Structural diversity in multinuclear tantalum polyhydrides formed via reductive hydrogenolysis of metal–carbon bonds
Abstract
Put the methyl to the metal: hydrogenolysis of metal–carbon bonds offers controlled access to low-valent early metal complexes.
- Authors:
-
- Department of Chemistry, University of California, Berkeley, USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1570788
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Name: ChemComm Journal Volume: 55 Journal Issue: 88; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Fostvedt, Jade I., Lohrey, Trevor D., Bergman, Robert G., and Arnold, John. Structural diversity in multinuclear tantalum polyhydrides formed via reductive hydrogenolysis of metal–carbon bonds. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9CC07686G.
Fostvedt, Jade I., Lohrey, Trevor D., Bergman, Robert G., & Arnold, John. Structural diversity in multinuclear tantalum polyhydrides formed via reductive hydrogenolysis of metal–carbon bonds. United Kingdom. https://doi.org/10.1039/C9CC07686G
Fostvedt, Jade I., Lohrey, Trevor D., Bergman, Robert G., and Arnold, John. Thu .
"Structural diversity in multinuclear tantalum polyhydrides formed via reductive hydrogenolysis of metal–carbon bonds". United Kingdom. https://doi.org/10.1039/C9CC07686G.
@article{osti_1570788,
title = {Structural diversity in multinuclear tantalum polyhydrides formed via reductive hydrogenolysis of metal–carbon bonds},
author = {Fostvedt, Jade I. and Lohrey, Trevor D. and Bergman, Robert G. and Arnold, John},
abstractNote = {Put the methyl to the metal: hydrogenolysis of metal–carbon bonds offers controlled access to low-valent early metal complexes.},
doi = {10.1039/C9CC07686G},
journal = {ChemComm},
number = 88,
volume = 55,
place = {United Kingdom},
year = {Thu Oct 31 00:00:00 EDT 2019},
month = {Thu Oct 31 00:00:00 EDT 2019}
}
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https://doi.org/10.1039/C9CC07686G
https://doi.org/10.1039/C9CC07686G
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Cited by: 10 works
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Works referenced in this record:
Hydrogenolysis of Tantalum Hydrocarbyl Complexes: Intermediates on the Road to a Dinuclear Tantalum Tetrahydride Derivative
journal, July 2015
- Parker, Kyle D. J.; Nied, Dominik; Fryzuk, Michael D.
- Organometallics, Vol. 34, Issue 14
Synthesis and structure of a di-tantalum(IV) hexahydride compound containing ancillary amido ligation
journal, January 1992
- Profilet, Robert D.; Fanwick, Phillip E.; Rothwell, Ian P.
- Polyhedron, Vol. 11, Issue 12
1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadienes as Strong Salt-Free Reductants for Generating Low-Valent Early Transition Metals with Electron-Donating Ligands
journal, March 2014
- Saito, Teruhiko; Nishiyama, Haruka; Tanahashi, Hiromasa
- Journal of the American Chemical Society, Vol. 136, Issue 13
Dis-assembly of a Benzylic CF 3 Group Mediated by a Niobium(III) Imido Complex
journal, May 2013
- Gianetti, Thomas L.; Bergman, Robert G.; Arnold, John
- Journal of the American Chemical Society, Vol. 135, Issue 22
Carbon–fluorine bond cleavage in fluoroarenes via a niobium(iii) imido complex: from stoichiometric to catalytic hydrodefluorination
journal, January 2014
- Gianetti, Thomas L.; Bergman, Robert G.; Arnold, John
- Chemical Science, Vol. 5, Issue 6
Carbon monoxide cleavage by (silox)3Ta (silox = tert-Bu3SiO-)
journal, October 1986
- LaPointe, Robert E.; Wolczanski, Peter T.; Mitchell, John F.
