Enormous electron-electron scattering in the filled-cage cubic compound Ba10Ti24Bi39

Han, Fei; Bao, Jin-Ke; Malliakas, Christos D.; Sturza, Mihai; Du, Yongping; Chung, Duck Young; Wan, Xiangang; Kanatzidis, Mercouri G.

doi:10.1103/PhysRevMaterials.3.105001

Title: Enormous electron-electron scattering in the filled-cage cubic compound $B a_{10} T i_{24} B i_{39}$

Journal Article · 06 October 2019 · Physical Review Materials

DOI: https://doi.org/10.1103/PhysRevMaterials.3.105001 · OSTI ID:1570005

Han, Fei ^[1]; Bao, Jin-Ke ^[2]; Malliakas, Christos D. ^[3]; Sturza, Mihai ^[4]; Du, Yongping ^[5]; Chung, Duck Young ^[2]; Wan, Xiangang ^[5]; Kanatzidis, Mercouri G. ^[3]

Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Materials Science and Engineering
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Leibniz Inst. for Solid State and Materials Research (IFW), Dresden (Germany)
Nanjing Univ. (China). National Laboratory of Solid State Microstructures, School of Physics, Collaborative Innovation Center of Advanced Microstructures

Cubic intermetallic compound Ba₁₀Ti₂₄Bi₃₉ has a Ba₆Bi₁₆ polyhedral cage with a Bi guest atom encapsulated inside. The compound can be formulated as Ba₅Ti₁₂Bi$$_{19+x}$$ when $$x$$ signifies the extra Bi atoms filling cages. It crystallizes in a complex noncentrosymmetric cubic structure in space group $P-43m$ with cell parameter $a = 12.6787(4)Å$. The guest Bi atoms distribute diffusely in the cages and seem to play a role in stabilizing the crystal structure. The magnetic susceptibility of this compound shows a weak temperature dependence with a positive slope coefficient. The charge transport properties as a function of temperature exhibit two competing components which are in charge of positive and negative magnetoresistances. Electronic band-structure calculations reveal the complex multiband hybridization of Ti/Bi orbitals near the Fermi surface, which may play a role in the enormous electron-electron scattering in this material evidenced by the large Kadowaki-Woods ratio.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1570005

Journal Information:: Physical Review Materials, Journal Name: Physical Review Materials Journal Issue: 10 Vol. 3; ISSN PRMHAR; ISSN 2475-9953

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

References (54)

