In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule
Abstract
C-alkylpyrogallol[4]arenes (PgCs) have been studied for their ability to form metal-organic nanocapsules (MONCs) through coordination to appropriate metal ions. Here we present the synthesis and characterization of an Mn II/Mn III-seamed MONC in addition to its electrochemical and magnetic behavior. This MONC assembles from 24 manganese ions and 6 PgCs, while an additional metal ion is located on the capsule interior, anchored through the introduction of bridging nitrite ions. The latter originate from an in situ redox reaction that occurs during the self-assembly process, thus representing a new route to otherwise unobtainable nanocapsules.
- Authors:
-
[1];
[4];
[1]
- Univ. of Missouri, Columbia, MO (United States)
- Univ. of Edinburgh, Scotland (United Kingdom)
- Heriot-Watt Univ., Edinburgh, Scotland (United Kingdom)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- OSTI Identifier:
- 1571128
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Rathnayake, Asanka S., Fraser, Hector W. L., Brechin, Euan K., Dalgarno, Scott J., Baumeister, Jakob E., White, Joshua, Rungthanaphatsophon, Pokpong, Walensky, Justin R., Barnes, Charles L., Teat, Simon J., and Atwood, Jerry L. In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule. United States: N. p., 2018.
Web. doi:10.1038/s41467-018-04541-w.
Rathnayake, Asanka S., Fraser, Hector W. L., Brechin, Euan K., Dalgarno, Scott J., Baumeister, Jakob E., White, Joshua, Rungthanaphatsophon, Pokpong, Walensky, Justin R., Barnes, Charles L., Teat, Simon J., & Atwood, Jerry L. In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule. United States. doi:10.1038/s41467-018-04541-w.
Rathnayake, Asanka S., Fraser, Hector W. L., Brechin, Euan K., Dalgarno, Scott J., Baumeister, Jakob E., White, Joshua, Rungthanaphatsophon, Pokpong, Walensky, Justin R., Barnes, Charles L., Teat, Simon J., and Atwood, Jerry L. Tue .
"In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule". United States. doi:10.1038/s41467-018-04541-w. https://www.osti.gov/servlets/purl/1571128.
@article{osti_1571128,
title = {In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule},
author = {Rathnayake, Asanka S. and Fraser, Hector W. L. and Brechin, Euan K. and Dalgarno, Scott J. and Baumeister, Jakob E. and White, Joshua and Rungthanaphatsophon, Pokpong and Walensky, Justin R. and Barnes, Charles L. and Teat, Simon J. and Atwood, Jerry L.},
abstractNote = {C-alkylpyrogallol[4]arenes (PgCs) have been studied for their ability to form metal-organic nanocapsules (MONCs) through coordination to appropriate metal ions. Here we present the synthesis and characterization of an MnII/MnIII-seamed MONC in addition to its electrochemical and magnetic behavior. This MONC assembles from 24 manganese ions and 6 PgCs, while an additional metal ion is located on the capsule interior, anchored through the introduction of bridging nitrite ions. The latter originate from an in situ redox reaction that occurs during the self-assembly process, thus representing a new route to otherwise unobtainable nanocapsules.},
doi = {10.1038/s41467-018-04541-w},
journal = {Nature Communications},
number = 1,
volume = 9,
place = {United States},
year = {2018},
month = {5}
}
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Works referencing / citing this record:
Single-Molecule Magnets
journal, November 2000
- Christou, George; Gatteschi, Dante; Hendrickson, David N.
- MRS Bulletin, Vol. 25, Issue 11
Supramolecular blueprint approach to metal-coordinated capsules
journal, April 2005
- McKinlay, R. M.; Cave, G. W. V.; Atwood, J. L.
- Proceedings of the National Academy of Sciences, Vol. 102, Issue 17
Pure manganese(III) 5,10,15,20-tetrakis(4-benzoic acid)porphyrin (MnTBAP) is not a superoxide dismutase mimic in aqueous systems: a case of structure–activity relationship as a watchdog mechanism in experimental therapeutics and biology
journal, November 2007
- Rebouças, Júlio S.; Spasojević, Ivan; Batinić-Haberle, Ines
- JBIC Journal of Biological Inorganic Chemistry, Vol. 13, Issue 2
Mixed-Valent Mn Supertetrahedra and Planar Discs as Enhanced Magnetic Coolers
journal, August 2008
- Manoli, Maria; Collins, Anna; Parsons, Simon
- Journal of the American Chemical Society, Vol. 130, Issue 33
Possible Intermediates in Biological Metalloporphyrin Oxidative Degradation. Nickel, Copper, and Cobalt Complexes of Octaethylformybiliverdin and Their Conversion to a Verdoheme
journal, February 1998
- Koerner, Richard; Olmstead, Marilyn M.; Ozarowski, Andrzej
- Journal of the American Chemical Society, Vol. 120, Issue 6
A Mixed-Valence Manganese Cubane Trapped by Inequivalent Trilacunary Polyoxometalate Ligands
journal, August 2011
- Mitchell, Scott G.; Molina, Pedro I.; Khanra, Sumit
- Angewandte Chemie International Edition, Vol. 50, Issue 39
Mixed metal-organic nanocapsules
journal, August 2010
- Jin, Ping; Dalgarno, Scott J.; Atwood, Jerry L.
