In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule
Abstract
C-alkylpyrogallol[4]arenes (PgCs) have been studied for their ability to form metal-organic nanocapsules (MONCs) through coordination to appropriate metal ions. Here we present the synthesis and characterization of an MnII/MnIII-seamed MONC in addition to its electrochemical and magnetic behavior. This MONC assembles from 24 manganese ions and 6 PgCs, while an additional metal ion is located on the capsule interior, anchored through the introduction of bridging nitrite ions. The latter originate from an in situ redox reaction that occurs during the self-assembly process, thus representing a new route to otherwise unobtainable nanocapsules.
- Authors:
-
[1];
[4];
[1]
- Univ. of Missouri, Columbia, MO (United States)
- Univ. of Edinburgh, Scotland (United Kingdom)
- Heriot-Watt Univ., Edinburgh, Scotland (United Kingdom)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1571128
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Rathnayake, Asanka S., Fraser, Hector W. L., Brechin, Euan K., Dalgarno, Scott J., Baumeister, Jakob E., White, Joshua, Rungthanaphatsophon, Pokpong, Walensky, Justin R., Barnes, Charles L., Teat, Simon J., and Atwood, Jerry L. In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule. United States: N. p., 2018.
Web. doi:10.1038/s41467-018-04541-w.
Rathnayake, Asanka S., Fraser, Hector W. L., Brechin, Euan K., Dalgarno, Scott J., Baumeister, Jakob E., White, Joshua, Rungthanaphatsophon, Pokpong, Walensky, Justin R., Barnes, Charles L., Teat, Simon J., & Atwood, Jerry L. In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule. United States. doi:https://doi.org/10.1038/s41467-018-04541-w
Rathnayake, Asanka S., Fraser, Hector W. L., Brechin, Euan K., Dalgarno, Scott J., Baumeister, Jakob E., White, Joshua, Rungthanaphatsophon, Pokpong, Walensky, Justin R., Barnes, Charles L., Teat, Simon J., and Atwood, Jerry L. Tue .
"In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule". United States. doi:https://doi.org/10.1038/s41467-018-04541-w. https://www.osti.gov/servlets/purl/1571128.
@article{osti_1571128,
title = {In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule},
author = {Rathnayake, Asanka S. and Fraser, Hector W. L. and Brechin, Euan K. and Dalgarno, Scott J. and Baumeister, Jakob E. and White, Joshua and Rungthanaphatsophon, Pokpong and Walensky, Justin R. and Barnes, Charles L. and Teat, Simon J. and Atwood, Jerry L.},
abstractNote = {C-alkylpyrogallol[4]arenes (PgCs) have been studied for their ability to form metal-organic nanocapsules (MONCs) through coordination to appropriate metal ions. Here we present the synthesis and characterization of an MnII/MnIII-seamed MONC in addition to its electrochemical and magnetic behavior. This MONC assembles from 24 manganese ions and 6 PgCs, while an additional metal ion is located on the capsule interior, anchored through the introduction of bridging nitrite ions. The latter originate from an in situ redox reaction that occurs during the self-assembly process, thus representing a new route to otherwise unobtainable nanocapsules.},
doi = {10.1038/s41467-018-04541-w},
journal = {Nature Communications},
number = 1,
volume = 9,
place = {United States},
year = {2018},
month = {5}
}
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Works referenced in this record:
Synthesis and characterization of water-soluble free-base, zinc and copper porphyrin–oligonucleotide conjugates
journal, July 2008
- Mammana, Angela; Asakawa, Tomohiro; Bitsch-Jensen, Klaus
- Bioorganic & Medicinal Chemistry, Vol. 16, Issue 13
Zinc(II)-Directed Self-Assembly of Metal–Organic Nanocapsules
journal, August 2017
- Rathnayake, Asanka S.; Barnes, Charles L.; Atwood, Jerry L.
- Crystal Growth & Design, Vol. 17, Issue 9
Mechanistic study of the nitration of naphthalene by its electrochemical oxidation in the presence of nitrite ion in acetonitrile solutions
journal, September 1995
- Cortona, Mariana N.; Vettorazzi, Nelio; Silber, Juana J.
