skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: The influence of fractional surface coverage on the core–core separation in ordered monolayers of thiol-ligated Au nanoparticles

Abstract

This study examines the way in which fractional surface coverage on a nanoparticle surface affects nanoparticle interactions and the long-range order of Langmuir monolayers.

Authors:
 [1];  [1]; ORCiD logo [1];  [2]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [1]
  1. James Franck Institute, University of Chicago, Chicago, USA
  2. Applied Materials Division, Argonne National Laboratory, Argonne, USA
  3. NSF's ChemMatCARS, University of Chicago, Chicago, USA
  4. James Franck Institute, University of Chicago, Chicago, USA, NSF's ChemMatCARS
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1570036
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Soft Matter
Additional Journal Information:
Journal Name: Soft Matter Journal Volume: 15 Journal Issue: 43; Journal ID: ISSN 1744-683X
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Reik, Morgan, Calabro, Melanie, Griesemer, Sean, Barry, Edward, Bu, Wei, Lin, Binhua, and Rice, Stuart A. The influence of fractional surface coverage on the core–core separation in ordered monolayers of thiol-ligated Au nanoparticles. United Kingdom: N. p., 2019. Web. doi:10.1039/C9SM01579E.
Reik, Morgan, Calabro, Melanie, Griesemer, Sean, Barry, Edward, Bu, Wei, Lin, Binhua, & Rice, Stuart A. The influence of fractional surface coverage on the core–core separation in ordered monolayers of thiol-ligated Au nanoparticles. United Kingdom. doi:10.1039/C9SM01579E.
Reik, Morgan, Calabro, Melanie, Griesemer, Sean, Barry, Edward, Bu, Wei, Lin, Binhua, and Rice, Stuart A. Wed . "The influence of fractional surface coverage on the core–core separation in ordered monolayers of thiol-ligated Au nanoparticles". United Kingdom. doi:10.1039/C9SM01579E.
@article{osti_1570036,
title = {The influence of fractional surface coverage on the core–core separation in ordered monolayers of thiol-ligated Au nanoparticles},
author = {Reik, Morgan and Calabro, Melanie and Griesemer, Sean and Barry, Edward and Bu, Wei and Lin, Binhua and Rice, Stuart A.},
abstractNote = {This study examines the way in which fractional surface coverage on a nanoparticle surface affects nanoparticle interactions and the long-range order of Langmuir monolayers.},
doi = {10.1039/C9SM01579E},
journal = {Soft Matter},
number = 43,
volume = 15,
place = {United Kingdom},
year = {2019},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C9SM01579E

Citation Metrics:
Cited by: 1 work
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Adsorption kinetic process of thiol ligands on gold nanocrystals
journal, January 2013

  • Cheng†, Hao; Yang†, Lina; Jiang, Yong
  • Nanoscale, Vol. 5, Issue 23
  • DOI: 10.1039/c3nr04020h

Structure, Wrinkling, and Reversibility of Langmuir Monolayers of Gold Nanoparticles
journal, December 2006

  • Schultz, David G.; Lin, Xiao-Min; Li, Dongxu
  • The Journal of Physical Chemistry B, Vol. 110, Issue 48
  • DOI: 10.1021/jp063820s

Vibrational Sum Frequency Generation Spectroscopy of Dodecanethiol on Metal Nanoparticles
journal, June 2007

  • Bordenyuk, Andrey N.; Weeraman, Champika; Yatawara, Achani
  • The Journal of Physical Chemistry C, Vol. 111, Issue 25
  • DOI: 10.1021/jp069062n

Formation of monolayer films by the spontaneous assembly of organic thiols from solution onto gold
journal, January 1989

  • Bain, Colin D.; Troughton, E. Barry; Tao, Yu Tai
  • Journal of the American Chemical Society, Vol. 111, Issue 1, p. 321-335
  • DOI: 10.1021/ja00183a049

Effect of Alkanethiol Chain Length on Gold Nanoparticle Monolayers at the Air–Water Interface
journal, December 2011

  • Comeau, Katelynn D.; Meli, M. Vicki
  • Langmuir, Vol. 28, Issue 1
  • DOI: 10.1021/la202895n

