Tuning the Reactivity of Cyclopropenes from Living Ring‐Opening Metathesis Polymerization (ROMP) to Single‐Addition and Alternating ROMP
- Authors:
-
[1];
[1];
[2];
[1]
- Department of Chemistry Stanford University Stanford CA 94305 USA
- Department of Chemistry University of Pittsburgh Pittsburgh PA 15260 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1571331
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition) Journal Volume: 58 Journal Issue: 49; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Su, Jessica K., Jin, Zexin, Zhang, Rui, Lu, Gang, Liu, Peng, and Xia, Yan. Tuning the Reactivity of Cyclopropenes from Living Ring‐Opening Metathesis Polymerization (ROMP) to Single‐Addition and Alternating ROMP. Germany: N. p., 2019.
Web. doi:10.1002/anie.201909688.
Su, Jessica K., Jin, Zexin, Zhang, Rui, Lu, Gang, Liu, Peng, & Xia, Yan. Tuning the Reactivity of Cyclopropenes from Living Ring‐Opening Metathesis Polymerization (ROMP) to Single‐Addition and Alternating ROMP. Germany. https://doi.org/10.1002/anie.201909688
Su, Jessica K., Jin, Zexin, Zhang, Rui, Lu, Gang, Liu, Peng, and Xia, Yan. Tue .
"Tuning the Reactivity of Cyclopropenes from Living Ring‐Opening Metathesis Polymerization (ROMP) to Single‐Addition and Alternating ROMP". Germany. https://doi.org/10.1002/anie.201909688.
@article{osti_1571331,
title = {Tuning the Reactivity of Cyclopropenes from Living Ring‐Opening Metathesis Polymerization (ROMP) to Single‐Addition and Alternating ROMP},
author = {Su, Jessica K. and Jin, Zexin and Zhang, Rui and Lu, Gang and Liu, Peng and Xia, Yan},
abstractNote = {},
doi = {10.1002/anie.201909688},
journal = {Angewandte Chemie (International Edition)},
number = 49,
volume = 58,
place = {Germany},
year = {2019},
month = {10}
}
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https://doi.org/10.1002/anie.201909688
https://doi.org/10.1002/anie.201909688
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Works referenced in this record:
A survey of strained organic molecules
journal, June 1976
- Liebman, Joel F.; Greenberg, Arthur
- Chemical Reviews, Vol. 76, Issue 3
Utility of a Ruthenium Metathesis Catalyst for the Preparation of End-Functionalized Polybutadiene
journal, February 1997
- Hillmyer, Marc A.; Nguyen, SonBinh T.; Grubbs, Robert H.
- Macromolecules, Vol. 30, Issue 4
Regio- and Stereoselective Ring-Opening Metathesis Polymerization of 3-Substituted Cyclooctenes
journal, March 2011
- Kobayashi, Shingo; Pitet, Louis M.; Hillmyer, Marc A.
- Journal of the American Chemical Society, Vol. 133, Issue 15, p. 5794-5797
Alternating ring-opening metathesis polymerization by Grubbs-type catalysts with N -pentiptycenyl, N -alkyl-NHC ligands
journal, January 2018
- Vasiuta, Roman; Stockert, Alexander; Plenio, Herbert
- Chemical Communications, Vol. 54, Issue 14
Theory of 1,3-Dipolar Cycloadditions: Distortion/Interaction and Frontier Molecular Orbital Models
journal, August 2008
- Ess, Daniel H.; Houk, K. N.
- Journal of the American Chemical Society, Vol. 130, Issue 31
Conformational Analysis of Olefin−Carbene Ruthenium Metathesis Catalysts
journal, April 2009
- Benitez, Diego; Tkatchouk, Ekaterina; Goddard, William A.
- Organometallics, Vol. 28, Issue 8
Ruthenium Alkylidene Initiated Living Ring-Opening Metathesis Polymerization (ROMP) of 3-Substituted Cyclobutenes
journal, June 1997
- Maughon, Bob R.; Grubbs, Robert H.
- Macromolecules, Vol. 30, Issue 12
Ring-opening metathesis polymerization of 8-membered cyclic olefins
journal, January 2014
- Martinez, Henry; Ren, Ning; Matta, Megan E.