- Coordination Chemistry Reviews, Vol. 254, Issue 15-16
Synthesis, Structure, and Magnetic Properties of a Large Lanthanide–Transition-Metal Single-Molecule Magnet
journal, July 2004
- Zaleski, Curtis M.; Depperman, Ezra C.; Kampf, Jeff W.
- Angewandte Chemie International Edition, Vol. 43, Issue 30
Oxacalix[3]arene-supported supertetrahedron
journal, January 2012
- Taylor, Stephanie M.; McIntosh, Ruaraidh D.; Rezé, Julien
- Chemical Communications, Vol. 48, Issue 74
X-ray Absorption Spectroscopy on Layered Photosystem II Membrane Particles Suggests Manganese-Centered Oxidation of the Oxygen-Evolving Complex for the S 0 -S 1 , S 1 -S 2 , and S 2 -S 3 Transitions of the Water Oxidation Cycle †
journal, December 1998
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Photoinhibition of Photosystem II and photodamage of the oxygen evolving manganese cluster
journal, February 2008
- Tyystjarvi, E.
- Coordination Chemistry Reviews, Vol. 252, Issue 3-4
Oxidation of Nitrites on Solid Electrodes
journal, January 2002
- Piela, Barbara; Wrona, Piotr K.
- Journal of The Electrochemical Society, Vol. 149, Issue 2
Metallo-supramolecular capsules
journal, April 2008
- Dalgarno, Scott J.; Power, Nicholas P.; Atwood, Jerry L.
- Coordination Chemistry Reviews, Vol. 252, Issue 8-9
Synthesis, X-ray crystal structures and biomimetic and anticancer activities of novel copper(II)benzoate complexes incorporating 2-(4′-thiazolyl)benzimidazole (thiabendazole), 2-(2-pyridyl)benzimidazole and 1,10-phenanthroline as chelating nitrogen donor ligands
journal, June 2007
- Devereux, Michael; O. Shea, Denis; Kellett, Andrew
- Journal of Inorganic Biochemistry, Vol. 101, Issue 6
Ferromagnetic Exchange Interactions for Cu 6 12+ and Mn 6 12+ Hexagons Sandwiched by Two B-α-[XW 9 O 33 ] 9- (X = As III and Sb III ) Ligands in D 3 d -Symmetric Polyoxotungstates
journal, September 2006
- Yamase, Toshihiro; Fukaya, Keisuke; Nojiri, Hiroyuki
- Inorganic Chemistry, Vol. 45, Issue 19
Polyoxometalate-Mediated Self-Assembly of Single-Molecule Magnets: {[XW 9 O 34 ] 2 [Mn III 4 Mn II 2 O 4 (H 2 O) 4 ]} 12−
journal, June 2008
- Ritchie, Chris; Ferguson, Alan; Nojiri, Hiroyuki
- Angewandte Chemie International Edition, Vol. 47, Issue 30
Transition-metal-based magnetic refrigerants for room-temperature applications
journal, January 2002
- Tegus, O.; Brück, E.; Buschow, K. H. J.
