In search of tris(trimethylsilylcyclopentadienyl) thorium
Abstract
Solution synthesis, characterization, and reactivity of a new Th( iii ) complex Cp′ 3 Th (Cp′ = C 5 H 4 SiMe 3 ).
- Authors:
-
- Department of Chemistry, University of California, Irvine, USA
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1572207
- Grant/Contract Number:
- SC0004739
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Dalton Transactions
- Additional Journal Information:
- Journal Name: Dalton Transactions Journal Volume: 48 Journal Issue: 44; Journal ID: ISSN 1477-9226
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Wedal, Justin C., Bekoe, Samuel, Ziller, Joseph W., Furche, Filipp, and Evans, William J. In search of tris(trimethylsilylcyclopentadienyl) thorium. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9DT03674A.
Wedal, Justin C., Bekoe, Samuel, Ziller, Joseph W., Furche, Filipp, & Evans, William J. In search of tris(trimethylsilylcyclopentadienyl) thorium. United Kingdom. doi:10.1039/C9DT03674A.
Wedal, Justin C., Bekoe, Samuel, Ziller, Joseph W., Furche, Filipp, and Evans, William J. Tue .
"In search of tris(trimethylsilylcyclopentadienyl) thorium". United Kingdom. doi:10.1039/C9DT03674A.
@article{osti_1572207,
title = {In search of tris(trimethylsilylcyclopentadienyl) thorium},
author = {Wedal, Justin C. and Bekoe, Samuel and Ziller, Joseph W. and Furche, Filipp and Evans, William J.},
abstractNote = {Solution synthesis, characterization, and reactivity of a new Th( iii ) complex Cp′ 3 Th (Cp′ = C 5 H 4 SiMe 3 ).},
doi = {10.1039/C9DT03674A},
journal = {Dalton Transactions},
number = 44,
volume = 48,
place = {United Kingdom},
year = {2019},
month = {11}
}
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DOI: 10.1039/C9DT03674A
DOI: 10.1039/C9DT03674A
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Works referenced in this record:
Synthesis, Structure, and Reactivity of the Sterically Crowded Th 3+ Complex (C 5 Me 5 ) 3 Th Including Formation of the Thorium Carbonyl, [(C 5 Me 5 ) 3 Th(CO)][BPh 4 ]
journal, February 2017
- Langeslay, Ryan R.; Chen, Guo P.; Windorff, Cory J.
- Journal of the American Chemical Society, Vol. 139, Issue 9
Synthesis and Characterization of the First Sandwich Complex of Trivalent Thorium: A Structural Comparison with the Uranium Analogue
journal, July 1999
- Parry, Julian S.; Coles, Simon J.
- Journal of the American Chemical Society, Vol. 121, Issue 29
New vistas in the molecular chemistry of thorium: low oxidation state complexes
journal, January 2016
- Ortu, Fabrizio; Formanuik, Alasdair; Innes, James R.
- Dalton Transactions, Vol. 45, Issue 18
Expanding Rare-Earth Oxidation State Chemistry to Molecular Complexes of Holmium(II) and Erbium(II)
journal, May 2012
- MacDonald, Matthew R.; Bates, Jefferson E.; Fieser, Megan E.
- Journal of the American Chemical Society, Vol. 134, Issue 20
Actinide Metallocene Hydride Chemistry: C–H Activation in Tetramethylcyclopentadienyl Ligands to Form [μ-η 5 -C 5 Me 3 H(CH 2 )- κC ] 2– Tuck-over Ligands in a Tetrathorium Octahydride Complex
journal, October 2013
- Siladke, Nathan A.; Webster, Christopher L.; Walensky, Justin R.
- Organometallics, Vol. 32, Issue 21
About the existence of Th(III) in aqueous solution
journal, May 1998
- Ionova, G.; Madic, C.; Guillaumont, R.