- Journal of Electroanalytical Chemistry, Vol. 394, Issue 1-2
Kinetics and mechanism of the electrochemical oxidation of nitrite ion dissolved as sodium nitrite in dimethylsulphoxide solutions on platinum electrodes
journal, April 1972
- Wargon, J. A.; Arvía, A. J.
- Electrochimica Acta, Vol. 17, Issue 4
A site-specific mechanism for free radical induced biological damage: The essential role of redox-active transition metals
journal, January 1988
- Chevion, M.
- Free Radical Biology and Medicine, Vol. 5, Issue 1
Calixarene-supported clusters: employment of complementary cluster ligands for the construction of a ferromagnetic [Mn5] cage
journal, January 2012
- Taylor, Stephanie M.; McIntosh, Ruaraidh D.; Piligkos, Stergios
- Chemical Communications, Vol. 48, Issue 91
Transition-metal-based magnetic refrigerants for room-temperature applications
journal, January 2002
- Tegus, O.; Brück, E.; Buschow, K. H. J.
- Nature, Vol. 415, Issue 6868
Investigating Reaction Conditions To Control the Self-Assembly of Cobalt-Seamed Nanocapsules
journal, May 2016
- Rathnayake, Asanka S.; Feaster, Kyle A.; White, Joshua
- Crystal Growth & Design, Vol. 16, Issue 7
A High Nuclearity, Mixed-Valence Manganese(III,IV) Complex: [Mn21O24(OMe)8(O2CCH2tBu)16(H2O)10]
journal, July 2002
- Brockman, Jonathan T.; Huffman, John C.; Christou, George
- Angewandte Chemie International Edition, Vol. 41, Issue 14
Design of functional metalloproteins
journal, August 2009
- Lu, Yi; Yeung, Natasha; Sieracki, Nathan
- Nature, Vol. 460, Issue 7257
High-spin molecules: [Mn12O12(O2CR)16(H2O)4]
journal, March 1993
- Sessoli, Roberta; Tsai, Hui Lien; Schake, Ann R.
- Journal of the American Chemical Society, Vol. 115, Issue 5
The manganese complex of photosystem II in its reaction cycle—Basic framework and possible realization at the atomic level
journal, February 2008
- Dau, H.; Haumann, M.
- Coordination Chemistry Reviews, Vol. 252, Issue 3-4
Biological polynuclear clusters coupled by magnetic interactions: From the point dipole approximation to a local spin model
journal, April 1994
- Bertrand, Patrick; More, Claude; Guigliarelli, Bruno
- Journal of the American Chemical Society, Vol. 116, Issue 7
Metallo-supramolecular capsules
journal, April 2008
- Dalgarno, Scott J.; Power, Nicholas P.; Atwood, Jerry L.
- Coordination Chemistry Reviews, Vol. 252, Issue 8-9
Novel Zinc Porphyrin Sensitizers for Dye-Sensitized Solar Cells: Synthesis and Spectral, Electrochemical, and Photovoltaic Properties
journal, January 2009
- Lee, Cheng-Wei; Lu, Hsueh-Pei; Lan, Chi-Ming
- Chemistry - A European Journal, Vol. 15, Issue 6
Bond-valence parameters obtained from a systematic analysis of the Inorganic Crystal Structure Database
journal, August 1985
- Brown, I. D.; Altermatt, D.
- Acta Crystallographica Section B Structural Science, Vol. 41, Issue 4
Coordination Polymer Chains of Dimeric Pyrogallol[4]arene Capsules
journal, July 2011
- Fowler, Drew A.; Mossine, Andrew V.; Beavers, Christine M.
- Journal of the American Chemical Society, Vol. 133, Issue 29
The tetra-manganese complex of photosystem II during its redox cycle – X-ray absorption results and mechanistic implications
journal, January 2001
- Dau, Holger; Iuzzolino, Lucia; Dittmer, Jens
- Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1503, Issue 1-2
Electrochemical Oxidation of Nitrite and the Oxidation and Reduction of NO 2 in the Room Temperature Ionic Liquid [C 2 mim][NTf 2 ]
journal, July 2007
- Broder, Tessa L.; Silvester, Debbie S.; Aldous, Leigh
- The Journal of Physical Chemistry B, Vol. 111, Issue 27
The electrochemical oxidation of nitrite dissolved in dimethylsulphoxide on platinum electrodes
journal, October 1971
- Wargon, J. A.; Arvía, A. J.