- Polymer Chemistry, Vol. 5, Issue 11
Alternating Copolymerizations of Polar and Nonpolar Cyclic Olefins by Ring-Opening Metathesis Polymerization
journal, January 2002
- Ilker, M. Firat; Coughlin, E. Bryan
- Macromolecules, Vol. 35, Issue 1
Synthesis of Discrete Oligomers by Sequential PET-RAFT Single-Unit Monomer Insertion
journal, December 2016
- Xu, Jiangtao; Fu, Changkui; Shanmugam, Sivaprakash
- Angewandte Chemie, Vol. 129, Issue 29
The ROMP toolbox upgraded
journal, June 2010
- Leitgeb, Anita; Wappel, Julia; Slugovc, Christian
- Polymer, Vol. 51, Issue 14, p. 2927-2946
Living Alternating Ring-Opening Metathesis Polymerization Based on Single Monomer Additions
journal, July 2015
- Elling, Benjamin R.; Xia, Yan
- Journal of the American Chemical Society, Vol. 137, Issue 31
A Bicyclo[4.2.0]octene-Derived Monomer Provides Completely Linear Alternating Copolymers via Alternating Ring-Opening Metathesis Polymerization (AROMP)
journal, September 2014
- Tan, Li; Parker, Kathlyn A.; Sampson, Nicole S.
- Macromolecules, Vol. 47, Issue 19
The Elusive Mechanism of Olefin Metathesis Promoted by (NHC)Ru-Based Catalysts: A Trade between Steric, Electronic, and Solvent Effects
journal, October 2006
- Correa, Andrea; Cavallo, Luigi
- Journal of the American Chemical Society, Vol. 128, Issue 41
Z-Selective and Syndioselective Ring-Opening Metathesis Polymerization (ROMP) Initiated by Monoaryloxidepyrrolide (MAP) Catalysts
journal, September 2010
- Flook, Margaret M.; Gerber, Laura C. H.; Debelouchina, Galia T.
- Macromolecules, Vol. 43, Issue 18, p. 7515-7522
The Living ROMP of trans -Cyclooctene
journal, February 2009
- Walker, Ron; Conrad, Rosemary M.; Grubbs, Robert H.
- Macromolecules, Vol. 42, Issue 3
Mechanochemical unzipping of insulating polyladderene to semiconducting polyacetylene
journal, August 2017
- Chen, Zhixing; Mercer, Jaron A. M.; Zhu, Xiaolei
- Science, Vol. 357, Issue 6350
Mechanism and Activity of Ruthenium Olefin Metathesis Catalysts: The Role of Ligands and Substrates from a Theoretical Perspective
journal, March 2004
- Adlhart, Christian; Chen, Peter
- Journal of the American Chemical Society, Vol. 126, Issue 11
PC-Polyolefins: Synthesis and Assembly Behavior in Water
journal, May 2009
- Kratz, Katrina; Breitenkamp, Kurt; Hule, Rohan
- Macromolecules, Vol. 42, Issue 9
Modeling Ring-Chain Equilibria in Ring-Opening Polymerization of Cycloolefins
journal, March 1995
- Chen, Zhong-Ren; Claverie, Jerome P.; Grubbs, Robert H.
- Macromolecules, Vol. 28, Issue 7
Alternierende Copolymerisation durch einen Grubbs-Initiator mit einem unsymmetrischen chiralen N-heterocyclischen Carbenliganden
journal, March 2008
- Vehlow, Kati; Wang, Dongren; Buchmeiser, Michael R.
- Angewandte Chemie, Vol. 120, Issue 14
Living Ring-Opening Metathesis Polymerization of Cyclopropenes
journal, February 2006
- Singh, Rojendra; Czekelius, Constantin; Schrock, Richard R.
- Macromolecules, Vol. 39, Issue 4
Synthesis of Discrete Oligomers by Sequential PET-RAFT Single-Unit Monomer Insertion
journal, December 2016
- Xu, Jiangtao; Fu, Changkui; Shanmugam, Sivaprakash
- Angewandte Chemie International Edition, Vol. 56, Issue 29
Tuning the Steric Properties of a Metathesis Catalyst for Copolymerization of Norbornene and Cyclooctene toward Complete Alternation
journal, June 2010
- Torker, Sebastian; Müller, Andre; Sigrist, Raphael
- Organometallics, Vol. 29, Issue 12
Relevance of cis- and trans-dichloride Ru intermediates in Grubbs-II olefin metathesis catalysis (H2IMesCl2RuCHR)
journal, January 2008
- Benitez, Diego; Tkatchouk, Ekaterina; Goddard III, William A.
