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Title: Influence of the heavy-atom effect on singlet fission: a study of platinum-bridged pentacene dimers

Abstract

Two platinum-bridged pentacene dimers undergo efficient singlet fission to form a correlated triplet pair (T 1 T 1 ). The internal heavy-atom effect of the platinum allows for 1 (T 1 T 1 )– 3 (T 1 T 1 ) mixing leading to the formation of mainly (T 1 S 0 ).

Authors:
 [1]; ORCiD logo [2]; ORCiD logo [2];  [1];  [1]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [4]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [1]
+ Show Author Affiliations
  1. Department of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 91058 Erlangen, Germany
  2. Department of Chemistry and Institute for Sustainability and Energy at Northwestern (ISEN), Northwestern University, Evanston, USA
  3. Department of Chemistry, University of Alberta, Edmonton, Canada
  4. Department of Chemistry and Pharmacy & Computer-Chemistry-Center (CCC), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 91052 Erlangen, Germany
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1572432
Grant/Contract Number:  
FG02-99ER14999
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 10 Journal Issue: 48; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Basel, Bettina S., Young, Ryan M., Krzyaniak, Matthew D., Papadopoulos, Ilias, Hetzer, Constantin, Gao, Yueze, La Porte, Nathan T., Phelan, Brian T., Clark, Timothy, Tykwinski, Rik R., Wasielewski, Michael R., and Guldi, Dirk M. Influence of the heavy-atom effect on singlet fission: a study of platinum-bridged pentacene dimers. United Kingdom: N. p., 2019. Web. doi:10.1039/C9SC04410H.
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Basel, Bettina S., Young, Ryan M., Krzyaniak, Matthew D., Papadopoulos, Ilias, Hetzer, Constantin, Gao, Yueze, La Porte, Nathan T., Phelan, Brian T., Clark, Timothy, Tykwinski, Rik R., Wasielewski, Michael R., & Guldi, Dirk M. Influence of the heavy-atom effect on singlet fission: a study of platinum-bridged pentacene dimers. United Kingdom. doi:10.1039/C9SC04410H.
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Basel, Bettina S., Young, Ryan M., Krzyaniak, Matthew D., Papadopoulos, Ilias, Hetzer, Constantin, Gao, Yueze, La Porte, Nathan T., Phelan, Brian T., Clark, Timothy, Tykwinski, Rik R., Wasielewski, Michael R., and Guldi, Dirk M. Wed . "Influence of the heavy-atom effect on singlet fission: a study of platinum-bridged pentacene dimers". United Kingdom. doi:10.1039/C9SC04410H.
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@article{osti_1572432,
title = {Influence of the heavy-atom effect on singlet fission: a study of platinum-bridged pentacene dimers},
author = {Basel, Bettina S. and Young, Ryan M. and Krzyaniak, Matthew D. and Papadopoulos, Ilias and Hetzer, Constantin and Gao, Yueze and La Porte, Nathan T. and Phelan, Brian T. and Clark, Timothy and Tykwinski, Rik R. and Wasielewski, Michael R. and Guldi, Dirk M.},
abstractNote = {Two platinum-bridged pentacene dimers undergo efficient singlet fission to form a correlated triplet pair (T 1 T 1 ). The internal heavy-atom effect of the platinum allows for 1 (T 1 T 1 )– 3 (T 1 T 1 ) mixing leading to the formation of mainly (T 1 S 0 ).},
doi = {10.1039/C9SC04410H},
journal = {Chemical Science},
number = 48,
volume = 10,
place = {United Kingdom},
year = {2019},
month = {12}
}
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DOI: 10.1039/C9SC04410H
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