- Electrochimica Acta, Vol. 16, Issue 10
Zeolite-encapsulated and clay-intercalated metal porphyrin, phthalocyanine and Schiff-base complexes as models for biomimetic oxidation catalysts: an overview
journal, October 1995
- Bedioui, Fethi
- Coordination Chemistry Reviews, Vol. 144
Nitrate reduction by metallic iron
journal, August 1998
- Huang, Chin-Pao; Wang, Hung-Wen; Chiu, Pei-Chun
- Water Research, Vol. 32, Issue 8
Metalloprotein and redox protein design
journal, August 2001
- Kennedy, M.
- Current Opinion in Structural Biology, Vol. 11, Issue 4
Mixed metal-organic nanocapsules
journal, August 2010
- Jin, Ping; Dalgarno, Scott J.; Atwood, Jerry L.
- Coordination Chemistry Reviews, Vol. 254, Issue 15-16
Pure manganese(III) 5,10,15,20-tetrakis(4-benzoic acid)porphyrin (MnTBAP) is not a superoxide dismutase mimic in aqueous systems: a case of structure–activity relationship as a watchdog mechanism in experimental therapeutics and biology
journal, November 2007
- Rebouças, Júlio S.; Spasojević, Ivan; Batinić-Haberle, Ines
- JBIC Journal of Biological Inorganic Chemistry, Vol. 13, Issue 2
Self-assembled biomimetic [2Fe2S]-hydrogenase-based photocatalyst for molecular hydrogen evolution
journal, January 2009
- Kluwer, A. M.; Kapre, R.; Hartl, F.
- Proceedings of the National Academy of Sciences, Vol. 106, Issue 26
Electrocatalytic oxidation of nitrite on a vitreous carbon electrode modified with cobalt phthalocyanine
journal, February 2002
- Caro, C.
- Electrochimica Acta, Vol. 47, Issue 9
Possible Intermediates in Biological Metalloporphyrin Oxidative Degradation. Nickel, Copper, and Cobalt Complexes of Octaethylformybiliverdin and Their Conversion to a Verdoheme
journal, February 1998
- Koerner, Richard; Olmstead, Marilyn M.; Ozarowski, Andrzej
- Journal of the American Chemical Society, Vol. 120, Issue 6
Giant metal-oxide-based spheres and their topology: from pentagonal building blocks to keplerates and unusual spin systems
journal, November 2001
- Müller, A.; Kögerler, P.; Dress, A. W. M.
- Coordination Chemistry Reviews, Vol. 222, Issue 1
Robust and stable pyrogallol[4]arene molecular capsules facilitated via an octanuclear zinc coordination belt
journal, January 2007
- Power, Nicholas P.; Dalgarno, Scott J.; Atwood, Jerry L.
- New J. Chem., Vol. 31, Issue 1
Polyoxometalate-Mediated Self-Assembly of Single-Molecule Magnets: {[XW 9 O 34 ] 2 [Mn III 4 Mn II 2 O 4 (H 2 O) 4 ]} 12−
journal, June 2008
- Ritchie, Chris; Ferguson, Alan; Nojiri, Hiroyuki
- Angewandte Chemie International Edition, Vol. 47, Issue 30
Oxacalix[3]arene-supported supertetrahedron
journal, January 2012
- Taylor, Stephanie M.; McIntosh, Ruaraidh D.; Rezé, Julien
- Chemical Communications, Vol. 48, Issue 74
Transition Metals, Ferritin, Glutathione, and Ascorbic Acid in Parkinsonian Brains
journal, February 1989
- Riederer, Peter; Sofic, Emin; Rausch, Wolf-Dieter
- Journal of Neurochemistry, Vol. 52, Issue 2
Synthesis, X-ray crystal structures and biomimetic and anticancer activities of novel copper(II)benzoate complexes incorporating 2-(4′-thiazolyl)benzimidazole (thiabendazole), 2-(2-pyridyl)benzimidazole and 1,10-phenanthroline as chelating nitrogen donor ligands
journal, June 2007
- Devereux, Michael; O. Shea, Denis; Kellett, Andrew
- Journal of Inorganic Biochemistry, Vol. 101, Issue 6
Supramolecular blueprint approach to metal-coordinated capsules
journal, April 2005
- McKinlay, R. M.; Cave, G. W. V.; Atwood, J. L.
