skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on September 24, 2020

Title: Kinetically controlled morphology in copolymer-based hydrogels crosslinked by crystalline nanodomains determines efficacy of ice inhibition

Abstract

Zone annealing crystalline cross-linked hydrogels manipulates the nanostructure that controls anti-icing performance.

Authors:
 [1]; ORCiD logo [1];  [2];  [2];  [1]; ORCiD logo [1]
  1. Department of Polymer Engineering, University of Akron, Akron, USA
  2. National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1569295
Grant/Contract Number:  
SC0012704
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Molecular Systems Design & Engineering
Additional Journal Information:
Journal Name: Molecular Systems Design & Engineering; Journal ID: ISSN 2058-9689
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Sepulveda-Medina, Pablo I., Wang, Chao, Li, Ruipeng, Fukuto, Masafumi, Weiss, R. A., and Vogt, Bryan D. Kinetically controlled morphology in copolymer-based hydrogels crosslinked by crystalline nanodomains determines efficacy of ice inhibition. United Kingdom: N. p., 2020. Web. doi:10.1039/C9ME00101H.
Sepulveda-Medina, Pablo I., Wang, Chao, Li, Ruipeng, Fukuto, Masafumi, Weiss, R. A., & Vogt, Bryan D. Kinetically controlled morphology in copolymer-based hydrogels crosslinked by crystalline nanodomains determines efficacy of ice inhibition. United Kingdom. doi:10.1039/C9ME00101H.
Sepulveda-Medina, Pablo I., Wang, Chao, Li, Ruipeng, Fukuto, Masafumi, Weiss, R. A., and Vogt, Bryan D. Wed . "Kinetically controlled morphology in copolymer-based hydrogels crosslinked by crystalline nanodomains determines efficacy of ice inhibition". United Kingdom. doi:10.1039/C9ME00101H.
@article{osti_1569295,
title = {Kinetically controlled morphology in copolymer-based hydrogels crosslinked by crystalline nanodomains determines efficacy of ice inhibition},
author = {Sepulveda-Medina, Pablo I. and Wang, Chao and Li, Ruipeng and Fukuto, Masafumi and Weiss, R. A. and Vogt, Bryan D.},
abstractNote = {Zone annealing crystalline cross-linked hydrogels manipulates the nanostructure that controls anti-icing performance.},
doi = {10.1039/C9ME00101H},
journal = {Molecular Systems Design & Engineering},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on September 24, 2020
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Evaluation of the impact of freezing preparation techniques on the characterisation of alginate hydrogels by cryo-SEM
journal, September 2016


States of water in partially swollen poly(vinyl alcohol) hydrogels
journal, November 2005


Bioinspired Materials for Controlling Ice Nucleation, Growth, and Recrystallization
journal, April 2018


Non-freezing water in protein solutions
journal, May 1985

  • Ali, S.; Bettelheim, F. A.
  • Colloid and Polymer Science, Vol. 263, Issue 5
  • DOI: 10.1007/BF01410387

Antifreeze Hydrogels from Amphiphilic Statistical Copolymers
journal, November 2018


Facially Amphipathic Glycopolymers Inhibit Ice Recrystallization
journal, April 2018

  • Graham, Ben; Fayter, Alice E. R.; Houston, Judith E.
  • Journal of the American Chemical Society, Vol. 140, Issue 17
  • DOI: 10.1021/jacs.8b02066

Absence of the Density Minimum of Supercooled Water in Hydrophobic Confinement
journal, April 2009

  • Zhang, Yang; Liu, Kao-Hsiang; Lagi, Marco
  • The Journal of Physical Chemistry B, Vol. 113, Issue 15
  • DOI: 10.1021/jp900641y

The crystal growth of δ-VN by floating zone and zone annealing techniques
journal, May 1977


Dynamics of supercooled water in confined geometry
journal, January 2000


Strain rate dependent nanostructure of hydrogels with reversible hydrophobic associations during uniaxial extension
journal, January 2019

  • Wang, Chao; Wiener, Clinton G.; Fukuto, Masafumi
  • Soft Matter, Vol. 15, Issue 2
  • DOI: 10.1039/C8SM02165A

