skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Enormous electron-electron scattering in the filled-cage cubic compound B a 10 T i 24 B i 39

Abstract

Cubic intermetallic compound Ba10Ti24Bi39 has a Ba6Bi16 polyhedral cage with a Bi guest atom encapsulated inside. The compound can be formulated as Ba5Ti12Bi$$_{19+x}$$ when $x$ signifies the extra Bi atoms filling cages. It crystallizes in a complex noncentrosymmetric cubic structure in space group $P-43m$ with cell parameter $a = 12.6787(4)Å$. The guest Bi atoms distribute diffusely in the cages and seem to play a role in stabilizing the crystal structure. The magnetic susceptibility of this compound shows a weak temperature dependence with a positive slope coefficient. The charge transport properties as a function of temperature exhibit two competing components which are in charge of positive and negative magnetoresistances. Electronic band-structure calculations reveal the complex multiband hybridization of Ti/Bi orbitals near the Fermi surface, which may play a role in the enormous electron-electron scattering in this material evidenced by the large Kadowaki-Woods ratio.

Authors:
 [1];  [2];  [3];  [4];  [5];  [2];  [5];  [3]
  1. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
  3. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
  4. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Leibniz Inst. for Solid State and Materials Research (IFW), Dresden (Germany)
  5. Nanjing Univ. (China). National Laboratory of Solid State Microstructures, School of Physics, Collaborative Innovation Center of Advanced Microstructures
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1570005
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review Materials
Additional Journal Information:
Journal Volume: 3; Journal Issue: 10; Journal ID: ISSN 2475-9953
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; Electrical properties; Crystal growth; Magnetization measurements; Resistivity measurements

Citation Formats

Han, Fei, Bao, Jin-Ke, Malliakas, Christos D., Sturza, Mihai, Du, Yongping, Chung, Duck Young, Wan, Xiangang, and Kanatzidis, Mercouri G. Enormous electron-electron scattering in the filled-cage cubic compound Ba10Ti24Bi39. United States: N. p., 2019. Web. doi:10.1103/PhysRevMaterials.3.105001.
Han, Fei, Bao, Jin-Ke, Malliakas, Christos D., Sturza, Mihai, Du, Yongping, Chung, Duck Young, Wan, Xiangang, & Kanatzidis, Mercouri G. Enormous electron-electron scattering in the filled-cage cubic compound Ba10Ti24Bi39. United States. doi:10.1103/PhysRevMaterials.3.105001.
Han, Fei, Bao, Jin-Ke, Malliakas, Christos D., Sturza, Mihai, Du, Yongping, Chung, Duck Young, Wan, Xiangang, and Kanatzidis, Mercouri G. Mon . "Enormous electron-electron scattering in the filled-cage cubic compound Ba10Ti24Bi39". United States. doi:10.1103/PhysRevMaterials.3.105001. https://www.osti.gov/servlets/purl/1570005.
@article{osti_1570005,
title = {Enormous electron-electron scattering in the filled-cage cubic compound Ba10Ti24Bi39},
author = {Han, Fei and Bao, Jin-Ke and Malliakas, Christos D. and Sturza, Mihai and Du, Yongping and Chung, Duck Young and Wan, Xiangang and Kanatzidis, Mercouri G.},
abstractNote = {Cubic intermetallic compound Ba10Ti24Bi39 has a Ba6Bi16 polyhedral cage with a Bi guest atom encapsulated inside. The compound can be formulated as Ba5Ti12Bi$_{19+x}$ when $x$ signifies the extra Bi atoms filling cages. It crystallizes in a complex noncentrosymmetric cubic structure in space group $P-43m$ with cell parameter $a = 12.6787(4)Å$. The guest Bi atoms distribute diffusely in the cages and seem to play a role in stabilizing the crystal structure. The magnetic susceptibility of this compound shows a weak temperature dependence with a positive slope coefficient. The charge transport properties as a function of temperature exhibit two competing components which are in charge of positive and negative magnetoresistances. Electronic band-structure calculations reveal the complex multiband hybridization of Ti/Bi orbitals near the Fermi surface, which may play a role in the enormous electron-electron scattering in this material evidenced by the large Kadowaki-Woods ratio.},
doi = {10.1103/PhysRevMaterials.3.105001},
journal = {Physical Review Materials},
number = 10,
volume = 3,
place = {United States},
year = {2019},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 1 work
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Atomic Interactions in the p-Type Clathrate I Ba 8 Au 5.3 Ge 40.7
journal, February 2011

