The influence of fractional surface coverage on the core–core separation in ordered monolayers of thiol-ligated Au nanoparticles

Reik, Morgan; Calabro, Melanie; Griesemer, Sean; Barry, Edward; Bu, Wei; Lin, Binhua; Rice, Stuart A.

doi:10.1039/C9SM01579E

Title: The influence of fractional surface coverage on the core–core separation in ordered monolayers of thiol-ligated Au nanoparticles

Abstract

This study examines the way in which fractional surface coverage on a nanoparticle surface affects nanoparticle interactions and the long-range order of Langmuir monolayers.

Authors:

Reik, Morgan ^[1]; Calabro, Melanie ^[1];

^[1]; Barry, Edward ^[2];

^[3];

^[4];

^[1]

James Franck Institute, University of Chicago, Chicago, USA
Applied Materials Division, Argonne National Laboratory, Argonne, USA
NSF's ChemMatCARS, University of Chicago, Chicago, USA
James Franck Institute, University of Chicago, Chicago, USA, NSF's ChemMatCARS

Publication Date:: 2019-11-06

Sponsoring Org.:: USDOE

OSTI Identifier:: 1570036

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Soft Matter

Additional Journal Information:: Journal Name: Soft Matter Journal Volume: 15 Journal Issue: 43; Journal ID: ISSN 1744-683X

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Reik, Morgan, Calabro, Melanie, Griesemer, Sean, Barry, Edward, Bu, Wei, Lin, Binhua, and Rice, Stuart A. The influence of fractional surface coverage on the core–core separation in ordered monolayers of thiol-ligated Au nanoparticles.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C9SM01579E.

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                    Reik, Morgan, Calabro, Melanie, Griesemer, Sean, Barry, Edward, Bu, Wei, Lin, Binhua, & Rice, Stuart A. The influence of fractional surface coverage on the core–core separation in ordered monolayers of thiol-ligated Au nanoparticles.  United Kingdom.  https://doi.org/10.1039/C9SM01579E

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                    Reik, Morgan, Calabro, Melanie, Griesemer, Sean, Barry, Edward, Bu, Wei, Lin, Binhua, and Rice, Stuart A. Wed .  
"The influence of fractional surface coverage on the core–core separation in ordered monolayers of thiol-ligated Au nanoparticles".  United Kingdom.  https://doi.org/10.1039/C9SM01579E.

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@article{osti_1570036,

  title        = {The influence of fractional surface coverage on the core–core separation in ordered monolayers of thiol-ligated Au nanoparticles},

  author       = {Reik, Morgan and Calabro, Melanie and Griesemer, Sean and Barry, Edward and Bu, Wei and Lin, Binhua and Rice, Stuart A.},

  abstractNote = {This study examines the way in which fractional surface coverage on a nanoparticle surface affects nanoparticle interactions and the long-range order of Langmuir monolayers.},

  doi          = {10.1039/C9SM01579E},

  journal      = {Soft Matter},

  number       = 43,

  volume       = 15,

  place        = {United Kingdom},

  year         = {2019},

  month        = {11}

}

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https://doi.org/10.1039/C9SM01579E

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Title: The influence of fractional surface coverage on the core–core separation in ordered monolayers of thiol-ligated Au nanoparticles

Abstract

Citation Formats

Adsorption kinetic process of thiol ligands on gold nanocrystals journal, January 2013

Structure, Wrinkling, and Reversibility of Langmuir Monolayers of Gold Nanoparticles journal, December 2006

Vibrational Sum Frequency Generation Spectroscopy of Dodecanethiol on Metal Nanoparticles † journal, June 2007

Formation of monolayer films by the spontaneous assembly of organic thiols from solution onto gold journal, January 1989

Effect of Alkanethiol Chain Length on Gold Nanoparticle Monolayers at the Air–Water Interface journal, December 2011

Nanoparticle Superlattices: The Roles of Soft Ligands journal, September 2017

Binary Self-Assembly of Gold Nanowires with Nanospheres and Nanorods journal, November 2010

The Chemistry of the Sulfur–Gold Interface: In Search of a Unified Model journal, March 2012

