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Title: Polymerization in soft nanoconfinement of lamellar and reverse hexagonal mesophases

Abstract

The polymerization rate decreases in the nanoconfined structure compared to the bulk state due to the segregation effect, which increases the local monomer concentration and enhances the termination reaction.

Authors:
ORCiD logo [1];  [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Chemical and Materials Engineering, New Mexico State University, Las Cruces, USA
  2. Materials Physics & Applications Division, Center for Integrated Nanotechnologies, Los Alamos National Laboratory, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1568936
Grant/Contract Number:  
89233218CNA000001
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Soft Matter
Additional Journal Information:
Journal Name: Soft Matter; Journal ID: ISSN 1744-683X
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Qavi, Sahar, Bandegi, Alireza, Firestone, Millicent, and Foudazi, Reza. Polymerization in soft nanoconfinement of lamellar and reverse hexagonal mesophases. United Kingdom: N. p., 2019. Web. doi:10.1039/C9SM01565E.
Qavi, Sahar, Bandegi, Alireza, Firestone, Millicent, & Foudazi, Reza. Polymerization in soft nanoconfinement of lamellar and reverse hexagonal mesophases. United Kingdom. doi:10.1039/C9SM01565E.
Qavi, Sahar, Bandegi, Alireza, Firestone, Millicent, and Foudazi, Reza. Tue . "Polymerization in soft nanoconfinement of lamellar and reverse hexagonal mesophases". United Kingdom. doi:10.1039/C9SM01565E.
@article{osti_1568936,
title = {Polymerization in soft nanoconfinement of lamellar and reverse hexagonal mesophases},
author = {Qavi, Sahar and Bandegi, Alireza and Firestone, Millicent and Foudazi, Reza},
abstractNote = {The polymerization rate decreases in the nanoconfined structure compared to the bulk state due to the segregation effect, which increases the local monomer concentration and enhances the termination reaction.},
doi = {10.1039/C9SM01565E},
journal = {Soft Matter},
number = ,
volume = ,
place = {United Kingdom},
year = {2019},
month = {1}
}

Journal Article:
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Works referenced in this record:

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Control of Pore Sizes in Mesoporous Silica Templated by Liquid Crystals in Block Copolymer−Cosurfactant−Water Systems
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