Transfer of Graphene with Protective Oxide Layers
Abstract
Transfer of graphene, grown by chemical vapor deposition (CVD), to a substrate of choice, typically involves the deposition of a polymeric layer (for example, poly(methyl methacrylate) (PMMA), or polydimethylsiloxane, PDMS). These polymers are quite hard to remove without leaving some residues behind. One method to improve the graphene transfer is to coat the graphene with a thin protective oxide layer, followed by the deposition of a very thin polymer layer on top of the oxide layer (much thinner than the usual thickness), followed by a more aggressive polymeric removal method, thus leaving the graphene intact. At the same time, having an oxide layer on graphene may serve applications, such as channeled transistors or sensing devices. Here, we study the transfer of graphene with a protective thin oxide layer grown by atomic layer deposition (ALD). We follow the transfer process from the graphene growth stage through oxide deposition until completion. We report on the nucleation growth process of oxides on graphene, their resultant strain and their optical transmission.
- Authors:
-
- New Jersey Inst. of Technology (NJIT), Newark, NJ (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1572724
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemEngineering
- Additional Journal Information:
- Journal Volume: 2; Journal Issue: 4; Journal ID: ISSN 2305-7084
- Publisher:
- MDPI
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Atomic Layer Deposition (ALD); Oxide layer deposition on graphene; Raman spectroscopy of graphene; Thin oxide films; Transfer of 24 graphene
Citation Formats
Grebel, Haim, Stan, Liliana, Sumant, Anirudha, Liu, Yuzi, Gosztola, David, Ocola, Leonidas, and Fisher, Brandon. Transfer of Graphene with Protective Oxide Layers. United States: N. p., 2018.
Web. doi:10.3390/chemengineering2040058.
Grebel, Haim, Stan, Liliana, Sumant, Anirudha, Liu, Yuzi, Gosztola, David, Ocola, Leonidas, & Fisher, Brandon. Transfer of Graphene with Protective Oxide Layers. United States. https://doi.org/10.3390/chemengineering2040058
Grebel, Haim, Stan, Liliana, Sumant, Anirudha, Liu, Yuzi, Gosztola, David, Ocola, Leonidas, and Fisher, Brandon. Mon .
"Transfer of Graphene with Protective Oxide Layers". United States. https://doi.org/10.3390/chemengineering2040058. https://www.osti.gov/servlets/purl/1572724.
@article{osti_1572724,
title = {Transfer of Graphene with Protective Oxide Layers},
author = {Grebel, Haim and Stan, Liliana and Sumant, Anirudha and Liu, Yuzi and Gosztola, David and Ocola, Leonidas and Fisher, Brandon},
abstractNote = {Transfer of graphene, grown by chemical vapor deposition (CVD), to a substrate of choice, typically involves the deposition of a polymeric layer (for example, poly(methyl methacrylate) (PMMA), or polydimethylsiloxane, PDMS). These polymers are quite hard to remove without leaving some residues behind. One method to improve the graphene transfer is to coat the graphene with a thin protective oxide layer, followed by the deposition of a very thin polymer layer on top of the oxide layer (much thinner than the usual thickness), followed by a more aggressive polymeric removal method, thus leaving the graphene intact. At the same time, having an oxide layer on graphene may serve applications, such as channeled transistors or sensing devices. Here, we study the transfer of graphene with a protective thin oxide layer grown by atomic layer deposition (ALD). We follow the transfer process from the graphene growth stage through oxide deposition until completion. We report on the nucleation growth process of oxides on graphene, their resultant strain and their optical transmission.},
doi = {10.3390/chemengineering2040058},
journal = {ChemEngineering},
number = 4,
volume = 2,
place = {United States},
year = {2018},
month = {12}
}
Works referenced in this record:
Automatic graphene transfer system for improved material quality and efficiency
journal, February 2016
- Boscá, Alberto; Pedrós, Jorge; Martínez, Javier
- Scientific Reports, Vol. 6, Issue 1
Structural Defects in Graphene
journal, November 2010
- Banhart, Florian; Kotakoski, Jani; Krasheninnikov, Arkady V.