Fabrication and Mechanical Properties of Large-Scale Freestanding Nanoparticle Membranes journal, June 2010

Two-Way Gold Nanoparticle Label-Free Sensing of Specific Sequence and Small Molecule Targets Using Switchable Concatemers journal, April 2017

Robust Gold Nanoparticle Sheets by Ligand Cross-Linking at the Air–Water Interface journal, January 2017

Enhanced Ordering in Gold Nanoparticles Self-Assembly through Excess Free Ligands journal, April 2011

Self-assembly of amphiphilic gold nanoparticles decorated with a mixed shell of oligo(p-phenylene vinylene)s and ethyleneoxide ligands journal, January 2008

Self-Assembly of Uniform Monolayer Arrays of Nanoparticles journal, September 2003

Tailoring the interparticle distance in Langmuir nanoparticle films journal, January 2019

Influence of Length of Alkyl Chains Used To Passivate Silver Sulfide Nanoparticles on Two- and Three-Dimensional Self-Organization journal, May 1998

Map of the Structural and Optical Properties of Gold Nanoparticles at Thermal Equilibrium journal, June 2012

Kinetics of Alkanethiol Adsorption on Gold journal, January 1996

The role of ligands in the mechanical properties of Langmuir nanoparticle films journal, January 2017

Spontaneously organized molecular assemblies. 4. Structural characterization of n-alkyl thiol monolayers on gold by optical ellipsometry, infrared spectroscopy, and electrochemistry journal, June 1987

Pair and many-body interactions between ligated Au nanoparticles journal, January 2019

Structure and growth of self-assembling monolayers journal, November 2000

Digestive Ripening of Thiolated Gold Nanoparticles: The Effect of Alkyl Chain Length journal, October 2002

Occurrence of the potent mutagens 2- nitrobenzanthrone and 3-nitrobenzanthrone in fine airborne particles journal, January 2019

Effect of nanometer surface morphology on surface stress and adsorption kinetics of alkanethiol self-assembled monolayers journal, June 2006

Molecular interaction between asymmetric ligand-capped gold nanocrystals journal, January 2019

Immunological properties of engineered nanomaterials journal, July 2007

Formation of monolayers by the coadsorption of thiols on gold: variation in the head group, tail group, and solvent journal, August 1989

Plasmon resonances in large noble-metal clusters journal, January 2002

Gold nanoparticles as sensitive optical probes journal, January 2016

Properties and emerging applications of self-assembled structures made from inorganic nanoparticles journal, December 2009

Place Exchange Reactions of Alkyl Thiols on Gold Nanoparticles journal, March 2006

Synthesis and Evaluation of Paclitaxel-Loaded Gold Nanoparticles for Tumor-Targeted Drug Delivery journal, October 2016

Spin-Dependent Tunneling in Self-Assembled Cobalt-Nanocrystal Superlattices journal, November 2000

Gold-nanoparticle-based biosensors for detection of enzyme activity journal, September 2013

Subnanometre ligand-shell asymmetry leads to Janus-like nanoparticle membranes journal, June 2015

Multiple Cotunneling in Large Quantum Dot Arrays journal, August 2005

Gold nanoparticle superlattices journal, January 2008

Direct Measurement of the Adsorption Kinetics of Alkanethiolate Self-Assembled Monolayers on a Microcrystalline Gold Surface journal, September 1994

Percolating through Networks of Random Thresholds: Finite Temperature Electron Tunneling in Metal Nanocrystal Arrays journal, February 2004

Effect of Postsynthesis Purifications on Gold and Silver Nanoparticle Ligand Coverage journal, March 2016

Adsorption kinetic process of thiol ligands on gold nanocrystals
journal, January 2013

Structure, Wrinkling, and Reversibility of Langmuir Monolayers of Gold Nanoparticles
journal, December 2006

Vibrational Sum Frequency Generation Spectroscopy of Dodecanethiol on Metal Nanoparticles ^†
journal, June 2007

Formation of monolayer films by the spontaneous assembly of organic thiols from solution onto gold
journal, January 1989