Order-Disorder Transition of a Hydrogel Containing an n-Alkyl Acrylate
journal, December 1994

  • Matsuda, Atsushi; Sato, Jun'ichi; Yasunaga, Hidekazu
  • Macromolecules, Vol. 27, Issue 26
  • DOI: 10.1021/ma00104a027

Synthetic polymers enable non-vitreous cellular cryopreservation by reducing ice crystal growth during thawing
journal, February 2014

  • Deller, Robert C.; Vatish, Manu; Mitchell, Daniel A.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4244

Structural and mechanical properties of glassy water in nanoscale confinement
journal, January 2009

  • Lombardo, Thomas G.; Giovambattista, Nicolás; Debenedetti, Pablo G.
  • Faraday Discuss., Vol. 141
  • DOI: 10.1039/B805361H

Water as an Active Constituent in Cell Biology
journal, January 2008


Supercooled Water in PVA Matrixes:  I. An Incoherent Quasi-Elastic Neutron Scattering (QENS) Study
journal, August 2003

  • Paradossi, Gaio; Cavalieri, Francesca; Chiessi, Ester
  • The Journal of Physical Chemistry B, Vol. 107, Issue 33
  • DOI: 10.1021/jp034542p

Ice crystallization in water’s “no-man’s land”
journal, June 2010

  • Moore, Emily B.; Molinero, Valeria
  • The Journal of Chemical Physics, Vol. 132, Issue 24
  • DOI: 10.1063/1.3451112

Coagulation size of freezable water in poly(vinyl alcohol) hydrogels formed by different freeze/thaw cycle periods
journal, September 2011

  • Nakano, Tatsuro; Nakaoki, Takahiko
  • Polymer Journal, Vol. 43, Issue 11
  • DOI: 10.1038/pj.2011.92

Comparison of simple potential functions for simulating liquid water
journal, July 1983

  • Jorgensen, William L.; Chandrasekhar, Jayaraman; Madura, Jeffry D.
  • The Journal of Chemical Physics, Vol. 79, Issue 2
  • DOI: 10.1063/1.445869

Experimental evidence of a liquid-liquid transition in interfacial water
journal, July 2005

  • Zanotti, J. -M; Bellissent-Funel, M. -C; Chen, S. -H
  • Europhysics Letters (EPL), Vol. 71, Issue 1
  • DOI: 10.1209/epl/i2004-10529-2

Irena : tool suite for modeling and analysis of small-angle scattering
journal, February 2009


The IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use
journal, June 2002

  • Wagner, W.; Pruß, A.
  • Journal of Physical and Chemical Reference Data, Vol. 31, Issue 2
  • DOI: 10.1063/1.1461829

Theory of amorphous ices
journal, May 2014

  • Limmer, David T.; Chandler, David
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 26
  • DOI: 10.1073/pnas.1407277111

Heterogeneous ice nucleation correlates with bulk-like interfacial water
journal, April 2019


Convergent evolution of antifreeze glycoproteins in Antarctic notothenioid fish and Arctic cod
journal, April 1997

  • Chen, L.; DeVries, A. L.; Cheng, C. -H. C.
  • Proceedings of the National Academy of Sciences, Vol. 94, Issue 8
  • DOI: 10.1073/pnas.94.8.3817

Supramolecular Hydrophobic Aggregates in Hydrogels Partially Inhibit Ice Formation
journal, June 2016

  • Wiener, Clinton G.; Tyagi, Madhusudan; Liu, Yun
  • The Journal of Physical Chemistry B, Vol. 120, Issue 24
  • DOI: 10.1021/acs.jpcb.6b02863

Thermodynamic functions of water and ice confined to 2nm radius pores
journal, March 2005

  • Tombari, E.; Salvetti, G.; Ferrari, C.
  • The Journal of Chemical Physics, Vol. 122, Issue 10
  • DOI: 10.1063/1.1862244

Polyproline as a Minimal Antifreeze Protein Mimic That Enhances the Cryopreservation of Cell Monolayers
journal, November 2017

