Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly
Abstract
Mesoporous FexOy and Pt@FexOy have proven promising performance in catalysis. Yet, current methods usually use wet chemistry, which poses several drawbacks. Here, we introduce a simple process of mechanochemical assembly between an iron salt and a triblock copolymer in the solid state that can not only directly form abundant mesopores into FexOy, but also enable a high dispersion of Pt species at the nm or sub-nm scale. In this regard, mesoporous FexOy and Pt@FexOy catalysts with high surface areas (up to 149 m2 g-1) and narrow pore size distributions (~5 nm) can be obtained in a solvent-free and rapid (0.5 h) way. The kinetic energy and frictional heating of ball milling are expected to promote the interaction and diffusion between iron precursors and surfactants, while the solvent-free feature confines their assembly to the mesophase of the P123 copolymer. Moreover, these Pt@FexOy catalysts provide good activity in the total oxidation of propylene and CO.
- Authors:
-
[2];
[4]
- East China Normal Univ., Shanghai (China)
- Shanghai Jiao Tong Univ. (China)
- Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; National Natural Science Foundation of China (NSFC)
- OSTI Identifier:
- 1570676
- Report Number(s):
- BNL-212200-2019-JAAM
Journal ID: ISSN 2044-4753; CSTAGD
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Catalysis Science and Technology
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 15; Journal ID: ISSN 2044-4753
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Zhou, Min, Zhao, Jiahua, Zhang, Pengfei, Chen, Nanqing, and Yang, Shize. Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly. United States: N. p., 2019.
Web. doi:10.1039/C9CY00970A.
Zhou, Min, Zhao, Jiahua, Zhang, Pengfei, Chen, Nanqing, & Yang, Shize. Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly. United States. https://doi.org/10.1039/C9CY00970A
Zhou, Min, Zhao, Jiahua, Zhang, Pengfei, Chen, Nanqing, and Yang, Shize. Mon .
"Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly". United States. https://doi.org/10.1039/C9CY00970A. https://www.osti.gov/servlets/purl/1570676.
@article{osti_1570676,
title = {Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly},
author = {Zhou, Min and Zhao, Jiahua and Zhang, Pengfei and Chen, Nanqing and Yang, Shize},
abstractNote = {Mesoporous FexOy and Pt@FexOy have proven promising performance in catalysis. Yet, current methods usually use wet chemistry, which poses several drawbacks. Here, we introduce a simple process of mechanochemical assembly between an iron salt and a triblock copolymer in the solid state that can not only directly form abundant mesopores into FexOy, but also enable a high dispersion of Pt species at the nm or sub-nm scale. In this regard, mesoporous FexOy and Pt@FexOy catalysts with high surface areas (up to 149 m2 g-1) and narrow pore size distributions (~5 nm) can be obtained in a solvent-free and rapid (0.5 h) way. The kinetic energy and frictional heating of ball milling are expected to promote the interaction and diffusion between iron precursors and surfactants, while the solvent-free feature confines their assembly to the mesophase of the P123 copolymer. Moreover, these Pt@FexOy catalysts provide good activity in the total oxidation of propylene and CO.},
doi = {10.1039/C9CY00970A},
journal = {Catalysis Science and Technology},
number = 15,
volume = 9,
place = {United States},
year = {2019},
month = {7}
}
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