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Title: The influence of fractional surface coverage on the core–core separation in ordered monolayers of thiol-ligated Au nanoparticles

Journal Article · · Soft Matter
DOI: https://doi.org/10.1039/C9SM01579E · OSTI ID:1570036

This study examines the way in which fractional surface coverage on a nanoparticle surface affects nanoparticle interactions and the long-range order of Langmuir monolayers.

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1570036
Journal Information:
Soft Matter, Journal Name: Soft Matter Journal Issue: 43 Vol. 15; ISSN SMOABF; ISSN 1744-683X
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (41)

Nanoparticle Superlattices: The Roles of Soft Ligands journal September 2017
Binary Self-Assembly of Gold Nanowires with Nanospheres and Nanorods journal November 2010
Fabrication and Mechanical Properties of Large-Scale Freestanding Nanoparticle Membranes journal June 2010
Structure and growth of self-assembling monolayers journal November 2000
Gold-nanoparticle-based biosensors for detection of enzyme activity journal September 2013
Effect of nanometer surface morphology on surface stress and adsorption kinetics of alkanethiol self-assembled monolayers journal June 2006
Synthesis and Evaluation of Paclitaxel-Loaded Gold Nanoparticles for Tumor-Targeted Drug Delivery journal October 2016
Effect of Postsynthesis Purifications on Gold and Silver Nanoparticle Ligand Coverage journal March 2016
Two-Way Gold Nanoparticle Label-Free Sensing of Specific Sequence and Small Molecule Targets Using Switchable Concatemers journal April 2017
Robust Gold Nanoparticle Sheets by Ligand Cross-Linking at the Air–Water Interface journal January 2017
The Chemistry of the Sulfur–Gold Interface: In Search of a Unified Model journal March 2012
Formation of monolayer films by the spontaneous assembly of organic thiols from solution onto gold journal January 1989
Formation of monolayers by the coadsorption of thiols on gold: variation in the head group, tail group, and solvent journal August 1989
Spontaneously organized molecular assemblies. 4. Structural characterization of n-alkyl thiol monolayers on gold by optical ellipsometry, infrared spectroscopy, and electrochemistry journal June 1987
Place Exchange Reactions of Alkyl Thiols on Gold Nanoparticles journal March 2006
Structure, Wrinkling, and Reversibility of Langmuir Monolayers of Gold Nanoparticles journal December 2006
Vibrational Sum Frequency Generation Spectroscopy of Dodecanethiol on Metal Nanoparticles journal June 2007
Map of the Structural and Optical Properties of Gold Nanoparticles at Thermal Equilibrium journal June 2012
Influence of Length of Alkyl Chains Used To Passivate Silver Sulfide Nanoparticles on Two- and Three-Dimensional Self-Organization journal May 1998
Direct Measurement of the Adsorption Kinetics of Alkanethiolate Self-Assembled Monolayers on a Microcrystalline Gold Surface journal September 1994
Digestive Ripening of Thiolated Gold Nanoparticles:  The Effect of Alkyl Chain Length journal October 2002
Self-Assembly of Uniform Monolayer Arrays of Nanoparticles journal September 2003
Enhanced Ordering in Gold Nanoparticles Self-Assembly through Excess Free Ligands journal April 2011
Effect of Alkanethiol Chain Length on Gold Nanoparticle Monolayers at the Air–Water Interface journal December 2011
Kinetics of Alkanethiol Adsorption on Gold journal January 1996
Subnanometre ligand-shell asymmetry leads to Janus-like nanoparticle membranes journal June 2015
Immunological properties of engineered nanomaterials journal July 2007
Properties and emerging applications of self-assembled structures made from inorganic nanoparticles journal December 2009
Occurrence of the potent mutagens 2- nitrobenzanthrone and 3-nitrobenzanthrone in fine airborne particles journal January 2019
Gold nanoparticles as sensitive optical probes journal January 2016
The role of ligands in the mechanical properties of Langmuir nanoparticle films journal January 2017
Tailoring the interparticle distance in Langmuir nanoparticle films journal January 2019
Gold nanoparticle superlattices journal January 2008
Self-assembly of amphiphilic gold nanoparticles decorated with a mixed shell of oligo(p-phenylene vinylene)s and ethyleneoxide ligands journal January 2008
Adsorption kinetic process of thiol ligands on gold nanocrystals journal January 2013
Pair and many-body interactions between ligated Au nanoparticles journal January 2019
Molecular interaction between asymmetric ligand-capped gold nanocrystals journal January 2019
Plasmon resonances in large noble-metal clusters journal January 2002
Percolating through Networks of Random Thresholds: Finite Temperature Electron Tunneling in Metal Nanocrystal Arrays journal February 2004
Multiple Cotunneling in Large Quantum Dot Arrays journal August 2005
Spin-Dependent Tunneling in Self-Assembled Cobalt-Nanocrystal Superlattices journal November 2000

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