Low-Temperature Thermopower in CoSbS
Abstract
Here, we report on giant thermopower of S = 2.5 mV/K in CoSbS single crystals: a material that shows strong high-temperature thermoelectric performance when doped with Ni or Se. Changes of low-temperature thermopower induced by a magnetic field point to the mechanism of electronic diffusion of carriers in the heavy valence band. Intrinsic magnetic susceptibility is consistent with the Kondo-insulatorlike accumulation of electronic states around the gap edges. This suggests that giant thermopower stems from temperature-dependent renormalization of the noninteracting bands and buildup of the electronic correlations on cooling.
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.; Stony Brook Univ., NY (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
- Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.
- Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.; Rutgers Univ., Piscataway, NJ (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1570672
- Alternate Identifier(s):
- OSTI ID: 1567981
- Report Number(s):
- BNL-212195-2019-JAAM
Journal ID: ISSN 0031-9007; PRLTAO; TRN: US2100167
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review Letters
- Additional Journal Information:
- Journal Volume: 123; Journal Issue: 7; Journal ID: ISSN 0031-9007
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Du, Qianheng, Abeykoon, Milinda, Liu, Yu, Kotliar, G., and Petrovic, C. Low-Temperature Thermopower in CoSbS. United States: N. p., 2019.
Web. doi:10.1103/PhysRevLett.123.076602.
Du, Qianheng, Abeykoon, Milinda, Liu, Yu, Kotliar, G., & Petrovic, C. Low-Temperature Thermopower in CoSbS. United States. https://doi.org/10.1103/PhysRevLett.123.076602
Du, Qianheng, Abeykoon, Milinda, Liu, Yu, Kotliar, G., and Petrovic, C. Fri .
"Low-Temperature Thermopower in CoSbS". United States. https://doi.org/10.1103/PhysRevLett.123.076602. https://www.osti.gov/servlets/purl/1570672.
@article{osti_1570672,
title = {Low-Temperature Thermopower in CoSbS},
author = {Du, Qianheng and Abeykoon, Milinda and Liu, Yu and Kotliar, G. and Petrovic, C.},
abstractNote = {Here, we report on giant thermopower of S = 2.5 mV/K in CoSbS single crystals: a material that shows strong high-temperature thermoelectric performance when doped with Ni or Se. Changes of low-temperature thermopower induced by a magnetic field point to the mechanism of electronic diffusion of carriers in the heavy valence band. Intrinsic magnetic susceptibility is consistent with the Kondo-insulatorlike accumulation of electronic states around the gap edges. This suggests that giant thermopower stems from temperature-dependent renormalization of the noninteracting bands and buildup of the electronic correlations on cooling.},
doi = {10.1103/PhysRevLett.123.076602},
journal = {Physical Review Letters},
number = 7,
volume = 123,
place = {United States},
year = {2019},
month = {8}
}
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