Title: Lateral charge carrier transport properties of B-10 enriched hexagonal BN thick epilayers

Journal Article · · Applied Physics Letters
DOI: https://doi.org/10.1063/1.5097984 · OSTI ID:1571782

Neutron detectors based on B-10 enriched hexagonal boron nitride (h-10BN or h-BN) epilayers have demonstrated the highest thermal neutron detection efficiency among solid-state neutron detectors at about 58%. However, many fundamental transport parameters of h-BN, including the room temperature carrier mobility, minority carrier lifetime, and surface recombination velocity, which are essential to the performance of detectors, are still unknown. Here, we report here the carrier drift mobilities (μ) and lifetimes (τ) of both electrons and holes in h-10BN epilayers measured by using a time-of-flight (TOF) technique. Lateral photoconductive type detectors fabricated from a 65 μm thick freestanding h-10BN epilayer were utilized to carry out the TOF measurements, which revealed μe ~34 cm2/V s for electrons and μh ~36 cm2/V s for holes and carrier lifetimes on the order of tens of microseconds. By combining the values of μ measured from TOF with S/μ (the ratio of the surface recombination velocity to mobility) deduced directly from the bias voltage dependence of photocurrent, S for both electrons (Se ~1.4 × 104 cm/s) and holes (Sh ~2.7 × 103 cm/s) in h-10BN has been extracted. The determination of these important fundamental parameters (μ, τ, and S) not only provides a better understanding of the carrier dynamics and electrical transport properties of h-BN but is also valuable for further advancing the development of h-BN materials and devices.

Research Organization:
Texas Tech Univ., Lubbock, TX (United States)
Sponsoring Organization:
USDOE; USDOE Advanced Research Projects Agency - Energy (ARPA-E)
Grant/Contract Number:
AR0000964; NA0002927
OSTI ID:
1571782
Journal Information:
Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 7 Vol. 115; ISSN 0003-6951
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
English

References (41)

Deep Ultraviolet Light-Emitting Hexagonal Boron Nitride Synthesized at Atmospheric Pressure. journal November 2007
High-field effects in photoconducting cadmium sulphide journal March 1965
Growth of hexagonal boron nitride on sapphire substrate by pulsed-mode metalorganic vapor phase epitaxy journal January 2018
Graphene based heterostructures journal August 2012
Bright UV Single Photon Emission at Point Defects in h -BN journal June 2016
AlN/h-BN Heterostructures for Mg Dopant-Free Deep Ultraviolet Photonics journal May 2017
Van der Waals heterostructures journal July 2013
Direct-bandgap properties and evidence for ultraviolet lasing of hexagonal boron nitride single crystal journal May 2004
Boron nitride substrates for high-quality graphene electronics journal August 2010
Quantum emission from hexagonal boron nitride monolayers journal October 2015
Flexible metal-semiconductor-metal device prototype on wafer-scale thick boron nitride layers grown by MOVPE journal April 2017
Nanoscale structure study of boron nitride nanosheets and development of a deep-UV photo-detector journal January 2014
High-performance deep ultraviolet photodetectors based on few-layer hexagonal boron nitride journal January 2018
Charge carrier mobility in poly(p-phenylenevinylene) studied by the time-of-flight technique journal November 1997
Efficiency of composite boron nitride neutron detectors in comparison with helium-3 detectors journal March 2007
Epitaxially grown semiconducting hexagonal boron nitride as a deep ultraviolet photonic material journal May 2011
Mobility lifetime product—A tool for correlating a ‐Si:H film properties and solar cell performances journal June 1996
Epitaxial growth and demonstration of hexagonal BN/AlGaN p-n junctions for deep ultraviolet photonics journal February 2012
Dielectric strength, optical absorption, and deep ultraviolet detectors of hexagonal boron nitride epilayers journal October 2012
Charge carrier transport properties in layer structured hexagonal boron nitride journal October 2014
Realization of highly efficient hexagonal boron nitride neutron detectors journal August 2016
Bandgap and exciton binding energies of hexagonal boron nitride probed by photocurrent excitation spectroscopy journal September 2016
Solid-state neutron detectors based on thickness scalable hexagonal boron nitride journal January 2017
Layer number dependent optical properties of multilayer hexagonal BN epilayers journal February 2017
Hexagonal boron nitride neutron detectors with high detection efficiencies journal January 2018
High sensitivity hexagonal boron nitride lateral neutron detectors journal June 2019
Long-range exciton dissociation in organic solar cells journal August 2012
Minority electron mobility in a p-n GaN photodetector journal January 2000
Light scattering study of boron nitride microcrystals journal June 1981
Jahn-Teller effect on exciton states in hexagonal boron nitride single crystal journal May 2009
Phonon-Photon Mapping in a Color Center in Hexagonal Boron Nitride journal August 2016
Huge Excitonic Effects in Layered Hexagonal Boron Nitride journal January 2006
Excitons in Boron Nitride Nanotubes: Dimensionality Effects journal March 2006
Recent progress in CdTe and CdZnTe detectors journal January 2001
High Carrier Mobility in Single-Crystal Plasma-Deposited Diamond journal September 2002
Deep Ultraviolet Light-Emitting Hexagonal Boron Nitride Synthesized at Atmospheric Pressure journal August 2007
Field-Effect Tunneling Transistor Based on Vertical Graphene Heterostructures journal February 2012
Characterization and Field Emission of Sulfur-Doped Boron Nitride Synthesized by Plasma-Assisted Chemical Vapor Deposition journal April 1997
Improved Time-of-Flight Technique for Measuring Carrier Mobility in Thin Films of Organic Electroluminescent Materials journal March 2000
Review—Hexagonal Boron Nitride Epilayers: Growth, Optical Properties and Device Applications journal September 2016
Quantum Emission from Hexagonal Boron Nitride Monolayers conference January 2016

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