Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Self-Assembled Room Temperature Multiferroic BiFeO3-LiFe5O8 Nanocomposites

Abstract

Multiferroic materials have driven significant research interest due to their promising technological potential. Developing new room-temperature multiferroics and understanding their fundamental properties are important to reveal unanticipated physical phenomena and potential applications. Here, a new room temperature multiferroic nanocomposite comprised of an ordered ferrimagnetic spinel α-LiFe5O8 (LFO) and a ferroelectric perovskite BiFeO3 (BFO) is presented. It is observed that lithium (Li)-doping in BFO favors the formation of LFO spinel as a secondary phase during the synthesis of LixBi1-xFeO3 ceramics. Multimodal functional and chemical imaging methods are used to map the relationship between doping-induced phase separation and local ferroic properties in both the BFO-LFO composite ceramics and self-assembled nanocomposite thin films. The energetics of phase separation in Li doped BFO and the formation of BFO-LFO composites are supported by first principles calculations. These findings shed light on Li's role in the formation of a functionally important room temperature multiferroic and open a new approach in the synthesis of light element doped nanocomposites for future energy, sensing, and memory applications.

Authors:
ORCiD logo [1];  [2];  [3];  [4];  [3];  [1];  [1];  [1];  [3];  [2];  [3];  [1];  [5]; ORCiD logo [1]
+ Show Author Affiliations
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
  2. Univ. of Puerto Rico, San Juan, PR (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division; Univ. of Tennessee, Knoxville, TN (United States)
  5. Korea Advanced Inst. Science and Technology (KAIST), Daejeon (Korea, Republic of)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1606993
Alternate Identifier(s):
OSTI ID: 1571694
Grant/Contract Number:  
AC05-00OR22725; AC02‐05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Volume: 30; Journal Issue: 3; Journal ID: ISSN 1616-301X
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; light element doping; multiferroics; nanoferroic properties; scanning probe microscopy; self‐assembled nanocomposites; thin film nanostructures

Citation Formats

Sharma, Yogesh, Agarwal, Radhe, Collins, Liam, Zheng, Qiang, Ievlev, Anton V., Hermann, Raphael P., Cooper, Valentino R., KC, Santosh, Ivanov, Ilia N., Katiyar, Ram S., Kalinin, Sergei V., Lee, Ho Nyung, Hong, Seungbum, and Ward, Thomas Z. Self-Assembled Room Temperature Multiferroic BiFeO3-LiFe5O8 Nanocomposites. United States: N. p., 2019. Web. doi:10.1002/adfm.201906849.
Copy to clipboard
Sharma, Yogesh, Agarwal, Radhe, Collins, Liam, Zheng, Qiang, Ievlev, Anton V., Hermann, Raphael P., Cooper, Valentino R., KC, Santosh, Ivanov, Ilia N., Katiyar, Ram S., Kalinin, Sergei V., Lee, Ho Nyung, Hong, Seungbum, & Ward, Thomas Z. Self-Assembled Room Temperature Multiferroic BiFeO3-LiFe5O8 Nanocomposites. United States. https://doi.org/10.1002/adfm.201906849
Copy to clipboard
Sharma, Yogesh, Agarwal, Radhe, Collins, Liam, Zheng, Qiang, Ievlev, Anton V., Hermann, Raphael P., Cooper, Valentino R., KC, Santosh, Ivanov, Ilia N., Katiyar, Ram S., Kalinin, Sergei V., Lee, Ho Nyung, Hong, Seungbum, and Ward, Thomas Z. Thu . "Self-Assembled Room Temperature Multiferroic BiFeO3-LiFe5O8 Nanocomposites". United States. https://doi.org/10.1002/adfm.201906849. https://www.osti.gov/servlets/purl/1606993.
Copy to clipboard
@article{osti_1606993,
title = {Self-Assembled Room Temperature Multiferroic BiFeO3-LiFe5O8 Nanocomposites},
author = {Sharma, Yogesh and Agarwal, Radhe and Collins, Liam and Zheng, Qiang and Ievlev, Anton V. and Hermann, Raphael P. and Cooper, Valentino R. and KC, Santosh and Ivanov, Ilia N. and Katiyar, Ram S. and Kalinin, Sergei V. and Lee, Ho Nyung and Hong, Seungbum and Ward, Thomas Z.},
abstractNote = {Multiferroic materials have driven significant research interest due to their promising technological potential. Developing new room-temperature multiferroics and understanding their fundamental properties are important to reveal unanticipated physical phenomena and potential applications. Here, a new room temperature multiferroic nanocomposite comprised of an ordered ferrimagnetic spinel α-LiFe5O8 (LFO) and a ferroelectric perovskite BiFeO3 (BFO) is presented. It is observed that lithium (Li)-doping in BFO favors the formation of LFO spinel as a secondary phase during the synthesis of LixBi1-xFeO3 ceramics. Multimodal functional and chemical imaging methods are used to map the relationship between doping-induced phase separation and local ferroic properties in both the BFO-LFO composite ceramics and self-assembled nanocomposite thin films. The energetics of phase separation in Li doped BFO and the formation of BFO-LFO composites are supported by first principles calculations. These findings shed light on Li's role in the formation of a functionally important room temperature multiferroic and open a new approach in the synthesis of light element doped nanocomposites for future energy, sensing, and memory applications.},
doi = {10.1002/adfm.201906849},
journal = {Advanced Functional Materials},
number = 3,
volume = 30,
place = {United States},
year = {Thu Oct 24 00:00:00 EDT 2019},
month = {Thu Oct 24 00:00:00 EDT 2019}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/adfm.201906849
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 11 works
Citation information provided by
Web of Science

