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Title: In situ transformation of hydraulic fracturing surfactants from well injection to produced water

Abstract

Chemical changes to hydraulic fracturing fluids within fractured unconventional reservoirs may affect hydrocarbon recovery and, in turn, the environmental impact of unconventional oil and gas development.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4]
  1. National Energy Technology Laboratory, United States Department of Energy, Pittsburgh, USA, Oak Ridge Institute for Science and Education
  2. Department of Civil and Environmental Engineering, Colorado State University, Fort Collins, USA
  3. Department of Civil and Environmental Engineering, Colorado State University, Fort Collins, USA, Department of Chemistry
  4. National Energy Technology Laboratory, United States Department of Energy, Pittsburgh, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Fossil Energy (FE), Oil and Natural Gas (FE-30)
OSTI Identifier:
1569496
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Environmental Science: Processes & Impacts
Additional Journal Information:
Journal Name: Environmental Science: Processes & Impacts Journal Volume: 21 Journal Issue: 10; Journal ID: ISSN 2050-7887
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

McAdams, Brandon C., Carter, Kimberly E., Blotevogel, Jens, Borch, Thomas, and Hakala, J. Alexandra. In situ transformation of hydraulic fracturing surfactants from well injection to produced water. United Kingdom: N. p., 2019. Web. doi:10.1039/C9EM00153K.
McAdams, Brandon C., Carter, Kimberly E., Blotevogel, Jens, Borch, Thomas, & Hakala, J. Alexandra. In situ transformation of hydraulic fracturing surfactants from well injection to produced water. United Kingdom. doi:10.1039/C9EM00153K.
McAdams, Brandon C., Carter, Kimberly E., Blotevogel, Jens, Borch, Thomas, and Hakala, J. Alexandra. Wed . "In situ transformation of hydraulic fracturing surfactants from well injection to produced water". United Kingdom. doi:10.1039/C9EM00153K.
@article{osti_1569496,
title = {In situ transformation of hydraulic fracturing surfactants from well injection to produced water},
author = {McAdams, Brandon C. and Carter, Kimberly E. and Blotevogel, Jens and Borch, Thomas and Hakala, J. Alexandra},
abstractNote = {Chemical changes to hydraulic fracturing fluids within fractured unconventional reservoirs may affect hydrocarbon recovery and, in turn, the environmental impact of unconventional oil and gas development.},
doi = {10.1039/C9EM00153K},
journal = {Environmental Science: Processes & Impacts},
number = 10,
volume = 21,
place = {United Kingdom},
year = {2019},
month = {10}
}

Journal Article:
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This content will become publicly available on October 2, 2020
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Works referenced in this record:

Physical, chemical, and biological characteristics of compounds used in hydraulic fracturing
journal, June 2014


Spatial and Temporal Correlation of Water Quality Parameters of Produced Waters from Devonian-Age Shale following Hydraulic Fracturing
journal, February 2013

  • Barbot, Elise; Vidic, Natasa S.; Gregory, Kelvin B.
  • Environmental Science & Technology, Vol. 47, Issue 6
  • DOI: 10.1021/es304638h

A critical review of water uptake by shales
journal, August 2016


Biodegradation Mechanisms of Linear Alcohol Ethoxylates under Anaerobic Conditions
journal, May 2000

  • Huber, Martin; Meyer, Ulrich; Rys, Paul
  • Environmental Science & Technology, Vol. 34, Issue 9
  • DOI: 10.1021/es9903680

Environmental Safety of the Use of Major Surfactant Classes in North America
journal, July 2014

  • Cowan-Ellsberry, Christina; Belanger, Scott; Dorn, Philip
  • Critical Reviews in Environmental Science and Technology, Vol. 44, Issue 17
  • DOI: 10.1080/10739149.2013.803777

Experimental investigation of the effect of imbibition on shale permeability during hydraulic fracturing
journal, February 2016


A Critical Review of the Risks to Water Resources from Unconventional Shale Gas Development and Hydraulic Fracturing in the United States
journal, March 2014

  • Vengosh, Avner; Jackson, Robert B.; Warner, Nathaniel
  • Environmental Science & Technology, Vol. 48, Issue 15
  • DOI: 10.1021/es405118y

Characterization of hydraulic fracturing flowback water in Colorado: Implications for water treatment
journal, April 2015