  • Graham, Ben; Bailey, Trisha L.; Healey, Joseph R. J.
  • Angewandte Chemie International Edition, Vol. 56, Issue 50
  • DOI: 10.1002/anie.201706703

Ice-binding structure and mechanism of an antifreeze protein from winter flounder
journal, June 1995

  • Sicheri, F.; Yang, D. S. C.
  • Nature, Vol. 375, Issue 6530
  • DOI: 10.1038/375427a0

Extending Dynamic Range of Block Copolymer Ordering with Rotational Cold Zone Annealing (RCZA) and Ionic Liquids
journal, October 2015


Impact of surface wettability on dynamics of supercooled water confined in nitrogen-doped ordered mesoporous carbon
journal, January 2018

  • Wiener, Clinton G.; Qiang, Zhe; Xia, Yanfeng
  • Physical Chemistry Chemical Physics, Vol. 20, Issue 44
  • DOI: 10.1039/C8CP05670F

Anti-icing and de-icing techniques for wind turbines: Critical review
journal, January 2011


Antifreeze Proteins:  Structures and Mechanisms of Function
journal, January 1996

  • Yeh, Yin; Feeney, Robert E.
  • Chemical Reviews, Vol. 96, Issue 2
  • DOI: 10.1021/cr950260c

Origin of hydrophobicity and enhanced water hydrogen bond strength near purely hydrophobic solutes
journal, December 2016

  • Grdadolnik, Joze; Merzel, Franci; Avbelj, Franc
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 2
  • DOI: 10.1073/pnas.1612480114

Physically Cross-Linked Alkylacrylamide Hydrogels:  A SANS Analysis of the Microstructure
journal, December 2004

  • Tian, Jun; Seery, Thomas A. P.; Ho, Derek L.
  • Macromolecules, Vol. 37, Issue 26
  • DOI: 10.1021/ma049474z

Nika : software for two-dimensional data reduction
journal, March 2012


Physical hydrogels composed of polyampholytes demonstrate high toughness and viscoelasticity
journal, July 2013

  • Sun, Tao Lin; Kurokawa, Takayuki; Kuroda, Shinya
  • Nature Materials, Vol. 12, Issue 10
  • DOI: 10.1038/nmat3713

Small-Angle Scattering from Polymeric Mass Fractals of Arbitrary Mass-Fractal Dimension
journal, April 1996


Potent inhibition of ice recrystallization by low molecular weight carbohydrate-based surfactants and hydrogelators
journal, January 2012

  • Capicciotti, Chantelle J.; Leclère, Mathieu; Perras, Frédéric A.
  • Chemical Science, Vol. 3, Issue 5
  • DOI: 10.1039/c2sc00885h

Structure and reactivity of water at biomaterial surfaces
journal, February 1998


Porous Gelatin Hydrogels:  1. Cryogenic Formation and Structure Analysis
journal, February 2007

  • Van Vlierberghe, Sandra; Cnudde, Veerle; Dubruel, Peter
  • Biomacromolecules, Vol. 8, Issue 2
  • DOI: 10.1021/bm060684o

Nature of Amorphous Polymorphism of Water
journal, April 2005


Hydrogel with Aligned and Tunable Pore Via “Hot Ice” Template Applies as Bioscaffold
journal, February 2016

  • He, Hongjian; Liu, Mingyu; Wei, Junjie
  • Advanced Healthcare Materials, Vol. 5, Issue 6
  • DOI: 10.1002/adhm.201500707

Quantitative study on the antifreeze protein mimetic ice growth inhibition properties of poly(ampholytes) derived from vinyl-based polymers
journal, January 2014

  • Mitchell, Daniel E.; Lilliman, Mary; Spain, Sebastian G.
  • Biomater. Sci., Vol. 2, Issue 12
  • DOI: 10.1039/C4BM00153B

Supercooled Water in PVA Matrixes. II. A Molecular Dynamics Simulation Study and Comparison with QENS Results
journal, April 2005

