Enhancement of magnetodielectric coupling in 6H-perovskites for heavier rare-earth cations ( )
Abstract
The role of rare-earth (R) ions in magnetodielectric (MD) coupling is always intriguing and markedly different for different systems. Although many reports are available concerning this aspect in frustrated 3d-transition metal oxides, no such reports exist on higher d (4d/5d)-orbital based systems due to the rare availability of highly insulating 4d/5d systems. Here, we systematically investigated the magnetic, dielectric, ferroelectric, and magnetodielectric behavior of the 6H-perovskites Ba3RRu2O9 for different R-ions, namely R = Sm, Tb, and Ho, which magnetically order at 12, 9.5, and 10.2 K, respectively. For R = Tb and Ho, the temperature and magnetic-field-dependent complex dielectric constant traces the magnetic features, which manifests MD coupling in this system. A weak magnetic-field (H) induced transition is observed for ~30 kOe, which is clearly captured in H-dependent dielectric measurements. No MD coupling is observed for Ba3SmRu2O9. The MD coupling is enhanced by a factor of 3 and 20 times for R = Tb and Ho, respectively, when compared to that of the Nd-counterpart. Here, these results evidence the gradual enhancement of MD coupling with the introduction of heavier R-ions in this series, which is attributed to their larger moment values. Our investigation establishes dominating 4d(Ru)-4ƒ(R) magnetic correlation in thismore »
- Authors:
-
[1];
[4];
[3];
- Lab. CRISMAT, Caen (France); Michigan State Univ., East Lansing, MI (United States); Univ. of Augsburg, Augsburg (Germany)
- Lab. CRISMAT, Caen (France)
- Univ. of Augsburg, Augsburg (Germany)
- Michigan State Univ., East Lansing, MI (United States)
- Publication Date:
- Research Org.:
- Michigan State Univ., East Lansing, MI (United States). Dept. of Physics and Astronomy
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
- OSTI Identifier:
- 1572689
- Grant/Contract Number:
- SC0019259
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review Materials
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 11; Journal ID: ISSN 2475-9953
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Magnetic; Multiferroic; magnetoelectric; Ru-based system
Citation Formats
Basu, Tathamay, Caignaert, Vincent, Ghara, Somnath, Ke, Xianglin, Pautrat, Alain, Krohns, Stephan, Loidl, Alois, and Raveau, Bernard. Enhancement of magnetodielectric coupling in 6H-perovskites Ba3RRu2O9 for heavier rare-earth cations (R=Ho,Tb). United States: N. p., 2019.
Web. doi:10.1103/PhysRevMaterials.3.114401.
Basu, Tathamay, Caignaert, Vincent, Ghara, Somnath, Ke, Xianglin, Pautrat, Alain, Krohns, Stephan, Loidl, Alois, & Raveau, Bernard. Enhancement of magnetodielectric coupling in 6H-perovskites Ba3RRu2O9 for heavier rare-earth cations (R=Ho,Tb). United States. https://doi.org/10.1103/PhysRevMaterials.3.114401
Basu, Tathamay, Caignaert, Vincent, Ghara, Somnath, Ke, Xianglin, Pautrat, Alain, Krohns, Stephan, Loidl, Alois, and Raveau, Bernard. Fri .
"Enhancement of magnetodielectric coupling in 6H-perovskites Ba3RRu2O9 for heavier rare-earth cations (R=Ho,Tb)". United States. https://doi.org/10.1103/PhysRevMaterials.3.114401. https://www.osti.gov/servlets/purl/1572689.
@article{osti_1572689,
title = {Enhancement of magnetodielectric coupling in 6H-perovskites Ba3RRu2O9 for heavier rare-earth cations (R=Ho,Tb)},
author = {Basu, Tathamay and Caignaert, Vincent and Ghara, Somnath and Ke, Xianglin and Pautrat, Alain and Krohns, Stephan and Loidl, Alois and Raveau, Bernard},
abstractNote = {The role of rare-earth (R) ions in magnetodielectric (MD) coupling is always intriguing and markedly different for different systems. Although many reports are available concerning this aspect in frustrated 3d-transition metal oxides, no such reports exist on higher d (4d/5d)-orbital based systems due to the rare availability of highly insulating 4d/5d systems. Here, we systematically investigated the magnetic, dielectric, ferroelectric, and magnetodielectric behavior of the 6H-perovskites Ba3RRu2O9 for different R-ions, namely R = Sm, Tb, and Ho, which magnetically order at 12, 9.5, and 10.2 K, respectively. For R = Tb and Ho, the temperature and magnetic-field-dependent complex dielectric constant traces the magnetic features, which manifests MD coupling in this system. A weak magnetic-field (H) induced transition is observed for ~30 kOe, which is clearly captured in H-dependent dielectric measurements. No MD coupling is observed for Ba3SmRu2O9. The MD coupling is enhanced by a factor of 3 and 20 times for R = Tb and Ho, respectively, when compared to that of the Nd-counterpart. Here, these results evidence the gradual enhancement of MD coupling with the introduction of heavier R-ions in this series, which is attributed to their larger moment values. Our investigation establishes dominating 4d(Ru)-4ƒ(R) magnetic correlation in this series for the heavier R-members.},
doi = {10.1103/PhysRevMaterials.3.114401},
journal = {Physical Review Materials},
number = 11,
volume = 3,
place = {United States},
year = {Fri Nov 01 00:00:00 EDT 2019},
month = {Fri Nov 01 00:00:00 EDT 2019}
}
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