Organic substances in produced and formation water from unconventional natural gas extraction in coal and shale
journal, June 2014


Fracture stimulation fundamentals
journal, September 2012


Ecosystem services lost to oil and gas in North America
journal, April 2015


Predicting the sorption of fatty alcohols and alcohol ethoxylates to effluent and receiving water solids
journal, May 2006

  • van Compernolle, R.; McAvoy, D. C.; Sherren, A.
  • Ecotoxicology and Environmental Safety, Vol. 64, Issue 1
  • DOI: 10.1016/j.ecoenv.2005.10.013

Microbial metabolisms in a 2.5-km-deep ecosystem created by hydraulic fracturing in shales
journal, September 2016


Effect of Surfactant Adsorption on the Wettability Alteration of Gas-Bearing Shales
journal, October 2016

  • Zhou, Letian; Das, Saikat; Ellis, Brian R.
  • Environmental Engineering Science, Vol. 33, Issue 10
  • DOI: 10.1089/ees.2016.0003

Identification of polypropylene glycols and polyethylene glycol carboxylates in flowback and produced water from hydraulic fracturing
journal, February 2017


Element release and reaction-induced porosity alteration during shale-hydraulic fracturing fluid interactions
journal, July 2017


Chemical Degradation of Polyacrylamide during Hydraulic Fracturing
journal, December 2017

  • Xiong, Boya; Miller, Zachary; Roman-White, Selina
  • Environmental Science & Technology, Vol. 52, Issue 1
  • DOI: 10.1021/acs.est.7b00792

Shale Gas Well, Hydraulic Fracturing, and Formation Data to Support Modeling of Gas and Water Flow in Shale Formations
journal, April 2018

  • Edwards, Ryan W. J.; Celia, Michael A.
  • Water Resources Research, Vol. 54, Issue 4
  • DOI: 10.1002/2017wr022130

Development, Land Use, and Collective Trauma: The Marcellus Shale Gas Boom in Rural Pennsylvania
journal, June 2012


Chain-Cleavage and hydrolysis of activated polyethylene glycol derivatives: Evidence for competitive processes
journal, November 1990

  • Mcmanus, S. P.; Karaman, R. M.; Sedaghat-Herati, M. R.
  • Journal of Polymer Science Part A: Polymer Chemistry, Vol. 28, Issue 12
  • DOI: 10.1002/pola.1990.080281213

The Effects of Shale Gas Exploration and Hydraulic Fracturing on the Quality of Water Resources in the United States
journal, January 2013


Aerobic biodegradation of organic compounds in hydraulic fracturing fluids
journal, June 2015


Experimental insights into geochemical changes in hydraulically fractured Marcellus Shale
journal, January 2017


In situ transformation of ethoxylate and glycol surfactants by shale-colonizing microorganisms during hydraulic fracturing
journal, June 2019


Indications of Transformation Products from Hydraulic Fracturing Additives in Shale-Gas Wastewater
journal, July 2016

  • Hoelzer, Kathrin; Sumner, Andrew J.; Karatum, Osman
  • Environmental Science & Technology, Vol. 50, Issue 15
  • DOI: 10.1021/acs.est.6b00430

Temporal Changes in Microbial Ecology and Geochemistry in Produced Water from Hydraulically Fractured Marcellus Shale Gas Wells
journal, May 2014

  • Cluff, Maryam A.; Hartsock, Angela; MacRae, Jean D.
  • Environmental Science & Technology, Vol. 48, Issue 11
  • DOI: 10.1021/es501173p

Physical-chemical evaluation of hydraulic fracturing chemicals in the context of produced water treatment
journal, December 2016

  • Camarillo, Mary Kay; Domen, Jeremy K.; Stringfellow, William T.
  • Journal of Environmental Management, Vol. 183
  • DOI: 10.1016/j.jenvman.2016.08.065

Comparative genomics and physiology of the genus Methanohalophilus , a prevalent methanogen in hydraulically fractured shale
journal, December 2018

  • Borton, Mikayla A.; Daly, Rebecca A.; O'Banion, Bridget
  • Environmental Microbiology, Vol. 20, Issue 12
  • DOI: 10.1111/1462-2920.14467

Trace metal distribution and mobility in drill cuttings and produced waters from Marcellus Shale gas extraction: Uranium, arsenic, barium
journal, September 2015