Figures / Tables:

Figure 1 Figure 1: Room temperature X-ray powder diffraction and microscopic Raman mapping. (a) Rietveld refinement of powder X-ray diffraction (XRD) data collected from Li0.09Bi0.91FeO3 (9Li- BFO) sample. The XRD pattern can be fitted by the three different phases; rhombohedral BiFeO3 (BFO, black), sillenite Bi12.5Fe0.5O20 (green) and ordered spinel $α$-LiFe5O8 (LFO, pink).more » (b) Micro-Raman mapping on 9Li-BFO shows the different phase-domains. (c) The Raman mapped area is comprised of three types of spectra from BFO, Bi-excess BFO, and LFO phases. The observation of additional modes at 358, 490, and 530 cm-1 of broader linewidth in Raman spectrum of the Bi-excess BFO suggests the presence of the Bi12.5Fe0.5O20 phase. The observed phonon modes of LFO phase are consistent with the Raman spectrum of bulk single crystal of ordered LFO (ref. 40). (d) The crystal structure of ordered spinel LFO (denoted as Fe[Li1+0.5 Fe3+1.5]O4) shows a specific 1:3 ordering of Li1+ and Fe3+ at the octahedral $B$ sites.« less
All figures and tables (9 total)
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Lattice dynamics of the α and β phases of LiFe 5 O 8
journal, May 2011

Room Temperature Multiferroicity of Charge Transfer Crystals
journal, August 2015

Heteroepitaxially enhanced magnetic anisotropy in BaTiO3–CoFe2O4 nanostructures
journal, March 2007

  • Zheng, Haimei; Kreisel, Jens; Chu, Ying-Hao
  • Applied Physics Letters, Vol. 90, Issue 11
  • DOI: 10.1063/1.2713131

Room-Temperature Magnetic Switching of the Electric Polarization in Ferroelectric Nanopillars
journal, January 2018

Non-conventional mechanism of ferroelectric fatigue via cation migration
journal, July 2019

Ionic Gating of Ultrathin and Leaky Ferroelectrics
journal, January 2019

  • Sharma, Yogesh; Wong, Anthony T.; Herklotz, Andreas
  • Advanced Materials Interfaces, Vol. 6, Issue 5
  • DOI: 10.1002/admi.201801723

Advances in magnetoelectric multiferroics
journal, February 2019

Design of Self-Assembled Multiferroic Nanostructures in Epitaxial Films
journal, August 2006

Nanoscale Control of Oxygen Defects and Metal–Insulator Transition in Epitaxial Vanadium Dioxides
journal, June 2018

  • Sharma, Yogesh; Balachandran, Janakiraman; Sohn, Changhee
  • ACS Nano, Vol. 12, Issue 7
  • DOI: 10.1021/acsnano.8b03031

Doping of BiFeO 3 : A comprehensive study on substitutional doping
journal, September 2018

Multiferroic BaTiO3-CoFe2O4 Nanostructures
journal, January 2004

Advances in the growth and characterization of magnetic, ferroelectric, and multiferroic oxide thin films
journal, May 2010

  • Martin, L. W.; Chu, Y. -H.; Ramesh, R.
  • Materials Science and Engineering: R: Reports, Vol. 68, Issue 4-6
  • DOI: 10.1016/j.mser.2010.03.001

The evolution of multiferroics
journal, July 2016

Comparative X-ray diffraction and Mössbauer spectroscopy studies of BiFeO3 ceramics prepared by conventional solid-state reaction and mechanical activation
journal, April 2013

  • Jartych, Elżbieta; Lisinska-Czekaj, Agata; Oleszak, Dariusz
  • Materials Science-Poland, Vol. 31, Issue 2
  • DOI: 10.2478/s13536-012-0093-1

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

Why Are There so Few Magnetic Ferroelectrics?
journal, July 2000

  • Hill, Nicola A.
  • The Journal of Physical Chemistry B, Vol. 104, Issue 29
  • DOI: 10.1021/jp000114x

