Colloidal plasmonic nanostar antennas with wide range resonance tunability

doi:10.1039/C9NR06533D

Title: Colloidal plasmonic nanostar antennas with wide range resonance tunability

Abstract

Gold nanostars with six branches and high shape anisotropy can be optically modeled and synthesized with high monodispersity providing a truly tridimensional plasmonic nanoantenna.

Authors:

Tsoulos, Ted V. ^[1]; Atta, Supriya ^[2];

^[3]; Beetz, Michael ^[4]; Batson, Philip E. ^[5]; Tsilomelekis, George ^[6];

^[1]

Department of Materials Science and Engineering, Rutgers University, Piscataway, USA
Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, USA
Department of Materials Science and Engineering, McMaster University, Ontario L8S 4L7, Canada
Department of Chemistry and Center for NanoScience (CeNS), Ludwig Maximilians Universität München, 81377 Munich, Germany
Department of Materials Science and Engineering, Rutgers University, Piscataway, USA, Department of Physics and Astronomy
Department of Chemical and Biochemical Engineering, Rutgers University, Piscataway, USA

Publication Date:: 2019-10-17

Sponsoring Org.:: USDOE

OSTI Identifier:: 1569300

Grant/Contract Number:: SC0005132

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Nanoscale

Additional Journal Information:: Journal Name: Nanoscale Journal Volume: 11 Journal Issue: 40; Journal ID: ISSN 2040-3364

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Tsoulos, Ted V., Atta, Supriya, Lagos, Maureen J., Beetz, Michael, Batson, Philip E., Tsilomelekis, George, and Fabris, Laura. Colloidal plasmonic nanostar antennas with wide range resonance tunability.  United Kingdom: N. p., 2019. 
        Web.  doi:10.1039/C9NR06533D.

Copy to clipboard


                    Tsoulos, Ted V., Atta, Supriya, Lagos, Maureen J., Beetz, Michael, Batson, Philip E., Tsilomelekis, George, & Fabris, Laura. Colloidal plasmonic nanostar antennas with wide range resonance tunability.  United Kingdom.  doi:10.1039/C9NR06533D.

Copy to clipboard


                    Tsoulos, Ted V., Atta, Supriya, Lagos, Maureen J., Beetz, Michael, Batson, Philip E., Tsilomelekis, George, and Fabris, Laura. Thu .  
        "Colloidal plasmonic nanostar antennas with wide range resonance tunability".  United Kingdom.  doi:10.1039/C9NR06533D.

Copy to clipboard


                    
@article{osti_1569300,

  title        = {Colloidal plasmonic nanostar antennas with wide range resonance tunability},

  author       = {Tsoulos, Ted V. and Atta, Supriya and Lagos, Maureen J. and Beetz, Michael and Batson, Philip E. and Tsilomelekis, George and Fabris, Laura},

  abstractNote = {Gold nanostars with six branches and high shape anisotropy can be optically modeled and synthesized with high monodispersity providing a truly tridimensional plasmonic nanoantenna.},

  doi          = {10.1039/C9NR06533D},

  journal      = {Nanoscale},

  number       = 40,

  volume       = 11,

  place        = {United Kingdom},

  year         = {2019},

  month        = {10}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
DOI: 10.1039/C9NR06533D

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 6 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Orientation of multiwalled carbon nanotubes in composites with polycarbonate by melt spinning
journal, November 2005

Pötschke, Petra; Brünig, Harald; Janke, Andreas
Polymer, Vol. 46, Issue 23
DOI: 10.1016/j.polymer.2005.07.106

TomoJ: tomography software for three-dimensional reconstruction in transmission electron microscopy
journal, January 2007

MessaoudiI, Cédric; Boudier, Thomas; Sorzano, Carlos
BMC Bioinformatics, Vol. 8, Issue 1
DOI: 10.1186/1471-2105-8-288

Spectroelectrochemistry of Silver Deposition on Single Gold Nanocrystals
journal, November 2014

