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Title: Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly

Abstract

Mesoporous FexOy and Pt@FexOy have proven promising performance in catalysis. Yet, current methods usually use wet chemistry, which poses several drawbacks. Here, we introduce a simple process of mechanochemical assembly between an iron salt and a triblock copolymer in the solid state that can not only directly form abundant mesopores into FexOy, but also enable a high dispersion of Pt species at the nm or sub-nm scale. In this regard, mesoporous FexOy and Pt@FexOy catalysts with high surface areas (up to 149 m2 g-1) and narrow pore size distributions (~5 nm) can be obtained in a solvent-free and rapid (0.5 h) way. The kinetic energy and frictional heating of ball milling are expected to promote the interaction and diffusion between iron precursors and surfactants, while the solvent-free feature confines their assembly to the mesophase of the P123 copolymer. Moreover, these Pt@FexOy catalysts provide good activity in the total oxidation of propylene and CO.

Authors:
 [1];  [2]; ORCiD logo [2];  [3]; ORCiD logo [4]
  1. East China Normal Univ., Shanghai (China)
  2. Shanghai Jiao Tong Univ. (China)
  3. Univ. of Tennessee, Knoxville, TN (United States)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; National Natural Science Foundation of China (NNSFC)
OSTI Identifier:
1570676
Report Number(s):
BNL-212200-2019-JAAM
Journal ID: ISSN 2044-4753; CSTAGD
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
Catalysis Science and Technology
Additional Journal Information:
Journal Volume: 9; Journal Issue: 15; Journal ID: ISSN 2044-4753
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Zhou, Min, Zhao, Jiahua, Zhang, Pengfei, Chen, Nanqing, and Yang, Shize. Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly. United States: N. p., 2019. Web. doi:10.1039/C9CY00970A.
Zhou, Min, Zhao, Jiahua, Zhang, Pengfei, Chen, Nanqing, & Yang, Shize. Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly. United States. doi:10.1039/C9CY00970A.
Zhou, Min, Zhao, Jiahua, Zhang, Pengfei, Chen, Nanqing, and Yang, Shize. Mon . "Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly". United States. doi:10.1039/C9CY00970A. https://www.osti.gov/servlets/purl/1570676.
@article{osti_1570676,
title = {Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly},
author = {Zhou, Min and Zhao, Jiahua and Zhang, Pengfei and Chen, Nanqing and Yang, Shize},
abstractNote = {Mesoporous FexOy and Pt@FexOy have proven promising performance in catalysis. Yet, current methods usually use wet chemistry, which poses several drawbacks. Here, we introduce a simple process of mechanochemical assembly between an iron salt and a triblock copolymer in the solid state that can not only directly form abundant mesopores into FexOy, but also enable a high dispersion of Pt species at the nm or sub-nm scale. In this regard, mesoporous FexOy and Pt@FexOy catalysts with high surface areas (up to 149 m2 g-1) and narrow pore size distributions (~5 nm) can be obtained in a solvent-free and rapid (0.5 h) way. The kinetic energy and frictional heating of ball milling are expected to promote the interaction and diffusion between iron precursors and surfactants, while the solvent-free feature confines their assembly to the mesophase of the P123 copolymer. Moreover, these Pt@FexOy catalysts provide good activity in the total oxidation of propylene and CO.},
doi = {10.1039/C9CY00970A},
journal = {Catalysis Science and Technology},
number = 15,
volume = 9,
place = {United States},
year = {2019},
month = {7}
}

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Cited by: 3 works
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    Works referencing / citing this record:

    Nanocasting: A Versatile Strategy for Creating Nanostructured Porous Materials
    journal, July 2006


    Mesoporous Mn2O3 and Mn3O4 with Crystalline Walls
    journal, November 2007


    Soluble Porous Coordination Polymers by Mechanochemistry: From Metal-Containing Films/Membranes to Active Catalysts for Aerobic Oxidation
    journal, November 2014

    • Zhang, Pengfei; Li, Haiying; Veith, Gabriel M.
    • Advanced Materials, Vol. 27, Issue 2
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    Chemical solvent in chemical solvent: A class of hybrid materials for effective capture of CO 2
    journal, September 2017

    • Chen, Feng-Feng; Huang, Kuan; Fan, Jie-Ping
    • AIChE Journal, Vol. 64, Issue 2
    • DOI: 10.1002/aic.15952

    High Reactivity of Metal-Organic Frameworks under Grinding Conditions: Parallels with Organic Molecular Materials
    journal, April 2010