- Proceedings of the National Academy of Sciences, Vol. 102, Issue 17
Nitrate-dependent iron(II) oxidation in paddy soil
journal, February 2001
- Ratering, Stefan; Schnell, Sylvia
- Environmental Microbiology, Vol. 3, Issue 2
Oxidation of Nitrites on Solid Electrodes
journal, January 2002
- Piela, Barbara; Wrona, Piotr K.
- Journal of The Electrochemical Society, Vol. 149, Issue 2
Ferromagnetic Exchange Interactions for Cu 6 12+ and Mn 6 12+ Hexagons Sandwiched by Two B-α-[XW 9 O 33 ] 9- (X = As III and Sb III ) Ligands in D 3 d -Symmetric Polyoxotungstates
journal, September 2006
- Yamase, Toshihiro; Fukaya, Keisuke; Nojiri, Hiroyuki
- Inorganic Chemistry, Vol. 45, Issue 19
Mixed-Valent Mn Supertetrahedra and Planar Discs as Enhanced Magnetic Coolers
journal, August 2008
- Manoli, Maria; Collins, Anna; Parsons, Simon
- Journal of the American Chemical Society, Vol. 130, Issue 33
Single-Molecule Magnets
journal, November 2000
- Christou, George; Gatteschi, Dante; Hendrickson, David N.
- MRS Bulletin, Vol. 25, Issue 11
Manganese Clusters with Relevance to Photosystem II
journal, September 2004
- Mukhopadhyay, Sumitra; Mandal, Sanjay K.; Bhaduri, Sumit
- Chemical Reviews, Vol. 104, Issue 9
Energy conversion catalysis using semiconducting transition metal cluster compounds
journal, October 1986
- Vante, N. Alonso; Tributsch, H.
- Nature, Vol. 323, Issue 6087
A Mixed-Valence Manganese Cubane Trapped by Inequivalent Trilacunary Polyoxometalate Ligands
journal, August 2011
- Mitchell, Scott G.; Molina, Pedro I.; Khanra, Sumit
- Angewandte Chemie International Edition, Vol. 50, Issue 39
Synthesis, Structure, and Magnetic Properties of a Large Lanthanide–Transition-Metal Single-Molecule Magnet
journal, July 2004
- Zaleski, Curtis M.; Depperman, Ezra C.; Kampf, Jeff W.
- Angewandte Chemie International Edition, Vol. 43, Issue 30
Albumin-Conjugated Corrole Metal Complexes: Extremely Simple Yet Very Efficient Biomimetic Oxidation Systems
journal, March 2005
- Mahammed, Atif; Gross, Zeev
- Journal of the American Chemical Society, Vol. 127, Issue 9
Photoinhibition of Photosystem II and photodamage of the oxygen evolving manganese cluster
journal, February 2008
- Tyystjarvi, E.
- Coordination Chemistry Reviews, Vol. 252, Issue 3-4
X-ray Absorption Spectroscopy on Layered Photosystem II Membrane Particles Suggests Manganese-Centered Oxidation of the Oxygen-Evolving Complex for the S 0 -S 1 , S 1 -S 2 , and S 2 -S 3 Transitions of the Water Oxidation Cycle †
journal, December 1998
- Iuzzolino, Lucia; Dittmer, Jens; Dörner, Wolfgang
- Biochemistry, Vol. 37, Issue 49
A Mixed-Valence Manganese Cubane Trapped by Inequivalent Trilacunary Polyoxometalate Ligands
journal, August 2011
- Mitchell, Scott G.; Molina, Pedro I.; Khanra, Sumit
- Angewandte Chemie, Vol. 123, Issue 39
Works referencing / citing this record:
Bond-valence parameters obtained from a systematic analysis of the Inorganic Crystal Structure Database
journal, August 1985
- Brown, I. D.; Altermatt, D.
- Acta Crystallographica Section B Structural Science, Vol. 41, Issue 4
Single-Molecule Magnets
journal, November 2000
- Christou, George; Gatteschi, Dante; Hendrickson, David N.
- MRS Bulletin, Vol. 25, Issue 11
Supramolecular blueprint approach to metal-coordinated capsules
journal, April 2005
- McKinlay, R. M.; Cave, G. W. V.; Atwood, J. L.