- Journal of the American Chemical Society, Vol. 108, Issue 20
Synthesis of (Pentamethylcyclopentadienyl)tantalum Sulfido Complexes via C−S Bond Cleavage of Triphenylmethanethiolate and Formation of a Novel Trithioborato Ligand
journal, February 1997
- Kawaguchi, Hiroyuki; Tatsumi, Kazuyuki
- Organometallics, Vol. 16, Issue 3
Diniobium Inverted Sandwich Complexes with μ-η 6 :η 6 -Arene Ligands: Synthesis, Kinetics of Formation, and Electronic Structure
journal, February 2013
- Gianetti, Thomas L.; Nocton, Grégory; Minasian, Stefan G.
- Journal of the American Chemical Society, Vol. 135, Issue 8
Hydroboration Reactivity of Niobium Bis(N-heterocyclic carbene)borate Complexes
journal, April 2018
- Ziegler, Jessica A.; Prange, Céline; Lohrey, Trevor D.
- Inorganic Chemistry, Vol. 57, Issue 9
Additive Covalent Radii for Single-, Double-, and Triple-Bonded Molecules and Tetrahedrally Bonded Crystals: A Summary
journal, September 2014
- Pyykkö, Pekka
- The Journal of Physical Chemistry A, Vol. 119, Issue 11
Intramolecular arene hydrogenation by niobium aryloxide compounds: Stereochemistry of cyclohexadiene formation
journal, January 1989
- Steffey, Bryan D.; Chesnut, Robert W.; Kerschner, Judith L.
- Journal of the American Chemical Society, Vol. 111, Issue 1
Metal-bridging benzene in a binuclear hydridovanadium complex
journal, August 1983
- Jonas, Klaus; Wiskamp, Volker; Tsay, Yi Hung
- Journal of the American Chemical Society, Vol. 105, Issue 16
Nitride Formation by Thermolysis of a Kinetically Stable Niobium Dinitrogen Complex
journal, July 2002
- Fryzuk, Michael D.; Kozak, Christopher M.; Bowdridge, Michael R.
- Journal of the American Chemical Society, Vol. 124, Issue 28
Hydrolysis of the metal-chloride bonds in (.eta.5-C5Me5)TaCl4 leading to stepwise formation of binuclear and trinuclear tantalum oxide clusters
journal, June 1987
- Jernakoff, Peter.; De Meric de Bellefon, Claude.; Geoffroy, Gregory L.
- Organometallics, Vol. 6, Issue 6
Reduction of carbon monoxide by binuclear tantalum hydride complexes
journal, May 1983
- Belmonte, Patricia A.; Cloke, F. Geoffrey N.; Schrock, Richard R.
- Journal of the American Chemical Society, Vol. 105, Issue 9
A niobaziridine hydride system for white phosphorus or dinitrogen activation and N- or P-atom transfer
journal, January 2006
- Figueroa, Joshua S.; Cummins, Christopher C.
- Dalton Transactions, Issue 18
Carbon monoxide hydrogenation, deoxygenation, and carbon-carbon coupling promoted by [(silox)2TaH2]2
journal, November 1987
- Toreki, Robert; LaPointe, Robert E.; Wolczanski, Peter T.
- Journal of the American Chemical Society, Vol. 109, Issue 24
Carbon monoxide cleavage by (silox)3Ta (silox = tert-Bu3SiO-): physical, theoretical, and mechanistic investigations
journal, December 1989
- Neithamer, David R.; LaPointe, Robert E.; Wheeler, Ralph A.
- Journal of the American Chemical Society, Vol. 111, Issue 25
The first practical niobium(III) reagent in organic synthesis. A convenient route to 2-amino alcohols via the coupling of imines with aldehydes or ketones promoted by NbCl3(DME)
journal, October 1987
- Roskamp, Eric J.; Pedersen, Steven F.
- Journal of the American Chemical Society, Vol. 109, Issue 21
Reduction of carbon monoxide by a tetrakis(aryloxide)diniobium complex having four bridging hydrides
journal, January 2013
- Kurogi, Takashi; Ishida, Yutaka; Hatanaka, Tsubasa
- Dalton Trans., Vol. 42, Issue 21
Reactions of tantalum(III) with alkynes and nitriles
journal, August 1979
- Cotton, F. Albert; Hall, William T.
