Effect of doping on the performance of high-crystalline SrMnO3 perovskite nanofibers as a supercapacitor electrode

George, Gibin; Jackson, Shanell L.; Luo, Charles Q.; Fang, Dong; Luo, Duan; Hu, Dongli; Wen, Jianguo; Luo, Zhiping

doi:10.1016/j.ceramint.2018.08.313

Title: Effect of doping on the performance of high-crystalline SrMnO₃ perovskite nanofibers as a supercapacitor electrode

Journal Article · 28 August 2018 · Ceramics International

DOI: https://doi.org/10.1016/j.ceramint.2018.08.313 · OSTI ID:1572464

George, Gibin ^[1]; Jackson, Shanell L. ^[1]; Luo, Charles Q. ^[1]; Fang, Dong ^[2]; Luo, Duan ^[3]; Hu, Dongli ^[3]; Wen, Jianguo ^[3]; Luo, Zhiping ^[1]

Fayetteville State Univ., Fayetteville, NC (United States)
Kunming Univ. of Science and Technology, Kunming (People's Republic of China)
Argonne National Lab. (ANL), Argonne, IL (United States)

Perovskite oxides are promising multi-functional materials with enhanced physical and chemical properties. In this study, high-crystalline SrMnO₃ perovskite oxide nanofibers have been successfully synthesized by sol–gel electrospinning followed by calcination at different temperatures, using polyvinylpyrrolidone as a sacrificial polymeric binder. The change in porosity and grain size with calcination temperature imparted a substantial effect on the electrochemical properties of the obtained SrMnO₃ nanofibers. The SrMnO₃ nanofiber electrode calcined at 700 °C exhibits an electrochemical capacitance of 321.7 F g^–1 at a discharge current density of 0.5 A g^–1. Here, the effect of doping Ba/Ca on Sr, and Co/Fe/Ni on Mn, respectively, on the specific capacitance of SrMnO₃ nanofibers is studied. 20 mol% Ba loading shows the best performance as a supercapacitor electrode with a specific capacitance of 446.8 F g^–1 at a discharge current density of 0.5 A g^–1. The nanofibers retained 87% its initial capacitance after 5000 successive cycles. The device fabricated using the nanofibers show an energy density of 37.3 W h kg^–1 at a power density of 400 W kg^–1, and it is retained as 15.7 W h kg^–1 even at a high-power density of 8006 W kg^–1, indicating the potential of this electrode material for high-rate charge/discharge operations in supercapacitors.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); U.S. Department of Defense (DOD); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1572464

Alternate ID(s):: OSTI ID: 1693768

Journal Information:: Ceramics International, Vol. 44, Issue 17; ISSN 0272-8842

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 75 works

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36 MATERIALS SCIENCE
SrMnO3
doping
electrode
electrospun nanofiber
perovskite
supercapacitor

Title: Effect of doping on the performance of high-crystalline SrMnO3 perovskite nanofibers as a supercapacitor electrode

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Title: Effect of doping on the performance of high-crystalline SrMnO₃ perovskite nanofibers as a supercapacitor electrode