Intermetallische Verbindungen Zintl, E. Angewandte Chemie, Vol. 52, Issue 1 https://doi.org/10.1002/ange.19390520102	journal	January 1939
CoBi ₃ : A Binary Cobalt-Bismuth Compound and Superconductor Schwarz, Ulrich; Tencé, Sophie; Janson, Oleg Angewandte Chemie International Edition, Vol. 52, Issue 37 https://doi.org/10.1002/anie.201302397	journal	July 2013
ɛ-TiO, a Novel Stable Polymorph of Titanium Monoxide Amano, Shinsaku; Bogdanovski, Dimitri; Yamane, Hisanori Angewandte Chemie International Edition, Vol. 55, Issue 5 https://doi.org/10.1002/anie.201510479	journal	December 2015
Discovery of a Superconducting Cu-Bi Intermetallic Compound by High-Pressure Synthesis Clarke, Samantha M.; Walsh, James P. S.; Amsler, Maximilian Angewandte Chemie International Edition, Vol. 55, Issue 43 https://doi.org/10.1002/anie.201605902	journal	September 2016
Synthesis, Crystal and Electronic Structure of the Titanium Bismuthides Sr ₅ Ti ₁₂ Bi _{19+ x} , Ba ₅ Ti ₁₂ Bi _{19+ x} , and Sr _5- _δ Eu _δ Ti ₁₂ Bi _{19+ x} ( x ≈ 0.5-1.0; δ ≈ 2.4, 4.0) : Synthesis, Crystal and Electronic Structure of the Titanium Bismuthides Sr5Ti12Bi19+x, Ba5Ti12Bi19+x, and Sr5-δEuδTi12Bi19+x (x ≈ 0.5-1.0; δ ≈ 2.4, 4. Ovchinnikov, Alexander; Bobev, Svilen European Journal of Inorganic Chemistry, Vol. 2018, Issue 11 https://doi.org/10.1002/ejic.201701426	journal	March 2018
Reaction of Ti and Ti-Al alloys with alumina Misra, Ajay K. Metallurgical Transactions A, Vol. 22, Issue 3 https://doi.org/10.1007/BF02670294	journal	March 1991
Universal relationship of the resistivity and specific heat in heavy-Fermion compounds Kadowaki, K.; Woods, S. B. Solid State Communications, Vol. 58, Issue 8 https://doi.org/10.1016/0038-1098(86)90785-4	journal	May 1986
Anisotropic magnetization and resistivity of single crystalline RNi1−xBi2±y (R=La–Nd, Sm, Gd–Dy) Lin, Xiao; Straszheim, Warren E.; Bud’ko, Sergey L. Journal of Alloys and Compounds, Vol. 554 https://doi.org/10.1016/j.jallcom.2012.11.138	journal	March 2013
Ba5Ti12Sb19+x, a polar intermetallic compound with a stuffed γ-brass structure Bie, Haiying; Mar, Arthur Journal of Solid State Chemistry, Vol. 182, Issue 11 https://doi.org/10.1016/j.jssc.2009.08.030	journal	November 2009
Structure and magnetic properties of the REAuBi2 (RE=La–Nd, Sm) phases Seibel, Elizabeth M.; Xie, Weiwei; Gibson, Quinn D. Journal of Solid State Chemistry, Vol. 230 https://doi.org/10.1016/j.jssc.2015.07.013	journal	October 2015
Magnetic Properties of the RAuBi2 (R = Ce, Pr, Nd, Gd, Sm) Series of Intermetallic Compounds Jesus, C. B. R.; Piva, M. M.; Rosa, P. F. S. Physics Procedia, Vol. 75 https://doi.org/10.1016/j.phpro.2015.12.079	journal	January 2015
Discovery of FeBi ₂ Walsh, James P. S.; Clarke, Samantha M.; Meng, Yue ACS Central Science, Vol. 2, Issue 11 https://doi.org/10.1021/acscentsci.6b00287	journal	October 2016
Atomic Interactions in the p-Type Clathrate I Ba ₈ Au _5.3 Ge _40.7 Zhang, Hui; Borrmann, Horst; Oeschler, Niels Inorganic Chemistry, Vol. 50, Issue 4 https://doi.org/10.1021/ic1016559	journal	February 2011
A Hydrogen Clathrate Hydrate with Cyclohexanone: Structure and Stability Strobel, Timothy A.; Hester, Keith C.; Sloan, E. Dendy Journal of the American Chemical Society, Vol. 129, Issue 31 https://doi.org/10.1021/ja072074h	journal	August 2007
Topologically protected surface states in a centrosymmetric superconductor β-PdBi2 Sakano, M.; Okawa, K.; Kanou, M. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9595	journal	October 2015
A unified explanation of the Kadowaki–Woods ratio in strongly correlated metals Jacko, A. C.; Fjærestad, J. O.; Powell, B. J. Nature Physics, Vol. 5, Issue 6 https://doi.org/10.1038/nphys1249	journal	April 2009
Temperature−field phase diagram of extreme magnetoresistance Fallah Tafti, Fazel; Gibson, Quinn; Kushwaha, Satya Proceedings of the National Academy of Sciences, Vol. 113, Issue 25 https://doi.org/10.1073/pnas.1607319113	journal	June 2016
A technique for relativistic spin-polarised calculations Koelling, D. D.; Harmon, B. N. Journal of Physics C: Solid State Physics, Vol. 10, Issue 16 https://doi.org/10.1088/0022-3719/10/16/019	journal	August 1977
Superconducting properties of BaBi ₃ Haldolaarachchige, Neel; Kushwaha, S. K.; Gibson, Quinn Superconductor Science and Technology, Vol. 27, Issue 10 https://doi.org/10.1088/0953-2048/27/10/105001	journal	August 2014
Superconducting properties and electronic structure of NaBi Kushwaha, S. K.; Krizan, J. W.; Xiong, J. Journal of Physics: Condensed Matter, Vol. 26, Issue 21 https://doi.org/10.1088/0953-8984/26/21/212201	journal	May 2014
Large magnetoresistance in LaBi: origin of field-induced resistivity upturn and plateau in compensated semimetals Sun, Shanshan; Wang, Qi; Guo, Peng-Jie New Journal of Physics, Vol. 18, Issue 8 https://doi.org/10.1088/1367-2630/18/8/082002	journal	August 2016
Ab initio molecular dynamics for open-shell transition metals Kresse, G.; Hafner, J. Physical Review B, Vol. 48, Issue 17 https://doi.org/10.1103/PhysRevB.48.13115	journal	November 1993
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Resistivity studies under hydrostatic pressure on a low-resistance variant of the quasi-two-dimensional organic superconductor κ − ( BEDT − TTF ) 2 Cu [ N ( C N ) 2 ] Br : Search for intrinsic scattering contributions Strack, Ch.; Akinci, C.; Pashchenko, V. Physical Review B, Vol. 72, Issue 5 https://doi.org/10.1103/PhysRevB.72.054511	journal	August 2005
Layered transition-metal pnictide SrMnBi 2 with metallic blocking layer Wang, Jiakui K.; Zhao, Liang L.; Yin, Quan Physical Review B, Vol. 84, Issue 6 https://doi.org/10.1103/PhysRevB.84.064428	journal	August 2011
Quantum transport of two-dimensional Dirac fermions in SrMnBi 2 Wang, Kefeng; Graf, D.; Lei, Hechang Physical Review B, Vol. 84, Issue 22 https://doi.org/10.1103/PhysRevB.84.220401	journal	December 2011
