Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3

Srivastava, A. M.; Comanzo, H. A.; Smith, D. J.; Choi, J. W.; Brik, M. G.; Beers, W. W.; Payne, S. A.

doi:10.1016/j.jlumin.2018.10.090

Title: Spectroscopy of Mn⁴⁺ in orthorhombic perovskite, LaInO₃

Journal Article · 23 October 2018 · Journal of Luminescence

DOI: https://doi.org/10.1016/j.jlumin.2018.10.090 · OSTI ID:1569172

Srivastava, A. M. ^[1]; Comanzo, H. A. ^[1]; Smith, D. J. ^[1]; Choi, J. W. ^[1]; Brik, M. G. ^[2]; Beers, W. W. ^[3]; Payne, S. A. ^[4]

GE Global Research, Niskayuna, NY (United States)
Chongqing Univ. of Posts and Telecommunications, Chongqing (People's Republic of China); Univ. of Tartu, Tartu (Estonia); Jan Dlugosz Univ., Czestochowa (Poland)
Current & Lighting, Current Powered by GE, Cleveland, OH (United States)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

The low temperature spectroscopic properties of Mn⁴⁺ (3d³) in the orthorhombic perovskite, LaInO₃, is examined in this work. The exchange charge model of crystal-field theory is used to calculate the Mn⁴⁺ energy levels. The spectra can be fitted by the parameters Dq = 1776 cm^–1, B = 700 cm^–1 and C = 3189 cm^–1, with C/B = 4.5. Discussions pertaining to the low luminescence efficiency of LaInO₃:Mn⁴⁺ are presented. A comparative study of the variations in the energy of the ²E_g → ⁴A_2g emission transition in a series of materials with the perovskite structure is presented. Here, the data suggest a relationship between the energy of the ²E_g → ⁴A_2g emission transition and the deviation of the octahedral O-Mn-O bond angle from the ideal 90°. It is concluded that the angular distortion is not large enough to support the development of high luminosity Mn⁴⁺ activated phosphors in the ABO₃ perovskite family of materials.

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Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC52-07NA27344; PUT PRG111; GDW20145200225; TK141

OSTI ID:: 1569172

Alternate ID(s):: OSTI ID: 1775957

Report Number(s):: LLNL-JRNL-775999; 968485

Journal Information:: Journal of Luminescence, Vol. 206, Issue C; ISSN 0022-2313

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 22 works

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