- Journal of the American Chemical Society, Vol. 101, Issue 17
Reductive Elimination of Diphosphine from a Thorium–NHC–Bis(phosphido) Complex
journal, May 2017
- Garner, Mary E.; Arnold, John
- Organometallics, Vol. 36, Issue 23
Alkyne cyclizations at reduced tantalum centers: synthesis and molecular structure of (.eta.6-C6Me6)Ta(O-2,6-i-Pr2C6H3)2Cl
journal, October 1987
- Bruck, M. A.; Copenhaver, A. S.; Wigley, D. E.
- Journal of the American Chemical Society, Vol. 109, Issue 21
Dinitrogen Cleavage by a Diniobium Tetrahydride Complex: Formation of a Nitride and Its Conversion into Imide Species
journal, November 2007
- Akagi, Fumio; Matsuo, Tsukasa; Kawaguchi, Hiroyuki
- Angewandte Chemie International Edition, Vol. 46, Issue 46
Synthesis and Bonding in the Diamagnetic Dinuclear Tantalum(IV) Hydride Species ([P 2 N 2 ]Ta) 2 (μ-H) 4 and the Paramagnetic Cationic Dinuclear Hydride Species {([P 2 N 2 ]Ta) 2 (μ-H) 4 } + I - ([P 2 N 2 ] = PhP(CH 2 SiMe 2 NSiMe 2 CH 2 ) 2 PPh): The Reducing Ability of a Metal−Metal Bond
journal, September 2000
- Fryzuk, Michael D.; Johnson, Samuel A.; Rettig, Steven J.
- Organometallics, Vol. 19, Issue 19
[(silox)3M]2(μ:η1,η1-P2) (M = Nb, Ta) and [(silox)3Nb]2{μ:η2,η2-(cP3–cP3)} from (silox)3M (M = NbPMe3, Ta) and P4 (silox = tBu3SiO)
journal, January 2009
- Hulley, Elliott B.; Wolczanski, Peter T.; Lobkovsky, Emil B.
- Chemical Communications, Issue 42
Four-electron reduction of dinitrogen during solution disproportionation of the organodimetallic (η-C5Me4R)2Ta2(µ-Cl)4(R = Me, Et) to a new µ-η1,η1-N2 complex and odd-electron organotrimetallic cluster
journal, January 2005
- Lee, Ting-Yu; Wooten, Alfred J.; Luci, Jeffrey J.
- Chemical Communications, Issue 43
All-cis catalytic hydrogenation of polynuclear aromatic hydrocarbons by Group 5 metal aryl oxide compounds
journal, February 1992
- Yu, Joyce S.; Ankianiec, Bernardeta C.; Rothwell, Ian P.
- Journal of the American Chemical Society, Vol. 114, Issue 5
Preparation and characterization of tantalum(III) olefin complexes and tantalum(V) metallacyclopentane complexes made from acyclic .alpha. olefins
journal, August 1979
- McLain, S. J.; Wood, C. D.; Schrock, R. R.
- Journal of the American Chemical Society, Vol. 101, Issue 16
Pyridine CN Bond Cleavage Mediated by (silox) 3 Nb (silox = t Bu 3 SiO)
journal, January 1997
- Kleckley, Troy S.; Bennett, Jordan L.; Wolczanski, Peter T.
- Journal of the American Chemical Society, Vol. 119, Issue 1
New synthetic routes for the preparation of niobium(III) and tantalum(III) triangular cluster compounds
journal, December 1990
- Babaian-Kibala, Elizabeth; Cotton, F. Albert; Shang, Maoyu
- Inorganic Chemistry, Vol. 29, Issue 26
Cleavage of Carbon Monoxide Promoted by a Dinuclear Tantalum Tetrahydride Complex
journal, December 2012
- Ballmann, Joachim; Pick, Fraser; Castro, Ludovic
- Organometallics, Vol. 31, Issue 24
Tethered Bis-Amidinates as Supporting Ligands: A Concerted Elimination/σ-π Rearrangement Reaction Forming an Unusual Titanium Arene Complex
journal, July 1998
- Hagadorn, John R.; Arnold, John
- Angewandte Chemie International Edition, Vol. 37, Issue 12
Binuclear tantalum hydride complexes
journal, June 1982
- Belmonte, Patricia A.; Schrock, Richard R.; Day, Cynthia S.