- Nature, Vol. 415, Issue 6868
Transition Metals, Ferritin, Glutathione, and Ascorbic Acid in Parkinsonian Brains
journal, February 1989
- Riederer, Peter; Sofic, Emin; Rausch, Wolf-Dieter
- Journal of Neurochemistry, Vol. 52, Issue 2
Synthesis and characterization of water-soluble free-base, zinc and copper porphyrin–oligonucleotide conjugates
journal, July 2008
- Mammana, Angela; Asakawa, Tomohiro; Bitsch-Jensen, Klaus
- Bioorganic & Medicinal Chemistry, Vol. 16, Issue 13
Manganese Clusters with Relevance to Photosystem II
journal, September 2004
- Mukhopadhyay, Sumitra; Mandal, Sanjay K.; Bhaduri, Sumit
- Chemical Reviews, Vol. 104, Issue 9
Design of functional metalloproteins
journal, August 2009
- Lu, Yi; Yeung, Natasha; Sieracki, Nathan
- Nature, Vol. 460, Issue 7257
Electrochemical Oxidation of Nitrite and the Oxidation and Reduction of NO 2 in the Room Temperature Ionic Liquid [C 2 mim][NTf 2 ]
journal, July 2007
- Broder, Tessa L.; Silvester, Debbie S.; Aldous, Leigh
- The Journal of Physical Chemistry B, Vol. 111, Issue 27
Novel Zinc Porphyrin Sensitizers for Dye-Sensitized Solar Cells: Synthesis and Spectral, Electrochemical, and Photovoltaic Properties
journal, January 2009
- Lee, Cheng-Wei; Lu, Hsueh-Pei; Lan, Chi-Ming
- Chemistry - A European Journal, Vol. 15, Issue 6
The electrochemical oxidation of nitrite dissolved in dimethylsulphoxide on platinum electrodes
journal, October 1971
- Wargon, J. A.; Arvía, A. J.
- Electrochimica Acta, Vol. 16, Issue 10
Kinetics and mechanism of the electrochemical oxidation of nitrite ion dissolved as sodium nitrite in dimethylsulphoxide solutions on platinum electrodes
journal, April 1972
- Wargon, J. A.; Arvía, A. J.
- Electrochimica Acta, Vol. 17, Issue 4
Albumin-Conjugated Corrole Metal Complexes: Extremely Simple Yet Very Efficient Biomimetic Oxidation Systems
journal, March 2005
- Mahammed, Atif; Gross, Zeev
- Journal of the American Chemical Society, Vol. 127, Issue 9
Investigating Reaction Conditions To Control the Self-Assembly of Cobalt-Seamed Nanocapsules
journal, May 2016
- Rathnayake, Asanka S.; Feaster, Kyle A.; White, Joshua
- Crystal Growth & Design, Vol. 16, Issue 7
Energy conversion catalysis using semiconducting transition metal cluster compounds
journal, October 1986
- Vante, N. Alonso; Tributsch, H.
- Nature, Vol. 323, Issue 6087
A site-specific mechanism for free radical induced biological damage: The essential role of redox-active transition metals
journal, January 1988
- Chevion, M.
- Free Radical Biology and Medicine, Vol. 5, Issue 1
Calixarene-supported clusters: employment of complementary cluster ligands for the construction of a ferromagnetic [Mn5] cage
journal, January 2012
- Taylor, Stephanie M.; McIntosh, Ruaraidh D.; Piligkos, Stergios
- Chemical Communications, Vol. 48, Issue 91
Self-assembled biomimetic [2Fe2S]-hydrogenase-based photocatalyst for molecular hydrogen evolution
journal, January 2009
- Kluwer, A. M.; Kapre, R.; Hartl, F.
- Proceedings of the National Academy of Sciences, Vol. 106, Issue 26
High-spin molecules: [Mn12O12(O2CR)16(H2O)4]
journal, March 1993
- Sessoli, Roberta; Tsai, Hui Lien; Schake, Ann R.
- Journal of the American Chemical Society, Vol. 115, Issue 5
Nitrate-dependent iron(II) oxidation in paddy soil
journal, February 2001
- Ratering, Stefan; Schnell, Sylvia
- Environmental Microbiology, Vol. 3, Issue 2
Biological polynuclear clusters coupled by magnetic interactions: From the point dipole approximation to a local spin model
journal, April 1994
- Bertrand, Patrick; More, Claude; Guigliarelli, Bruno
- Journal of the American Chemical Society, Vol. 116, Issue 7
The manganese complex of photosystem II in its reaction cycle—Basic framework and possible realization at the atomic level
journal, February 2008
- Dau, H.; Haumann, M.
- Coordination Chemistry Reviews, Vol. 252, Issue 3-4
Zinc(II)-Directed Self-Assembly of Metal–Organic Nanocapsules
journal, August 2017
- Rathnayake, Asanka S.; Barnes, Charles L.; Atwood, Jerry L.
- Crystal Growth & Design, Vol. 17, Issue 9
Coordination Polymer Chains of Dimeric Pyrogallol[4]arene Capsules
journal, July 2011
- Fowler, Drew A.; Mossine, Andrew V.; Beavers, Christine M.
- Journal of the American Chemical Society, Vol. 133, Issue 29