Chirea, Mariana; Collins, Sean S. E.; Wei, Xingzhan
The Journal of Physical Chemistry Letters, Vol. 5, Issue 24
DOI: 10.1021/jz502349x

Glass-forming ability of TeO ₂ and temperature induced changes on the structure of the glassy, supercooled, and molten states
journal, April 2015

Kalampounias, A. G.; Tsilomelekis, G.; Boghosian, S.
The Journal of Chemical Physics, Vol. 142, Issue 15
DOI: 10.1063/1.4917536

Three-Dimensional Self-Assembling of Gold Nanorods with Controlled Macroscopic Shape and Local Smectic B Order
journal, April 2012

Hamon, Cyrille; Postic, Marie; Mazari, Elsa
ACS Nano, Vol. 6, Issue 5
DOI: 10.1021/nn3006027

High Relaxivity Gd(III)–DNA Gold Nanostars: Investigation of Shape Effects on Proton Relaxation
journal, February 2015

Rotz, Matthew W.; Culver, Kayla S. B.; Parigi, Giacomo
ACS Nano, Vol. 9, Issue 3
DOI: 10.1021/nn5070953

Manipulation of the Geometry and Modulation of the Optical Response of Surfactant-Free Gold Nanostars: A Systematic Bottom-Up Synthesis
journal, February 2018

De Silva Indrasekara, Agampodi S.; Johnson, Sean F.; Odion, Ren A.
ACS Omega, Vol. 3, Issue 2
DOI: 10.1021/acsomega.7b01700

TOM software toolbox: acquisition and analysis for electron tomography
journal, March 2005

Nickell, Stephan; Förster, Friedrich; Linaroudis, Alexandros
Journal of Structural Biology, Vol. 149, Issue 3
DOI: 10.1016/j.jsb.2004.10.006

Gold nanostars: surfactant-free synthesis, 3D modelling, and two-photon photoluminescence imaging
journal, January 2012

Yuan, Hsiangkuo; Khoury, Christopher G.; Hwang, Hanjun
Nanotechnology, Vol. 23, Issue 7
DOI: 10.1088/0957-4484/23/7/075102

Nanoantennas for visible and infrared radiation
journal, January 2012

Biagioni, Paolo; Huang, Jer-Shing; Hecht, Bert
Reports on Progress in Physics, Vol. 75, Issue 2
DOI: 10.1088/0034-4885/75/2/024402

Ultralocal Modification of Surface Plasmons Properties in Silver Nanocubes
journal, February 2012

Mazzucco, Stefano; Geuquet, Nicolas; Ye, Jian
Nano Letters, Vol. 12, Issue 3
DOI: 10.1021/nl2037672

A closer look at the physical and optical properties of gold nanostars: an experimental and computational study
journal, January 2017

Tsoulos, T. V.; Han, L.; Weir, J.
Nanoscale, Vol. 9, Issue 11
DOI: 10.1039/C6NR09091E

Surface plasmon modes of a single silver nanorod: an electron energy loss study
journal, January 2011

Nicoletti, Olivia; Wubs, Martijn; Mortensen, N. Asger
Optics Express, Vol. 19, Issue 16
DOI: 10.1364/OE.19.015371

Plasmon Resonances of a Gold Nanostar
journal, March 2007

Hao, Feng; Nehl, Colleen L.; Hafner, Jason H.
Nano Letters, Vol. 7, Issue 3
DOI: 10.1021/nl062969c

Unraveling the role of microenvironment and hydrodynamic forces on the vibrational relaxation rates of pyridine–water complexes
journal, October 2014

Kalampounias, A. G.; Tsilomelekis, G.; Boghosian, S.
Journal of Molecular Liquids, Vol. 198
DOI: 10.1016/j.molliq.2014.07.020

Triton X-100 for three-plasmon gold nanostars with two photothermally active NIR (near IR) and SWIR (short-wavelength IR) channels
journal, January 2013

