in State Space: Voltage-Dependent Conductance Calculations of Benzene-1,4-dithiol
journal, May 2009

  • Yeganeh, Sina; Ratner, Mark A.; Galperin, Michael
  • Nano Letters, Vol. 9, Issue 5
  • DOI: 10.1021/nl803635t

Adsorption of Benzene-1,4-dithiol on the Au(111) Surface and Its Possible Role in Molecular Conductance
journal, July 2006

  • Pontes, Renato B.; Novaes, Frederico D.; Fazzio, Adalberto
  • Journal of the American Chemical Society, Vol. 128, Issue 28
  • DOI: 10.1021/ja0612495

Chemical Self-Assembly Strategies for Designing Molecular Electronic Circuits: Demonstration of Concept
journal, April 2019

  • Olson, Dustin; Boscoboinik, Alejandro; Manzi, Sergio
  • The Journal of Physical Chemistry C, Vol. 123, Issue 16
  • DOI: 10.1021/acs.jpcc.9b00666

Progress in self-assembled single-molecule electronic devices
journal, January 2013

  • Gschneidtner, Tina A.; Diaz Fernandez, Yuri A.; Moth-Poulsen, Kasper
  • Journal of Materials Chemistry C, Vol. 1, Issue 43
  • DOI: 10.1039/c3tc31483a

Directed Nanoscale Self-Assembly of Molecular Wires Interconnecting Nodal Points Using Monte Carlo Simulations
journal, September 2015


An approach to transport measurements of electronic molecules
journal, April 2002

  • Amlani, Islamshah; Rawlett, Adam M.; Nagahara, Larry A.
  • Applied Physics Letters, Vol. 80, Issue 15
  • DOI: 10.1063/1.1469655

Tuning the Coulomb charging energy in cross-linked nanoparticle films
journal, December 2007


High-conductance states of single benzenedithiol molecules
journal, October 2006

  • Tsutsui, Makusu; Teramae, Yumi; Kurokawa, Shu
  • Applied Physics Letters, Vol. 89, Issue 16
  • DOI: 10.1063/1.2363995

A Comparative Investigation of Aryl Isocyanides Chemisorbed to Palladium and Gold:  An ATR-IR Spectroscopic Study
journal, March 2004

  • Murphy, Kristen L.; Tysoe, Wilfred T.; Bennett, Dennis W.
  • Langmuir, Vol. 20, Issue 5
  • DOI: 10.1021/la030293k

Molecular rectifiers
journal, November 1974


Conductance of a single molecule anchored by an isocyanide substituent to gold electrodes
journal, November 2006

  • Kiguchi, Manabu; Miura, Shinichi; Hara, Kenji
  • Applied Physics Letters, Vol. 89, Issue 21
  • DOI: 10.1063/1.2392816

Structural and electrical properties of granular metal films
journal, May 1975


Contact configuration dependence of conductance of 1,4-phenylene diisocyanide molecular junction
journal, September 2006


Surface chemistry and structures of 1,4-phenylene diisocyanide on gold films from solution
journal, July 2016


Ab Initio Calculations of Structural Evolution and Conductance of Benzene-1,4-dithiol on Gold Leads
journal, January 2011

  • Pontes, Renato Borges; Rocha, Alexandre Reily; Sanvito, Stefano
  • ACS Nano, Vol. 5, Issue 2
  • DOI: 10.1021/nn101628w

Adsorption Structures and Electronic Properties of 1,4-Phenylene Diisocyanide on the Au(111) Surface
journal, October 2011

  • Zhou, J.; Acharya, D.; Camillone, N.
  • The Journal of Physical Chemistry C, Vol. 115, Issue 43
  • DOI: 10.1021/jp205349e

Spontaneous self-assembly of conductive molecular linkages between gold nanoelectrodes from aryl diisocyanides
journal, October 2018


One-dimensional supramolecular surface structures: 1,4-diisocyanobenzene on Au(111) surfaces
journal, January 2010

  • Boscoboinik, Jorge A.; Calaza, Florencia C.; Habeeb, Zeesham
  • Physical Chemistry Chemical Physics, Vol. 12, Issue 37
  • DOI: 10.1039/c003239e

Hopping conductivity in granular disordered systems
journal, February 1983


Understanding and Controlling the 1,4-Phenylene Diisocyanide–Gold Oligomer Formation Pathways
journal, August 2014

  • Garvey, Michael; Kestell, John; Abuflaha, Rasha
  • The Journal of Physical Chemistry C, Vol. 118, Issue 36
  • DOI: 10.1021/jp504799p