skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on September 30, 2020

Title: Influence of organic cation planarity on structural templating in hybrid metal-halides

Abstract

The structure and planarity of aromatic organic cations directly influence both the inorganic connectivity and the resulting optical properties of hybrid semiconductors, thus providing tunability for optoelectronic applications.

Authors:
ORCiD logo [1];  [1]; ORCiD logo [1]
  1. Department of Chemistry, Colorado State University, Fort Collins, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1570791
Grant/Contract Number:  
SC0016083
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 48 Journal Issue: 43; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Oswald, Iain W. H., Ahn, Hyochul, and Neilson, James R. Influence of organic cation planarity on structural templating in hybrid metal-halides. United Kingdom: N. p., 2019. Web. doi:10.1039/C9DT03207J.
Oswald, Iain W. H., Ahn, Hyochul, & Neilson, James R. Influence of organic cation planarity on structural templating in hybrid metal-halides. United Kingdom. doi:10.1039/C9DT03207J.
Oswald, Iain W. H., Ahn, Hyochul, and Neilson, James R. Tue . "Influence of organic cation planarity on structural templating in hybrid metal-halides". United Kingdom. doi:10.1039/C9DT03207J.
@article{osti_1570791,
title = {Influence of organic cation planarity on structural templating in hybrid metal-halides},
author = {Oswald, Iain W. H. and Ahn, Hyochul and Neilson, James R.},
abstractNote = {The structure and planarity of aromatic organic cations directly influence both the inorganic connectivity and the resulting optical properties of hybrid semiconductors, thus providing tunability for optoelectronic applications.},
doi = {10.1039/C9DT03207J},
journal = {Dalton Transactions},
number = 43,
volume = 48,
place = {United Kingdom},
year = {2019},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on September 30, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

A short history of SHELX
journal, December 2007

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
  • DOI: 10.1107/S0108767307043930

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


Conducting tin halides with a layered organic-based perovskite structure
journal, June 1994

  • Mitzi, D. B.; Feild, C. A.; Harrison, W. T. A.
  • Nature, Vol. 369, Issue 6480, p. 467-469
  • DOI: 10.1038/369467a0

Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors
journal, April 2016

  • Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J.
  • Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867
  • DOI: 10.1021/acs.chemmater.6b00847

Single-crystal structure validation with the program PLATON
journal, January 2003


Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties
journal, July 2013

  • Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G.
  • Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038
  • DOI: 10.1021/ic401215x

SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8
  • DOI: 10.1107/S2053273314026370

Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells
journal, October 2013

  • Snaith, Henry J.
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 21, p. 3623-3630
  • DOI: 10.1021/jz4020162