Pallavicini, Piersandro; Donà, Alice; Casu, Alberto
Chemical Communications, Vol. 49, Issue 56
DOI: 10.1039/c3cc42999g

Discrete tomography of demanding samples based on a modified SIRT algorithm
journal, April 2012

Zürner, Andreas; Döblinger, Markus; Cauda, Valentina
Ultramicroscopy, Vol. 115
DOI: 10.1016/j.ultramic.2012.01.015

Surface Plasmon Damping Quantified with an Electron Nanoprobe
journal, February 2013

Bosman, Michel; Ye, Enyi; Tan, Shu Fen
Scientific Reports, Vol. 3, Issue 1
DOI: 10.1038/srep01312

Harnessing Hot Electrons from Near IR Light for Hydrogen Production Using Pt-End-Capped-AuNRs
journal, July 2017

Ortiz, Nathalia; Zoellner, Brandon; Hong, Soung Joung
ACS Applied Materials & Interfaces, Vol. 9, Issue 31
DOI: 10.1021/acsami.7b05064

Femtosecond laser reshaping yields gold nanorods with ultranarrow surface plasmon resonances
journal, November 2017

González-Rubio, Guillermo; Díaz-Núñez, Pablo; Rivera, Antonio
Science, Vol. 358, Issue 6363
DOI: 10.1126/science.aan8478

Boosting Hot Electron-Driven Photocatalysis through Anisotropic Plasmonic Nanoparticles with Hot Spots in Au–TiO ₂ Nanoarchitectures
journal, May 2016

Sousa-Castillo, Ana; Comesaña-Hermo, Miguel; Rodríguez-González, Benito
The Journal of Physical Chemistry C, Vol. 120, Issue 21
DOI: 10.1021/acs.jpcc.6b02370

Understanding the role of AgNO ₃ concentration and seed morphology in the achievement of tunable shape control in gold nanostars
journal, January 2019

Atta, Supriya; Beetz, Michael; Fabris, Laura
Nanoscale, Vol. 11, Issue 6
DOI: 10.1039/C8NR07615D

Multipole Plasmon Resonances in Gold Nanorods
journal, February 2006

Payne, Emma Kathryn; Shuford, Kevin L.; Park, Sungho
The Journal of Physical Chemistry B, Vol. 110, Issue 5
DOI: 10.1021/jp056606x

Simultaneous observation of the quantization and the interference pattern of a plasmonic near-field
journal, March 2015

Piazza, L.; Lummen, T. T. A.; Quiñonez, E.
Nature Communications, Vol. 6, Issue 1
DOI: 10.1038/ncomms7407

Interface and Bulk Standing Waves Drive the Coupling of Plasmonic Nanostar Antennas
journal, November 2018

Tsoulos, Ted V.; Fabris, Laura
The Journal of Physical Chemistry C, Vol. 122, Issue 50
DOI: 10.1021/acs.jpcc.8b09263

Gold nanostar substrates for SERS-based chemical sensing in the femtomolar regime
journal, January 2014

Indrasekara, A. S. D. S.; Meyers, S.; Shubeita, S.
Nanoscale, Vol. 6, Issue 15
DOI: 10.1039/C4NR02513J

Multiparametric Assessment of Gold Nanoparticle Cytotoxicity in Cancerous and Healthy Cells: The Role of Size, Shape, and Surface Chemistry
journal, December 2016

Bhamidipati, Manjari; Fabris, Laura
Bioconjugate Chemistry, Vol. 28, Issue 2
DOI: 10.1021/acs.bioconjchem.6b00605

Ultrafast Plasmon Propagation in Nanowires Characterized by Far-Field Spectral Interferometry
journal, December 2011

Rewitz, Christian; Keitzl, Thomas; Tuchscherer, Philip
Nano Letters, Vol. 12, Issue 1
DOI: 10.1021/nl202864n

Investigation of the Orientation in Composite Fibers of Polycarbonate with Multiwalled Carbon Nanotubes by Raman Microscopy
journal, December 2005