  • Zhang, Hui; Borrmann, Horst; Oeschler, Niels
  • Inorganic Chemistry, Vol. 50, Issue 4
  • DOI: 10.1021/ic1016559

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Two-dimensional Dirac fermions and quantum magnetoresistance in CaMnBi 2
journal, January 2012


Magnetic Properties of the RAuBi2 (R = Ce, Pr, Nd, Gd, Sm) Series of Intermetallic Compounds
journal, January 2015


Topological insulators and superconductors
journal, October 2011


A technique for relativistic spin-polarised calculations
journal, August 1977


Strongly Correlated Superconductivity in Rh 17 S 15
journal, January 2008


Ba5Ti12Sb19+x, a polar intermetallic compound with a stuffed γ-brass structure
journal, November 2009


Observation of Fermi arc surface states in a topological metal
journal, December 2014


ɛ-TiO, a Novel Stable Polymorph of Titanium Monoxide
journal, December 2015

  • Amano, Shinsaku; Bogdanovski, Dimitri; Yamane, Hisanori
  • Angewandte Chemie International Edition, Vol. 55, Issue 5
  • DOI: 10.1002/anie.201510479

Large Anisotropic Normal-State Magnetoresistance in Clean MgB 2 Thin Films
journal, April 2006


Layered transition-metal pnictide SrMnBi 2 with metallic blocking layer
journal, August 2011


From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999


Surface-induced magnetic fluctuations in a single-crystal NiBi 3 superconductor
journal, July 2012


Topological R PdBi half-Heusler semimetals: A new family of noncentrosymmetric magnetic superconductors
journal, June 2015

  • Nakajima, Yasuyuki; Hu, Rongwei; Kirshenbaum, Kevin
  • Science Advances, Vol. 1, Issue 5
  • DOI: 10.1126/sciadv.1500242

LiV 2 O 4 Spinel as a Heavy-Mass Fermi Liquid: Anomalous Transport and Role of Geometrical Frustration
journal, July 2000


Topologically protected surface states in a centrosymmetric superconductor β-PdBi2
journal, October 2015

  • Sakano, M.; Okawa, K.; Kanou, M.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9595

Disordered electronic systems
journal, April 1985


Quasi-two-dimensional Dirac fermions and quantum magnetoresistance in LaAgBi 2
journal, June 2013


Intermetallische Verbindungen
journal, January 1939


Reaction of Ti and Ti-Al alloys with alumina
journal, March 1991


A unified explanation of the Kadowaki–Woods ratio in strongly correlated metals
journal, April 2009

  • Jacko, A. C.; Fjærestad, J. O.; Powell, B. J.
  • Nature Physics, Vol. 5, Issue 6
  • DOI: 10.1038/nphys1249

Anisotropic magnetization and resistivity of single crystalline RNi1−xBi2±y (R=La–Nd, Sm, Gd–Dy)
journal, March 2013


Superconductivity and role of pnictogen and Fe substitution in 112- LaPd x P n 2 ( P n = Sb , Bi )
journal, March 2015


Anisotropic Dirac Fermions in a Bi Square Net of SrMnBi 2
journal, September 2011


Quantum transport of two-dimensional Dirac fermions in SrMnBi 2
journal, December 2011


Kapellasite: A Kagome Quantum Spin Liquid with Competing Interactions
journal, July 2012