Two-dimensional Dirac fermions and quantum magnetoresistance in CaMnBi 2 Wang, Kefeng; Graf, D.; Wang, Limin Physical Review B, Vol. 85, Issue 4 https://doi.org/10.1103/PhysRevB.85.041101	journal	January 2012
Dirac semimetal and topological phase transitions in A 3 Bi ( A = Na , K, Rb) Wang, Zhijun; Sun, Yan; Chen, Xing-Qiu Physical Review B, Vol. 85, Issue 19 https://doi.org/10.1103/PhysRevB.85.195320	journal	May 2012
Surface-induced magnetic fluctuations in a single-crystal NiBi 3 superconductor Zhu, Xiangde; Lei, Hechang; Petrovic, Cedomir Physical Review B, Vol. 86, Issue 2 https://doi.org/10.1103/PhysRevB.86.024527	journal	July 2012
Quasi-two-dimensional Dirac fermions and quantum magnetoresistance in LaAgBi 2 Wang, Kefeng; Graf, D.; Petrovic, C. Physical Review B, Vol. 87, Issue 23 https://doi.org/10.1103/PhysRevB.87.235101	journal	June 2013
Superconductivity and strong intrinsic defects in LaPd 1 − x Bi 2 Han, Fei; Malliakas, Christos D.; Stoumpos, Constantinos C. Physical Review B, Vol. 88, Issue 14 https://doi.org/10.1103/PhysRevB.88.144511	journal	October 2013
Superconductivity in the intermetallic pnictide compound Ca 11 Bi 10 − x Sturza, Mihai; Han, Fei; Malliakas, Christos D. Physical Review B, Vol. 89, Issue 5 https://doi.org/10.1103/PhysRevB.89.054512	journal	February 2014
Superconductivity and role of pnictogen and Fe substitution in 112- LaPd x P n 2 ( P n = Sb , Bi ) Retzlaff, Reiner; Buckow, Alexander; Komissinskiy, Philipp Physical Review B, Vol. 91, Issue 10 https://doi.org/10.1103/PhysRevB.91.104519	journal	March 2015
Antiferromagnetic Kondo lattice in the layered compound CePd 1 − x Bi 2 and comparison to the superconductor LaPd 1 − x Bi 2 Han, Fei; Wan, Xiangang; Phelan, Daniel Physical Review B, Vol. 92, Issue 4 https://doi.org/10.1103/PhysRevB.92.045112	journal	July 2015
Electron-hole asymmetry, Dirac fermions, and quantum magnetoresistance in BaMnBi 2 Li, Lijun; Wang, Kefeng; Graf, D. Physical Review B, Vol. 93, Issue 11 https://doi.org/10.1103/PhysRevB.93.115141	journal	March 2016
Observation of pseudo-two-dimensional electron transport in the rock salt-type topological semimetal LaBi Kumar, Nitesh; Shekhar, Chandra; Wu, Shu-Chun Physical Review B, Vol. 93, Issue 24 https://doi.org/10.1103/PhysRevB.93.241106	journal	June 2016
Strongly Correlated Superconductivity in Rh 17 S 15 Naren, H. R.; Thamizhavel, A.; Nigam, A. K. Physical Review Letters, Vol. 100, Issue 2 https://doi.org/10.1103/PhysRevLett.100.026404	journal	January 2008
Fully Band-Resolved Scattering Rate in MgB 2 Revealed by the Nonlinear Hall Effect and Magnetoresistance Measurements Yang, Huan; Liu, Yi; Zhuang, Chenggang Physical Review Letters, Vol. 101, Issue 6 https://doi.org/10.1103/PhysRevLett.101.067001	journal	August 2008
Anisotropic Dirac Fermions in a Bi Square Net of SrMnBi 2 Park, Joonbum; Lee, G.; Wolff-Fabris, F. Physical Review Letters, Vol. 107, Issue 12 https://doi.org/10.1103/PhysRevLett.107.126402	journal	September 2011
Kapellasite: A Kagome Quantum Spin Liquid with Competing Interactions Fåk, B.; Kermarrec, E.; Messio, L. Physical Review Letters, Vol. 109, Issue 3 https://doi.org/10.1103/PhysRevLett.109.037208	journal	July 2012
Electron-Electron Scattering in Transition Metals Rice, M. J. Physical Review Letters, Vol. 20, Issue 25 https://doi.org/10.1103/PhysRevLett.20.1439	journal	June 1968
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
LiV 2 O 4 Spinel as a Heavy-Mass Fermi Liquid: Anomalous Transport and Role of Geometrical Frustration Urano, C.; Nohara, M.; Kondo, S. Physical Review Letters, Vol. 85, Issue 5 https://doi.org/10.1103/PhysRevLett.85.1052	journal	July 2000
Giant Electron-Electron Scattering in the Fermi-Liquid State of N a 0.7 C o O 2 Li, S. Y.; Taillefer, Louis; Hawthorn, D. G. Physical Review Letters, Vol. 93, Issue 5 https://doi.org/10.1103/PhysRevLett.93.056401	journal	July 2004
Anomalous Pressure Dependence of the Kadowaki-Woods Ratio and Crystal-Field Effects in Mixed-Valence YbInCu 4 Park, Tuson; Sidorov, V. A.; Sarrao, J. L. Physical Review Letters, Vol. 96, Issue 4 https://doi.org/10.1103/PhysRevLett.96.046405	journal	January 2006
Large Anisotropic Normal-State Magnetoresistance in Clean MgB 2 Thin Films Li, Qi; Liu, B. T.; Hu, Y. F. Physical Review Letters, Vol. 96, Issue 16 https://doi.org/10.1103/PhysRevLett.96.167003	journal	April 2006
Disordered electronic systems Lee, Patrick A.; Ramakrishnan, T. V. Reviews of Modern Physics, Vol. 57, Issue 2 https://doi.org/10.1103/RevModPhys.57.287	journal	April 1985
Colloquium: Topological insulators Hasan, M. Z.; Kane, C. L. Reviews of Modern Physics, Vol. 82, Issue 4, p. 3045-3067 https://doi.org/10.1103/RevModPhys.82.3045	journal	November 2010
Topological insulators and superconductors Qi, Xiao-Liang; Zhang, Shou-Cheng Reviews of Modern Physics, Vol. 83, Issue 4 https://doi.org/10.1103/RevModPhys.83.1057	journal	October 2011
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
Topological R PdBi half-Heusler semimetals: A new family of noncentrosymmetric magnetic superconductors Nakajima, Yasuyuki; Hu, Rongwei; Kirshenbaum, Kevin Science Advances, Vol. 1, Issue 5 https://doi.org/10.1126/sciadv.1500242	journal	June 2015
Discovery of a Three-Dimensional Topological Dirac Semimetal, Na3Bi Liu, Z. K.; Zhou, B.; Zhang, Y. Science, Vol. 343, Issue 6173 https://doi.org/10.1126/science.1245085	journal	January 2014
Observation of Fermi arc surface states in a topological metal Xu, S. -Y.; Liu, C.; Kushwaha, S. K. Science, Vol. 347, Issue 6219 https://doi.org/10.1126/science.1256742	journal	December 2014
Universal linear-temperature dependence of static magnetic susceptibility in iron pnictides Zhang, G. M.; Su, Y. H.; Lu, Z. Y. EPL (Europhysics Letters), Vol. 86, Issue 3 https://doi.org/10.1209/0295-5075/86/37006	journal	May 2009

