Neutron scattering study of the quasi-one-dimensional antiferromagnet Ba2CoSi2O7

doi:10.1103/PhysRevB.100.144410

This content will become publicly available on October 7, 2020

Title: Neutron scattering study of the quasi-one-dimensional antiferromagnet ${Ba}_{2} {CoSi}_{2} O_{7}$

Abstract

Magnetization and neutron scattering measurements have been carried out on an antiferromagnet Ba ₂CoSi ₂O ₇. The observed magnetic excitation is almost dispersionless, and the neutron intensity is only modulated along the [101] direction. The dispersionless magnetic excitation suggest that the Ba ₂CoSi ₂O ₇ system is a quasi-one-dimensional antiferromagnet. Classical spin-wave theory for a one-dimensional antiferromagnet can explain the dispersionless spin excitation. Additionally, the magnetic structure determined by the measurement of the neutron powder diffraction is consistent with no observation of the multiferroic property in this system.

Authors:

Soda, Minoru ^[1];

^[2]; Avdeev, Maxim ^[3]; Yoshizawa, Hideki ^[4]; Masuda, Takatsugu ^[5]; Furukawa, H. ^[6]

RIKEN Center for Emergent Matter Science (CEMS), Wako, Saitama (Japan); The Univ. of Tokyo, Tokai, Ibaraki (Japan). Neutron Science Lab., Inst. for Solid State Physics
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Science Division
Australian Nuclear Science and Technology Organisation (ANSTO), Menai, NSW (Australia). Bragg Inst.
RIKEN Center for Emergent Matter Science (CEMS), Wako, Saitama (Japan)
The Univ. of Tokyo, Tokai, Ibaraki (Japan). Neutron Science Lab., Inst. for Solid State Physics
RIKEN Center for Emergent Matter Science (CEMS), Wako, Saitama (Japan); Ochanomizu Univ., Tokyo (Japan). Dept. of Physics, Advanced Sciences, (GSHS)

Publication Date:: 2019-10-07

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1570127

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 100; Journal Issue: 14; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; magnetic interactions

Citation Formats


                    Soda, Minoru, Hong, Tao, Avdeev, Maxim, Yoshizawa, Hideki, Masuda, Takatsugu, and Furukawa, H. Neutron scattering study of the quasi-one-dimensional antiferromagnet Ba2CoSi2O7.  United States: N. p., 2019. 
        Web.  doi:10.1103/PhysRevB.100.144410.

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                    Soda, Minoru, Hong, Tao, Avdeev, Maxim, Yoshizawa, Hideki, Masuda, Takatsugu, & Furukawa, H. Neutron scattering study of the quasi-one-dimensional antiferromagnet Ba2CoSi2O7.  United States.  doi:10.1103/PhysRevB.100.144410.

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                    Soda, Minoru, Hong, Tao, Avdeev, Maxim, Yoshizawa, Hideki, Masuda, Takatsugu, and Furukawa, H. Mon .  
        "Neutron scattering study of the quasi-one-dimensional antiferromagnet Ba2CoSi2O7".  United States.  doi:10.1103/PhysRevB.100.144410.

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@article{osti_1570127,

  title        = {Neutron scattering study of the quasi-one-dimensional antiferromagnet Ba2CoSi2O7},

  author       = {Soda, Minoru and Hong, Tao and Avdeev, Maxim and Yoshizawa, Hideki and Masuda, Takatsugu and Furukawa, H.},

  abstractNote = {Magnetization and neutron scattering measurements have been carried out on an antiferromagnet Ba2CoSi2O7. The observed magnetic excitation is almost dispersionless, and the neutron intensity is only modulated along the [101] direction. The dispersionless magnetic excitation suggest that the Ba2CoSi2O7 system is a quasi-one-dimensional antiferromagnet. Classical spin-wave theory for a one-dimensional antiferromagnet can explain the dispersionless spin excitation. Additionally, the magnetic structure determined by the measurement of the neutron powder diffraction is consistent with no observation of the multiferroic property in this system.},

  doi          = {10.1103/PhysRevB.100.144410},

  journal      = {Physical Review B},

  number       = 14,

  volume       = 100,

  place        = {United States},

  year         = {2019},

  month        = {10}

}

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DOI: 10.1103/PhysRevB.100.144410

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Works referenced in this record:

Continuous control of local magnetic moment by applied electric field in multiferroics ${Ba}_{2} {CoGe}_{2} O_{7}$
journal, September 2016

Soda, Minoru; Hayashida, Shohei; Roessli, Bertrand
Physical Review B, Vol. 94, Issue 9
DOI: 10.1103/PhysRevB.94.094418

Dynamical Correlation Functions of One-Dimensional Anisotropic Heisenberg Model with Spin 1/2. I: Ising-Like Antiferromagnets
journal, March 1980

Ishimura, N.; Shiba, H.
Progress of Theoretical Physics, Vol. 63, Issue 3
DOI: 10.1143/PTP.63.743