  • Chiessi, Ester; Cavalieri, Francesca; Paradossi, Gaio
  • The Journal of Physical Chemistry B, Vol. 109, Issue 16
  • DOI: 10.1021/jp044807f

Behaviour and fate of perfluoroalkyl and polyfluoroalkyl substances (PFASs) in drinking water treatment: A review
journal, March 2014


Nonfreezing Water Structuration in Heteroprotein Coacervates
journal, April 2015


Tough and Self-Healing Hydrogels Formed via Hydrophobic Interactions
journal, June 2011

  • Tuncaboylu, Deniz C.; Sari, Murat; Oppermann, Wilhelm
  • Macromolecules, Vol. 44, Issue 12
  • DOI: 10.1021/ma200579v

X-ray Structure of Snow Flea Antifreeze Protein Determined by Racemic Crystallization of Synthetic Protein Enantiomers
journal, July 2008

  • Pentelute, Brad L.; Gates, Zachary P.; Tereshko, Valentina
  • Journal of the American Chemical Society, Vol. 130, Issue 30
  • DOI: 10.1021/ja8013538

The relationship between liquid, supercooled and glassy water
journal, November 1998

  • Mishima, Osamu; Stanley, H. Eugene
  • Nature, Vol. 396, Issue 6709
  • DOI: 10.1038/24540

Water motion in reverse micelles studied by quasielastic neutron scattering and molecular dynamics simulations
journal, January 2004

  • Harpham, Michael R.; Ladanyi, Branka M.; Levinger, Nancy E.
  • The Journal of Chemical Physics, Vol. 121, Issue 16
  • DOI: 10.1063/1.1792592

X-ray diffraction study of water confined in activated carbon pores over a temperature range of 228–298 K
journal, October 2006


Water crystallization and its importance to freezing of foods: A review
journal, August 2011


Phase diagram of water in carbon nanotubes
journal, December 2007

  • Takaiwa, D.; Hatano, I.; Koga, K.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 1
  • DOI: 10.1073/pnas.0707917105

Properties of Water Bound in Hydrogels
journal, October 2017

  • Gun’ko, Vladimir; Savina, Irina; Mikhalovsky, Sergey
  • Gels, Vol. 3, Issue 4
  • DOI: 10.3390/gels3040037

Water nanodroplets confined in zeolite pores
journal, January 2009

  • Coudert, François-Xavier; Cailliez, Fabien; Vuilleumier, Rodolphe
  • Faraday Discuss., Vol. 141
  • DOI: 10.1039/B804992K

Neutron Diffraction of Ice in Hydrogels
journal, September 2014

  • Sekine, Yurina; Ikeda-Fukazawa, Tomoko; Aizawa, Mamoru
  • The Journal of Physical Chemistry B, Vol. 118, Issue 47
  • DOI: 10.1021/jp508269b

First-order transition in confined water between high-density liquid and low-density amorphous phases
journal, November 2000

  • Koga, Kenichiro; Tanaka, Hideki; Zeng, X. C.
  • Nature, Vol. 408, Issue 6812
  • DOI: 10.1038/35046035

A new method for the determination of particle size distributions from small-angle neutron scattering measurements
journal, December 1988

  • Potton, J. A.; Daniell, G. J.; Rainford, B. D.
  • Journal of Applied Crystallography, Vol. 21, Issue 6
  • DOI: 10.1107/S0021889888004595

Influence of Pore Wall Hydrophobicity on Freezing and Melting of Confined Water
journal, January 2018


A Fully Size-Resolved Perspective on the Crystallization of Water Clusters
journal, September 2012


Thermoresponsive Composite Hydrogels with Aligned Macroporous Structure by Ice-Templated Assembly
journal, November 2013

  • Bai, Hao; Polini, Alessandro; Delattre, Benjamin
  • Chemistry of Materials, Vol. 25, Issue 22
  • DOI: 10.1021/cm4025827

The structure of a new phase of ice
journal, January 1998

  • Lobban, C.; Finney, J. L.; Kuhs, W. F.
  • Nature, Vol. 391, Issue 6664
  • DOI: 10.1038/34622