- Polyhedron, Vol. 17, Issue 11-12
Expanding Thorium Hydride Chemistry Through Th 2+ , Including the Synthesis of a Mixed-Valent Th 4+ /Th 3+ Hydride Complex
journal, March 2016
- Langeslay, Ryan R.; Fieser, Megan E.; Ziller, Joseph W.
- Journal of the American Chemical Society, Vol. 138, Issue 12
Carbon Monoxide and Isocyanide Complexes of Trivalent Uranium Metallocenes
journal, October 1999
- del Mar Conejo, M.; Parry, Julian S.; Carmona, Ernesto
- Chemistry - A European Journal, Vol. 5, Issue 10
Actinide covalency measured by pulsed electron paramagnetic resonance spectroscopy
journal, December 2016
- Formanuik, Alasdair; Ariciu, Ana-Maria; Ortu, Fabrizio
- Nature Chemistry, Vol. 9, Issue 6
Reactions of potassium-graphite
journal, March 1978
- Bergbreiter, David E.; Killough, James M.
- Journal of the American Chemical Society, Vol. 100, Issue 7
Trimethylsilylcyclopentadienyl (Cp ′ ) Uranium Chemistry: Synthetic and Structural Studies of Cp ′ 4 U and Cp ′ 3 U X ( X = Cl, I, Me) : Trimethylsilylcyclopentadienyl (Cp
journal, June 2015
- Windorff, Cory J.; MacDonald, Matthew R.; Ziller, Joseph W.
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 643, Issue 23
Some aspects of the coordination and organometallic chemistry of thorium and uranium (MIII, MIV, UV) in +3 and +4 oxidation states
journal, December 1987
- Blake, Paul C.; Lappert, Michael F.; Taylor, Richard G.
- Inorganica Chimica Acta, Vol. 139, Issue 1-2
Thorium(IV) alkyl synthesis from a thorium(III) cyclopentadienyl complex and an N-heterocyclic olefin
journal, February 2018
- Liu, Jingjing; Seed, John A.; Formanuik, Alasdair
- Journal of Organometallic Chemistry, Vol. 857
Tetramethylcyclopentadienyl Ligands Allow Isolation of Ln(II) Ions across the Lanthanide Series in [K(2.2.2-cryptand)][(C 5 Me 4 H) 3 Ln] Complexes
journal, October 2018
- Jenkins, Tener F.; Woen, David H.; Mohanam, Luke N.
- Organometallics, Vol. 37, Issue 21
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976
- Shannon, R. D.
- Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
Importance of Energy Level Matching for Bonding in Th 3+ -Am 3+ Actinide Metallocene Amidinates, (C 5 Me 5 ) 2 [ i PrNC(Me)N i Pr]An
journal, November 2010
- Walensky, Justin R.; Martin, Richard L.; Ziller, Joseph W.
- Inorganic Chemistry, Vol. 49, Issue 21
Mechanistic study of photoinduced .beta.-hydride elimination. The facile photochemical synthesis of low-valent thorium and uranium organometallics
journal, April 1982
- Bruno, Joseph W.; Kalina, Dale G.; Mintz, Eric A.
- Journal of the American Chemical Society, Vol. 104, Issue 7
Lanthanide thermodynamic predictions. 7. Thermodynamics of 2+, 3+, and 4+ aquo ions and standard electrode potentials at 298.15 K
journal, July 1985
- Bratsch, Steven G.; Lagowski, J. J.
- The Journal of Physical Chemistry, Vol. 89, Issue 15
Synthesis and x-ray crystallographic characterization of an oxo-bridged bimetallic organosamarium complex, [(C5Me5)2Sm]2(.mu.-O)
journal, January 1985
- Evans, William J.; Grate, Jay W.; Bloom, Ira
- Journal of the American Chemical Society, Vol. 107, Issue 2
Small Molecule Activation by Uranium Tris(aryloxides): Experimental and Computational Studies of Binding of N 2 , Coupling of CO, and Deoxygenation Insertion of CO 2 under Ambient Conditions
journal, June 2011
- Mansell, Stephen M.; Kaltsoyannis, Nikolas; Arnold, Polly L.
