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Title: Macromolecular design strategies toward tailoring free volume in glassy polymers for high performance gas separation membranes

Abstract

This review highlights recently reported novel macromolecular design strategies providing tailorable free volume for high performance gas separation membranes.

Authors:
 [1]; ORCiD logo [1]
  1. Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1569090
Grant/Contract Number:  
SC0019024
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Molecular Systems Design & Engineering
Additional Journal Information:
Journal Name: Molecular Systems Design & Engineering; Journal ID: ISSN 2058-9689
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Corrado, Tanner, and Guo, Ruilan. Macromolecular design strategies toward tailoring free volume in glassy polymers for high performance gas separation membranes. United Kingdom: N. p., 2020. Web. doi:10.1039/C9ME00099B.
Corrado, Tanner, & Guo, Ruilan. Macromolecular design strategies toward tailoring free volume in glassy polymers for high performance gas separation membranes. United Kingdom. doi:10.1039/C9ME00099B.
Corrado, Tanner, and Guo, Ruilan. Wed . "Macromolecular design strategies toward tailoring free volume in glassy polymers for high performance gas separation membranes". United Kingdom. doi:10.1039/C9ME00099B.
@article{osti_1569090,
title = {Macromolecular design strategies toward tailoring free volume in glassy polymers for high performance gas separation membranes},
author = {Corrado, Tanner and Guo, Ruilan},
abstractNote = {This review highlights recently reported novel macromolecular design strategies providing tailorable free volume for high performance gas separation membranes.},
doi = {10.1039/C9ME00099B},
journal = {Molecular Systems Design & Engineering},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
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Works referenced in this record:

Molecular simulation of small molecule diffusion and solution in dense amorphous polysiloxanes and polyimides
journal, June 2000


Triptycene-based copolyimides with tailored backbone rigidity for enhanced gas transport
journal, September 2017


Gas Permeation Properties, Physical Aging, and Its Mitigation in High Free Volume Glassy Polymers
journal, May 2018


Pore size distribution analysis of microporous carbons: a density functional theory approach
journal, May 1993

  • Lastoskie, Christian; Gubbins, Keith E.; Quirke, Nicholas
  • The Journal of Physical Chemistry, Vol. 97, Issue 18
  • DOI: 10.1021/j100120a035

Using “Internal Free Volume” to Increase Chromophore Alignment
journal, April 2002

  • Long, Timothy M.; Swager, Timothy M.
  • Journal of the American Chemical Society, Vol. 124, Issue 15
  • DOI: 10.1021/ja017499x

Correlation between the ortho -Positronium Pick-off Annihilation Lifetime and the Free Volume in Molecular Liquids and Polymers
journal, January 1992

  • Kobayashi, Yoshinori; Haraya, Kenji; Kamiya, Yoshinori
  • Bulletin of the Chemical Society of Japan, Vol. 65, Issue 1
  • DOI: 10.1246/bcsj.65.160

The origin of size-selective gas transport through polymers of intrinsic microporosity
journal, January 2019

  • Fuoco, Alessio; Rizzuto, Carmen; Tocci, Elena
  • Journal of Materials Chemistry A, Vol. 7, Issue 35
  • DOI: 10.1039/C9TA07159H

Microporous Polyimides from Ladder Diamines Synthesized by Facile Catalytic Arene–Norbornene Annulation as High-Performance Membranes for Gas Separation
journal, February 2019


Seven chemical separations to change the world
journal, April 2016

  • Sholl, David S.; Lively, Ryan P.
  • Nature, Vol. 532, Issue 7600
  • DOI: 10.1038/532435a

Quenching of positronium atoms by nitrobenzene in various solutions
journal, January 1991

  • Kobayashi, Yoshinori
  • Journal of the Chemical Society, Faraday Transactions, Vol. 87, Issue 22
  • DOI: 10.1039/ft9918703641

Synthesis and gas permeation properties of novel spirobisindane-based polyimides of intrinsic microporosity
journal, January 2013

  • Rogan, Yulia; Starannikova, Ludmila; Ryzhikh, Victoria
  • Polymer Chemistry, Vol. 4, Issue 13
  • DOI: 10.1039/c3py00451a

Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials
journal, January 2004

  • Budd, Peter M.; Ghanem, Bader S.; Makhseed, Saad
  • Chemical Communications, Issue 2
  • DOI: 10.1039/b311764b

Effect of structural symmetry on gas transport properties of polysulfones
journal, June 1992

  • Aitken, C. L.; Koros, W. J.; Paul, D. R.
  • Macromolecules, Vol. 25, Issue 13
  • DOI: 10.1021/ma00039a018

