Continuous production of pure liquid fuel solutions via electrocatalytic CO2 reduction using solid-electrolyte devices

Xia, Chuan; Zhu, Peng; Jiang, Qiu; Pan, Ying; Liang, Wentao; Stavitsk, Eli; Alshareef, Husam N.; Wang, Haotian

doi:10.1038/s41560-019-0451-x

Title: Continuous production of pure liquid fuel solutions via electrocatalytic CO₂ reduction using solid-electrolyte devices

Journal Article · 02 September 2019 · Nature Energy

DOI: https://doi.org/10.1038/s41560-019-0451-x · OSTI ID:1571402

^[1]; Zhu, Peng ^[2]; Jiang, Qiu ^[3];

^[4]; Liang, Wentao ^[5]; Stavitsk, Eli ^[6];

^[3];

^[2]

Rice Univ., Houston, TX (United States); Harvard Univ., Cambridge, MA (United States)
Rice Univ., Houston, TX (United States)
King Abdullah Univ. of Science and Technology (KAUST), Thuwal (Saudi Arabia)
Harvard Univ., Cambridge, MA (United States)
Northeastern Univ., Burlington, MA (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Electrocatalytic CO₂ reduction is often carried out in a solution electrolyte such as KHCO₃(aq), which allows for ion conduction between electrodes. Thus, liquid products that form are in a mixture with the dissolved salts, requiring energy-intensive downstream separation. In this work, we report continuous electrocatalytic conversion of CO₂ to pure liquid fuel solutions in cells that utilize solid electrolytes, where electrochemically generated cations (such as H+) and anions (such as HCOO–) are combined to form pure product solutions without mixing with other ions. Using a HCOOH-selective (Faradaic efficiencies>90%) and easily scaled Bi catalyst at the cathode, we demonstrate production of pure HCOOH solutions with concentrations up to 12M. We also show 100h continuous and stable generation of 0.1 M HCOOH with negligible degradation in selectivity and activity. Production of other electrolyte-free C₂₊ liquid oxygenate solutions, including acetic acid, ethanol and n-propanol, are also demonstrated using a Cu catalyst. Lastly, we show that our CO₂ reduction cell with solid electrolytes can be modified to suit other, more complex practical applications.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012704

OSTI ID:: 1571402

Report Number(s):: BNL--212214-2019-JAAM

Journal Information:: Nature Energy, Journal Name: Nature Energy Journal Issue: 9 Vol. 4; ISSN 2058-7546

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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