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Title: How does a small structural change of anode ionomer make a big difference in alkaline membrane fuel cell performance?

Abstract

Small changes in anode ionomeric binder structure may bring significant performance and durability improvement of anion-exchange membrane fuel cells.

Authors:
 [1]; ORCiD logo [1];  [1];  [1];  [1];  [2];  [2]; ORCiD logo [1]
  1. MPA-11: Materials Synthesis & Integrated Devices, Los Alamos National Laboratory, Los Alamos, USA
  2. Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1571303
Grant/Contract Number:  
Fuel Cell Technologies Program (Lab Call); 89233218CNA000001
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 7 Journal Issue: 43; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Park, Eun Joo, Maurya, Sandip, Lee, Albert S., Leonard, Daniel P., Li, Dongguo, Jeon, Jong Yeob, Bae, Chulsung, and Kim, Yu Seung. How does a small structural change of anode ionomer make a big difference in alkaline membrane fuel cell performance?. United Kingdom: N. p., 2019. Web. doi:10.1039/C9TA10157H.
Park, Eun Joo, Maurya, Sandip, Lee, Albert S., Leonard, Daniel P., Li, Dongguo, Jeon, Jong Yeob, Bae, Chulsung, & Kim, Yu Seung. How does a small structural change of anode ionomer make a big difference in alkaline membrane fuel cell performance?. United Kingdom. doi:10.1039/C9TA10157H.
Park, Eun Joo, Maurya, Sandip, Lee, Albert S., Leonard, Daniel P., Li, Dongguo, Jeon, Jong Yeob, Bae, Chulsung, and Kim, Yu Seung. Tue . "How does a small structural change of anode ionomer make a big difference in alkaline membrane fuel cell performance?". United Kingdom. doi:10.1039/C9TA10157H.
@article{osti_1571303,
title = {How does a small structural change of anode ionomer make a big difference in alkaline membrane fuel cell performance?},
author = {Park, Eun Joo and Maurya, Sandip and Lee, Albert S. and Leonard, Daniel P. and Li, Dongguo and Jeon, Jong Yeob and Bae, Chulsung and Kim, Yu Seung},
abstractNote = {Small changes in anode ionomeric binder structure may bring significant performance and durability improvement of anion-exchange membrane fuel cells.},
doi = {10.1039/C9TA10157H},
journal = {Journal of Materials Chemistry. A},
number = 43,
volume = 7,
place = {United Kingdom},
year = {2019},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9TA10157H

Citation Metrics:
Cited by: 4 works
Citation information provided by
Web of Science

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Works referenced in this record:

A one-shot sequence for high-resolution diffusion-ordered spectroscopy
journal, January 2002

  • Pelta, Michelle D.; Morris, Gareth A.; Stchedroff, Marc J.
  • Magnetic Resonance in Chemistry, Vol. 40, Issue 13
  • DOI: 10.1002/mrc.1107

Preparation of radiation-grafted powders for use as anion exchange ionomers in alkaline polymer electrolyte fuel cells
journal, January 2014

  • Poynton, Simon D.; Slade, Robert C. T.; Omasta, Travis J.
  • J. Mater. Chem. A, Vol. 2, Issue 14
  • DOI: 10.1039/C4TA00558A

Robust Hydroxide Ion Conducting Poly(biphenyl alkylene)s for Alkaline Fuel Cell Membranes
journal, July 2015


Anion conducting multiblock copolymer membranes with partial fluorination and long head-group tethers
journal, January 2016

  • Liu, Lisha; Ahlfield, John; Tricker, Andrew
  • Journal of Materials Chemistry A, Vol. 4, Issue 41
  • DOI: 10.1039/C6TA06653D

Cationic Polyelectrolytes, Stable in 10 M KOH aq at 100 °C
journal, September 2017


Resonance Stabilized Perfluorinated Ionomers for Alkaline Membrane Fuel Cells
journal, September 2013

  • Kim, Dae Sik; Fujimoto, Cy H.; Hibbs, Michael R.
  • Macromolecules, Vol. 46, Issue 19, p. 7826-7833
  • DOI: 10.1021/ma401568f

Alkaline Stability of Quaternary Ammonium Cations for Alkaline Fuel Cell Membranes and Ionic Liquids
journal, November 2014


NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist
journal, May 2010

  • Fulmer, Gregory R.; Miller, Alexander J. M.; Sherden, Nathaniel H.
  • Organometallics, Vol. 29, Issue 9
  • DOI: 10.1021/om100106e