- Proceedings of the National Academy of Sciences, Vol. 102, Issue 17
Pure manganese(III) 5,10,15,20-tetrakis(4-benzoic acid)porphyrin (MnTBAP) is not a superoxide dismutase mimic in aqueous systems: a case of structure–activity relationship as a watchdog mechanism in experimental therapeutics and biology
journal, November 2007
- Rebouças, Júlio S.; Spasojević, Ivan; Batinić-Haberle, Ines
- JBIC Journal of Biological Inorganic Chemistry, Vol. 13, Issue 2
Mixed-Valent Mn Supertetrahedra and Planar Discs as Enhanced Magnetic Coolers
journal, August 2008
- Manoli, Maria; Collins, Anna; Parsons, Simon
- Journal of the American Chemical Society, Vol. 130, Issue 33
Possible Intermediates in Biological Metalloporphyrin Oxidative Degradation. Nickel, Copper, and Cobalt Complexes of Octaethylformybiliverdin and Their Conversion to a Verdoheme
journal, February 1998
- Koerner, Richard; Olmstead, Marilyn M.; Ozarowski, Andrzej
- Journal of the American Chemical Society, Vol. 120, Issue 6
A Mixed-Valence Manganese Cubane Trapped by Inequivalent Trilacunary Polyoxometalate Ligands
journal, August 2011
- Mitchell, Scott G.; Molina, Pedro I.; Khanra, Sumit
- Angewandte Chemie International Edition, Vol. 50, Issue 39
Mixed metal-organic nanocapsules
journal, August 2010
- Jin, Ping; Dalgarno, Scott J.; Atwood, Jerry L.
- Coordination Chemistry Reviews, Vol. 254, Issue 15-16
Synthesis, Structure, and Magnetic Properties of a Large Lanthanide–Transition-Metal Single-Molecule Magnet
journal, July 2004
- Zaleski, Curtis M.; Depperman, Ezra C.; Kampf, Jeff W.
- Angewandte Chemie International Edition, Vol. 43, Issue 30
Giant metal-oxide-based spheres and their topology: from pentagonal building blocks to keplerates and unusual spin systems
journal, November 2001
- Müller, A.; Kögerler, P.; Dress, A. W. M.
- Coordination Chemistry Reviews, Vol. 222, Issue 1
Robust and stable pyrogallol[4]arene molecular capsules facilitated via an octanuclear zinc coordination belt
journal, January 2007
- Power, Nicholas P.; Dalgarno, Scott J.; Atwood, Jerry L.
- New J. Chem., Vol. 31, Issue 1
Electrocatalytic oxidation of nitrite on a vitreous carbon electrode modified with cobalt phthalocyanine
journal, February 2002
- Caro, C.
- Electrochimica Acta, Vol. 47, Issue 9
Oxacalix[3]arene-supported supertetrahedron
journal, January 2012
- Taylor, Stephanie M.; McIntosh, Ruaraidh D.; Rezé, Julien
- Chemical Communications, Vol. 48, Issue 74
X-ray Absorption Spectroscopy on Layered Photosystem II Membrane Particles Suggests Manganese-Centered Oxidation of the Oxygen-Evolving Complex for the S 0 -S 1 , S 1 -S 2 , and S 2 -S 3 Transitions of the Water Oxidation Cycle †
journal, December 1998
- Iuzzolino, Lucia; Dittmer, Jens; Dörner, Wolfgang
- Biochemistry, Vol. 37, Issue 49
Photoinhibition of Photosystem II and photodamage of the oxygen evolving manganese cluster
journal, February 2008
- Tyystjarvi, E.
- Coordination Chemistry Reviews, Vol. 252, Issue 3-4
Oxidation of Nitrites on Solid Electrodes
journal, January 2002
- Piela, Barbara; Wrona, Piotr K.
- Journal of The Electrochemical Society, Vol. 149, Issue 2
Zeolite-encapsulated and clay-intercalated metal porphyrin, phthalocyanine and Schiff-base complexes as models for biomimetic oxidation catalysts: an overview
journal, October 1995
- Bedioui, Fethi
- Coordination Chemistry Reviews, Vol. 144
Metallo-supramolecular capsules
journal, April 2008
- Dalgarno, Scott J.; Power, Nicholas P.; Atwood, Jerry L.
