Fluoride-ion solvation in non-aqueous electrolyte solutions

doi:10.1039/C9QM00512A

Title: Fluoride-ion solvation in non-aqueous electrolyte solutions

Abstract

Non-aqueous electrolytes comprising the fluoride ion are characterized using a variety of experimental and computational methods.

Authors:

^[1];

^[2]; Kim, Jeongmin ^[2];

^[2]; Momčilović, Nebojša ^[2]; Billings, Keith J. ^[1];

^[2];

^[1]

Electrochemical Technologies Group, Jet Propulsion Laboratory, California Institute of Technology, Pasadena, USA
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, USA

Publication Date:: 2019-11-21

Sponsoring Org.:: USDOE

OSTI Identifier:: 1571540

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Materials Chemistry Frontiers

Additional Journal Information:: Journal Name: Materials Chemistry Frontiers Journal Volume: 3 Journal Issue: 12; Journal ID: ISSN 2052-1537

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Davis, Victoria K., Munoz, Stephen, Kim, Jeongmin, Bates, Christopher M., Momčilović, Nebojša, Billings, Keith J., Miller, Thomas F., Grubbs, Robert H., and Jones, Simon C. Fluoride-ion solvation in non-aqueous electrolyte solutions.  United Kingdom: N. p., 2019. 
        Web.  doi:10.1039/C9QM00512A.

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                    Davis, Victoria K., Munoz, Stephen, Kim, Jeongmin, Bates, Christopher M., Momčilović, Nebojša, Billings, Keith J., Miller, Thomas F., Grubbs, Robert H., & Jones, Simon C. Fluoride-ion solvation in non-aqueous electrolyte solutions.  United Kingdom.  doi:10.1039/C9QM00512A.

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                    Davis, Victoria K., Munoz, Stephen, Kim, Jeongmin, Bates, Christopher M., Momčilović, Nebojša, Billings, Keith J., Miller, Thomas F., Grubbs, Robert H., and Jones, Simon C. Thu .  
        "Fluoride-ion solvation in non-aqueous electrolyte solutions".  United Kingdom.  doi:10.1039/C9QM00512A.

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@article{osti_1571540,

  title        = {Fluoride-ion solvation in non-aqueous electrolyte solutions},

  author       = {Davis, Victoria K. and Munoz, Stephen and Kim, Jeongmin and Bates, Christopher M. and Momčilović, Nebojša and Billings, Keith J. and Miller, Thomas F. and Grubbs, Robert H. and Jones, Simon C.},

  abstractNote = {Non-aqueous electrolytes comprising the fluoride ion are characterized using a variety of experimental and computational methods.},

  doi          = {10.1039/C9QM00512A},

  journal      = {Materials Chemistry Frontiers},

  number       = 12,

  volume       = 3,

  place        = {United Kingdom},

  year         = {2019},

  month        = {11}

}

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DOI: 10.1039/C9QM00512A

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Works referenced in this record:

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Enhancing Cation Diffusion and Suppressing Anion Diffusion via Lewis-Acidic Polymer Electrolytes
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Introducing Interlayer Electrolytes: Toward Room-Temperature High-Potential Solid-State Rechargeable Fluoride Ion Batteries
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Mohammad, Irshad; Witter, Raiker; Fichtner, Maximilian
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Stabilization and Extraction of Fluoride Anion Using a Tetralactam Receptor
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Liu, Wenqi; Oliver, Allen G.; Smith, Bradley D.
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Room-Temperature, Rechargeable Solid-State Fluoride-Ion Batteries
journal, August 2018

Mohammad, Irshad; Witter, Raiker; Fichtner, Maximilian
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A fluoride-doped PEG matrix as an electrolyte for anion transportation in a room-temperature fluoride ion battery
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Gschwind, Fabienne; Zao-Karger, Zhirong; Fichtner, Maximilian
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Correlations from Ion Pairing and the Nernst-Einstein Equation
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Electrolytes and Interphases in Li-Ion Batteries and Beyond
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Room-temperature cycling of metal fluoride electrodes: Liquid electrolytes for high-energy fluoride ion cells
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Fluoride ion batteries: Theoretical performance, safety, toxicity, and a combinatorial screening of new electrodes
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Similar Records