- Journal of the American Chemical Society, Vol. 104, Issue 11
Syntheses, carbonylations, and dihydrogen exchange studies of monomeric and dimeric silox (tert-Bu3SiO-) hydrides of tantalum: structure of [(silox)2TaH2]2
journal, June 1993
- Miller, Rebecca L.; Toreki, Robert; LaPointe, Robert E.
- Journal of the American Chemical Society, Vol. 115, Issue 13
Modern applications of low-valent early transition metals in synthesis and catalysis
journal, November 2018
- Beaumier, Evan P.; Pearce, Adam J.; See, Xin Yi
- Nature Reviews Chemistry, Vol. 3, Issue 1
Synthesis and reactivity of (dialkylacetylene)niobium(III) complexes and derivatives. Contrast between protonation and methylation pathways
journal, March 1975
- Labinger, Jay A.; Schwartz, Jeffrey
- Journal of the American Chemical Society, Vol. 97, Issue 6
Carbon-Nitrogen Bond Cleavage in an .eta.2(N,C)-Pyridine Complex Induced by Intramolecular Metal-to-Ligand Alkyl Migration: Models for Hydrodenitrogenation Catalysis
journal, November 1995
- Gray, Steven D.; Weller, Keith J.; Bruck, Michael A.
- Journal of the American Chemical Society, Vol. 117, Issue 43
Synthesis by spontaneous self-assembly of metal atom clusters of zirconium, niobium, and tantalum
journal, January 1988
- Cotton, F. Albert.; Kibala, Piotr A.; Roth, Wieslaw J.
- Journal of the American Chemical Society, Vol. 110, Issue 1
Activation of Atmospheric Nitrogen and Azobenzene NN Bond Cleavage by a Transient Nb(III) Complex
journal, December 2006
- Kilgore, Uriah J.; Yang, Xiaofan; Tomaszewski, John
- Inorganic Chemistry, Vol. 45, Issue 26
An overview of N-heterocyclic carbenes
journal, June 2014
- Hopkinson, Matthew N.; Richter, Christian; Schedler, Michael
- Nature, Vol. 510, Issue 7506, p. 485-496
Intramolecular alkane dehydrogenation and functionalization at niobium metal centers
journal, October 1990
- Yu, Joyce S.; Fanwick, Phillip E.; Rothwell, Ian P.
- Journal of the American Chemical Society, Vol. 112, Issue 22
Direct Evidence for a [4+2] Cycloaddition Mechanism of Alkynes to Tantallacyclopentadiene on Dinuclear Tantalum Complexes as a Model of Alkyne Cyclotrimerization
journal, June 2015
- Yamamoto, Keishi; Tsurugi, Hayato; Mashima, Kazushi
- Chemistry - A European Journal, Vol. 21, Issue 32
A new generation of homogeneous arene hydrogenation catalysts
journal, January 1997
- Rothwell, Ian P.
- Chemical Communications, Issue 15
Redox-Initiated Reactivity of Dinuclear β-Diketiminatoniobium Imido Complexes
journal, January 2017
- Kriegel, Benjamin M.; Naested, Lara C. E.; Nocton, Grégory
- Inorganic Chemistry, Vol. 56, Issue 3
η6-Bonded Alkylbenzenes as Novel Bridging Ligands in Dinuclear Complexes of Iron and Cobalt
journal, August 1983
- Jonas, Klaus; Koepe, Gerd; Schieferstein, Ludwig
- Angewandte Chemie International Edition in English, Vol. 22, Issue 8
A New Supporting Ligand in Actinide Chemistry Leads to Reactive Bis(NHC)borate-Supported Thorium Complexes
journal, August 2016
- Garner, Mary E.; Hohloch, Stephan; Maron, Laurent
- Organometallics, Vol. 35, Issue 17