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Title: Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3

Abstract

The low temperature spectroscopic properties of Mn4+ (3d3) in the orthorhombic perovskite, LaInO3, is examined in this work. The exchange charge model of crystal-field theory is used to calculate the Mn4+ energy levels. The spectra can be fitted by the parameters Dq = 1776 cm–1, B = 700 cm–1 and C = 3189 cm–1, with C/B = 4.5. Discussions pertaining to the low luminescence efficiency of LaInO3:Mn4+ are presented. A comparative study of the variations in the energy of the 2Eg4A2g emission transition in a series of materials with the perovskite structure is presented. Here, the data suggest a relationship between the energy of the 2Eg4A2g emission transition and the deviation of the octahedral O-Mn-O bond angle from the ideal 90°. It is concluded that the angular distortion is not large enough to support the development of high luminosity Mn4+ activated phosphors in the ABO3 perovskite family of materials.

Authors:
 [1];  [1];  [1];  [1];  [2];  [3];  [4]
  1. GE Global Research, Niskayuna, NY (United States)
  2. Chongqing Univ. of Posts and Telecommunications, Chongqing (People's Republic of China); Univ. of Tartu, Tartu (Estonia); Jan Dlugosz Univ., Czestochowa (Poland)
  3. Current & Lighting, Current Powered by GE, Cleveland, OH (United States)
  4. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Publication Date:
Research Org.:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA); USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1569172
Alternate Identifier(s):
OSTI ID: 1775957
Report Number(s):
LLNL-JRNL-775999
Journal ID: ISSN 0022-2313; 968485
Grant/Contract Number:  
AC52-07NA27344; PUT PRG111; GDW20145200225; TK141
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Luminescence
Additional Journal Information:
Journal Volume: 206; Journal Issue: C; Journal ID: ISSN 0022-2313
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; Mn4+; Luminescence; Perovskite; LaInO3; Crystal-field theory; MnO6 distortion

Citation Formats

Srivastava, A. M., Comanzo, H. A., Smith, D. J., Choi, J. W., Brik, M. G., Beers, W. W., and Payne, S. A. Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3. United States: N. p., 2018. Web. doi:10.1016/j.jlumin.2018.10.090.
Srivastava, A. M., Comanzo, H. A., Smith, D. J., Choi, J. W., Brik, M. G., Beers, W. W., & Payne, S. A. Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3. United States. https://doi.org/10.1016/j.jlumin.2018.10.090
Srivastava, A. M., Comanzo, H. A., Smith, D. J., Choi, J. W., Brik, M. G., Beers, W. W., and Payne, S. A. Tue . "Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3". United States. https://doi.org/10.1016/j.jlumin.2018.10.090. https://www.osti.gov/servlets/purl/1569172.
@article{osti_1569172,
title = {Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3},
author = {Srivastava, A. M. and Comanzo, H. A. and Smith, D. J. and Choi, J. W. and Brik, M. G. and Beers, W. W. and Payne, S. A.},
abstractNote = {The low temperature spectroscopic properties of Mn4+ (3d3) in the orthorhombic perovskite, LaInO3, is examined in this work. The exchange charge model of crystal-field theory is used to calculate the Mn4+ energy levels. The spectra can be fitted by the parameters Dq = 1776 cm–1, B = 700 cm–1 and C = 3189 cm–1, with C/B = 4.5. Discussions pertaining to the low luminescence efficiency of LaInO3:Mn4+ are presented. A comparative study of the variations in the energy of the 2Eg → 4A2g emission transition in a series of materials with the perovskite structure is presented. Here, the data suggest a relationship between the energy of the 2Eg → 4A2g emission transition and the deviation of the octahedral O-Mn-O bond angle from the ideal 90°. It is concluded that the angular distortion is not large enough to support the development of high luminosity Mn4+ activated phosphors in the ABO3 perovskite family of materials.},
doi = {10.1016/j.jlumin.2018.10.090},
journal = {Journal of Luminescence},
number = C,
volume = 206,
place = {United States},
year = {2018},
month = {10}
}

Journal Article:

Citation Metrics:
Cited by: 11 works
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Figures / Tables:

Table 1 Table 1: Spectroscopic properties of Mn4+ in ABO3 perovskites. The values of Dq, Mn-O bond distance, energy of the 2Eg4A2g emission transition (E:2Eg), Racah parameters (B, C), $β$1 parameter and the angular deviation of the M-O-M bond angle from the ideal 90° are given.

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Works referencing / citing this record:

Rare‐earth‐free Li 5 La 3 Ta 2 O 12 :Mn 4+ deep‐red‐emitting phosphor: Synthesis and photoluminescence properties
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Luminescence of Mn 4+ in the Orthorhombic Perovskites, ASnO 3 (A=Ca, Sr)
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Review—Tanabe−Sugano Energy-Level Diagram and Racah Parameters in Mn 4+ -Activated Red and Deep Red-Emitting Phosphors
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Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.