Fischer, Dieter; Pötschke, Petra; Brünig, Harald
Macromolecular Symposia, Vol. 230, Issue 1
DOI: 10.1002/masy.200551156

Similar Records in DOE PAGES and OSTI.GOV collections:

Manipulation of the Geometry and Modulation of the Optical Response of Surfactant-Free Gold Nanostars: A Systematic Bottom-Up Synthesis

Journal Article De Silva Indrasekara, Agampodi S. ; Johnson, Sean F. ; Odion, Ren A. ; ... - ACS Omega

Among plasmonic nanoparticles, surfactant-free branched gold nanoparticles have exhibited exceptional properties as a nanoplatform for a wide variety of applications ranging from surface-enhanced Raman scattering sensing and imaging applications to photothermal treatment and photoimmunotherapy for cancer treatments. The effectiveness and reliability of branched gold nanoparticles in biomedical applications strongly rely on the consistency and reproducibility of physical, chemical, optical, and therapeutic properties of nanoparticles, which are mainly governed by their morphological features. Herein, we present an optimized bottom-up synthesis that improves the reproducibility and homogeneity of the gold-branched nanoparticles with desired morphological features and optical properties. We identified that themore »« less
Cited by 8
DOI: 10.1021/acsomega.7b01700
A closer look at the physical and optical properties of gold nanostars: an experimental and computational study

Journal Article Tsoulos, T. V. ; Han, L. ; Weir, J. ; ... - Nanoscale

A combined experimental and computational study was carried out to design a semi-empirical method to determine the volume, surface area, and extinction coefficients of gold nanostars. The values obtained were confirmed by reconstructing the nanostar 3D topography through high-tilt TEM tomography and introducing the finite elements in COMSOL Multiphysics through which we have also calculated the morphology-dependent extinction coefficient. We have, for the first time, modeled the heat losses of a real, experimentally synthesized nanostar, and found the plasmon resonances to be in excellent agreement with those obtained experimentally. Furthermore, we believe that our approach could substantially improve the applicabilitymore » of this remarkable nanomaterial.« less
DOI: 10.1039/C6NR09091E

Full Text Available
Highly Tunable Hollow Gold Nanospheres: Gaining Size Control and Uniform Galvanic Exchange of Sacrificial Cobalt Boride Scaffolds

Journal Article Lindley, Sarah A. ; Cooper, Jason K. ; Rojas-Andrade, Mauricio D. ; ... - ACS Applied Materials and Interfaces

In principle, the diameter and surface plasmon resonance (SPR) frequency of hollow metal nanostructures can be independently adjusted, allowing the formation of targeted photoactivated structures of specific size and optical functionality. Although tunable SPRs have been reported for various systems, the shift in SPR is usually concomitant with a change in particle size. As such, more advanced tunability, including constant diameter with varying SPR or constant SPR with varying diameter, has not been properly achieved experimentally. In this paper, we demonstrate this advanced tunability with hollow gold nanospheres (HGNs). HGNs were synthesized through galvanic exchange using cobalt-based nanoparticles (NPs) asmore »« less
Cited by 2
DOI: 10.1021/acsami.8b00726

Full Text Available
Gold-Copper alloy “nano-dumplings” with tunable compositions and plasmonic properties

Journal Article Verma, Manoj ; Kedia, Abhitosh ; Kumar, P. Senthil - AIP Conference Proceedings

The unique yet tunable optical properties of plasmonic metal nanoparticles have made them attractive targets for a wide range of applications including nanophotonics, molecular sensing, catalysis etc. Such diverse applications that require precisely stable / reproducible plasmonic properties depend sensitively on the particle morphology ie. the shape, size and constituents. Herein, we systematically study the size / shape controlled synthesis of gold-copper “dumpling” shaped alloy nanoparticles by simultaneous reduction of gold and copper salts in the PVP-methanol solute-solvent system, by effectively utilizing the efficient but mild reduction as well as capping abilities of Poly (N-vinylpyrrolidone). Introduction of copper salts notmore »« less
DOI: 10.1063/1.4946376
Super-Stable, Highly Monodisperse Plasmonic Nanocrystals with 500 Gold Atoms: Au~500(SR)~120