- Journal of the American Chemical Society, Vol. 133, Issue 23
Models for organometallic molecule-support complexes. Synthesis and properties of cationic organoactinides
journal, June 1987
- Lin, Zerong; Le Marechal, Jean Francois; Sabat, Michal
- Journal of the American Chemical Society, Vol. 109, Issue 13
The experimental determination of Th( iv )/Th( iii ) redox potentials in organometallic thorium complexes
journal, January 2019
- Inman, Christopher J.; Cloke, F. Geoffrey N.
- Dalton Transactions, Vol. 48, Issue 29
Energy‐adjusted pseudopotentials for the actinides. Parameter sets and test calculations for thorium and thorium monoxide
journal, May 1994
- Küchle, W.; Dolg, M.; Stoll, H.
- The Journal of Chemical Physics, Vol. 100, Issue 10
Synthesis and crystal structure of the oxo-bridged bimetallic organouranium complex [(Me3SiC5H4)3U]2[μ-O]
journal, May 1991
- Berthet, Jean-Claude; Le Maréchal, Jean-François; Nierlich, Martine
- Journal of Organometallic Chemistry, Vol. 408, Issue 3
Synthesis, properties and structures of the tris(cyclopentadienyl)thorium(III) complexes [Th{η5-C5H3(SiMe2R)2-1,3}3] (R=Me or tBu)
journal, November 2001
- Blake, Paul C.; Edelstein, Norman M.; Hitchcock, Peter B.
- Journal of Organometallic Chemistry, Vol. 636, Issue 1-2
Reactions of a Uranium(IV) Tertiary Alkyl Bond: Facile Ligand-Assisted Reduction and Insertion of Ethylene and Carbon Monoxide
journal, August 1995
- Weydert, Marc; Brennan, John G.; Andersen, Richard A.
- Organometallics, Vol. 14, Issue 8
The synthesis and characterisation, including X-ray diffraction study, of [Th{η-C 5 H 3 (SiMe 3 ) 2 } 3 ]; the first thorium( III ) crystal structure
journal, January 1986
- Blake, Paul C.; Lappert, Michael F.; Atwood, Jerry L.
- J. Chem. Soc., Chem. Commun., Vol. 0, Issue 15
Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C 5 H 3 (SiMe 3 ) 2 ] 3 Th} 1− anion containing thorium in the formal +2 oxidation state
journal, January 2015
- Langeslay, Ryan R.; Fieser, Megan E.; Ziller, Joseph W.
- Chemical Science, Vol. 6, Issue 1
Structural, Spectroscopic, and Theoretical Comparison of Traditional vs Recently Discovered Ln 2+ Ions in the [K(2.2.2-cryptand)][(C 5 H 4 SiMe 3 ) 3 Ln] Complexes: The Variable Nature of Dy 2+ and Nd 2+
journal, December 2014
- Fieser, Megan E.; MacDonald, Matthew R.; Krull, Brandon T.
- Journal of the American Chemical Society, Vol. 137, Issue 1
Formation of a THF adduct of the organometallic samarium oxide [(C5Me5) 2Sm]2(μ-O)
journal, October 1994
- Evans, William J.; Gonzales, Shirley L.
- Journal of Organometallic Chemistry, Vol. 480, Issue 1-2
U(IV) Chalcogenolates Synthesized via Oxidation of Uranium Metal by Dichalcogenides
journal, September 2006
- Gaunt, Andrew J.; Scott, Brian L.; Neu, Mary P.