Title: Fluoride-ion solvation in non-aqueous electrolyte solutions

Abstract

Citation Formats

Syntheses, properties, and structures of anhydrous tetramethylammonium fluoride and its 1:1 adduct with trans-3-amino-2-butenenitrile journal, October 1990

Enhancing Cation Diffusion and Suppressing Anion Diffusion via Lewis-Acidic Polymer Electrolytes journal, January 2017

Introducing Interlayer Electrolytes: Toward Room-Temperature High-Potential Solid-State Rechargeable Fluoride Ion Batteries journal, January 2019

Reaction of the fluoride anion with acetonitrile. Chloroform and methylene chloride journal, April 1990

Carbon acids. 13. Acidifying effects of phenylthio substituents journal, January 1977

Ion Pairing in Molecular Simulations of Aqueous Alkali Halide Solutions journal, May 2009

Stabilization and Extraction of Fluoride Anion Using a Tetralactam Receptor journal, January 2019

Room-Temperature, Rechargeable Solid-State Fluoride-Ion Batteries journal, August 2018

A fluoride-doped PEG matrix as an electrolyte for anion transportation in a room-temperature fluoride ion battery journal, January 2014

Anhydrous Tetrabutylammonium Fluoride journal, February 2005

Correlations from Ion Pairing and the Nernst-Einstein Equation journal, April 2019

Electrolytes and Interphases in Li-Ion Batteries and Beyond journal, October 2014

Room-temperature cycling of metal fluoride electrodes: Liquid electrolytes for high-energy fluoride ion cells journal, December 2018

Fluoride ion batteries: Theoretical performance, safety, toxicity, and a combinatorial screening of new electrodes journal, February 2016

Acyl Azolium Fluorides for Room Temperature Nucleophilic Aromatic Fluorination of Chloro- and Nitroarenes journal, March 2015

Synthesis, Characterization, and Reactivity of Thermally Stable Anhydrous Quaternary Ammonium Fluorides journal, May 2017

Electrochemical Performance of a Bismuth Fluoride Electrode in a Reserve-Type Fluoride Shuttle Battery journal, January 2017

Syntheses, properties, and structures of anhydrous tetramethylammonium fluoride and its 1:1 adduct with trans-3-amino-2-butenenitrile
journal, October 1990

Enhancing Cation Diffusion and Suppressing Anion Diffusion via Lewis-Acidic Polymer Electrolytes
journal, January 2017

Introducing Interlayer Electrolytes: Toward Room-Temperature High-Potential Solid-State Rechargeable Fluoride Ion Batteries
journal, January 2019

Reaction of the fluoride anion with acetonitrile. Chloroform and methylene chloride
journal, April 1990

Carbon acids. 13. Acidifying effects of phenylthio substituents
journal, January 1977

Ion Pairing in Molecular Simulations of Aqueous Alkali Halide Solutions
journal, May 2009

Stabilization and Extraction of Fluoride Anion Using a Tetralactam Receptor
journal, January 2019

Room-Temperature, Rechargeable Solid-State Fluoride-Ion Batteries
journal, August 2018

A fluoride-doped PEG matrix as an electrolyte for anion transportation in a room-temperature fluoride ion battery
journal, January 2014

Anhydrous Tetrabutylammonium Fluoride
journal, February 2005

Correlations from Ion Pairing and the Nernst-Einstein Equation
journal, April 2019

Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014

Room-temperature cycling of metal fluoride electrodes: Liquid electrolytes for high-energy fluoride ion cells
journal, December 2018

Fluoride ion batteries: Theoretical performance, safety, toxicity, and a combinatorial screening of new electrodes
journal, February 2016

Acyl Azolium Fluorides for Room Temperature Nucleophilic Aromatic Fluorination of Chloro- and Nitroarenes
journal, March 2015

Synthesis, Characterization, and Reactivity of Thermally Stable Anhydrous Quaternary Ammonium Fluorides
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Electrochemical Performance of a Bismuth Fluoride Electrode in a Reserve-Type Fluoride Shuttle Battery
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