Tuning two-dimensional phase formation through epitaxial strain and growth conditions: silica and silicate on Ni x Pd 1−x (111) alloy substrates

doi:10.1039/C9NR05944J

This content will become publicly available on October 24, 2020

Title: Tuning two-dimensional phase formation through epitaxial strain and growth conditions: silica and silicate on Ni _x Pd _1−x (111) alloy substrates

Abstract

The combined experimental and theoretical results demonstrate the manipulation of 2D VDW silica and 2D Ni silicate through growth conditions, and the determination of the maximum epitaxial strain imparted to the 2D system through alloy substrate.

Authors:

^[1]; Liang, Xin ^[2];

^[3]; Jhang, Jin-Hao ^[3];

^[3];

^[4];

^[5];

^[6];

^[3]

Department of Mechanical Engineering and Materials Science, Yale University, New Haven, USA
Department of Applied Physics, Yale University, New Haven, USA
Department of Chemical and Environmental Engineering, Yale University, New Haven, USA
Department of Applied Physics, Yale University, New Haven, USA, Energy Sciences Institute
Department of Mechanical Engineering and Materials Science, Yale University, New Haven, USA, Department of Chemical and Environmental Engineering
Department of Mechanical Engineering and Materials Science, Yale University, New Haven, USA, Department of Applied Physics

Publication Date:: 2019-01-01

Sponsoring Org.:: USDOE

OSTI Identifier:: 1572588

Grant/Contract Number:: SC0012704; SC0014414

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Nanoscale

Additional Journal Information:: Journal Name: Nanoscale; Journal ID: ISSN 2040-3364

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Zhou, Chao, Liang, Xin, Hutchings, Gregory S., Jhang, Jin-Hao, Fishman, Zachary S., Wu, Rongting, Gozar, Adrian, Schwarz, Udo D., Ismail-Beigi, Sohrab, and Altman, Eric I. Tuning two-dimensional phase formation through epitaxial strain and growth conditions: silica and silicate on Ni x Pd 1−x (111) alloy substrates.  United Kingdom: N. p., 2019. 
        Web.  doi:10.1039/C9NR05944J.

Copy to clipboard


                    Zhou, Chao, Liang, Xin, Hutchings, Gregory S., Jhang, Jin-Hao, Fishman, Zachary S., Wu, Rongting, Gozar, Adrian, Schwarz, Udo D., Ismail-Beigi, Sohrab, & Altman, Eric I. Tuning two-dimensional phase formation through epitaxial strain and growth conditions: silica and silicate on Ni x Pd 1−x (111) alloy substrates.  United Kingdom.  doi:10.1039/C9NR05944J.

Copy to clipboard


                    Zhou, Chao, Liang, Xin, Hutchings, Gregory S., Jhang, Jin-Hao, Fishman, Zachary S., Wu, Rongting, Gozar, Adrian, Schwarz, Udo D., Ismail-Beigi, Sohrab, and Altman, Eric I. Tue .  
        "Tuning two-dimensional phase formation through epitaxial strain and growth conditions: silica and silicate on Ni x Pd 1−x (111) alloy substrates".  United Kingdom.  doi:10.1039/C9NR05944J.

Copy to clipboard


                    
@article{osti_1572588,

  title        = {Tuning two-dimensional phase formation through epitaxial strain and growth conditions: silica and silicate on Ni x Pd 1−x (111) alloy substrates},

  author       = {Zhou, Chao and Liang, Xin and Hutchings, Gregory S. and Jhang, Jin-Hao and Fishman, Zachary S. and Wu, Rongting and Gozar, Adrian and Schwarz, Udo D. and Ismail-Beigi, Sohrab and Altman, Eric I.},

  abstractNote = {The combined experimental and theoretical results demonstrate the manipulation of 2D VDW silica and 2D Ni silicate through growth conditions, and the determination of the maximum epitaxial strain imparted to the 2D system through alloy substrate.},

  doi          = {10.1039/C9NR05944J},

  journal      = {Nanoscale},

  number       = ,

  volume       = ,

  place        = {United Kingdom},

  year         = {2019},

  month        = {1}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

This content will become publicly available on October 24, 2020

Publisher's Version of Record

DOI: 10.1039/C9NR05944J

Other availability

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
DOI: 10.1103/PhysRevLett.77.3865

Epitaxial graphene on ruthenium
journal, April 2008

Sutter, Peter W.; Flege, Jan-Ingo; Sutter, Eli A.
Nature Materials, Vol. 7, Issue 5, p. 406-411
DOI: 10.1038/nmat2166

Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene
journal, March 2013

Butler, Sheneve Z.; Hollen, Shawna M.; Cao, Linyou
ACS Nano, Vol. 7, Issue 4, p. 2898-2926
DOI: 10.1021/nn400280c

Grains and grain boundaries in single-layer graphene atomic patchwork quilts
journal, January 2011

Huang, Pinshane Y.; Ruiz-Vargas, Carlos S.; van der Zande, Arend M.
Nature, Vol. 469, Issue 7330, p. 389-392
DOI: 10.1038/nature09718

Graphene-Like Two-Dimensional Materials
journal, January 2013

Xu, Mingsheng; Liang, Tao; Shi, Minmin
Chemical Reviews, Vol. 113, Issue 5, p. 3766-3798
DOI: 10.1021/cr300263a

Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965

Kohn, W.; Sham, L. J.
Physical Review, Vol. 140, Issue 4A, p. A1133-A1138
DOI: 10.1103/PhysRev.140.A1133

Van der Waals heterostructures
journal, July 2013

Geim, A. K.; Grigorieva, I. V.
Nature, Vol. 499, Issue 7459, p. 419-425
DOI: 10.1038/nature12385

Inhomogeneous Electron Gas
journal, November 1964

Hohenberg, P.; Kohn, W.
Physical Review, Vol. 136, Issue 3B, p. B864-B871
DOI: 10.1103/PhysRev.136.B864

Semiempirical GGA-type density functional constructed with a long-range dispersion correction
journal, January 2006

Grimme, Stefan
Journal of Computational Chemistry, Vol. 27, Issue 15, p. 1787-1799
DOI: 10.1002/jcc.20495

Similar Records in DOE PAGES and OSTI.GOV collections:

Epitaxial Ni _x Pd _1–x (111) Alloy Substrates with Continuously Tunable Lattice Constants for 2D Materials Growth

Journal Article Hutchings, Gregory S. ; Jhang, Jin-Hao ; Zhou, Chao ; ... - ACS Applied Materials and Interfaces

Not provided.
DOI: 10.1021/acsami.7b01369
Vapor-liquid-solid epitaxial growth of Si ₁₋ _x Ge _x alloy nanowires: Composition dependence on precursor reactivity and morphology control for vertical forests

Journal Article Choi, S. G. ; Manandhar, P. ; Picraux, S. T. - Journal of Applied Physics
Cited by 2
DOI: 10.1063/1.4923355
Multi-functional ultrathin Pd _xCu _1-x and Pt~Pd _xCu _1-x one-dimensional nanowire motifs for various small molecule oxidation reactions

Journal Article Liu, Haiqing ; Wong, Stanislaus S. ; Adzic, Radoslav R. - ACS Applied Materials and Interfaces

Developing novel electrocatalysts for small molecule oxidation processes, including formic acid oxidation (FAOR), methanol oxidation reaction (MOR), and ethanol oxidation reaction (EOR), denoting the key anodic reactions for their respective fuel cell configurations, is a significant and relevant theme of recent efforts in the field. Herein, in this report, we demonstrated a concerted effort to couple and combine the benefits of small size, anisotropic morphology, and tunable chemical composition in order to devise a novel “family” of functional architectures. In particular, we have fabricated not only ultrathin 1-D Pd _1–xCu _x alloys but also Pt-coated Pd _1–xCu _x (i.e., Pt~Pdmore »« less
Cited by 20
DOI: 10.1021/acsami.5b07964
Electronic structure of epitaxial Ni{sub x}Pd{sub 1{minus}x} alloy films on Cu{sub 3}Au(100)

Journal Article Muschiol, U. ; Seider, M. ; Schneider, C. M. ; ... - Journal of Applied Physics

We studied epitaxially grown single-crystalline chemically disordered ultrathin Ni{sub x}Pd{sub 1{minus}x} alloy films on Cu{sub 3}Au(100) by means of photoemission using magnetic circular dichroism in the angular distribution. We clearly observe a well-defined three-dimensional band dispersion in 15 monolayer films. On the basis of relativistic selection rules, this dispersion can be related to specific electronic states. Since the spin{endash}orbit coupling ({Delta}E{sub so}) is smaller for Ni than for Pd, the alloy will assume an average value. We find that this average spin{endash}orbit coupling clearly shows up in the electronic structure and correlates directly to the composition of the NiPd alloymore »« less
DOI: 10.1063/1.1361261
Growth of GaP ₁ ₋ _x ₋ _y As _y N _x on Si substrates by chemical beam epitaxy

Journal Article Ben Saddik, K. ; Braña, A. F. ; López, N. ; ... - Journal of Applied Physics
DOI: 10.1063/1.5111090

Similar Records

This content will become publicly available on October 24, 2020

Title: Tuning two-dimensional phase formation through epitaxial strain and growth conditions: silica and silicate on Ni x Pd 1−x (111) alloy substrates

Abstract

Citation Formats

Generalized Gradient Approximation Made Simple journal, October 1996

Epitaxial graphene on ruthenium journal, April 2008

Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene journal, March 2013

Grains and grain boundaries in single-layer graphene atomic patchwork quilts journal, January 2011

Graphene-Like Two-Dimensional Materials journal, January 2013

Self-Consistent Equations Including Exchange and Correlation Effects journal, November 1965

Van der Waals heterostructures journal, July 2013

Inhomogeneous Electron Gas journal, November 1964

Semiempirical GGA-type density functional constructed with a long-range dispersion correction journal, January 2006

Title: Tuning two-dimensional phase formation through epitaxial strain and growth conditions: silica and silicate on Ni _x Pd _1−x (111) alloy substrates

Generalized Gradient Approximation Made Simple
journal, October 1996

Epitaxial graphene on ruthenium
journal, April 2008

Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene
journal, March 2013

Grains and grain boundaries in single-layer graphene atomic patchwork quilts
journal, January 2011

Graphene-Like Two-Dimensional Materials
journal, January 2013

Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965

Van der Waals heterostructures
journal, July 2013

Inhomogeneous Electron Gas
journal, November 1964

Semiempirical GGA-type density functional constructed with a long-range dispersion correction
journal, January 2006