Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3

Srivastava, A. M.; Comanzo, H. A.; Smith, D. J.; Choi, J. W.; Brik, M. G.; Beers, W. W.; Payne, S. A.

doi:10.1016/j.jlumin.2018.10.090

Title: Spectroscopy of Mn⁴⁺ in orthorhombic perovskite, LaInO₃

Abstract

The low temperature spectroscopic properties of Mn⁴⁺ (3d³) in the orthorhombic perovskite, LaInO₃, is examined in this work. The exchange charge model of crystal-field theory is used to calculate the Mn⁴⁺ energy levels. The spectra can be fitted by the parameters Dq = 1776 cm^–1, B = 700 cm^–1 and C = 3189 cm^–1, with C/B = 4.5. Discussions pertaining to the low luminescence efficiency of LaInO₃:Mn⁴⁺ are presented. A comparative study of the variations in the energy of the ²E_g → ⁴A_2g emission transition in a series of materials with the perovskite structure is presented. Here, the data suggest a relationship between the energy of the ²E_g → ⁴A_2g emission transition and the deviation of the octahedral O-Mn-O bond angle from the ideal 90°. It is concluded that the angular distortion is not large enough to support the development of high luminosity Mn⁴⁺ activated phosphors in the ABO₃ perovskite family of materials.

Authors:

Srivastava, A. M. ^[1]; Comanzo, H. A. ^[1]; Smith, D. J. ^[1]; Choi, J. W. ^[1]; Brik, M. G. ^[2]; Beers, W. W. ^[3]; Payne, S. A. ^[4]

GE Global Research, Niskayuna, NY (United States)
Chongqing Univ. of Posts and Telecommunications, Chongqing (People's Republic of China); Univ. of Tartu, Tartu (Estonia); Jan Dlugosz Univ., Czestochowa (Poland)
Current & Lighting, Current Powered by GE, Cleveland, OH (United States)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Publication Date:: 2018-10-23

Research Org.:: Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Sponsoring Org.:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1569172

Alternate Identifier(s):: OSTI ID: 1775957

Report Number(s):: LLNL-JRNL-775999
Journal ID: ISSN 0022-2313; 968485

Grant/Contract Number:: AC52-07NA27344; PUT PRG111; GDW20145200225; TK141

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Luminescence

Additional Journal Information:: Journal Volume: 206; Journal Issue: C; Journal ID: ISSN 0022-2313

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; Mn4+; Luminescence; Perovskite; LaInO3; Crystal-field theory; MnO6 distortion

Citation Formats


                    Srivastava, A. M., Comanzo, H. A., Smith, D. J., Choi, J. W., Brik, M. G., Beers, W. W., and Payne, S. A. Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3.  United States: N. p., 2018. 
        Web.  doi:10.1016/j.jlumin.2018.10.090.

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                    Srivastava, A. M., Comanzo, H. A., Smith, D. J., Choi, J. W., Brik, M. G., Beers, W. W., & Payne, S. A. Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3.  United States.  doi:https://doi.org/10.1016/j.jlumin.2018.10.090

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                    Srivastava, A. M., Comanzo, H. A., Smith, D. J., Choi, J. W., Brik, M. G., Beers, W. W., and Payne, S. A. Tue .  
        "Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3".  United States.  doi:https://doi.org/10.1016/j.jlumin.2018.10.090.  https://www.osti.gov/servlets/purl/1569172.

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@article{osti_1569172,

  title        = {Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3},

  author       = {Srivastava, A. M. and Comanzo, H. A. and Smith, D. J. and Choi, J. W. and Brik, M. G. and Beers, W. W. and Payne, S. A.},

  abstractNote = {The low temperature spectroscopic properties of Mn4+ (3d3) in the orthorhombic perovskite, LaInO3, is examined in this work. The exchange charge model of crystal-field theory is used to calculate the Mn4+ energy levels. The spectra can be fitted by the parameters Dq = 1776 cm–1, B = 700 cm–1 and C = 3189 cm–1, with C/B = 4.5. Discussions pertaining to the low luminescence efficiency of LaInO3:Mn4+ are presented. A comparative study of the variations in the energy of the 2Eg → 4A2g emission transition in a series of materials with the perovskite structure is presented. Here, the data suggest a relationship between the energy of the 2Eg → 4A2g emission transition and the deviation of the octahedral O-Mn-O bond angle from the ideal 90°. It is concluded that the angular distortion is not large enough to support the development of high luminosity Mn4+ activated phosphors in the ABO3 perovskite family of materials.},

  doi          = {10.1016/j.jlumin.2018.10.090},

  journal      = {Journal of Luminescence},

  number       = C,

  volume       = 206,

  place        = {United States},

  year         = {2018},

  month        = {10}

}

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DOI: https://doi.org/10.1016/j.jlumin.2018.10.090

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Cited by: 11 works

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Figures / Tables:

Table 1: Spectroscopic properties of Mn⁴⁺ in ABO₃ perovskites. The values of Dq, Mn-O bond distance, energy of the ²E_g→⁴A_2g emission transition (E:²Eg), Racah parameters (B, C), $β$₁ parameter and the angular deviation of the M-O-M bond angle from the ideal 90° are given.

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Works referencing / citing this record:

Mn ⁴⁺ -activated BaLaMgSbO ₆ double-perovskite phosphor: a novel high-efficiency far-red-emitting luminescent material for indoor plant growth lighting
journal, January 2019

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Journal of the American Ceramic Society, Vol. 102, Issue 10
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Review—Mn ⁴⁺ -Activated Red and Deep Red-Emitting Phosphors
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Adachi, Sadao
ECS Journal of Solid State Science and Technology, Vol. 9, Issue 1
DOI: 10.1149/2.0022001jss

Luminescence of Mn ⁴⁺ in the Orthorhombic Perovskites, ASnO ₃ (A=Ca, Sr)
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ECS Journal of Solid State Science and Technology, Vol. 9, Issue 1
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Review—Tanabe−Sugano Energy-Level Diagram and Racah Parameters in Mn ⁴⁺ -Activated Red and Deep Red-Emitting Phosphors
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Adachi, Sadao
ECS Journal of Solid State Science and Technology, Vol. 8, Issue 12
DOI: 10.1149/2.0281912jss

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Title: Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3

Abstract

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