Journal Article Kumara, Chanaka ; Zuo, Xiaobing ; Ilavsky, Dr. Jan ; ... - Journal of the American Chemical Society

Determining the composition of plasmonic nanoparticles is challenging due to a deficiency in tools capable of accurately evaluating the number of atoms. Mass spectrometry plays a significant role in determining nanoparticle composition at the atomic level. Significant progress has been made in understanding ultra-small gold nanoparticles, like Au25(SR)18 and Au38(SR)24, with a Au core diameter of 0.97 and 1.3 nm, respectively. However, progress in small plasmonic nanoparticles (2 - 5 nm) is currently challenging, due in part to limitations in synthesizing monodisperse nanoparticles. Here, we report a plasmonic nanocrystal that is highly monodisperse, with an unprecedented variation of less thanmore »« less
DOI: 10.1021/ja502327a

Similar Records

Title: Colloidal plasmonic nanostar antennas with wide range resonance tunability

Abstract

Citation Formats

Orientation of multiwalled carbon nanotubes in composites with polycarbonate by melt spinning journal, November 2005

TomoJ: tomography software for three-dimensional reconstruction in transmission electron microscopy journal, January 2007

Spectroelectrochemistry of Silver Deposition on Single Gold Nanocrystals journal, November 2014

Glass-forming ability of TeO 2 and temperature induced changes on the structure of the glassy, supercooled, and molten states journal, April 2015

Three-Dimensional Self-Assembling of Gold Nanorods with Controlled Macroscopic Shape and Local Smectic B Order journal, April 2012

High Relaxivity Gd(III)–DNA Gold Nanostars: Investigation of Shape Effects on Proton Relaxation journal, February 2015

Manipulation of the Geometry and Modulation of the Optical Response of Surfactant-Free Gold Nanostars: A Systematic Bottom-Up Synthesis journal, February 2018

TOM software toolbox: acquisition and analysis for electron tomography journal, March 2005

Gold nanostars: surfactant-free synthesis, 3D modelling, and two-photon photoluminescence imaging journal, January 2012

Nanoantennas for visible and infrared radiation journal, January 2012

Ultralocal Modification of Surface Plasmons Properties in Silver Nanocubes journal, February 2012

A closer look at the physical and optical properties of gold nanostars: an experimental and computational study journal, January 2017

Surface plasmon modes of a single silver nanorod: an electron energy loss study journal, January 2011

Plasmon Resonances of a Gold Nanostar journal, March 2007

Unraveling the role of microenvironment and hydrodynamic forces on the vibrational relaxation rates of pyridine–water complexes journal, October 2014

Triton X-100 for three-plasmon gold nanostars with two photothermally active NIR (near IR) and SWIR (short-wavelength IR) channels journal, January 2013

Discrete tomography of demanding samples based on a modified SIRT algorithm journal, April 2012

Surface Plasmon Damping Quantified with an Electron Nanoprobe journal, February 2013

Harnessing Hot Electrons from Near IR Light for Hydrogen Production Using Pt-End-Capped-AuNRs journal, July 2017

Femtosecond laser reshaping yields gold nanorods with ultranarrow surface plasmon resonances journal, November 2017

Boosting Hot Electron-Driven Photocatalysis through Anisotropic Plasmonic Nanoparticles with Hot Spots in Au–TiO 2 Nanoarchitectures journal, May 2016

Understanding the role of AgNO 3 concentration and seed morphology in the achievement of tunable shape control in gold nanostars journal, January 2019

Multipole Plasmon Resonances in Gold Nanorods journal, February 2006

Simultaneous observation of the quantization and the interference pattern of a plasmonic near-field journal, March 2015

Interface and Bulk Standing Waves Drive the Coupling of Plasmonic Nanostar Antennas journal, November 2018