- Coordination Chemistry Reviews, Vol. 252, Issue 8-9
Metalloprotein and redox protein design
journal, August 2001
- Kennedy, M.
- Current Opinion in Structural Biology, Vol. 11, Issue 4
Nitrate reduction by metallic iron
journal, August 1998
- Huang, Chin-Pao; Wang, Hung-Wen; Chiu, Pei-Chun
- Water Research, Vol. 32, Issue 8
Synthesis, X-ray crystal structures and biomimetic and anticancer activities of novel copper(II)benzoate complexes incorporating 2-(4′-thiazolyl)benzimidazole (thiabendazole), 2-(2-pyridyl)benzimidazole and 1,10-phenanthroline as chelating nitrogen donor ligands
journal, June 2007
- Devereux, Michael; O. Shea, Denis; Kellett, Andrew
- Journal of Inorganic Biochemistry, Vol. 101, Issue 6
Ferromagnetic Exchange Interactions for Cu 6 12+ and Mn 6 12+ Hexagons Sandwiched by Two B-α-[XW 9 O 33 ] 9- (X = As III and Sb III ) Ligands in D 3 d -Symmetric Polyoxotungstates
journal, September 2006
- Yamase, Toshihiro; Fukaya, Keisuke; Nojiri, Hiroyuki
- Inorganic Chemistry, Vol. 45, Issue 19
The tetra-manganese complex of photosystem II during its redox cycle – X-ray absorption results and mechanistic implications
journal, January 2001
- Dau, Holger; Iuzzolino, Lucia; Dittmer, Jens
- Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1503, Issue 1-2
Polyoxometalate-Mediated Self-Assembly of Single-Molecule Magnets: {[XW 9 O 34 ] 2 [Mn III 4 Mn II 2 O 4 (H 2 O) 4 ]} 12−
journal, June 2008
- Ritchie, Chris; Ferguson, Alan; Nojiri, Hiroyuki
- Angewandte Chemie International Edition, Vol. 47, Issue 30
Transition-metal-based magnetic refrigerants for room-temperature applications
journal, January 2002
- Tegus, O.; Brück, E.; Buschow, K. H. J.
- Nature, Vol. 415, Issue 6868
Transition Metals, Ferritin, Glutathione, and Ascorbic Acid in Parkinsonian Brains
journal, February 1989
- Riederer, Peter; Sofic, Emin; Rausch, Wolf-Dieter
- Journal of Neurochemistry, Vol. 52, Issue 2
Synthesis and characterization of water-soluble free-base, zinc and copper porphyrin–oligonucleotide conjugates
journal, July 2008
- Mammana, Angela; Asakawa, Tomohiro; Bitsch-Jensen, Klaus
- Bioorganic & Medicinal Chemistry, Vol. 16, Issue 13
Mechanistic study of the nitration of naphthalene by its electrochemical oxidation in the presence of nitrite ion in acetonitrile solutions
journal, September 1995
- Cortona, Mariana N.; Vettorazzi, Nelio; Silber, Juana J.
- Journal of Electroanalytical Chemistry, Vol. 394, Issue 1-2
Manganese Clusters with Relevance to Photosystem II
journal, September 2004
- Mukhopadhyay, Sumitra; Mandal, Sanjay K.; Bhaduri, Sumit
- Chemical Reviews, Vol. 104, Issue 9
Design of functional metalloproteins
journal, August 2009
- Lu, Yi; Yeung, Natasha; Sieracki, Nathan
- Nature, Vol. 460, Issue 7257
Electrochemical Oxidation of Nitrite and the Oxidation and Reduction of NO 2 in the Room Temperature Ionic Liquid [C 2 mim][NTf 2 ]
journal, July 2007
- Broder, Tessa L.; Silvester, Debbie S.; Aldous, Leigh
- The Journal of Physical Chemistry B, Vol. 111, Issue 27
Novel Zinc Porphyrin Sensitizers for Dye-Sensitized Solar Cells: Synthesis and Spectral, Electrochemical, and Photovoltaic Properties
journal, January 2009
- Lee, Cheng-Wei; Lu, Hsueh-Pei; Lan, Chi-Ming
- Chemistry - A European Journal, Vol. 15, Issue 6
The electrochemical oxidation of nitrite dissolved in dimethylsulphoxide on platinum electrodes
journal, October 1971
- Wargon, J. A.; Arvía, A. J.