Physical aging of thin glassy polymer films: Free volume interpretation
journal, June 2006


Isomeric polyimides based on fluorinated dianhydrides and diamines for gas separation applications
journal, July 1990


Physical Aging of Thin Glassy Polymer Films Monitored by Optical Properties
journal, February 2006


Free Volume Investigation of Polymers of Intrinsic Microporosity (PIMs): PIM-1 and PIM1 Copolymers Incorporating Ethanoanthracene Units
journal, July 2010

  • Emmler, Thomas; Heinrich, Kathleen; Fritsch, Detlev
  • Macromolecules, Vol. 43, Issue 14
  • DOI: 10.1021/ma1008786

Gas permeation and physical aging properties of iptycene diamine-based microporous polyimides
journal, September 2015


NLDFT Pore Size Distribution in Amorphous Microporous Materials
journal, August 2017


A Spirobifluorene-Based Polymer of Intrinsic Microporosity with Improved Performance for Gas Separation
journal, September 2012

  • Bezzu, C. Grazia; Carta, Mariolino; Tonkins, Alexander
  • Advanced Materials, Vol. 24, Issue 44
  • DOI: 10.1002/adma.201202393

Gas transport properties of polysulphones: 2. Effect of bisphenol connector groups
journal, January 1991


Gas separation membranes from polymers of intrinsic microporosity
journal, April 2005


Atomistic models of amorphous polybutadienes. 3. Static free volume
journal, December 1993


Triptycene polymers
journal, January 1969

  • Hoffmeister, E.; Kropp, J. E.; McDowell, T. L.
  • Journal of Polymer Science Part A-1: Polymer Chemistry, Vol. 7, Issue 1
  • DOI: 10.1002/pol.1969.150070107

Redefining the Robeson upper bounds for CO 2 /CH 4 and CO 2 /N 2 separations using a series of ultrapermeable benzotriptycene-based polymers of intrinsic microporosity
journal, January 2019

  • Comesaña-Gándara, Bibiana; Chen, Jie; Bezzu, C. Grazia
  • Energy & Environmental Science, Vol. 12, Issue 9
  • DOI: 10.1039/C9EE01384A

A highly permeable polyimide with enhanced selectivity for membrane gas separations
journal, January 2014

  • Rogan, Yulia; Malpass-Evans, Richard; Carta, Mariolino
  • J. Mater. Chem. A, Vol. 2, Issue 14
  • DOI: 10.1039/C4TA00564C

Highly Selective and Permeable Microporous Polymer Membranes for Hydrogen Purification and CO 2 Removal from Natural Gas
journal, July 2018


Maximizing the right stuff: The trade-off between membrane permeability and selectivity
journal, June 2017


Polymer Rigidity Improves Microporous Membranes
journal, January 2013


The synthesis, chain-packing simulation and long-term gas permeability of highly selective spirobifluorene-based polymers of intrinsic microporosity
journal, January 2018

  • Bezzu, C. Grazia; Carta, Mariolino; Ferrari, Maria-Chiara
  • Journal of Materials Chemistry A, Vol. 6, Issue 22
  • DOI: 10.1039/C8TA02601G

50th Anniversary Perspective : Polymers and Mixed Matrix Membranes for Gas and Vapor Separation: A Review and Prospective Opportunities
journal, October 2017


Tritriptycene: a D3h C62 hydrocarbon with three U-shaped cavities
journal, October 1986

  • Bashir-Hashemi, Abdollah.; Hart, Harold.; Ward, Donald L.
  • Journal of the American Chemical Society, Vol. 108, Issue 21
  • DOI: 10.1021/ja00281a038

Characterization of Microvoids in Glassy Polymers by Means of 129Xe NMR Spectroscopy.
journal, January 2001

  • Suzuki, Tomoyuki; Miyauchi, Minoru; Yoshimizu, Hiroaki
  • Polymer Journal, Vol. 33, Issue 12
  • DOI: 10.1295/polymj.33.934

Synthesis and characterization of triptycene-based polyimides with tunable high fractional free volume for gas separation membranes
journal, January 2014

  • Wiegand, Jennifer R.; Smith, Zachary P.; Liu, Qiang
  • J. Mater. Chem. A, Vol. 2, Issue 33
  • DOI: 10.1039/C4TA02303J

Physical aging of polymers of intrinsic microporosity: a SAXS/WAXS study
journal, January 2014

  • McDermott, Amanda G.; Budd, Peter M.; McKeown, Neil B.
  • J. Mater. Chem. A, Vol. 2, Issue 30
  • DOI: 10.1039/C4TA02165G