Nanoparticle Superlattices: The Roles of Soft Ligands
journal, September 2017


Binary Self-Assembly of Gold Nanowires with Nanospheres and Nanorods
journal, November 2010

  • Sánchez-Iglesias, Ana; Grzelczak, Marek; Pérez-Juste, Jorge
  • Angewandte Chemie International Edition, Vol. 49, Issue 51
  • DOI: 10.1002/anie.201005891

The Chemistry of the Sulfur–Gold Interface: In Search of a Unified Model
journal, March 2012

  • Pensa, Evangelina; Cortés, Emiliano; Corthey, Gastón
  • Accounts of Chemical Research, Vol. 45, Issue 8
  • DOI: 10.1021/ar200260p

Fabrication and Mechanical Properties of Large-Scale Freestanding Nanoparticle Membranes
journal, June 2010


Two-Way Gold Nanoparticle Label-Free Sensing of Specific Sequence and Small Molecule Targets Using Switchable Concatemers
journal, April 2017


Robust Gold Nanoparticle Sheets by Ligand Cross-Linking at the Air–Water Interface
journal, January 2017


Enhanced Ordering in Gold Nanoparticles Self-Assembly through Excess Free Ligands
journal, April 2011

  • Lau, Cindy Y.; Duan, Huigao; Wang, Fuke
  • Langmuir, Vol. 27, Issue 7
  • DOI: 10.1021/la104786z

Self-assembly of amphiphilic gold nanoparticles decorated with a mixed shell of oligo(p-phenylene vinylene)s and ethyleneoxide ligands
journal, January 2008

  • Jakobs, Robert T. M.; van Herrikhuyzen, Jeroen; Gielen, Jeroen C.
  • Journal of Materials Chemistry, Vol. 18, Issue 29
  • DOI: 10.1039/b803935f

Self-Assembly of Uniform Monolayer Arrays of Nanoparticles
journal, September 2003

  • Santhanam, Venugopal; Liu, Jia; Agarwal, Rajan
  • Langmuir, Vol. 19, Issue 19
  • DOI: 10.1021/la0341761

Tailoring the interparticle distance in Langmuir nanoparticle films
journal, January 2019

  • Benkovičová, Monika; Hološ, Ana; Nádaždy, Peter
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 18
  • DOI: 10.1039/C9CP02064K

Influence of Length of Alkyl Chains Used To Passivate Silver Sulfide Nanoparticles on Two- and Three-Dimensional Self-Organization
journal, May 1998

  • Motte, L.; Pileni, M. P.
  • The Journal of Physical Chemistry B, Vol. 102, Issue 21
  • DOI: 10.1021/jp9808173

Map of the Structural and Optical Properties of Gold Nanoparticles at Thermal Equilibrium
journal, June 2012

  • González, A. L.; Noguez, C.; Barnard, A. S.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 26
  • DOI: 10.1021/jp3047906

Kinetics of Alkanethiol Adsorption on Gold
journal, January 1996

  • Pan, W.; Durning, C. J.; Turro, N. J.
  • Langmuir, Vol. 12, Issue 18
  • DOI: 10.1021/la9408634

The role of ligands in the mechanical properties of Langmuir nanoparticle films
journal, January 2017

  • Griesemer, Sean D.; You, Siheng Sean; Kanjanaboos, Pongsakorn
  • Soft Matter, Vol. 13, Issue 17
  • DOI: 10.1039/C7SM00319F

Spontaneously organized molecular assemblies. 4. Structural characterization of n-alkyl thiol monolayers on gold by optical ellipsometry, infrared spectroscopy, and electrochemistry
journal, June 1987

  • Porter, Marc D.; Bright, Thomas B.; Allara, David L.
  • Journal of the American Chemical Society, Vol. 109, Issue 12
  • DOI: 10.1021/ja00246a011

Pair and many-body interactions between ligated Au nanoparticles
journal, January 2019

  • Liepold, Christopher; Smith, Alex; Lin, Binhua
  • The Journal of Chemical Physics, Vol. 150, Issue 4
  • DOI: 10.1063/1.5064545