    • Yuan, Wenbing; Friščić, Tomislav; Apperley, David
    • Angewandte Chemie, Vol. 122, Issue 23
    • DOI: 10.1002/ange.200906965

    Crystal-to-Crystal Phase Transition in Self-Assembled Mesoporous Iron Oxide Films
    journal, January 2006

    • Brezesinski, Torsten; Groenewolt, Matthijs; Antonietti, Markus
    • Angewandte Chemie International Edition, Vol. 45, Issue 5, p. 781-784
    • DOI: 10.1002/anie.200502332

    Pharmaceutical Nano-Cocrystals: Sonochemical Synthesis by Solvent Selection and Use of a Surfactant
    journal, September 2010

    • Sander, John R. G.; Bučar, Dejan-Krešimir; Henry, Rodger F.
    • Angewandte Chemie International Edition, Vol. 49, Issue 40
    • DOI: 10.1002/anie.201002588

    Rapid Room-Temperature Synthesis of Zeolitic Imidazolate Frameworks by Using Mechanochemistry
    journal, November 2010

    • Beldon, Patrick J.; Fábián, László; Stein, Robin S.
    • Angewandte Chemie International Edition, Vol. 49, Issue 50
    • DOI: 10.1002/anie.201005547

    Solvent-Free Synthesis of Silicoaluminophosphate Zeolites
    journal, July 2013

    • Jin, Yinying; Sun, Qi; Qi, Guodong
    • Angewandte Chemie International Edition, Vol. 52, Issue 35
    • DOI: 10.1002/anie.201302672

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    • Zhang, Pengfei; Jiang, Xueguang; Wan, Shun
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    • DOI: 10.1002/chem.201501814

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    journal, February 2016

    • Papadas, Ioannis T.; Fountoulaki, Stella; Lykakis, Ioannis N.
    • Chemistry - A European Journal, Vol. 22, Issue 13
    • DOI: 10.1002/chem.201504685

    Ultrathin Coating of Confined Pt Nanocatalysts by Atomic Layer Deposition for Enhanced Catalytic Performance in Hydrogenation Reactions
    journal, May 2016

    • Wang, Meihua; Gao, Zhe; Zhang, Bin
    • Chemistry - A European Journal, Vol. 22, Issue 25
    • DOI: 10.1002/chem.201601892

    Solvent-Free Mechanochemical Synthesis of Nitrogen-Doped Nanoporous Carbon for Electrochemical Energy Storage
    journal, May 2017

    • Schneidermann, Christina; Jäckel, Nicolas; Oswald, Steffen
    • ChemSusChem, Vol. 10, Issue 11
    • DOI: 10.1002/cssc.201700459

    Mesoporous Metallic Cells: Design of Uniformly Sized Hollow Mesoporous Pt-Ru Particles with Tunable Shell Thicknesses
    journal, December 2012


    Evaporation-Induced Coating of Hydrous Ruthenium Oxide on Mesoporous Silica Nanoparticles to Develop High-Performance Supercapacitors
    journal, March 2013


    Some Difficult Challenges for the Synthesis of Nanoporous Materials
    journal, October 2010


    Synthesis of ordered mesoporous iron manganese bimetal oxides for arsenic removal from aqueous solutions
    journal, December 2014


    Mechanochemical synthesis of metal–organic frameworks
    journal, April 2019


    Solid-state CTAB-assisted synthesis of mesoporous Fe3O4 and Au@Fe3O4 by mechanochemistry
    journal, July 2019


    Synthesis of Nanoporous Metals, Oxides, Carbides, and Sulfides: Beyond Nanocasting
    journal, June 2016


    Protocol for the Nanocasting Method: Preparation of Ordered Mesoporous Metal Oxides
    journal, September 2016


    Incorporating Rich Mesoporosity into a Ceria-Based Catalyst via Mechanochemistry
    journal, August 2017


    Facile Synthesis of Highly Porous Metal Oxides by Mechanochemical Nanocasting
    journal, April 2018


    Engineering Ordered and Nonordered Porous Noble Metal Nanostructures: Synthesis, Assembly, and Their Applications in Electrochemistry
    journal, July 2015


    Synthesis of Mesoporous Iron Oxides by an Inverse Micelle Method and Their Application in the Degradation of Orange II under Visible Light at Neutral pH
    journal, April 2015

    • Jiang, Ting; Poyraz, Altug S.; Iyer, Aparna
    • The Journal of Physical Chemistry C, Vol. 119, Issue 19
    • DOI: 10.1021/acs.jpcc.5b02057