Gold nanostar substrates for SERS-based chemical sensing in the femtomolar regime journal, January 2014

Multiparametric Assessment of Gold Nanoparticle Cytotoxicity in Cancerous and Healthy Cells: The Role of Size, Shape, and Surface Chemistry journal, December 2016

Ultrafast Plasmon Propagation in Nanowires Characterized by Far-Field Spectral Interferometry journal, December 2011

Investigation of the Orientation in Composite Fibers of Polycarbonate with Multiwalled Carbon Nanotubes by Raman Microscopy journal, December 2005

Orientation of multiwalled carbon nanotubes in composites with polycarbonate by melt spinning
journal, November 2005

TomoJ: tomography software for three-dimensional reconstruction in transmission electron microscopy
journal, January 2007

Spectroelectrochemistry of Silver Deposition on Single Gold Nanocrystals
journal, November 2014

Glass-forming ability of TeO ₂ and temperature induced changes on the structure of the glassy, supercooled, and molten states
journal, April 2015

Three-Dimensional Self-Assembling of Gold Nanorods with Controlled Macroscopic Shape and Local Smectic B Order
journal, April 2012

High Relaxivity Gd(III)–DNA Gold Nanostars: Investigation of Shape Effects on Proton Relaxation
journal, February 2015

Manipulation of the Geometry and Modulation of the Optical Response of Surfactant-Free Gold Nanostars: A Systematic Bottom-Up Synthesis
journal, February 2018

TOM software toolbox: acquisition and analysis for electron tomography
journal, March 2005

Gold nanostars: surfactant-free synthesis, 3D modelling, and two-photon photoluminescence imaging
journal, January 2012

Nanoantennas for visible and infrared radiation
journal, January 2012

Ultralocal Modification of Surface Plasmons Properties in Silver Nanocubes
journal, February 2012

A closer look at the physical and optical properties of gold nanostars: an experimental and computational study
journal, January 2017

Surface plasmon modes of a single silver nanorod: an electron energy loss study
journal, January 2011

Plasmon Resonances of a Gold Nanostar
journal, March 2007

Unraveling the role of microenvironment and hydrodynamic forces on the vibrational relaxation rates of pyridine–water complexes
journal, October 2014

Triton X-100 for three-plasmon gold nanostars with two photothermally active NIR (near IR) and SWIR (short-wavelength IR) channels
journal, January 2013

Discrete tomography of demanding samples based on a modified SIRT algorithm
journal, April 2012

Surface Plasmon Damping Quantified with an Electron Nanoprobe
journal, February 2013

Harnessing Hot Electrons from Near IR Light for Hydrogen Production Using Pt-End-Capped-AuNRs
journal, July 2017

Femtosecond laser reshaping yields gold nanorods with ultranarrow surface plasmon resonances
journal, November 2017

Boosting Hot Electron-Driven Photocatalysis through Anisotropic Plasmonic Nanoparticles with Hot Spots in Au–TiO ₂ Nanoarchitectures
journal, May 2016

Understanding the role of AgNO ₃ concentration and seed morphology in the achievement of tunable shape control in gold nanostars
journal, January 2019

Multipole Plasmon Resonances in Gold Nanorods
journal, February 2006

Simultaneous observation of the quantization and the interference pattern of a plasmonic near-field
journal, March 2015

Interface and Bulk Standing Waves Drive the Coupling of Plasmonic Nanostar Antennas
journal, November 2018

Gold nanostar substrates for SERS-based chemical sensing in the femtomolar regime
journal, January 2014

Multiparametric Assessment of Gold Nanoparticle Cytotoxicity in Cancerous and Healthy Cells: The Role of Size, Shape, and Surface Chemistry
journal, December 2016

Ultrafast Plasmon Propagation in Nanowires Characterized by Far-Field Spectral Interferometry
journal, December 2011

Investigation of the Orientation in Composite Fibers of Polycarbonate with Multiwalled Carbon Nanotubes by Raman Microscopy
journal, December 2005