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Title: Correlating structure and transport behavior in Li + and O 2 containing pyrrolidinium ionic liquids

Abstract

Using experiments and molecular simulations, we evaluate pyrrolidinium-based ionic liquid Li electrolytes and find that Li + and O 2 transport can be enhanced by varying the pyrrolidinium structure and Li concentration.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [2];  [2];  [2];  [2]
  1. BMW Technology Office, Mountain View, CA (United States); Mountain View; USA; Sandia National Lab. (SNL-CA), Livermore, CA (United States)
  2. Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1570269
Alternate Identifier(s):
OSTI ID: 1544907
Report Number(s):
SAND-2019-10362J
Journal ID: ISSN 1463-9076; PPCPFQ; 679030
Grant/Contract Number:  
AC04-94AL85000; NA0003525
Resource Type:
Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print); Journal Volume: 21; Journal Issue: 31; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Gittleson, Forrest S., Ward, Donald K., Jones, Reese E., Zarkesh, Ryan A., Sheth, Tanvi, and Foster, Michael E. Correlating structure and transport behavior in Li+ and O2 containing pyrrolidinium ionic liquids. United States: N. p., 2019. Web. doi:10.1039/C9CP02355K.
Gittleson, Forrest S., Ward, Donald K., Jones, Reese E., Zarkesh, Ryan A., Sheth, Tanvi, & Foster, Michael E. Correlating structure and transport behavior in Li+ and O2 containing pyrrolidinium ionic liquids. United States. doi:10.1039/C9CP02355K.
Gittleson, Forrest S., Ward, Donald K., Jones, Reese E., Zarkesh, Ryan A., Sheth, Tanvi, and Foster, Michael E. Mon . "Correlating structure and transport behavior in Li+ and O2 containing pyrrolidinium ionic liquids". United States. doi:10.1039/C9CP02355K.
@article{osti_1570269,
title = {Correlating structure and transport behavior in Li+ and O2 containing pyrrolidinium ionic liquids},
author = {Gittleson, Forrest S. and Ward, Donald K. and Jones, Reese E. and Zarkesh, Ryan A. and Sheth, Tanvi and Foster, Michael E.},
abstractNote = {Using experiments and molecular simulations, we evaluate pyrrolidinium-based ionic liquid Li electrolytes and find that Li+ and O2 transport can be enhanced by varying the pyrrolidinium structure and Li concentration.},
doi = {10.1039/C9CP02355K},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
number = 31,
volume = 21,
place = {United States},
year = {2019},
month = {7}
}

Journal Article:
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