Evolution of two-dimensional antiferromagnetism with temperature and magnetic field in multiferroic ${Ba}_{2} {CoGe}_{2} O_{7}$
journal, February 2014

Hutanu, V.; Sazonov, A. P.; Meven, M.
Physical Review B, Vol. 89, Issue 6
DOI: 10.1103/PhysRevB.89.064403

Syntheses, Structural Analyses, and Unusual Magnetic Properties of Ba ₂ CoSi ₂ O ₇ and BaCo ₂ Si ₂ O ₇
journal, January 1996

Adams, Richard D.; Payen, Christophe; Datta, Timir
Inorganic Chemistry, Vol. 35, Issue 12
DOI: 10.1021/ic960167m

Magnetic Structure and Dielectric State in the Multiferroic Ca ₂ CoSi ₂ O ₇
journal, June 2017

Soda, Minoru; Hayashida, Shohei; Yoshida, Toshiya
Journal of the Physical Society of Japan, Vol. 86, Issue 6
DOI: 10.7566/JPSJ.86.064703

Dynamical correlation functions in a one-dimensional Ising-like antiferromagnetic CsCo ${Cl}_{3}$ : A neutron scattering study
journal, March 1981

Yoshizawa, H.; Hirakawa, K.; Satija, S. K.
Physical Review B, Vol. 23, Issue 5
DOI: 10.1103/PhysRevB.23.2298

Multiferroicity in the square-lattice antiferromagnet of Ba2CoGe2O7
journal, May 2008

Yi, H. T.; Choi, Y. J.; Lee, S.
Applied Physics Letters, Vol. 92, Issue 21
DOI: 10.1063/1.2937110

Polarization analysis of magnetic excitation in multiferroic ${Ba}_{2} {CoGe}_{2} O_{7}$
journal, June 2018

Soda, Minoru; Chang, Lieh-Jeng; Matsumoto, Masashige
Physical Review B, Vol. 97, Issue 21
DOI: 10.1103/PhysRevB.97.214437

Ferroelectricity Induced by Proper-Screw Type Magnetic Order
journal, July 2007

Arima, Taka-hisa
Journal of the Physical Society of Japan, Vol. 76, Issue 7
DOI: 10.1143/JPSJ.76.073702

Ferroelectricity Induced by Spin-Dependent Metal-Ligand Hybridization in ${Ba}_{2} {CoGe}_{2} O_{7}$
journal, September 2010

Murakawa, H.; Onose, Y.; Miyahara, S.
Physical Review Letters, Vol. 105, Issue 13
DOI: 10.1103/PhysRevLett.105.137202

Structures of the Stuffed Tridymite Derivatives, BaMSiO4 (M = Co, Zn, Mg)
journal, January 1993

Liu, B.; Barbier, J.
Journal of Solid State Chemistry, Vol. 102, Issue 1
DOI: 10.1006/jssc.1993.1013

Microscopic theory of spin-polarization coupling in multiferroic transition metal oxides
journal, October 2007

Jia, Chenglong; Onoda, Shigeki; Nagaosa, Naoto
Physical Review B, Vol. 76, Issue 14
DOI: 10.1103/PhysRevB.76.144424

Neutron Scattering Study of Spin Dynamics in CsCo ${Cl}_{3}$
journal, June 1980

Satija, S. K.; Shirane, G.; Yoshizawa, Y.
Physical Review Letters, Vol. 44, Issue 23
DOI: 10.1103/PhysRevLett.44.1548

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011

Momma, Koichi; Izumi, Fujio
Journal of Applied Crystallography, Vol. 44, Issue 6
DOI: 10.1107/S0021889811038970

Magnetic and dielectric properties of A ₂ CoSi ₂ O ₇ ( A =Ca, Sr, Ba) crystals
journal, March 2009

Akaki, M.; Tozawa, J.; Akahoshi, D.
Journal of Physics: Conference Series, Vol. 150, Issue 4
DOI: 10.1088/1742-6596/150/4/042001

Successive Magnetic Transitions of Ca ₂ CoSi ₂ O ₇ in High Magnetic Fields
journal, September 2014

Akaki, Mitsuru; Kuwahara, Hideki; Matsuo, Akira
Journal of the Physical Society of Japan, Vol. 83, Issue 9
DOI: 10.7566/JPSJ.83.093704

Quantization of Magnetic Excitation Continuum Due to Interchain Coupling in Nearly One-Dimensional Ising-Like Antiferromagnets
journal, August 1980

Shiba, H.
Progress of Theoretical Physics, Vol. 64, Issue 2
DOI: 10.1143/PTP.64.466

Spin-Nematic Interaction in the Multiferroic Compound ${Ba}_{2} {CoGe}_{2} O_{7}$
journal, March 2014

Soda, M.; Matsumoto, M.; Månsson, M.
Physical Review Letters, Vol. 112, Issue 12
DOI: 10.1103/PhysRevLett.112.127205

