A Simple Electrode-Level Chemical Presodiation Route by Solution Spraying to Improve the Energy Density of Sodium-Ion Batteries
Abstract
The formation of a solid electrolyte interface (SEI) on the surface of a carbon anode consumes the active sodium ions from the cathode and reduces the energy density of sodium-ion batteries (SIBs). In this work, a simple electrode-level presodiation strategy by spraying a sodium naphthaline (Naph-Na) solution onto a carbon electrode is reported, which compensates the initial sodium loss and improves the energy density of SIBs. After presodiation, an SEI layer is preformed on the surface of carbon anode before battery cycling. It is shown that a large irreversible capacity of 60 mAh g–1 is replenished and 20% increase of the first-cycle Coulombic efficiency is achieved for a hard carbon anode using this presodiation strategy, and the energy density of a Na0.9[Cu0.22Fe0.30Mn0.48]O2||carbon full cell is increased from 141 to 240 Wh kg–1 by using the presodiated carbon anode. This simple and scalable electrode-level chemical presodiation route also shows generality and value for the presodiation of other anodes in SIBs.
- Authors:
-
[1]
- Huazhong Univ. of Science and Technology, Wuhan (China)
- Argonne National Lab. (ANL), Argonne, IL (United States); Peking Univ., Shenzhen (China)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; National Natural Science Foundation of China (NSFC); China Postdoctoral Science Foundation
- OSTI Identifier:
- 1763888
- Alternate Identifier(s):
- OSTI ID: 1569774
- Grant/Contract Number:
- AC02-06CH11357; 51802105; 0106187114
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Volume: 29; Journal Issue: 50; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; carbon anodes; presodiation; electrode level; solution spraying; sodium-ion batteries
Citation Formats
Liu, Xiaoxiao, Tan, Yuchen, Liu, Tongchao, Wang, Wenyu, Li, Chunhao, Lu, Jun, and Sun, Yongming. A Simple Electrode-Level Chemical Presodiation Route by Solution Spraying to Improve the Energy Density of Sodium-Ion Batteries. United States: N. p., 2019.
Web. doi:10.1002/adfm.201903795.
Liu, Xiaoxiao, Tan, Yuchen, Liu, Tongchao, Wang, Wenyu, Li, Chunhao, Lu, Jun, & Sun, Yongming. A Simple Electrode-Level Chemical Presodiation Route by Solution Spraying to Improve the Energy Density of Sodium-Ion Batteries. United States. https://doi.org/10.1002/adfm.201903795
Liu, Xiaoxiao, Tan, Yuchen, Liu, Tongchao, Wang, Wenyu, Li, Chunhao, Lu, Jun, and Sun, Yongming. Tue .
"A Simple Electrode-Level Chemical Presodiation Route by Solution Spraying to Improve the Energy Density of Sodium-Ion Batteries". United States. https://doi.org/10.1002/adfm.201903795. https://www.osti.gov/servlets/purl/1763888.
@article{osti_1763888,
title = {A Simple Electrode-Level Chemical Presodiation Route by Solution Spraying to Improve the Energy Density of Sodium-Ion Batteries},
author = {Liu, Xiaoxiao and Tan, Yuchen and Liu, Tongchao and Wang, Wenyu and Li, Chunhao and Lu, Jun and Sun, Yongming},
abstractNote = {The formation of a solid electrolyte interface (SEI) on the surface of a carbon anode consumes the active sodium ions from the cathode and reduces the energy density of sodium-ion batteries (SIBs). In this work, a simple electrode-level presodiation strategy by spraying a sodium naphthaline (Naph-Na) solution onto a carbon electrode is reported, which compensates the initial sodium loss and improves the energy density of SIBs. After presodiation, an SEI layer is preformed on the surface of carbon anode before battery cycling. It is shown that a large irreversible capacity of 60 mAh g–1 is replenished and 20% increase of the first-cycle Coulombic efficiency is achieved for a hard carbon anode using this presodiation strategy, and the energy density of a Na0.9[Cu0.22Fe0.30Mn0.48]O2||carbon full cell is increased from 141 to 240 Wh kg–1 by using the presodiated carbon anode. This simple and scalable electrode-level chemical presodiation route also shows generality and value for the presodiation of other anodes in SIBs.},
doi = {10.1002/adfm.201903795},
journal = {Advanced Functional Materials},
number = 50,
volume = 29,
place = {United States},
year = {Tue Oct 08 00:00:00 EDT 2019},
month = {Tue Oct 08 00:00:00 EDT 2019}
}
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Works referencing / citing this record:
Chemically Prelithiated Hard‐Carbon Anode for High Power and High Capacity Li‐Ion Batteries
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