- Chemical Communications, Issue 46
Synthesis of cis,syndiotactic ROMP Polymers Containing Alternating Enantiomers
journal, January 2011
- Flook, Margaret M.; Ng, Victor W. L.; Schrock, Richard R.
- Journal of the American Chemical Society, Vol. 133, Issue 6, p. 1784-1786
Synthesis of cis,syndiotactic- A -alt -B Copolymers from Enantiomerically Pure Endo -2-Substituted-5,6-Norbornenes
journal, March 2017
- Jang, Eun Sil; John, Jeremy M.; Schrock, Richard R.
- Journal of the American Chemical Society, Vol. 139, Issue 14
Kinetics and thermodynamics of the metathesis reaction of cycloolefins. 2. Molecular weight distribution
journal, July 1984
- Reif, Lothar; Hoecker, Hartwig
- Macromolecules, Vol. 17, Issue 4
Isomeric Cyclopropenes Exhibit Unique Bioorthogonal Reactivities
journal, September 2013
- Kamber, David N.; Nazarova, Lidia A.; Liang, Yong
- Journal of the American Chemical Society, Vol. 135, Issue 37
Efficient and Facile End Group Control of Living Ring-Opening Metathesis Polymers via Single Addition of Functional Cyclopropenes
journal, May 2018
- Elling, Benjamin R.; Xia, Yan
- ACS Macro Letters, Vol. 7, Issue 6
Selectivity in Ring-Opening Metathesis Polymerization of Z -Cyclooctenes Catalyzed by a Second-generation Grubbs Catalyst
journal, November 2012
- Martinez, Henry; Miró, Pere; Charbonneau, Patrick
- ACS Catalysis, Vol. 2, Issue 12
Scope of the Ring-Opening Metathesis Polymerization (ROMP) Reaction of 1-Substituted Cyclobutenes
journal, August 2010
- Song, Airong; Lee, Jae Chul; Parker, Kathlyn A.
- Journal of the American Chemical Society, Vol. 132, Issue 30
Synthesis of A,B-Alternating Copolymers by Ring-Opening-Insertion-Metathesis Polymerization
journal, October 2002
- Choi, Tae-Lim; Rutenberg, Isaac M.; Grubbs, Robert H.
- Angewandte Chemie, Vol. 114, Issue 20
Synthesis of Stereoregular Polymers through Ring-Opening Metathesis Polymerization
journal, June 2014
- Schrock, Richard R.
- Accounts of Chemical Research, Vol. 47, Issue 8
3-Hydroxymethyl-3-phenylcyclopropene
journal, January 2014
- Selvaraj, Ramajeyam
- Organic Syntheses, Vol. 91
Alternating Copolymerizations Using a Grubbs-Type Initiator with an Unsymmetrical, Chiral N-Heterocyclic Carbene Ligand
journal, March 2008
- Vehlow, Kati; Wang, Dongren; Buchmeiser, Michael R.
- Angewandte Chemie International Edition, Vol. 47, Issue 14
Analyzing Reaction Rates with the Distortion/Interaction-Activation Strain Model
journal, July 2017
- Bickelhaupt, F. Matthias; Houk, Kendall N.
- Angewandte Chemie International Edition, Vol. 56, Issue 34
Iterative Radical Addition with a Special Monomer Carrying Bulky and Convertible Pendant: A New Concept toward Controlling the Sequence for Vinyl Polymers
journal, May 2016
- Oh, Dongyoung; Ouchi, Makoto; Nakanishi, Tomoya
- ACS Macro Letters, Vol. 5, Issue 6
Benzoladderene Mechanophores: Synthesis, Polymerization, and Mechanochemical Transformation
journal, April 2019
- Yang, Jinghui; Horst, Matias; Romaniuk, Joseph A. H.
- Journal of the American Chemical Society, Vol. 141, Issue 16
Precise Placement of Single Monomer Units in Living Ring-Opening Metathesis Polymerization
journal, October 2019
- Elling, Benjamin R.; Su, Jessica K.; Feist, John D.
- Chem, Vol. 5, Issue 10
Synthesis of Copolymers by Alternating ROMP (AROMP)
journal, March 2009
- Song, Airong; Parker, Kathlyn A.; Sampson, Nicole S.