A short history of SHELX
journal, December 2007

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
  • DOI: 10.1107/S0108767307043930

Anomalous Pressure Dependence of the Kadowaki-Woods Ratio and Crystal-Field Effects in Mixed-Valence YbInCu 4
journal, January 2006


Superconducting properties and electronic structure of NaBi
journal, May 2014


Ab initio molecular dynamics for open-shell transition metals
journal, November 1993


Colloquium: Topological insulators
journal, November 2010


Temperature−field phase diagram of extreme magnetoresistance
journal, June 2016

  • Fallah Tafti, Fazel; Gibson, Quinn; Kushwaha, Satya
  • Proceedings of the National Academy of Sciences, Vol. 113, Issue 25
  • DOI: 10.1073/pnas.1607319113

Superconductivity in the intermetallic pnictide compound Ca 11 Bi 10 x
journal, February 2014


Discovery of a Three-Dimensional Topological Dirac Semimetal, Na3Bi
journal, January 2014


Electron-Electron Scattering in Transition Metals
journal, June 1968


Discovery of a Superconducting Cu-Bi Intermetallic Compound by High-Pressure Synthesis
journal, September 2016

  • Clarke, Samantha M.; Walsh, James P. S.; Amsler, Maximilian
  • Angewandte Chemie International Edition, Vol. 55, Issue 43
  • DOI: 10.1002/anie.201605902

Universal relationship of the resistivity and specific heat in heavy-Fermion compounds
journal, May 1986


Giant Electron-Electron Scattering in the Fermi-Liquid State of N a 0.7 C o O 2
journal, July 2004


Dirac semimetal and topological phase transitions in A 3 Bi ( A = Na , K, Rb)
journal, May 2012


Superconductivity and strong intrinsic defects in LaPd 1 x Bi 2
journal, October 2013

  • Han, Fei; Malliakas, Christos D.; Stoumpos, Constantinos C.
  • Physical Review B, Vol. 88, Issue 14
  • DOI: 10.1103/PhysRevB.88.144511

CoBi 3 : A Binary Cobalt-Bismuth Compound and Superconductor
journal, July 2013

  • Schwarz, Ulrich; Tencé, Sophie; Janson, Oleg
  • Angewandte Chemie International Edition, Vol. 52, Issue 37
  • DOI: 10.1002/anie.201302397

A Hydrogen Clathrate Hydrate with Cyclohexanone:  Structure and Stability
journal, August 2007

  • Strobel, Timothy A.; Hester, Keith C.; Sloan, E. Dendy
  • Journal of the American Chemical Society, Vol. 129, Issue 31
  • DOI: 10.1021/ja072074h

Universal linear-temperature dependence of static magnetic susceptibility in iron pnictides
journal, May 2009


Large magnetoresistance in LaBi: origin of field-induced resistivity upturn and plateau in compensated semimetals
journal, August 2016


Structure and magnetic properties of the REAuBi2 (RE=La–Nd, Sm) phases
journal, October 2015


Observation of pseudo-two-dimensional electron transport in the rock salt-type topological semimetal LaBi
journal, June 2016


Electron-hole asymmetry, Dirac fermions, and quantum magnetoresistance in BaMnBi 2
journal, March 2016


Discovery of FeBi 2
journal, October 2016


Superconducting properties of BaBi 3
journal, August 2014

  • Haldolaarachchige, Neel; Kushwaha, S. K.; Gibson, Quinn
  • Superconductor Science and Technology, Vol. 27, Issue 10
  • DOI: 10.1088/0953-2048/27/10/105001

Fully Band-Resolved Scattering Rate in MgB 2 Revealed by the Nonlinear Hall Effect and Magnetoresistance Measurements
journal, August 2008


    Works referencing / citing this record:

    Exploration of Multi-Component Vanadium and Titanium Pnictides Using Flux Growth and Conventional High-Temperature Methods
    journal, January 2020