- Electrochimica Acta, Vol. 16, Issue 10
Kinetics and mechanism of the electrochemical oxidation of nitrite ion dissolved as sodium nitrite in dimethylsulphoxide solutions on platinum electrodes
journal, April 1972
- Wargon, J. A.; Arvía, A. J.
- Electrochimica Acta, Vol. 17, Issue 4
Albumin-Conjugated Corrole Metal Complexes: Extremely Simple Yet Very Efficient Biomimetic Oxidation Systems
journal, March 2005
- Mahammed, Atif; Gross, Zeev
- Journal of the American Chemical Society, Vol. 127, Issue 9
Investigating Reaction Conditions To Control the Self-Assembly of Cobalt-Seamed Nanocapsules
journal, May 2016
- Rathnayake, Asanka S.; Feaster, Kyle A.; White, Joshua
- Crystal Growth & Design, Vol. 16, Issue 7
Energy conversion catalysis using semiconducting transition metal cluster compounds
journal, October 1986
- Vante, N. Alonso; Tributsch, H.
- Nature, Vol. 323, Issue 6087
A site-specific mechanism for free radical induced biological damage: The essential role of redox-active transition metals
journal, January 1988
- Chevion, M.
- Free Radical Biology and Medicine, Vol. 5, Issue 1
Calixarene-supported clusters: employment of complementary cluster ligands for the construction of a ferromagnetic [Mn5] cage
journal, January 2012
- Taylor, Stephanie M.; McIntosh, Ruaraidh D.; Piligkos, Stergios
- Chemical Communications, Vol. 48, Issue 91
Self-assembled biomimetic [2Fe2S]-hydrogenase-based photocatalyst for molecular hydrogen evolution
journal, January 2009
- Kluwer, A. M.; Kapre, R.; Hartl, F.
- Proceedings of the National Academy of Sciences, Vol. 106, Issue 26
High-spin molecules: [Mn12O12(O2CR)16(H2O)4]
journal, March 1993
- Sessoli, Roberta; Tsai, Hui Lien; Schake, Ann R.
- Journal of the American Chemical Society, Vol. 115, Issue 5
Nitrate-dependent iron(II) oxidation in paddy soil
journal, February 2001
- Ratering, Stefan; Schnell, Sylvia
- Environmental Microbiology, Vol. 3, Issue 2
Biological polynuclear clusters coupled by magnetic interactions: From the point dipole approximation to a local spin model
journal, April 1994
- Bertrand, Patrick; More, Claude; Guigliarelli, Bruno
- Journal of the American Chemical Society, Vol. 116, Issue 7
The manganese complex of photosystem II in its reaction cycle—Basic framework and possible realization at the atomic level
journal, February 2008
- Dau, H.; Haumann, M.
- Coordination Chemistry Reviews, Vol. 252, Issue 3-4
Zinc(II)-Directed Self-Assembly of Metal–Organic Nanocapsules
journal, August 2017
- Rathnayake, Asanka S.; Barnes, Charles L.; Atwood, Jerry L.
- Crystal Growth & Design, Vol. 17, Issue 9
Coordination Polymer Chains of Dimeric Pyrogallol[4]arene Capsules
journal, July 2011
- Fowler, Drew A.; Mossine, Andrew V.; Beavers, Christine M.
- Journal of the American Chemical Society, Vol. 133, Issue 29
A High Nuclearity, Mixed-Valence Manganese(III,IV) Complex: [Mn21O24(OMe)8(O2CCH2tBu)16(H2O)10]
journal, July 2002
- Brockman, Jonathan T.; Huffman, John C.; Christou, George
- Angewandte Chemie International Edition, Vol. 41, Issue 14
An Indium‐Seamed Hexameric Metal–Organic Cage as an Example of a Hexameric Pyrogallol[4]arene Capsule Conjoined Exclusively by Trivalent Metal Ions
journal, February 2020
- Wagle, Durgesh V.; Kelley, Steven P.; Baker, Gary A.
- Angewandte Chemie International Edition, Vol. 59, Issue 21