Redox Conditions Alter Biodegradation Rates and Microbial Community Dynamics of Hydraulic Fracturing Fluid Organic Additives in Soil–Groundwater Microcosms
journal, October 2016

  • Mouser, Paula J.; Liu, Shuai; Cluff, Maryam A.
  • Environmental Engineering Science, Vol. 33, Issue 10
  • DOI: 10.1089/ees.2016.0031

Oxide Surface-Catalyzed Hydrolysis of Carboxylate Esters and Phosphorothioate Esters
journal, January 1994


Behavior of aliphatic alcohol polyethoxylates and their metabolites under standardized aerobic biodegradation conditions
journal, March 2000

  • Marcomini, Antonio; Zanette, Mauro; Pojana, Giulio
  • Environmental Toxicology and Chemistry, Vol. 19, Issue 3
  • DOI: 10.1002/etc.5620190305

Produced Water Exposure Alters Bacterial Response to Biocides
journal, October 2014

  • Vikram, Amit; Lipus, Daniel; Bibby, Kyle
  • Environmental Science & Technology, Vol. 48, Issue 21
  • DOI: 10.1021/es5036915

Adsorption of surfactants on minerals for wettability control in improved oil recovery processes
journal, June 2006


Organic Chemical Characterization and Mass Balance of a Hydraulically Fractured Well: From Fracturing Fluid to Produced Water over 405 Days
journal, November 2017

  • Rosenblum, James; Thurman, E. Michael; Ferrer, Imma
  • Environmental Science & Technology, Vol. 51, Issue 23
  • DOI: 10.1021/acs.est.7b03362

Temporal analysis of flowback and produced water composition from shale oil and gas operations: Impact of frac fluid characteristics
journal, November 2016

  • Kim, Seongyun; Omur-Ozbek, Pinar; Dhanasekar, Ashwin
  • Journal of Petroleum Science and Engineering, Vol. 147
  • DOI: 10.1016/j.petrol.2016.06.019

An Improved Approach for Forecasting Ecological Impacts from Future Drilling in Unconventional Shale Oil and Gas Plays
journal, April 2018

  • Wolaver, Brad D.; Pierre, Jon Paul; Ikonnikova, Svetlana A.
  • Environmental Management, Vol. 62, Issue 2
  • DOI: 10.1007/s00267-018-1042-5

Comparison of biodegradation of poly(ethylene glycol)s and poly(propylene glycol)s
journal, July 2006


Aerobic biodegradation of monobranched aliphatic alcohol polyethoxylates
journal, March 2000

  • Marcomini, Antonio; Pojana, Giulio; Carrer, Claudio
  • Environmental Toxicology and Chemistry, Vol. 19, Issue 3
  • DOI: 10.1002/etc.5620190306

Organic geochemistry and toxicology of a stream impacted by unconventional oil and gas wastewater disposal operations
journal, May 2017


Spills of Hydraulic Fracturing Chemicals on Agricultural Topsoil: Biodegradation, Sorption, and Co-contaminant Interactions
journal, May 2016

  • McLaughlin, Molly C.; Borch, Thomas; Blotevogel, Jens
  • Environmental Science & Technology, Vol. 50, Issue 11
  • DOI: 10.1021/acs.est.6b00240

A Mass Scale Based on CH 2 = 14.0000 for High Resolution Mass Spectrometry of Organic Compounds.
journal, December 1963


Natural Gas Residual Fluids: Sources, Endpoints, and Organic Chemical Composition after Centralized Waste Treatment in Pennsylvania
journal, July 2015

  • Getzinger, Gordon J.; O’Connor, Megan P.; Hoelzer, Kathrin
  • Environmental Science & Technology, Vol. 49, Issue 14
  • DOI: 10.1021/acs.est.5b00471

Hybrid membrane bio-systems for sustainable treatment of oil and gas produced water and fracturing flowback water
journal, October 2016

  • Riley, Stephanie M.; Oliveira, Jean M. S.; Regnery, Julia
  • Separation and Purification Technology, Vol. 171
  • DOI: 10.1016/j.seppur.2016.07.008

Nonylphenol in the environment: A critical review on occurrence, fate, toxicity and treatment in wastewaters
journal, October 2008


Microbial Community Changes in Hydraulic Fracturing Fluids and Produced Water from Shale Gas Extraction
journal, October 2013