Structure and growth of self-assembling monolayers
journal, November 2000


Digestive Ripening of Thiolated Gold Nanoparticles:  The Effect of Alkyl Chain Length
journal, October 2002

  • Prasad, B. L. V.; Stoeva, Savka I.; Sorensen, Christopher M.
  • Langmuir, Vol. 18, Issue 20
  • DOI: 10.1021/la020181d

Occurrence of the potent mutagens 2- nitrobenzanthrone and 3-nitrobenzanthrone in fine airborne particles
journal, January 2019

  • Santos, Aldenor G.; da Rocha, Gisele O.; de Andrade, Jailson B.
  • Scientific Reports, Vol. 9, Issue 1
  • DOI: 10.1038/s41598-018-37186-2

Effect of nanometer surface morphology on surface stress and adsorption kinetics of alkanethiol self-assembled monolayers
journal, June 2006


Molecular interaction between asymmetric ligand-capped gold nanocrystals
journal, January 2019

  • Liu, Xuepeng; Lu, Pin; Zhai, Hua
  • The Journal of Chemical Physics, Vol. 150, Issue 3
  • DOI: 10.1063/1.5065476

Immunological properties of engineered nanomaterials
journal, July 2007

  • Dobrovolskaia, Marina A.; McNeil, Scott E.
  • Nature Nanotechnology, Vol. 2, Issue 8
  • DOI: 10.1038/nnano.2007.223

Formation of monolayers by the coadsorption of thiols on gold: variation in the head group, tail group, and solvent
journal, August 1989

  • Bain, Colin D.; Evall, Joe; Whitesides, George M.
  • Journal of the American Chemical Society, Vol. 111, Issue 18, p. 7155-7164
  • DOI: 10.1021/ja00200a039

Plasmon resonances in large noble-metal clusters
journal, January 2002


Gold nanoparticles as sensitive optical probes
journal, January 2016

  • Yuan, Zhiqin; Hu, Cho-Chun; Chang, Huan-Tsung
  • The Analyst, Vol. 141, Issue 5
  • DOI: 10.1039/C5AN02651B

Properties and emerging applications of self-assembled structures made from inorganic nanoparticles
journal, December 2009

  • Nie, Zhihong; Petukhova, Alla; Kumacheva, Eugenia
  • Nature Nanotechnology, Vol. 5, Issue 1
  • DOI: 10.1038/nnano.2009.453

Place Exchange Reactions of Alkyl Thiols on Gold Nanoparticles
journal, March 2006

  • Kassam, Adil; Bremner, Glen; Clark, Brad
  • Journal of the American Chemical Society, Vol. 128, Issue 11
  • DOI: 10.1021/ja057091q

Synthesis and Evaluation of Paclitaxel-Loaded Gold Nanoparticles for Tumor-Targeted Drug Delivery
journal, October 2016


Spin-Dependent Tunneling in Self-Assembled Cobalt-Nanocrystal Superlattices
journal, November 2000


Gold-nanoparticle-based biosensors for detection of enzyme activity
journal, September 2013


Subnanometre ligand-shell asymmetry leads to Janus-like nanoparticle membranes
journal, June 2015

  • Jiang, Zhang; He, Jinbo; Deshmukh, Sanket A.
  • Nature Materials, Vol. 14, Issue 9
  • DOI: 10.1038/nmat4321

Multiple Cotunneling in Large Quantum Dot Arrays
journal, August 2005


Gold nanoparticle superlattices
journal, January 2008

  • Prasad, B. L. V.; Sorensen, C. M.; Klabunde, Kenneth J.
  • Chemical Society Reviews, Vol. 37, Issue 9
  • DOI: 10.1039/b712175j

Percolating through Networks of Random Thresholds: Finite Temperature Electron Tunneling in Metal Nanocrystal Arrays
journal, February 2004


Effect of Postsynthesis Purifications on Gold and Silver Nanoparticle Ligand Coverage
journal, March 2016

  • Ansar, Siyam M.; Mohammed, Fiaz S.; von White, Gregory
  • The Journal of Physical Chemistry C, Vol. 120, Issue 12
  • DOI: 10.1021/acs.jpcc.5b12423