Analysis of the transport properties of thermally rearranged (TR) polymers and polymers of intrinsic microporosity (PIM) relative to upper bound performance
journal, March 2017


Porous Organic Polymers via Ring Opening Metathesis Polymerization
journal, February 2018


Triptycene Polyimides: Soluble Polymers with High Thermal Stability and Low Refractive Indices
journal, February 2011

  • Sydlik, Stefanie A.; Chen, Zhihua; Swager, Timothy M.
  • Macromolecules, Vol. 44, Issue 4
  • DOI: 10.1021/ma101333p

Detailed-atomistic molecular modeling of small molecule diffusion and solution processes in polymeric membrane materials
journal, July 2000


The upper bound revisited
journal, July 2008


Highly permeable polymers for gas separation membranes
journal, January 2010

  • Budd, Peter M.; McKeown, Neil B.
  • Polymer Chemistry, Vol. 1, Issue 1
  • DOI: 10.1039/b9py00319c

Comparison of transport properties of rubbery and glassy polymers and the relevance to the upper bound relationship
journal, February 2015


Gas Separation Membrane Materials: A Perspective
journal, September 2014

  • Baker, Richard W.; Low, Bee Ting
  • Macromolecules, Vol. 47, Issue 20
  • DOI: 10.1021/ma501488s

Positronium Annihilation in Molecular Substances
journal, June 1972

  • Tao, S. J.
  • The Journal of Chemical Physics, Vol. 56, Issue 11
  • DOI: 10.1063/1.1677067

Enhancing the Gas Permeability of Tröger’s Base Derived Polyimides of Intrinsic Microporosity
journal, May 2016


Physical aging in polymers and polymer nanocomposites: recent results and open questions
journal, January 2013

  • Cangialosi, Daniele; Boucher, Virginie M.; Alegría, Angel
  • Soft Matter, Vol. 9, Issue 36
  • DOI: 10.1039/c3sm51077h

Intrinsically Microporous Poly(imide)s: Structure−Porosity Relationship Studied by Gas Sorption and X-ray Scattering
journal, April 2011

  • Ritter, Nicola; Senkovska, Irena; Kaskel, Stefan
  • Macromolecules, Vol. 44, Issue 7
  • DOI: 10.1021/ma102448h

Effect of Film Thickness on the Gas-Permeation Characteristics of Glassy Polymer Membranes
journal, April 2007

  • Huang, Y.; Paul, D. R.
  • Industrial & Engineering Chemistry Research, Vol. 46, Issue 8
  • DOI: 10.1021/ie0610804

Molecular origins of fast and selective gas transport in pentiptycene-containing polyimide membranes and their physical aging behavior
journal, November 2016


The Use of Iptycenes in Rational Macromolecular Design for Gas Separation Membrane Applications
journal, April 2017

  • Weidman, Jennifer R.; Guo, Ruilan
  • Industrial & Engineering Chemistry Research, Vol. 56, Issue 15
  • DOI: 10.1021/acs.iecr.7b00540

Investigation of Polymers by Inverse Gas Chromatography
journal, September 2015


Physical aging of thin glassy polymer films monitored by gas permeability
journal, November 2004


van der Waals Volumes and Radii
journal, March 1964

  • Bondi, A.
  • The Journal of Physical Chemistry, Vol. 68, Issue 3, p. 441-451
  • DOI: 10.1021/j100785a001

Gas transport properties of polysulphones: 3. Comparison of tetramethyl-substituted bisphenols
journal, January 1992


Triptycene-containing poly(benzoxazole-co-imide) membranes with enhanced mechanical strength for high-performance gas separation
journal, April 2018


High performance polymers for membrane separation
journal, November 1994


The temperature dependence of positron lifetimes in solid pivalic acid
journal, December 1981


Rigid and microporous polymers for gas separation membranes
journal, April 2015


Physical Aging, Plasticization and Their Effects on Gas Permeation in “Rigid” Polymers of Intrinsic Microporosity
journal, August 2015


Structural Characterization of a Polymer of Intrinsic Microporosity: X-ray Scattering with Interpretation Enhanced by Molecular Dynamics Simulations
journal, January 2011

  • McDermott, Amanda G.; Larsen, Gregory S.; Budd, Peter M.
  • Macromolecules, Vol. 44, Issue 1
  • DOI: 10.1021/ma1024945

Gas separation using polymer membranes: an overview
journal, November 1994


Triptycene 1 (9,10-o-Benzenoanthracene)
journal, November 1942

  • Bartlett, Paul D.; Ryan, M. Josephine; Cohen, Saul G.
  • Journal of the American Chemical Society, Vol. 64, Issue 11
  • DOI: 10.1021/ja01263a035