- ACS Nano, Vol. 5, Issue 1
Raman spectroscopy of graphene and graphite: Disorder, electron–phonon coupling, doping and nonadiabatic effects
journal, July 2007
- Ferrari, Andrea C.
- Solid State Communications, Vol. 143, Issue 1-2, p. 47-57
Realization of a high mobility dual-gated graphene field-effect transistor with Al2O3 dielectric
journal, February 2009
- Kim, Seyoung; Nah, Junghyo; Jo, Insun
- Applied Physics Letters, Vol. 94, Issue 6
Current saturation in zero-bandgap, top-gated graphene field-effect transistors
journal, September 2008
- Meric, Inanc; Han, Melinda Y.; Young, Andrea F.
- Nature Nanotechnology, Vol. 3, Issue 11
Simple method to transfer graphene from metallic catalytic substrates to flexible surfaces without chemical etching
journal, April 2013
- Ko, P. J.; Takahashi, H.; Koide, S.
- Journal of Physics: Conference Series, Vol. 433
Epitaxial-Graphene RF Field-Effect Transistors on Si-Face 6H-SiC Substrates
journal, June 2009
- Moon, J. S.; Curtis, D.; Hu, M.
- IEEE Electron Device Letters, Vol. 30, Issue 6
Substrate-assisted nucleation of ultra-thin dielectric layers on graphene by atomic layer deposition
journal, April 2012
- Dlubak, B.; Kidambi, P. R.; Weatherup, R. S.
- Applied Physics Letters, Vol. 100, Issue 17
Efficient etching-free transfer of high quality, large-area CVD grown graphene onto polyvinyl alcohol films
journal, February 2016
- Marta, Bogdan; Leordean, Cosmin; Istvan, Todor
- Applied Surface Science, Vol. 363
Graphene Strained by Defects
journal, April 2017
- Robinson, Jeremy T.; Zalalutdinov, Maxim K.; Cress, Cory D.
- ACS Nano, Vol. 11, Issue 5
Wafer-Scale Synthesis and Transfer of Graphene Films
journal, February 2010
- Lee, Youngbin; Bae, Sukang; Jang, Houk
- Nano Letters, Vol. 10, Issue 2
Conformal Al2O3 dielectric layer deposited by atomic layer deposition for graphene-based nanoelectronics
journal, May 2008
- Lee, Bongki; Park, Seong-Yong; Kim, Hyun-Chul
- Applied Physics Letters, Vol. 92, Issue 20
Atomic Layer Deposition of Metal Oxides on Pristine and Functionalized Graphene
journal, July 2008
- Wang, Xinran; Tabakman, Scott M.; Dai, Hongjie
- Journal of the American Chemical Society, Vol. 130, Issue 26
Improvement of Al 2 O 3 Films on Graphene Grown by Atomic Layer Deposition with Pre-H 2 O Treatment
journal, May 2014
- Zheng, Li; Cheng, Xinhong; Cao, Duo
- ACS Applied Materials & Interfaces, Vol. 6, Issue 10
Electrical characterization of thin Al2O3 films grown by atomic layer deposition on silicon and various metal substrates
journal, June 2002
- Groner, M. D.; Elam, J. W.; Fabreguette, F. H.
- Thin Solid Films, Vol. 413, Issue 1-2, p. 186-197
The role of interlayer adhesion in graphene oxide upon its reinforcement of nanocomposites
journal, July 2016
- Li, Zheling; Kinloch, Ian A.; Young, Robert J.
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 374, Issue 2071
Progress and Challenges in Transfer of Large-Area Graphene Films
journal, February 2016
- Chen, Yi; Gong, Xiao-Lei; Gai, Jing-Gang
- Advanced Science, Vol. 3, Issue 8
Deposition of High-Quality on Graphene and the Effect of Remote Oxide Phonon Scattering
journal, September 2010
- Zou, K.; Hong, X.; Keefer, D.
- Physical Review Letters, Vol. 105, Issue 12
Utilization of a Buffered Dielectric to Achieve High Field-Effect Carrier Mobility in Graphene Transistors
journal, December 2009
- Farmer, Damon B.; Chiu, Hsin-Ying; Lin, Yu-Ming
- Nano Letters, Vol. 9, Issue 12
Nitrogen-doped graphene: beyond single substitution and enhanced molecular sensing
journal, August 2012
- Lv, Ruitao; Li, Qing; Botello-Méndez, Andrés R.