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Similar Records

This content will become publicly available on October 7, 2020

Title: Neutron scattering study of the quasi-one-dimensional antiferromagnet Ba 2 CoSi 2 O 7

Abstract

Citation Formats

Continuous control of local magnetic moment by applied electric field in multiferroics Ba 2 CoGe 2 O 7 journal, September 2016

Dynamical Correlation Functions of One-Dimensional Anisotropic Heisenberg Model with Spin 1/2. I: Ising-Like Antiferromagnets journal, March 1980

Evolution of two-dimensional antiferromagnetism with temperature and magnetic field in multiferroic Ba 2 CoGe 2 O 7 journal, February 2014

Syntheses, Structural Analyses, and Unusual Magnetic Properties of Ba 2 CoSi 2 O 7 and BaCo 2 Si 2 O 7 journal, January 1996

Magnetic Structure and Dielectric State in the Multiferroic Ca 2 CoSi 2 O 7 journal, June 2017

Dynamical correlation functions in a one-dimensional Ising-like antiferromagnetic CsCo Cl 3 : A neutron scattering study journal, March 1981

Multiferroicity in the square-lattice antiferromagnet of Ba2CoGe2O7 journal, May 2008

Polarization analysis of magnetic excitation in multiferroic Ba 2 CoGe 2 O 7 journal, June 2018

Ferroelectricity Induced by Proper-Screw Type Magnetic Order journal, July 2007

Ferroelectricity Induced by Spin-Dependent Metal-Ligand Hybridization in Ba 2 CoGe 2 O 7 journal, September 2010

Structures of the Stuffed Tridymite Derivatives, BaMSiO4 (M = Co, Zn, Mg) journal, January 1993

Microscopic theory of spin-polarization coupling in multiferroic transition metal oxides journal, October 2007

Neutron Scattering Study of Spin Dynamics in CsCo Cl 3 journal, June 1980

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data journal, October 2011

Magnetic and dielectric properties of A 2 CoSi 2 O 7 ( A =Ca, Sr, Ba) crystals journal, March 2009

Successive Magnetic Transitions of Ca 2 CoSi 2 O 7 in High Magnetic Fields journal, September 2014

Quantization of Magnetic Excitation Continuum Due to Interchain Coupling in Nearly One-Dimensional Ising-Like Antiferromagnets journal, August 1980

Spin-Nematic Interaction in the Multiferroic Compound Ba 2 CoGe 2 O 7 journal, March 2014

Title: Neutron scattering study of the quasi-one-dimensional antiferromagnet ${Ba}_{2} {CoSi}_{2} O_{7}$

Continuous control of local magnetic moment by applied electric field in multiferroics ${Ba}_{2} {CoGe}_{2} O_{7}$
journal, September 2016

Dynamical Correlation Functions of One-Dimensional Anisotropic Heisenberg Model with Spin 1/2. I: Ising-Like Antiferromagnets
journal, March 1980

Evolution of two-dimensional antiferromagnetism with temperature and magnetic field in multiferroic ${Ba}_{2} {CoGe}_{2} O_{7}$
journal, February 2014

Syntheses, Structural Analyses, and Unusual Magnetic Properties of Ba ₂ CoSi ₂ O ₇ and BaCo ₂ Si ₂ O ₇
journal, January 1996

Magnetic Structure and Dielectric State in the Multiferroic Ca ₂ CoSi ₂ O ₇
journal, June 2017

Dynamical correlation functions in a one-dimensional Ising-like antiferromagnetic CsCo ${Cl}_{3}$ : A neutron scattering study
journal, March 1981

Multiferroicity in the square-lattice antiferromagnet of Ba2CoGe2O7
journal, May 2008

Polarization analysis of magnetic excitation in multiferroic ${Ba}_{2} {CoGe}_{2} O_{7}$
journal, June 2018

Ferroelectricity Induced by Proper-Screw Type Magnetic Order
journal, July 2007

Ferroelectricity Induced by Spin-Dependent Metal-Ligand Hybridization in ${Ba}_{2} {CoGe}_{2} O_{7}$
journal, September 2010

Structures of the Stuffed Tridymite Derivatives, BaMSiO4 (M = Co, Zn, Mg)
journal, January 1993

Microscopic theory of spin-polarization coupling in multiferroic transition metal oxides
journal, October 2007

Neutron Scattering Study of Spin Dynamics in CsCo ${Cl}_{3}$
journal, June 1980

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011

Magnetic and dielectric properties of A ₂ CoSi ₂ O ₇ ( A =Ca, Sr, Ba) crystals
journal, March 2009

Successive Magnetic Transitions of Ca ₂ CoSi ₂ O ₇ in High Magnetic Fields
journal, September 2014

Quantization of Magnetic Excitation Continuum Due to Interchain Coupling in Nearly One-Dimensional Ising-Like Antiferromagnets
journal, August 1980

Spin-Nematic Interaction in the Multiferroic Compound ${Ba}_{2} {CoGe}_{2} O_{7}$
journal, March 2014