- Journal of the American Chemical Society, Vol. 131, Issue 10
DFT Study of the Isomerization and Spectroscopic/Structural Properties of Ruthenacyclobutane Intermediates Relevant to Olefin Metathesis
journal, December 2008
- Rowley, Christopher N.; van der Eide, Edwin F.; Piers, Warren E.
- Organometallics, Vol. 27, Issue 23
Alternating Ring-Opening Metathesis Polymerization (AROMP) of Hydrophobic and Hydrophilic Monomers Provides Oligomers with Side-Chain Sequence Control
journal, May 2018
- Li, Guofang; Sampson, Nicole S.
- Macromolecules, Vol. 51, Issue 11
Stereospecific Ring-Opening Metathesis Polymerization of 3-Methyl-3-phenylcylopropene by Molybdenum Alkylidene Initiators
journal, May 2008
- Singh, Rojendra; Schrock, Richard R.
- Macromolecules, Vol. 41, Issue 9
Discrete and Stereospecific Oligomers Prepared by Sequential and Alternating Single Unit Monomer Insertion
journal, September 2018
- Huang, Zixuan; Noble, Benjamin B.; Corrigan, Nathaniel
- Journal of the American Chemical Society, Vol. 140, Issue 41
Polycyclooctatetraene (polyacetylene) produced with a ruthenium olefin metathesis catalyst
journal, October 2001
- Scherman, Oren A.; Grubbs, Robert H.
- Synthetic Metals, Vol. 124, Issue 2-3
Homologous Poly(isobutylene)s: Poly(isobutylene)/High-Density Poly(ethylene) Hybrid Polymers
journal, November 2008
- Binder, Wolfgang H.; Kurzhals, Steffen; Pulamagatta, Bhanuprathap
- Macromolecules, Vol. 41, Issue 22
Das Distortion/Interaction-Activation-Strain-Modell zur Analyse von Reaktionsgeschwindigkeiten
journal, July 2017
- Bickelhaupt, F. Matthias; Houk, Kendall N.
- Angewandte Chemie, Vol. 129, Issue 34
Precision Synthesis of Alternating Copolymers via Ring-Opening Polymerization of 1-Substituted Cyclobutenes
journal, February 2016
- Parker, Kathlyn A.; Sampson, Nicole S.
- Accounts of Chemical Research, Vol. 49, Issue 3
Synthesis of Cis , syndiotactic A -alt -B Copolymers from Two Enantiomerically Pure Trans -2,3-Disubstituted-5,6-Norbornenes
journal, August 2016
- Jang, Eun Sil; John, Jeremy M.; Schrock, Richard R.
- ACS Central Science, Vol. 2, Issue 9
Synthesis of Alternating trans -AB Copolymers through Ring-Opening Metathesis Polymerization Initiated by Molybdenum Alkylidenes
journal, February 2015
- Jeong, Hyangsoo; John, Jeremy M.; Schrock, Richard R.
- Journal of the American Chemical Society, Vol. 137, Issue 6
Efficient and Recyclable Monomeric and Dendritic Ru-Based Metathesis Catalysts
journal, August 2000
- Garber, Steven B.; Kingsbury, Jason S.; Gray, Brian L.
- Journal of the American Chemical Society, Vol. 122, Issue 34
Ru-Catalyzed Isomerization Provides Access to Alternating Copolymers via Ring-Opening Metathesis Polymerization
journal, July 2015
- Tan, Li; Li, Guofang; Parker, Kathlyn A.
- Macromolecules, Vol. 48, Issue 14
Synthesis of A,B-Alternating Copolymers by Ring-Opening-Insertion-Metathesis Polymerization
journal, October 2002
- Choi, Tae-Lim; Rutenberg, Isaac M.; Grubbs, Robert H.
- Angewandte Chemie International Edition, Vol. 41, Issue 20
Living Polymerization Caught in the Act: Direct Observation of an Arrested Intermediate in Metathesis Polymerization
journal, June 2019
- Song, Jung-Ah; Park, Bohyun; Kim, Soohyung
- Journal of the American Chemical Society, Vol. 141, Issue 25
Mechanism of Olefin Metathesis with Catalysis by Ruthenium Carbene Complexes: Density Functional Studies on Model Systems
journal, September 2002
- Vyboishchikov, Sergei F.; Bühl, Michael; Thiel, Walter
- Chemistry - A European Journal, Vol. 8, Issue 17