- Inorganic Chemistry, Vol. 45, Issue 18
Reduction chemistry of neptunium cyclopentadienide complexes: from structure to understanding
journal, January 2017
- Dutkiewicz, Michał S.; Apostolidis, Christos; Walter, Olaf
- Chemical Science, Vol. 8, Issue 4
[Th(III)[.eta.5-C5H3(SiMe3)2]3], an actinide compound with a 6d1 ground state
journal, February 1988
- Kot, Wing K.; Shalimoff, George V.; Edelstein, Norman M.
- Journal of the American Chemical Society, Vol. 110, Issue 3
Comparative assessment of a new nonempirical density functional: Molecules and hydrogen-bonded complexes
journal, December 2003
- Staroverov, Viktor N.; Scuseria, Gustavo E.; Tao, Jianmin
- The Journal of Chemical Physics, Vol. 119, Issue 23
Tris(trimethylsilylcyclopentadienyl)uranium(III)
journal, December 1988
- Zalkin, A.; Brennan, J. G.; Andersen, R. A.
- Acta Crystallographica Section C Crystal Structure Communications, Vol. 44, Issue 12
Organometallic chemistry of the actinides
journal, January 1998
- Blake, Paul C.; Edelman, Michael A.; Hitchcock, Peter B.
- Journal of Organometallic Chemistry, Vol. 551, Issue 1-2
Fully optimized contracted Gaussian basis sets for atoms Li to Kr
journal, August 1992
- Schäfer, Ansgar; Horn, Hans; Ahlrichs, Reinhart
- The Journal of Chemical Physics, Vol. 97, Issue 4
The Importance of a Single Methyl Group in Determining the Reaction Chemistry of Pentamethylcyclopentadienyl Cyclooctatetraenyl Uranium Metallocenes
journal, March 2011
- Takase, Michael K.; Ziller, Joseph W.; Evans, William J.
- Chemistry - A European Journal, Vol. 17, Issue 17
Identification of the +2 Oxidation State for Uranium in a Crystalline Molecular Complex, [K(2.2.2-Cryptand)][(C 5 H 4 SiMe 3 ) 3 U]
journal, August 2013
- MacDonald, Matthew R.; Fieser, Megan E.; Bates, Jefferson E.
- Journal of the American Chemical Society, Vol. 135, Issue 36
Isolation of a Square-Planar Th(III) Complex: Synthesis and Structure of [Th(OC 6 H 2 t Bu 2 -2,6-Me-4) 4 ] 1–
journal, July 2019
- Huh, Daniel N.; Roy, Saswata; Ziller, Joseph W.
- Journal of the American Chemical Society, Vol. 141, Issue 32
Chemical structure and bonding in a thorium( iii )–aluminum heterobimetallic complex
journal, January 2018
- Altman, Alison B.; Brown, Alexandra C.; Rao, Guodong
- Chemical Science, Vol. 9, Issue 18
Synthesis of a Crystalline Molecular Complex of Y 2+ , [(18-crown-6)K][(C 5 H 4 SiMe 3 ) 3 Y]
journal, October 2011
- MacDonald, Matthew R.; Ziller, Joseph W.; Evans, William J.
- Journal of the American Chemical Society, Vol. 133, Issue 40
Completing the Series of +2 Ions for the Lanthanide Elements: Synthesis of Molecular Complexes of Pr 2+ , Gd 2+ , Tb 2+ , and Lu 2+
journal, May 2013
- MacDonald, Matthew R.; Bates, Jefferson E.; Ziller, Joseph W.
- Journal of the American Chemical Society, Vol. 135, Issue 26
Electron-transfer and f-d absorption bands of some lanthanide and actinide complexes and the standard (II-III) oxidation potential for each member of the lanthanide and actinide series
journal, June 1973
- Nugent, L. J.; Baybarz, R. D.; Burnett, J. L.
- The Journal of Physical Chemistry, Vol. 77, Issue 12
Segmented contraction scheme for small-core actinide pseudopotential basis sets
journal, March 2004
- Cao, Xiaoyan; Dolg, Michael
- Journal of Molecular Structure: THEOCHEM, Vol. 673, Issue 1-3