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999

Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study
journal, January 1998

  • Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y.
  • Physical Review B, Vol. 57, Issue 3, p. 1505-1509
  • DOI: 10.1103/PhysRevB.57.1505

Quantitative measurements of electromechanical response with a combined optical beam and interferometric atomic force microscope
journal, June 2015

  • Labuda, Aleksander; Proksch, Roger
  • Applied Physics Letters, Vol. 106, Issue 25
  • DOI: 10.1063/1.4922210

Engineered Magnetic Shape Anisotropy in BiFeO 3 –CoFe 2 O 4 Self-Assembled Thin Films
journal, March 2013

  • Wang, Zhiguang; Li, Yanxi; Viswan, Ravindranath
  • ACS Nano, Vol. 7, Issue 4
  • DOI: 10.1021/nn4003506

First-principles modelling of lithium iron oxides as battery cathode materials
journal, April 2011

Cation Ordering in LiFe5O8 Studied by Mössbauer Spectroscopy and X-Ray Crystallography
journal, June 1983

Chemical Phenomena of Atomic Force Microscopy Scanning
journal, January 2018

Weak ferromagnetism and magnetoelectric coupling in bismuth ferrite
journal, February 2005

Mössbauer spectra and electric properties of 57 Fe-enriched BiFeO 3 thin films
journal, September 2014

  • Tanaka, Kiyotaka; Fujita, Yuya; Okamura, Soichiro
  • Japanese Journal of Applied Physics, Vol. 53, Issue 9S
  • DOI: 10.7567/JJAP.53.09PA15

Domain Engineering of Lead-Free Li-Modified (K,Na)NbO3 Polycrystals with Highly Enhanced Piezoelectricity
journal, May 2010

Metal Oxide Nanocomposites: A Perspective from Strain, Defect, and Interface
journal, October 2018

Emergent functions of quantum materials
journal, September 2017

  • Tokura, Yoshinori; Kawasaki, Masashi; Nagaosa, Naoto
  • Nature Physics, Vol. 13, Issue 11
  • DOI: 10.1038/nphys4274

Quantitative Electromechanical Atomic Force Microscopy
journal, July 2019

Accuracy of density functional theory in predicting formation energies of ternary oxides from binary oxides and its implication on phase stability
journal, April 2012

Magnetoelectric Coupling Effects in Multiferroic Complex Oxide Composite Structures
journal, April 2010

  • Vaz, Carlos A. F.; Hoffman, Jason; Ahn, Charles H.
  • Advanced Materials, Vol. 22, Issue 26-27
  • DOI: 10.1002/adma.200904326

Lead-free piezoceramics
journal, October 2004

  • Saito, Yasuyoshi; Takao, Hisaaki; Tani, Toshihiko
  • Nature, Vol. 432, Issue 7013
  • DOI: 10.1038/nature03028

Automated Interpretation and Extraction of Topographic Information from Time of Flight Secondary Ion Mass Spectrometry Data
journal, December 2017

The band excitation method in scanning probe microscopy for rapid mapping of energy dissipation on the nanoscale
journal, September 2007

Directed Self-Assembly of Epitaxial CoFe 2 O 4 –BiFeO 3 Multiferroic Nanocomposites
journal, April 2012

  • Comes, Ryan; Liu, Hongxue; Khokhlov, Mikhail
  • Nano Letters, Vol. 12, Issue 5
  • DOI: 10.1021/nl3003396

Quantitative phase analysis from neutron powder diffraction data using the Rietveld method
journal, December 1987

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996

Nucleation-Induced Self-Assembly of Multiferroic BiFeO 3 –CoFe 2 O 4 Nanocomposites
journal, July 2013

  • Stratulat, Sergiu M.; Lu, Xiaoli; Morelli, Alessio
  • Nano Letters, Vol. 13, Issue 8
  • DOI: 10.1021/nl401965z

Recent advances in multiferroic oxide heterostructures and devices
journal, January 2016

  • Yang, X.; Zhou, Z.; Nan, T.
  • Journal of Materials Chemistry C, Vol. 4, Issue 2
  • DOI: 10.1039/C5TC03008K

Multi-ferroic magnetoelectrics
journal, January 1994

Design of magnetoelectric coupling in a self-assembled epitaxial nanocomposite via chemical interaction
journal, January 2014

  • Liang, Wen I.; Liu, Yuangming; Liao, Sheng Chieh
  • J. Mater. Chem. C, Vol. 2, Issue 5
  • DOI: 10.1039/C3TC31987C

Tuning the magnetic properties of self-assembled BiFeO 3 –CoFe 2 O 4 heteroepitaxy by magneto-structural coupling
journal, January 2016