The role of ortho-, meta- and para-substitutions in the main-chain structure of poly(etherimide)s and the effects on CO2/CH4 gas separation performance
journal, February 2019

  • Madzarevic, Zeljka P.; Shahid, Salman; Nijmeijer, Kitty
  • Separation and Purification Technology, Vol. 210
  • DOI: 10.1016/j.seppur.2018.08.006

Polyimides in membrane gas separation: Monomer’s molecular design and structural engineering
journal, April 2019


Correlation of separation factor versus permeability for polymeric membranes
journal, October 1991


Polymer ultrapermeability from the inefficient packing of 2D chains
journal, July 2017

  • Rose, Ian; Bezzu, C. Grazia; Carta, Mariolino
  • Nature Materials, Vol. 16, Issue 9
  • DOI: 10.1038/nmat4939

Recent Developments in Synthesis and Applications of Triptycene and Pentiptycene Derivatives
journal, August 2011

  • Jiang, Yi; Chen, Chuan-Feng
  • European Journal of Organic Chemistry, Vol. 2011, Issue 32
  • DOI: 10.1002/ejoc.201100684

Efficient Synthesis of Rigid Ladder Polymers via Palladium Catalyzed Annulation
journal, December 2014

  • Liu, Sheng; Jin, Zexin; Teo, Yew Chin
  • Journal of the American Chemical Society, Vol. 136, Issue 50
  • DOI: 10.1021/ja5110415

Gas transport properties of polysulphones: 1. Role of symmetry of methyl group placement on bisphenol rings
journal, January 1991


Energy-Efficient Hydrogen Separation by AB-Type Ladder-Polymer Molecular Sieves
journal, July 2014

  • Ghanem, Bader S.; Swaidan, Raja; Ma, Xiaohua
  • Advanced Materials, Vol. 26, Issue 39
  • DOI: 10.1002/adma.201401328

An Efficient Polymer Molecular Sieve for Membrane Gas Separations
journal, January 2013


Thermally Rearranged (TR) Polybenzoxazole: Effects of Diverse Imidization Routes on Physical Properties and Gas Transport Behaviors
journal, September 2010

  • Han, Sang Hoon; Misdan, Nurasyikin; Kim, Seungju
  • Macromolecules, Vol. 43, Issue 18
  • DOI: 10.1021/ma101549z

Preparation and Characterization of Polysulfones Containing Both Hexafluoroisopropylidene and Trimethylsilyl Groups as Gas Separation Membrane Materials
journal, February 2004

  • Dai, Ying; Guiver, Michael D.; Robertson, Gilles P.
  • Macromolecules, Vol. 37, Issue 4
  • DOI: 10.1021/ma035739i

Microporous polyimides containing bulky tetra-o-isopropyl and naphthalene groups for gas separation membranes
journal, September 2019


Structure Manipulation in Triptycene-Based Polyimides through Main Chain Geometry Variation and Its Effect on Gas Transport Properties
journal, February 2017

  • Weidman, Jennifer R.; Luo, Shuangjiang; Zhang, Qinnan
  • Industrial & Engineering Chemistry Research, Vol. 56, Issue 7
  • DOI: 10.1021/acs.iecr.6b04946

Physical Aging in Polymer Glasses
journal, March 1995


Modeling Gas and Vapor Sorption and Swelling in Triptycene-Based Polybenzoxazole: Evidence for Entropy-Driven Sorption Behavior
journal, May 2019


Physical aging of polymers
journal, January 1995


Intrinsically Microporous Soluble Polyimides Incorporating Tröger’s Base for Membrane Gas Separation
journal, May 2014

  • Zhuang, Yongbing; Seong, Jong Geun; Do, Yu Seong
  • Macromolecules, Vol. 47, Issue 10
  • DOI: 10.1021/ma5007073

The solution-diffusion model: a review
journal, November 1995


Effect of Hexafluoro-2-propanol Substituents in Polymers on Gas Permeability and Fractional Free Volume
journal, November 2005

  • Dai, Ying; Guiver, Michael D.; Robertson, Gilles P.
  • Macromolecules, Vol. 38, Issue 23
  • DOI: 10.1021/ma051662h

Physical Adsorption Characterization of Nanoporous Materials
journal, June 2010


Physical aging of ultrathin glassy polymer films tracked by gas permeability
journal, November 2009


Gas transport properties of biphenol polysulfones
journal, July 1992

  • Aitken, C. L.; Koros, W. J.; Paul, D. R.
  • Macromolecules, Vol. 25, Issue 14
  • DOI: 10.1021/ma00040a008

Basis of Permeability/Selectivity Tradeoff Relations in Polymeric Gas Separation Membranes
journal, January 1999


Highly CO 2 -Selective Gas Separation Membranes Based on Segmented Copolymers of Poly(Ethylene oxide) Reinforced with Pentiptycene-Containing Polyimide Hard Segments
journal, January 2016

  • Luo, Shuangjiang; Stevens, Kevin A.; Park, Jae Sung
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 3
  • DOI: 10.1021/acsami.5b11355

UV-Rearranged PIM-1 Polymeric Membranes for Advanced Hydrogen Purification and Production
journal, July 2012

  • Li, Fu Yun; Xiao, Youchang; Ong, Yee Kang
  • Advanced Energy Materials, Vol. 2, Issue 12
  • DOI: 10.1002/aenm.201200296

Positron annihilation and 129Xe NMR studies of free volume in polymers
journal, June 2000


Energy-efficient polymeric gas separation membranes for a sustainable future: A review
journal, August 2013


High-Performance Membranes from Polyimides with Intrinsic Microporosity
journal, July 2008

  • Ghanem, Bader S.; McKeown, Neil B.; Budd, Peter M.
  • Advanced Materials, Vol. 20, Issue 14
  • DOI: 10.1002/adma.200702400

Elimination of CO 2 /N 2 Langmuir Sorption and Promotion of “N 2 -Phobicity” within High- T g Glassy Membranes
journal, February 2019


Triptycene Induced Enhancement of Membrane Gas Selectivity for Microporous Tröger's Base Polymers
journal, March 2014

  • Carta, Mariolino; Croad, Matthew; Malpass-Evans, Richard
  • Advanced Materials, Vol. 26, Issue 21
  • DOI: 10.1002/adma.201305783

Physical aging in plastics and other glassy materials
journal, March 1977


Analysis of governing factors controlling gas transport through fresh and aged triptycene-based polyimide films
journal, January 2017


Polymers with Side Chain Porosity for Ultrapermeable and Plasticization Resistant Materials for Gas Separations
journal, April 2019

  • He, Yuan; Benedetti, Francesco M.; Lin, Sharon
  • Advanced Materials, Vol. 31, Issue 21
  • DOI: 10.1002/adma.201807871

Iptycenes in the Design of High Performance Polymers
journal, September 2008

  • Swager, Timothy M.
  • Accounts of Chemical Research, Vol. 41, Issue 9
  • DOI: 10.1021/ar800107v

Free-Volume Distribution of High Permeability Membrane Materials Probed by Positron Annihilation
journal, June 1998

  • Shantarovich, V. P.; Azamatova, Z. K.; Novikov, Yu. A.
  • Macromolecules, Vol. 31, Issue 12
  • DOI: 10.1021/ma971128c

Minimization of Internal Molecular Free Volume:  A Mechanism for the Simultaneous Enhancement of Polymer Stiffness, Strength, and Ductility
journal, May 2006

  • Tsui, Nicholas T.; Paraskos, Alex J.; Torun, Lokman
  • Macromolecules, Vol. 39, Issue 9
  • DOI: 10.1021/ma060047q

Functionalized Rigid Ladder Polymers from Catalytic Arene-Norbornene Annulation Polymerization
journal, November 2017


Gas permeation parameters and other physicochemical properties of a polymer of intrinsic microporosity: Polybenzodioxane PIM-1
journal, December 2008


Highly Permeable Benzotriptycene-Based Polymer of Intrinsic Microporosity
journal, August 2015


Pentiptycene-based polyimides with hierarchically controlled molecular cavity architecture for efficient membrane gas separation
journal, April 2015


Norbornyl benzocyclobutene ladder polymers: Conformation and microporosity
journal, May 2017

  • Lai, Holden W. H.; Liu, Sheng; Xia, Yan
  • Journal of Polymer Science Part A: Polymer Chemistry, Vol. 55, Issue 18
  • DOI: 10.1002/pola.28640

High Performance Polyimide with High Internal Free Volume Elements
journal, January 2011

  • Cho, Yoon Jin; Park, Ho Bum
  • Macromolecular Rapid Communications, Vol. 32, Issue 7
  • DOI: 10.1002/marc.201000690

Polymers of intrinsic microporosity for energy-intensive membrane-based gas separations
journal, August 2018


Ultra-Microporous Triptycene-based Polyimide Membranes for High-Performance Gas Separation
journal, March 2014

  • Ghanem, Bader S.; Swaidan, Raja; Litwiller, Eric
  • Advanced Materials, Vol. 26, Issue 22
  • DOI: 10.1002/adma.201306229