Determination of Molecular Self-Diffusion Coefficients Using Pulsed-Field-Gradient NMR: An Experiment for Undergraduate Physical Chemistry Laboratory
journal, March 2012

  • Harmon, Jennifer; Coffman, Cierra; Villarrial, Spring
  • Journal of Chemical Education, Vol. 89, Issue 6
  • DOI: 10.1021/ed200471k

Quaternized aryl ether-free polyaromatics for alkaline membrane fuel cells: synthesis, properties, and performance – a topical review
journal, January 2018

  • Park, Eun Joo; Kim, Yu Seung
  • Journal of Materials Chemistry A, Vol. 6, Issue 32
  • DOI: 10.1039/C8TA05428B

Synthesis of Aromatic Anion Exchange Membranes by Friedel–Crafts Bromoalkylation and Cross-Linking of Polystyrene Block Copolymers
journal, February 2019


An electron-beam-grafted ETFE alkaline anion-exchange membrane in metal-cation-free solid-state alkaline fuel cells
journal, May 2006


Precision Synthesis of Narrow Polydispersity, Ultrahigh Molecular Weight Linear Aromatic Polymers by A 2 + B 2 Nonstoichiometric Step-Selective Polymerization
journal, August 2012

  • Cruz, Alfredo R.; Hernandez, M. Carmen G.; Guzmán-Gutiérrez, Maria T.
  • Macromolecules, Vol. 45, Issue 17
  • DOI: 10.1021/ma301691f

Poly(terphenylene) Anion Exchange Membranes: The Effect of Backbone Structure on Morphology and Membrane Property
journal, April 2017


Adsorption of Polyaromatic Backbone Impacts the Performance of Anion Exchange Membrane Fuel Cells
journal, May 2019


Backbone stability of quaternized polyaromatics for alkaline membrane fuel cells
journal, December 2012


Effect of Organic Cations on Hydrogen Oxidation Reaction of Carbon Supported Platinum
journal, January 2016

  • Chung, Hoon Taek; Choe, Yoong-Kee; Martinez, Ulises
  • Journal of The Electrochemical Society, Vol. 163, Issue 14
  • DOI: 10.1149/2.0511614jes

A Method of Casting Sound Ingots of Thermoelectric Materials
journal, January 1966

  • Borle, W. N.; Sharma, B. L.
  • Journal of The Electrochemical Society, Vol. 113, Issue 3
  • DOI: 10.1149/1.2423942

Effect of Water on the Stability of Quaternary Ammonium Groups for Anion Exchange Membrane Fuel Cell Applications
journal, May 2017


Anion exchange membranes composed of perfluoroalkylene chains and ammonium-functionalized oligophenylenes
journal, January 2015

  • Ono, Hideaki; Miyake, Junpei; Shimada, Shigehumi
  • Journal of Materials Chemistry A, Vol. 3, Issue 43
  • DOI: 10.1039/C5TA06454F

Gas transport properties of polysulphones: 1. Role of symmetry of methyl group placement on bisphenol rings
journal, January 1991


1,2,3-Triazolium-Based Poly(2,6-Dimethyl Phenylene Oxide) Copolymers as Anion Exchange Membranes
journal, February 2016

  • Liu, Lei; He, Shuqing; Zhang, Shufang
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 7
  • DOI: 10.1021/acsami.5b11519

Fourier transform pulsed-gradient spin-echo studies of molecular diffusion
journal, January 1987


Alkaline Stability of Quaternized Diels–Alder Polyphenylenes
journal, July 2019


Sorption, Transport, and Structural Evidence for Enhanced Free Volume in Poly(4-methyl-2-pentyne)/Fumed Silica Nanocomposite Membranes
journal, January 2003

  • Merkel, T. C.; Freeman, B. D.; Spontak, R. J.
  • Chemistry of Materials, Vol. 15, Issue 1
  • DOI: 10.1021/cm020672j

Rational design of polyaromatic ionomers for alkaline membrane fuel cells with >1 W cm −2 power density
journal, January 2018

  • Maurya, Sandip; Noh, Sangtaik; Matanovic, Ivana
  • Energy & Environmental Science, Vol. 11, Issue 11
  • DOI: 10.1039/C8EE02192A

Importance of balancing membrane and electrode water in anion exchange membrane fuel cells
journal, January 2018