    Mesoporous Iron Oxide Synthesized Using Poly(styrene- b -acrylic acid- b -ethylene glycol) Block Copolymer Micelles as Templates for Colorimetric and Electrochemical Detection of Glucose
    journal, December 2017

    • Tanaka, Shunsuke; Kaneti, Yusuf Valentino; Bhattacharjee, Ripon
    • ACS Applied Materials & Interfaces, Vol. 10, Issue 1
    • DOI: 10.1021/acsami.7b13835

    Synthesis of Porous Polymeric Catalysts for the Conversion of Carbon Dioxide
    journal, August 2018


    Synthesis of Hard Magnetic Ordered Mesoporous Co 3 O 4 /CoFe 2 O 4 Nanocomposites
    journal, June 2012

    • Tüysüz, Harun; Salabaş, Elena Lorena; Bill, Eckhard
    • Chemistry of Materials, Vol. 24, Issue 13
    • DOI: 10.1021/cm3005166

    Design of Ordered Mesoporous Composite Materials and Their Electrocatalytic Activities for Water Oxidation
    journal, December 2013

    • Grewe, Tobias; Deng, Xiaohui; Weidenthaler, Claudia
    • Chemistry of Materials, Vol. 25, Issue 24
    • DOI: 10.1021/cm403153u

    Green Routes for Synthesis of Zeolites
    journal, November 2013

    • Meng, Xiangju; Xiao, Feng-Shou
    • Chemical Reviews, Vol. 114, Issue 2
    • DOI: 10.1021/cr4001513

    Synthesis of Ordered Mesoporous Fe 3 O 4 and γ-Fe 2 O 3 with Crystalline Walls Using Post-Template Reduction/Oxidation
    journal, October 2006

    • Jiao, Feng; Jumas, Jean-Claude; Womes, Manfred
    • Journal of the American Chemical Society, Vol. 128, Issue 39
    • DOI: 10.1021/ja063662i

    Container Effect in Nanocasting Synthesis of Mesoporous Metal Oxides
    journal, September 2011

    • Sun, Xiaohong; Shi, Yifeng; Zhang, Peng
    • Journal of the American Chemical Society, Vol. 133, Issue 37
    • DOI: 10.1021/ja2060512

    Solvent-Free Synthesis of Zeolites from Solid Raw Materials
    journal, September 2012

    • Ren, Limin; Wu, Qinming; Yang, Chengguang
    • Journal of the American Chemical Society, Vol. 134, Issue 37
    • DOI: 10.1021/ja3044954

    Mechanochemical Synthesis of Chemically Stable Isoreticular Covalent Organic Frameworks
    journal, March 2013

    • Biswal, Bishnu P.; Chandra, Suman; Kandambeth, Sharath
    • Journal of the American Chemical Society, Vol. 135, Issue 14
    • DOI: 10.1021/ja4017842

    Synthetic Control of FePtM Nanorods (M = Cu, Ni) To Enhance the Oxygen Reduction Reaction
    journal, May 2013

    • Zhu, Huiyuan; Zhang, Sen; Guo, Shaojun
    • Journal of the American Chemical Society, Vol. 135, Issue 19
    • DOI: 10.1021/ja403041g

    Chemically Stable Multilayered Covalent Organic Nanosheets from Covalent Organic Frameworks via Mechanical Delamination
    journal, November 2013

    • Chandra, Suman; Kandambeth, Sharath; Biswal, Bishnu P.
    • Journal of the American Chemical Society, Vol. 135, Issue 47
    • DOI: 10.1021/ja408121p

    Solvent-Free Synthesis of Zeolites from Anhydrous Starting Raw Solids
    journal, January 2015

    • Wu, Qinming; Liu, Xiaolong; Zhu, Longfeng
    • Journal of the American Chemical Society, Vol. 137, Issue 3
    • DOI: 10.1021/ja5124013

    Evolution of Standing Mesochannels on Porous Anodic Alumina Substrates with Designed Conical Holes
    journal, August 2008

    • Yamauchi, Yusuke; Nagaura, Tomota; Ishikawa, Ayako
    • Journal of the American Chemical Society, Vol. 130, Issue 31
    • DOI: 10.1021/ja7107036

    Synthesis of Ordered Mesoporous NiO with Crystalline Walls and a Bimodal Pore Size Distribution
    journal, April 2008

    • Jiao, Feng; Hill, Adrian H.; Harrison, Andrew
    • Journal of the American Chemical Society, Vol. 130, Issue 15
    • DOI: 10.1021/ja710849r

    Pseudomorphic Transformation of Highly Ordered Mesoporous Co 3 O 4 to CoO via Reduction with Glycerol
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