- Scientific Reports, Vol. 2, Issue 1
Kinetic theory of two-component (“hetero-molecular”) nucleation and condensation
journal, July 1976
- Stauffer, D.
- Journal of Aerosol Science, Vol. 7, Issue 4
PMMA-Etching-Free Transfer of Wafer-scale Chemical Vapor Deposition Two-dimensional Atomic Crystal by a Water Soluble Polyvinyl Alcohol Polymer Method
journal, September 2016
- Van Ngoc, Huynh; Qian, Yongteng; Han, Suk Kil
- Scientific Reports, Vol. 6, Issue 1
Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor
journal, March 2008
- Das, A.; Pisana, S.; Chakraborty, B.
- Nature Nanotechnology, Vol. 3, Issue 4
Repeated growth and bubbling transfer of graphene with millimetre-size single-crystal grains using platinum
journal, January 2012
- Gao, Libo; Ren, Wencai; Xu, Huilong
- Nature Communications, Vol. 3, Issue 1
A sustainable approach to large area transfer of graphene and recycling of the copper substrate
journal, January 2017
- Wang, Michael Cai; Moestopo, Widianto P.; Takekuma, Satoshi
- Journal of Materials Chemistry C, Vol. 5, Issue 43
Crystallinity of inorganic films grown by atomic layer deposition: Overview and general trends
journal, January 2013
- Miikkulainen, Ville; Leskelä, Markku; Ritala, Mikko
- Journal of Applied Physics, Vol. 113, Issue 2, Article No. 021301
Characteristics of high-k Al2O3 dielectric using ozone-based atomic layer deposition for dual-gated graphene devices
journal, July 2010
- Lee, B.; Mordi, G.; Kim, M. J.
- Applied Physics Letters, Vol. 97, Issue 4
Atomic layer deposition of HfO2 on graphene from HfCl4 and H2O
journal, January 2011
- Alles, Harry; Aarik, Jaan; Aidla, Aleks
- Open Physics, Vol. 9, Issue 2
Effect of hydrogen flow during cooling phase to achieve uniform and repeatable growth of bilayer graphene on copper foils over large area
journal, October 2014
- Gulotty, Richard; Das, Saptarshi; Liu, Yuzi
- Carbon, Vol. 77
Clean transfer of graphene and its effect on contact resistance
journal, September 2013
- Lee, Jooho; Kim, Yongsung; Shin, Hyeon-Jin
- Applied Physics Letters, Vol. 103, Issue 10
Transfer of CVD-Grown Monolayer Graphene onto Arbitrary Substrates
journal, August 2011
- Suk, Ji Won; Kitt, Alexander; Magnuson, Carl W.
- ACS Nano, Vol. 5, Issue 9
Atomic layer deposited oxide films as protective interface layers for integrated graphene transfer
journal, November 2017
- Cabrero-Vilatela, A.; Alexander-Webber, J. A.; Sagade, A. A.
- Nanotechnology, Vol. 28, Issue 48
Two-component heterogeneous nucleation kinetics and an application to Mars
journal, October 2007
- Määttänen, Anni; Vehkamäki, Hanna; Lauri, Antti
- The Journal of Chemical Physics, Vol. 127, Issue 13
Atomic layer deposited oxide films as protective interface layers for integrated graphene transfer
text, January 2017
- Cabrero-Vilatela, A.; Alexander-Webber, Jack Allen; Sagade, Abhay
- Apollo - University of Cambridge Repository
The Deposition of High-Quality HfO2 on Graphene and the Effect of Remote Oxide Phonon Scattering
text, January 2009
- Zou, Ke; Hong, Xia; Keefer, Derek
- arXiv
Works referencing / citing this record:
Recent Advances in Seeded and Seed-Layer-Free Atomic Layer Deposition of High-K Dielectrics on Graphene for Electronics
journal, September 2019
- Schilirò, Emanuela; Lo Nigro, Raffaella; Roccaforte, Fabrizio
- C — Journal of Carbon Research, Vol. 5, Issue 3