  • Murali Mohan, Arvind; Hartsock, Angela; Bibby, Kyle J.
  • Environmental Science & Technology, Vol. 47, Issue 22
  • DOI: 10.1021/es402928b

Chemical constituents and analytical approaches for hydraulic fracturing waters
journal, February 2015


Viruses control dominant bacteria colonizing the terrestrial deep biosphere after hydraulic fracturing
journal, December 2018


Degradation of Alkylphenol Ethoxylate Surfactants in Water with Ultrasonic Irradiation
journal, January 2000

  • Destaillats, Hugo; Hung, Hui-Ming; Hoffmann, Michael R.
  • Environmental Science & Technology, Vol. 34, Issue 2
  • DOI: 10.1021/es990384x

Coupled laboratory and field investigations resolve microbial interactions that underpin persistence in hydraulically fractured shales
journal, June 2018

  • Borton, Mikayla A.; Hoyt, David W.; Roux, Simon
  • Proceedings of the National Academy of Sciences, Vol. 115, Issue 28
  • DOI: 10.1073/pnas.1800155115

Quantitative Survey and Structural Classification of Hydraulic Fracturing Chemicals Reported in Unconventional Gas Production
journal, March 2016

  • Elsner, Martin; Hoelzer, Kathrin
  • Environmental Science & Technology, Vol. 50, Issue 7
  • DOI: 10.1021/acs.est.5b02818

Effect of Anionic Surfactant on Wettability of Shale and Its Implication on Gas Adsorption/Desorption Behavior
journal, January 2018


Impact of Organics and Carbonates on the Oxidation and Precipitation of Iron during Hydraulic Fracturing of Shale
journal, March 2017


Numerical Modeling of Gas and Water Flow in Shale Gas Formations with a Focus on the Fate of Hydraulic Fracturing Fluid
journal, November 2017

  • Edwards, Ryan W. J.; Doster, Florian; Celia, Michael A.
  • Environmental Science & Technology, Vol. 51, Issue 23
  • DOI: 10.1021/acs.est.7b03270

Analysis of Hydraulic Fracturing Flowback and Produced Waters Using Accurate Mass: Identification of Ethoxylated Surfactants
journal, September 2014

  • Thurman, E. Michael; Ferrer, Imma; Blotevogel, Jens
  • Analytical Chemistry, Vol. 86, Issue 19
  • DOI: 10.1021/ac502163k

Mineral Reactions in Shale Gas Reservoirs: Barite Scale Formation from Reusing Produced Water As Hydraulic Fracturing Fluid
journal, July 2017

  • Paukert Vankeuren, Amelia N.; Hakala, J. Alexandra; Jarvis, Karl
  • Environmental Science & Technology, Vol. 51, Issue 16
  • DOI: 10.1021/acs.est.7b01979

Natural Attenuation of Nonionic Surfactants Used in Hydraulic Fracturing Fluids: Degradation Rates, Pathways, and Mechanisms
journal, November 2017

  • Heyob, Katie M.; Blotevogel, Jens; Brooker, Michael
  • Environmental Science & Technology, Vol. 51, Issue 23
  • DOI: 10.1021/acs.est.7b01539

Advanced liquid chromatography-mass spectrometry (LC-MS) methods applied to wastewater removal and the fate of surfactants in the environment
journal, February 2007

  • González, Susana; Barceló, Damià; Petrovic, Mira
  • TrAC Trends in Analytical Chemistry, Vol. 26, Issue 2
  • DOI: 10.1016/j.trac.2006.12.003

Temporal characterization and statistical analysis of flowback and produced waters and their potential for reuse
journal, April 2018


Chemical reactions of organic compounds on clay surfaces.
journal, November 1989


Potential of Improving Oil Recovery with Surfactant Additives to Completion Fluids for the Bakken
journal, May 2017


Watershed-Scale Impacts from Surface Water Disposal of Oil and Gas Wastewater in Western Pennsylvania
journal, July 2017

  • Burgos, William D.; Castillo-Meza, Luis; Tasker, Travis L.
  • Environmental Science & Technology, Vol. 51, Issue 15
  • DOI: 10.1021/acs.est.7b01696

Aerobic biodegradation of polyethylene glycols of different molecular weights in wastewater and seawater
journal, December 2008