Effect of Alkanethiol Chain Length on Gold Nanoparticle Monolayers at the Air–Water Interface
journal, December 2011

Nanoparticle Superlattices: The Roles of Soft Ligands
journal, September 2017

Binary Self-Assembly of Gold Nanowires with Nanospheres and Nanorods
journal, November 2010

The Chemistry of the Sulfur–Gold Interface: In Search of a Unified Model
journal, March 2012

Fabrication and Mechanical Properties of Large-Scale Freestanding Nanoparticle Membranes
journal, June 2010

Two-Way Gold Nanoparticle Label-Free Sensing of Specific Sequence and Small Molecule Targets Using Switchable Concatemers
journal, April 2017

Robust Gold Nanoparticle Sheets by Ligand Cross-Linking at the Air–Water Interface
journal, January 2017

Enhanced Ordering in Gold Nanoparticles Self-Assembly through Excess Free Ligands
journal, April 2011

Self-assembly of amphiphilic gold nanoparticles decorated with a mixed shell of oligo(p-phenylene vinylene)s and ethyleneoxide ligands
journal, January 2008

Self-Assembly of Uniform Monolayer Arrays of Nanoparticles
journal, September 2003

Tailoring the interparticle distance in Langmuir nanoparticle films
journal, January 2019

Influence of Length of Alkyl Chains Used To Passivate Silver Sulfide Nanoparticles on Two- and Three-Dimensional Self-Organization
journal, May 1998

Map of the Structural and Optical Properties of Gold Nanoparticles at Thermal Equilibrium
journal, June 2012

Kinetics of Alkanethiol Adsorption on Gold
journal, January 1996

The role of ligands in the mechanical properties of Langmuir nanoparticle films
journal, January 2017

Spontaneously organized molecular assemblies. 4. Structural characterization of n-alkyl thiol monolayers on gold by optical ellipsometry, infrared spectroscopy, and electrochemistry
journal, June 1987

Pair and many-body interactions between ligated Au nanoparticles
journal, January 2019

Structure and growth of self-assembling monolayers
journal, November 2000

Digestive Ripening of Thiolated Gold Nanoparticles: The Effect of Alkyl Chain Length
journal, October 2002

Occurrence of the potent mutagens 2- nitrobenzanthrone and 3-nitrobenzanthrone in fine airborne particles
journal, January 2019

Effect of nanometer surface morphology on surface stress and adsorption kinetics of alkanethiol self-assembled monolayers
journal, June 2006

Molecular interaction between asymmetric ligand-capped gold nanocrystals
journal, January 2019

Immunological properties of engineered nanomaterials
journal, July 2007

Formation of monolayers by the coadsorption of thiols on gold: variation in the head group, tail group, and solvent
journal, August 1989

Plasmon resonances in large noble-metal clusters
journal, January 2002

Gold nanoparticles as sensitive optical probes
journal, January 2016

Properties and emerging applications of self-assembled structures made from inorganic nanoparticles
journal, December 2009

Place Exchange Reactions of Alkyl Thiols on Gold Nanoparticles
journal, March 2006

Synthesis and Evaluation of Paclitaxel-Loaded Gold Nanoparticles for Tumor-Targeted Drug Delivery
journal, October 2016

Spin-Dependent Tunneling in Self-Assembled Cobalt-Nanocrystal Superlattices
journal, November 2000

Gold-nanoparticle-based biosensors for detection of enzyme activity
journal, September 2013

Subnanometre ligand-shell asymmetry leads to Janus-like nanoparticle membranes
journal, June 2015

Multiple Cotunneling in Large Quantum Dot Arrays
journal, August 2005

Gold nanoparticle superlattices
journal, January 2008

Direct Measurement of the Adsorption Kinetics of Alkanethiolate Self-Assembled Monolayers on a Microcrystalline Gold Surface
journal, September 1994

Percolating through Networks of Random Thresholds: Finite Temperature Electron Tunneling in Metal Nanocrystal Arrays
journal, February 2004

Effect of Postsynthesis Purifications on Gold and Silver Nanoparticle Ligand Coverage
journal, March 2016