Cited By (1)

Exploration of Multi-Component Vanadium and Titanium Pnictides Using Flux Growth and Conventional High-Temperature Methods Ovchinnikov, Alexander; Bobev, Svilen Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00909	journal	January 2020

Similar Records

Local structure in

BaTi O_{3} - BiSc O_{3}

dipole glasses

Journal Article · 2016 · Physical Review B · OSTI ID:1344890

Levin, I.; Krayzman, V.; Woicik, J. C.; +5 more

Electric field dependent local structure of

{(K_{x} N a_{1 - x})}_{0.5} B i_{0.5} Ti O_{3}

Journal Article · 2017 · Physical Review B · OSTI ID:1376340

Goetzee-Barral, A. J.; Usher, T. -M.; Stevenson, T. J.; +4 more

Tunable inverse topological heterostructure utilizing

{(B i_{1 - x} I n_{x})}_{2} S e_{3}

and multichannel weak-antilocalization effect

Journal Article · 2016 · Physical Review B · OSTI ID:1248807

Brahlek, Matthew J.; Koirala, Nikesh; Liu, Jianpeng; +6 more

Related Subjects

36 MATERIALS SCIENCE
Crystal growth
Electrical properties
Magnetization measurements
Resistivity measurements

Title: Enormous electron-electron scattering in the filled-cage cubic compound B a 10 T i 24 B i 39

Citation Formats

References (54)

Cited By (1)

Similar Records

Related Subjects

Title: Enormous electron-electron scattering in the filled-cage cubic compound $B a_{10} T i_{24} B i_{39}$