  • Amrillah, Tahta; Vandrangi, Suresh K.; Bitla, Yugandhar
  • Nanoscale, Vol. 8, Issue 16
  • DOI: 10.1039/C5NR09269H

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

Electrical Modulation of the Local Conduction at Oxide Tubular Interfaces
journal, September 2013

  • Hsieh, Ying-Hui; Strelcov, Evgheni; Liou, Jia-Ming
  • ACS Nano, Vol. 7, Issue 10
  • DOI: 10.1021/nn402763w

Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium
journal, May 1994

Electric Field-Induced Magnetization Switching in Epitaxial Columnar Nanostructures
journal, September 2005

  • Zavaliche, F.; Zheng, H.; Mohaddes-Ardabili, L.
  • Nano Letters, Vol. 5, Issue 9, p. 1793-1796
  • DOI: 10.1021/nl051406i

Classifying multiferroics: Mechanisms and effects
journal, March 2009

Multiferroic Behavior of Templated BiFeO 3 –CoFe 2 O 4 Self-Assembled Nanocomposites
journal, January 2015

  • Aimon, Nicolas M.; Kim, Dong Hun; Sun, XueYin
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 4
  • DOI: 10.1021/am506089c

Pillar shape modulation in epitaxial BiFeO 3 –CoFe 2 O 4 vertical nanocomposite films
journal, August 2014

  • Kim, Dong Hun; Aimon, Nicolas M.; Ross, C. A.
  • APL Materials, Vol. 2, Issue 8
  • DOI: 10.1063/1.4892695

Band Excitation in Scanning Probe Microscopy: Recognition and Functional Imaging
journal, April 2014

Magnetostatic Interactions in Self-Assembled Co x Ni 1– x Fe 2 O 4 /BiFeO 3 Multiferroic Nanocomposites
journal, July 2016

Raman spectroscopy evidence of inhomogeneous disorder in the bismuth-oxygen framework of Bi 25 InO 39 and other sillenites
journal, October 2012

Multiferroics: Past, present, and future
journal, October 2010

  • Spaldin, Nicola A.; Cheong, Sang-Wook; Ramesh, Ramamoorthy
  • Physics Today, Vol. 63, Issue 10
  • DOI: 10.1063/1.3502547

Strain relaxation and enhanced perpendicular magnetic anisotropy in BiFeO 3 :CoFe 2 O 4 vertically aligned nanocomposite thin films
journal, February 2014

  • Zhang, Wenrui; Jian, Jie; Chen, Aiping
  • Applied Physics Letters, Vol. 104, Issue 6
  • DOI: 10.1063/1.4864405

Multiferroics progress and prospects in thin films
journal, January 2007

  • Ramesh, R.; Spaldin, Nicola A.
  • Nature Materials, Vol. 6, Issue 1, p. 21-29
  • DOI: 10.1038/nmat1805

Multiferroics: a magnetic twist for ferroelectricity
journal, January 2007

  • Cheong, Sang-Wook; Mostovoy, Maxim
  • Nature Materials, Vol. 6, Issue 1
  • DOI: 10.1038/nmat1804

A profile refinement method for nuclear and magnetic structures
journal, June 1969

Spintronic Functionality of BiFeO 3 Domain Walls
journal, September 2014

Push-pull mode magnetostrictive/piezoelectric laminate composite with an enhanced magnetoelectric voltage coefficient
journal, August 2005

  • Dong, Shuxiang; Zhai, Jungyi; Bai, Feiming
  • Applied Physics Letters, Vol. 87, Issue 6
  • DOI: 10.1063/1.2007868

Lead-Free Piezoceramics.
journal, January 2005

Voltage- and time-dependent valence state transition in cobalt oxide catalysts during the oxygen evolution reaction
journal, April 2020

Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets
journal, May 2021

High-resolution X-ray luminescence extension imaging
journal, February 2021

Quantitative Electromechanical Atomic Force Microscopy
preprint, January 2019

    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Cobalt doping of bismuth ferrite for matched dielectric and magnetic loss
    journal, November 2019

    • Zhang, Min; Yang, Hui-Jing; Li, Yong
    • Applied Physics Letters, Vol. 115, Issue 21
    • DOI: 10.1063/1.5134741
      Sort by:
      [ × clear filter / sort ]

      Figures / Tables found in this record:

      Figure 1 (p. 5)figure
      Figure 2 (p. 7)figure
      Figure 3 (p. 8)figure
      Figure 4 (p. 9)figure
      Figure 5 (p. 10)figure
      Figure 6 (p. 12)figure
      Figure 7 (p. 13)figure
      Table 1 (p. 14)table
      Figure 8 (p. 16)figure
        [ × clear filter / sort ]
        Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

        Similar Records in DOE PAGES and OSTI.GOV collections: