Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly

Zhou, Min; Zhao, Jiahua; Zhang, Pengfei; Chen, Nanqing; Yang, Shize

doi:10.1039/C9CY00970A

Title: Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly

Journal Article · 01 July 2019 · Catalysis Science and Technology

DOI: https://doi.org/10.1039/C9CY00970A · OSTI ID:1570676

Zhou, Min ^[1]; Zhao, Jiahua ^[2];

^[2]; Chen, Nanqing ^[3];

^[4]

East China Normal Univ., Shanghai (China)
Shanghai Jiao Tong Univ. (China)
Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Mesoporous Fe_xO_y and Pt@Fe_xO_y have proven promising performance in catalysis. Yet, current methods usually use wet chemistry, which poses several drawbacks. Here, we introduce a simple process of mechanochemical assembly between an iron salt and a triblock copolymer in the solid state that can not only directly form abundant mesopores into Fe_xO_y, but also enable a high dispersion of Pt species at the nm or sub-nm scale. In this regard, mesoporous FexOy and Pt@Fe_xO_y catalysts with high surface areas (up to 149 m² g^-1) and narrow pore size distributions (~5 nm) can be obtained in a solvent-free and rapid (0.5 h) way. The kinetic energy and frictional heating of ball milling are expected to promote the interaction and diffusion between iron precursors and surfactants, while the solvent-free feature confines their assembly to the mesophase of the P123 copolymer. Moreover, these Pt@Fe_xO_y catalysts provide good activity in the total oxidation of propylene and CO.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; National Natural Science Foundation of China (NNSFC)

Grant/Contract Number:: SC0012704

OSTI ID:: 1570676

Report Number(s):: BNL--212200-2019-JAAM

Journal Information:: Catalysis Science and Technology, Journal Name: Catalysis Science and Technology Journal Issue: 15 Vol. 9; ISSN CSTAGD; ISSN 2044-4753

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (65)

Nanocasting: A Versatile Strategy for Creating Nanostructured Porous Materials Lu, A. -H.; Schüth, F. Advanced Materials, Vol. 18, Issue 14 https://doi.org/10.1002/adma.200600148	journal	July 2006
Mesoporous Mn2O3 and Mn3O4 with Crystalline Walls Jiao, F.; Harrison, A.; Hill, A. H. Advanced Materials, Vol. 19, Issue 22 https://doi.org/10.1002/adma.200700336	journal	November 2007
Soluble Porous Coordination Polymers by Mechanochemistry: From Metal-Containing Films/Membranes to Active Catalysts for Aerobic Oxidation Zhang, Pengfei; Li, Haiying; Veith, Gabriel M. Advanced Materials, Vol. 27, Issue 2 https://doi.org/10.1002/adma.201403299	journal	November 2014
Solvent-Free Self-Assembly to the Synthesis of Nitrogen-Doped Ordered Mesoporous Polymers for Highly Selective Capture and Conversion of CO ₂ Liu, Fujian; Huang, Kuan; Wu, Qin Advanced Materials, Vol. 29, Issue 27 https://doi.org/10.1002/adma.201700445	journal	May 2017
Chemical solvent in chemical solvent: A class of hybrid materials for effective capture of CO ₂ Chen, Feng-Feng; Huang, Kuan; Fan, Jie-Ping AIChE Journal, Vol. 64, Issue 2 https://doi.org/10.1002/aic.15952	journal	September 2017
Crystal-to-Crystal Phase Transition in Self-Assembled Mesoporous Iron Oxide Films Brezesinski, Torsten; Groenewolt, Matthijs; Antonietti, Markus Angewandte Chemie, Vol. 118, Issue 5 https://doi.org/10.1002/ange.200502332	journal	January 2006
High Reactivity of Metal-Organic Frameworks under Grinding Conditions: Parallels with Organic Molecular Materials Yuan, Wenbing; Friščić, Tomislav; Apperley, David Angewandte Chemie, Vol. 122, Issue 23 https://doi.org/10.1002/ange.200906965	journal	April 2010
Pharmaceutical Nano-Cocrystals: Sonochemical Synthesis by Solvent Selection and Use of a Surfactant Sander, John R. G.; Bučar, Dejan-Krešimir; Henry, Rodger F. Angewandte Chemie, Vol. 122, Issue 40 https://doi.org/10.1002/ange.201002588	journal	September 2010
Rapid Room-Temperature Synthesis of Zeolitic Imidazolate Frameworks by Using Mechanochemistry Beldon, Patrick J.; Fábián, László; Stein, Robin S. Angewandte Chemie, Vol. 122, Issue 50 https://doi.org/10.1002/ange.201005547	journal	November 2010
Crystal-to-Crystal Phase Transition in Self-Assembled Mesoporous Iron Oxide Films Brezesinski, Torsten; Groenewolt, Matthijs; Antonietti, Markus Angewandte Chemie International Edition, Vol. 45, Issue 5, p. 781-784 https://doi.org/10.1002/anie.200502332	journal	January 2006
High Reactivity of Metal-Organic Frameworks under Grinding Conditions: Parallels with Organic Molecular Materials Yuan, Wenbing; Friščić, Tomislav; Apperley, David Angewandte Chemie International Edition, Vol. 49, Issue 23 https://doi.org/10.1002/anie.200906965	journal	April 2010
Pharmaceutical Nano-Cocrystals: Sonochemical Synthesis by Solvent Selection and Use of a Surfactant Sander, John R. G.; Bučar, Dejan-Krešimir; Henry, Rodger F. Angewandte Chemie International Edition, Vol. 49, Issue 40 https://doi.org/10.1002/anie.201002588	journal	September 2010
Rapid Room-Temperature Synthesis of Zeolitic Imidazolate Frameworks by Using Mechanochemistry Beldon, Patrick J.; Fábián, László; Stein, Robin S. Angewandte Chemie International Edition, Vol. 49, Issue 50 https://doi.org/10.1002/anie.201005547	journal	November 2010
Solvent-Free Synthesis of Silicoaluminophosphate Zeolites Jin, Yinying; Sun, Qi; Qi, Guodong Angewandte Chemie International Edition, Vol. 52, Issue 35 https://doi.org/10.1002/anie.201302672	journal	July 2013
Charged Porous Polymers using a Solid CO Cross-Coupling Reaction Zhang, Pengfei; Jiang, Xueguang; Wan, Shun Chemistry - A European Journal, Vol. 21, Issue 37 https://doi.org/10.1002/chem.201501814	journal	July 2015
Controllable Synthesis of Mesoporous Iron Oxide Nanoparticle Assemblies for Chemoselective Catalytic Reduction of Nitroarenes Papadas, Ioannis T.; Fountoulaki, Stella; Lykakis, Ioannis N. Chemistry - A European Journal, Vol. 22, Issue 13 https://doi.org/10.1002/chem.201504685	journal	February 2016
Ultrathin Coating of Confined Pt Nanocatalysts by Atomic Layer Deposition for Enhanced Catalytic Performance in Hydrogenation Reactions Wang, Meihua; Gao, Zhe; Zhang, Bin Chemistry - A European Journal, Vol. 22, Issue 25 https://doi.org/10.1002/chem.201601039	journal	May 2016
Ultrathin Coating of Confined Pt Nanocatalysts by Atomic Layer Deposition for Enhanced Catalytic Performance in Hydrogenation Reactions Wang, Meihua; Gao, Zhe; Zhang, Bin Chemistry - A European Journal, Vol. 22, Issue 25 https://doi.org/10.1002/chem.201601892	journal	May 2016
Solvent-Free Mechanochemical Synthesis of Nitrogen-Doped Nanoporous Carbon for Electrochemical Energy Storage Schneidermann, Christina; Jäckel, Nicolas; Oswald, Steffen ChemSusChem, Vol. 10, Issue 11 https://doi.org/10.1002/cssc.201700459	journal	May 2017
Mesoporous Metallic Cells: Design of Uniformly Sized Hollow Mesoporous Pt-Ru Particles with Tunable Shell Thicknesses Ataee-Esfahani, Hamed; Liu, Jian; Hu, Ming Small, Vol. 9, Issue 7 https://doi.org/10.1002/smll.201202539	journal	December 2012
Evaporation-Induced Coating of Hydrous Ruthenium Oxide on Mesoporous Silica Nanoparticles to Develop High-Performance Supercapacitors Huang, Hou-Sheng; Chang, Kuo-Hsin; Suzuki, Norihiro Small, Vol. 9, Issue 15 https://doi.org/10.1002/smll.201202786	journal	March 2013
Some Difficult Challenges for the Synthesis of Nanoporous Materials Morris, Russell E. Topics in Catalysis, Vol. 53, Issue 19-20 https://doi.org/10.1007/s11244-010-9586-5	journal	October 2010
Solid-state CTAB-assisted synthesis of mesoporous Fe3O4 and Au@Fe3O4 by mechanochemistry Zhao, Jiahua; Shu, Yuan; Zhang, Pengfei Chinese Journal of Catalysis, Vol. 40, Issue 7 https://doi.org/10.1016/S1872-2067(19)63288-2	journal	July 2019
Synthesis of ordered mesoporous iron manganese bimetal oxides for arsenic removal from aqueous solutions Wen, Zhipan; Zhang, Yalei; Dai, Chaomeng Microporous and Mesoporous Materials, Vol. 200 https://doi.org/10.1016/j.micromeso.2014.08.049	journal	December 2014
Mechanochemical synthesis of metal–organic frameworks Chen, Dong; Zhao, Jiahua; Zhang, Pengfei Polyhedron, Vol. 162 https://doi.org/10.1016/j.poly.2019.01.024	journal	April 2019
Synthesis of Nanoporous Metals, Oxides, Carbides, and Sulfides: Beyond Nanocasting Luc, Wesley; Jiao, Feng Accounts of Chemical Research, Vol. 49, Issue 7 https://doi.org/10.1021/acs.accounts.6b00109	journal	June 2016
Protocol for the Nanocasting Method: Preparation of Ordered Mesoporous Metal Oxides Deng, Xiaohui; Chen, Kun; Tüysüz, Harun Chemistry of Materials, Vol. 29, Issue 1 https://doi.org/10.1021/acs.chemmater.6b02645	journal	September 2016
Incorporating Rich Mesoporosity into a Ceria-Based Catalyst via Mechanochemistry Zhan, Wangcheng; Yang, Shize; Zhang, Pengfei Chemistry of Materials, Vol. 29, Issue 17 https://doi.org/10.1021/acs.chemmater.7b02206	journal	August 2017
Facile Synthesis of Highly Porous Metal Oxides by Mechanochemical Nanocasting Xiao, Weiming; Yang, Shize; Zhang, Pengfei Chemistry of Materials, Vol. 30, Issue 9 https://doi.org/10.1021/acs.chemmater.7b05405	journal	April 2018
Engineering Ordered and Nonordered Porous Noble Metal Nanostructures: Synthesis, Assembly, and Their Applications in Electrochemistry Zhu, Chengzhou; Du, Dan; Eychmüller, Alexander Chemical Reviews, Vol. 115, Issue 16 https://doi.org/10.1021/acs.chemrev.5b00255	journal	July 2015
Synthesis of Mesoporous Iron Oxides by an Inverse Micelle Method and Their Application in the Degradation of Orange II under Visible Light at Neutral pH Jiang, Ting; Poyraz, Altug S.; Iyer, Aparna The Journal of Physical Chemistry C, Vol. 119, Issue 19 https://doi.org/10.1021/acs.jpcc.5b02057	journal	April 2015
Mesoporous Iron Oxide Synthesized Using Poly(styrene- b -acrylic acid- b -ethylene glycol) Block Copolymer Micelles as Templates for Colorimetric and Electrochemical Detection of Glucose Tanaka, Shunsuke; Kaneti, Yusuf Valentino; Bhattacharjee, Ripon ACS Applied Materials & Interfaces, Vol. 10, Issue 1 https://doi.org/10.1021/acsami.7b13835	journal	December 2017
Synthesis of Porous Polymeric Catalysts for the Conversion of Carbon Dioxide Huang, Kuan; Zhang, Jia-Yin; Liu, Fujian ACS Catalysis, Vol. 8, Issue 10 https://doi.org/10.1021/acscatal.8b02151	journal	August 2018
Synthesis of Hard Magnetic Ordered Mesoporous Co ₃ O ₄ /CoFe ₂ O ₄ Nanocomposites Tüysüz, Harun; Salabaş, Elena Lorena; Bill, Eckhard Chemistry of Materials, Vol. 24, Issue 13 https://doi.org/10.1021/cm3005166	journal	June 2012
Design of Ordered Mesoporous Composite Materials and Their Electrocatalytic Activities for Water Oxidation Grewe, Tobias; Deng, Xiaohui; Weidenthaler, Claudia Chemistry of Materials, Vol. 25, Issue 24 https://doi.org/10.1021/cm403153u	journal	December 2013
Green Routes for Synthesis of Zeolites Meng, Xiangju; Xiao, Feng-Shou Chemical Reviews, Vol. 114, Issue 2 https://doi.org/10.1021/cr4001513	journal	November 2013
Synthesis of Ordered Mesoporous Fe ₃ O ₄ and γ-Fe ₂ O ₃ with Crystalline Walls Using Post-Template Reduction/Oxidation Jiao, Feng; Jumas, Jean-Claude; Womes, Manfred Journal of the American Chemical Society, Vol. 128, Issue 39 https://doi.org/10.1021/ja063662i	journal	October 2006
Container Effect in Nanocasting Synthesis of Mesoporous Metal Oxides Sun, Xiaohong; Shi, Yifeng; Zhang, Peng Journal of the American Chemical Society, Vol. 133, Issue 37 https://doi.org/10.1021/ja2060512	journal	September 2011
Solvent-Free Synthesis of Zeolites from Solid Raw Materials Ren, Limin; Wu, Qinming; Yang, Chengguang Journal of the American Chemical Society, Vol. 134, Issue 37 https://doi.org/10.1021/ja3044954	journal	September 2012
Mechanochemical Synthesis of Chemically Stable Isoreticular Covalent Organic Frameworks Biswal, Bishnu P.; Chandra, Suman; Kandambeth, Sharath Journal of the American Chemical Society, Vol. 135, Issue 14 https://doi.org/10.1021/ja4017842	journal	March 2013
Synthetic Control of FePtM Nanorods (M = Cu, Ni) To Enhance the Oxygen Reduction Reaction Zhu, Huiyuan; Zhang, Sen; Guo, Shaojun Journal of the American Chemical Society, Vol. 135, Issue 19 https://doi.org/10.1021/ja403041g	journal	May 2013
Chemically Stable Multilayered Covalent Organic Nanosheets from Covalent Organic Frameworks via Mechanical Delamination Chandra, Suman; Kandambeth, Sharath; Biswal, Bishnu P. Journal of the American Chemical Society, Vol. 135, Issue 47 https://doi.org/10.1021/ja408121p	journal	November 2013
Solvent-Free Synthesis of Zeolites from Anhydrous Starting Raw Solids Wu, Qinming; Liu, Xiaolong; Zhu, Longfeng Journal of the American Chemical Society, Vol. 137, Issue 3 https://doi.org/10.1021/ja5124013	journal	January 2015
Evolution of Standing Mesochannels on Porous Anodic Alumina Substrates with Designed Conical Holes Yamauchi, Yusuke; Nagaura, Tomota; Ishikawa, Ayako Journal of the American Chemical Society, Vol. 130, Issue 31 https://doi.org/10.1021/ja7107036	journal	August 2008
Synthesis of Ordered Mesoporous NiO with Crystalline Walls and a Bimodal Pore Size Distribution Jiao, Feng; Hill, Adrian H.; Harrison, Andrew Journal of the American Chemical Society, Vol. 130, Issue 15 https://doi.org/10.1021/ja710849r	journal	April 2008
Pseudomorphic Transformation of Highly Ordered Mesoporous Co ₃ O ₄ to CoO via Reduction with Glycerol Tüysüz, Harun; Liu, Yong; Weidenthaler, Claudia Journal of the American Chemical Society, Vol. 130, Issue 43 https://doi.org/10.1021/ja806202v	journal	October 2008
Synthesis of Mesoporous Metal Oxide by the Thermal Decomposition of Oxalate Precursor Guo, Limin; Arafune, Hiroyuki; Teramae, Norio Langmuir, Vol. 29, Issue 13 https://doi.org/10.1021/la400323f	journal	February 2013
Polymeric Micelle Assembly for Preparation of Large-Sized Mesoporous Metal Oxides with Various Compositions Bastakoti, Bishnu Prasad; Ishihara, Shinsuke; Leo, Sin-Yen Langmuir, Vol. 30, Issue 2 https://doi.org/10.1021/la403901x	journal	January 2014
Self-Assembled Fe ₃ O ₄ Nanoparticle Clusters as High-Performance Anodes for Lithium Ion Batteries via Geometric Confinement Lee, Soo Hong; Yu, Seung-Ho; Lee, Ji Eun Nano Letters, Vol. 13, Issue 9 https://doi.org/10.1021/nl401952h	journal	August 2013
Real-time and in situ monitoring of mechanochemical milling reactions Friščić, Tomislav; Halasz, Ivan; Beldon, Patrick J. Nature Chemistry, Vol. 5, Issue 1 https://doi.org/10.1038/nchem.1505	journal	December 2012
Solid-state synthesis of ordered mesoporous carbon catalysts via a mechanochemical assembly through coordination cross-linking Zhang, Pengfei; Wang, Li; Yang, Shize Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15020	journal	April 2017
Hierarchical porous carbons with layer-by-layer motif architectures from confined soft-template self-assembly in layered materials Wang, Jie; Tang, Jing; Ding, Bing Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15717	journal	June 2017
In situ X-ray diffraction monitoring of a mechanochemical reaction reveals a unique topology metal-organic framework Katsenis, Athanassios D.; Puškarić, Andreas; Štrukil, Vjekoslav Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7662	journal	March 2015
Mechanochemistry: opportunities for new and cleaner synthesis James, Stuart L.; Adams, Christopher J.; Bolm, Carsten Chem. Soc. Rev., Vol. 41, Issue 1 https://doi.org/10.1039/C1CS15171A	journal	January 2012
Mechanosynthesis of imine, β-ketoenamine, and hydrogen-bonded imine-linked covalent organic frameworks using liquid-assisted grinding Das, Gobinda; Balaji Shinde, Digambar; Kandambeth, Sharath Chem. Commun., Vol. 50, Issue 84 https://doi.org/10.1039/C4CC03389B	journal	January 2014
Mechanochemical synthesis of advanced nanomaterials for catalytic applications Xu, Chunping; De, Sudipta; Balu, Alina M. Chemical Communications, Vol. 51, Issue 31 https://doi.org/10.1039/C4CC09876E	journal	January 2015
Advancing polymers of intrinsic microporosity by mechanochemistry Zhang, Pengfei; Jiang, Xueguang; Wan, Shun Journal of Materials Chemistry A, Vol. 3, Issue 13 https://doi.org/10.1039/C4TA07196D	journal	January 2015
Mechanochemical Suzuki polycondensation – from linear to hyperbranched polyphenylenes Grätz, S.; Wolfrum, B.; Borchardt, L. Green Chemistry, Vol. 19, Issue 13 https://doi.org/10.1039/C7GC00693D	journal	January 2017
Gold nanoparticles supported on mesoporous iron oxide for enhanced CO oxidation reaction Tanaka, Shunsuke; Lin, Jianjian; Kaneti, Yusuf Valentino Nanoscale, Vol. 10, Issue 10 https://doi.org/10.1039/C7NR08895G	journal	January 2018
Cubic Ia3d large mesoporous silica: synthesis and replication to platinum nanowires, carbon nanorods and carbon nanotubesElectronic supplementary information (ESI) available: TEM images of mesoporous cubic silica and Pt networks, XRD patterns during formation of the cubic phase. See http://www.rsc.org/suppdata/cc/b3/b306504a/ Kleitz, Freddy; Hei Choi, Shin; Ryoo, Ryong Chemical Communications, Issue 17 https://doi.org/10.1039/b306504a	journal	January 2003
Ordered mesoporous non-oxide materials Shi, Yifeng; Wan, Ying; Zhao, Dongyuan Chemical Society Reviews, Vol. 40, Issue 7 https://doi.org/10.1039/c0cs00186d	journal	January 2011
Application of heterogeneous catalysts prepared by mechanochemical synthesis Ralphs, Kathryn; Hardacre, Christopher; James, Stuart L. Chemical Society Reviews, Vol. 42, Issue 18 https://doi.org/10.1039/c3cs60066a	journal	January 2013
Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores Zhao, Dongyuan; Feng, Jianglin; Huo, Qisheng Science, Vol. 279, Issue 5350, p. 548-552 https://doi.org/10.1126/science.279.5350.548	journal	January 1998
Hierarchically Ordered Oxides Yang, P.; Deng, T.; Zhao, D. Science, Vol. 282, Issue 5397 https://doi.org/10.1126/science.282.5397.2244	journal	December 1998
Solvent-Free Mechanochemical Synthesis of Nitrogen-Doped Nanoporous Carbon for Electrochemical Energy Storage Schneidermann, Christina; Jäckel, Nicolas; Oswald, Steffen Universität des Saarlandes https://doi.org/10.22028/d291-29123	collection	January 2017

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