Pt–Ru catalyzed hydrogen oxidation in alkaline media: oxophilic effect or electronic effect?
journal, January 2015

  • Wang, Ying; Wang, Gongwei; Li, Guangwei
  • Energy & Environmental Science, Vol. 8, Issue 1
  • DOI: 10.1039/C4EE02564D

Gas transport properties of polysulphones: 2. Effect of bisphenol connector groups
journal, January 1991


Alkaline polymer electrolyte fuel cells stably working at 80 °C
journal, June 2018


Impact of ionomer adsorption on alkaline hydrogen oxidation activity and fuel cell performance
journal, December 2018


Functionalization of Poly(2,6-dimethyl-1,4-phenylene oxide)s with Hindered Fluorene Side Chains for Anion Exchange Membranes
journal, April 2016


Poly(aryl piperidinium) membranes and ionomers for hydroxide exchange membrane fuel cells
journal, April 2019


Benzene Adsorption: A Significant Inhibitor for the Hydrogen Oxidation Reaction in Alkaline Conditions
journal, September 2017

  • Matanovic, Ivana; Chung, Hoon Taek; Kim, Yu Seung
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 19
  • DOI: 10.1021/acs.jpclett.7b02228

Nuclear Relaxation of H 2 and H 2 @C 60 in Organic Solvents
journal, November 2006

  • Sartori, Elena; Ruzzi, Marco; Turro, Nicholas J.
  • Journal of the American Chemical Society, Vol. 128, Issue 46
  • DOI: 10.1021/ja065172w

An optimised synthesis of high performance radiation-grafted anion-exchange membranes
journal, January 2017

  • Wang, Lianqin; Magliocca, Emanuele; Cunningham, Emma L.
  • Green Chemistry, Vol. 19, Issue 3
  • DOI: 10.1039/C6GC02526A

Alkaline quaternary ammonium hydroxides and their polymer electrolytes for electrochemical capacitors
journal, January 2014


Phenyl Oxidation Impacts the Durability of Alkaline Membrane Water Electrolyzer
journal, February 2019

  • Li, Dongguo; Matanovic, Ivana; Lee, Albert S.
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 10
  • DOI: 10.1021/acsami.9b00711

Cation–Hydroxide–Water Coadsorption Inhibits the Alkaline Hydrogen Oxidation Reaction
journal, October 2016

  • Chung, Hoon Taek; Martinez, Ulises; Matanovic, Ivana
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 22
  • DOI: 10.1021/acs.jpclett.6b02025

Surface enhanced spectroscopic investigations of adsorption of cations on electrochemical interfaces
journal, January 2017

  • Dunwell, M.; Wang, Junhua; Yan, Y.
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 2
  • DOI: 10.1039/C6CP07207K

Anion exchange membranes with branched ionic clusters for fuel cells
journal, January 2018

  • He, Yubin; Ge, Xiaolin; Liang, Xian
  • Journal of Materials Chemistry A, Vol. 6, Issue 14
  • DOI: 10.1039/C8TA01114A

Anion exchange membrane fuel cells: Current status and remaining challenges
journal, January 2018


Toward Improved Alkaline Membrane Fuel Cell Performance Using Quaternized Aryl-Ether Free Polyaromatics
journal, March 2018


N -Spirocyclic Quaternary Ammonium Ionenes for Anion-Exchange Membranes
journal, February 2017

  • Pham, Thanh Huong; Olsson, Joel S.; Jannasch, Patric
  • Journal of the American Chemical Society, Vol. 139, Issue 8
  • DOI: 10.1021/jacs.6b12944

Highly Conductive Anion-Exchange Membranes Based on Cross-Linked Poly(norbornene): Vinyl Addition Polymerization
journal, March 2019

  • Mandal, Mrinmay; Huang, Garrett; Kohl, Paul A.
  • ACS Applied Energy Materials, Vol. 2, Issue 4
  • DOI: 10.1021/acsaem.8b02051

A Microelectrode Study of Interfacial Reactions at the Platinum-Alkaline Polymer Interface
journal, January 2015

  • Yim, Sung-Dae; Chung, Hoon T.; Chlistunoff, Jerzy
  • Journal of The Electrochemical Society, Vol. 162, Issue 6
  • DOI: 10.1149/2.0151506jes

On the origin of permanent performance loss of anion exchange membrane fuel cells: Electrochemical oxidation of phenyl group
journal, October 2019