Laboratory study of the heterogeneous ice nucleation on black-carbon-containing aerosol

Nichman, Leonid; Wolf, Martin; Davidovits, Paul; Onasch, Timothy B.; Zhang, Yue; Worsnop, Doug R.; Bhandari, Janarjan; Mazzoleni, Claudio; Cziczo, Daniel J.

doi:10.5194/acp-19-12175-2019

Title: Laboratory study of the heterogeneous ice nucleation on black-carbon-containing aerosol

Journal Article · 01 October 2019 · Atmospheric Chemistry and Physics (Online)

DOI: https://doi.org/10.5194/acp-19-12175-2019 · OSTI ID:1568917

;

; Davidovits, Paul;

;

; Worsnop, Doug R.;

;

; Cziczo, Daniel J.

Abstract. Soot and black carbon (BC) particles are generated in the incomplete combustion of fossil fuels, biomass, and biofuels. These airborne particles affect air quality, human health, aerosol–cloud interactions, precipitation formation, and climate. At present, the climate effects of BC particles are not well understood. Their role in cloud formation is obscured by their chemical and physical variability and by the internal mixing states of these particles with other compounds. Ice nucleation in field studies is often difficult to interpret. Nonetheless, most field studies seem to suggest that BC particles are not efficient ice-nucleating particles (INPs). On the other hand, laboratory measurements show that in some cases, BC particles can be highly active INPs under certain conditions. By working with well-characterized BC particles, our aim is to systematically establish the factors that govern the ice nucleation activity of BC. The current study focuses on laboratory measurements of the effectiveness of BC-containing aerosol in the formation of ice crystals in temperature and ice supersaturation conditions relevant to cirrus clouds. We examine ice nucleation on BC particles under water-subsaturated cirrus cloud conditions, commonly understood as deposition-mode ice nucleation. We study a series of well-characterized commercial carbon black particles with varying morphologies and surface chemistries as well as ethylene flame-generated combustion soot. The carbon black particles used in this study are proxies for atmospherically relevant BC aerosols. These samples were characterized by electron microscopy, mass spectrometry, and optical scattering measurements. Ice nucleation activity was systematically examined in temperature and saturation conditions in the ranges of 217≤T≤235 K and 1.0≤Sice≤1.5 and 0.59≤Swater≤0.98, respectively, using a SPectrometer for Ice Nuclei (SPIN) instrument, which is a continuous-flow diffusion chamber coupled with instrumentation to measure light scattering and polarization. To study the effect of coatings on INPs, the BC-containing particles were coated with organic acids found in the atmosphere, namely stearic acid, cis-pinonic acid, and oxalic acid. The results show significant variations in ice nucleation activity as a function of size, morphology, and surface chemistry of the BC particles. The measured ice nucleation activity dependencies on temperature, supersaturation conditions, and the physicochemical properties of the BC particles are consistent with an ice nucleation mechanism of pore condensation followed by freezing. Coatings and surface oxidation modify the initial formation efficiency of pristine ice crystals on BC-containing aerosol. Depending on the BC material and the coating, both inhibition and enhancement in INP activity were observed. Our measurements at low temperatures complement published data and highlight the capability of some BC particles to nucleate ice under low ice supersaturation conditions. These results are expected to help refine theories relating to soot INP activation in the atmosphere.

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0011935

OSTI ID:: 1568917

Journal Information:: Atmospheric Chemistry and Physics (Online), Journal Name: Atmospheric Chemistry and Physics (Online) Journal Issue: 19 Vol. 19; ISSN 1680-7324

Publisher:: Copernicus Publications, EGUCopyright Statement

Country of Publication:: Germany

Language:: English

References (120)

Morphology and mixing state of aged soot particles at a remote marine free troposphere site: Implications for optical properties: Morphology and mixing state of aged soot China, Swarup; Scarnato, Barbara; Owen, Robert C. Geophysical Research Letters, Vol. 42, Issue 4 https://doi.org/10.1002/2014GL062404	journal	February 2015
Aircraft soot indirect effect on large-scale cirrus clouds: Is the indirect forcing by aircraft soot positive or negative?: AIRCRAFT SOOT INDIRECT EFFECT Zhou, Cheng; Penner, Joyce E. Journal of Geophysical Research: Atmospheres, Vol. 119, Issue 19 https://doi.org/10.1002/2014JD021914	journal	October 2014
Characteristics of atmospheric ice nucleating particles associated with biomass burning in the US: Prescribed burns and wildfires: Biomass burning ice nucleating particles McCluskey, Christina S.; DeMott, Paul J.; Prenni, Anthony J. Journal of Geophysical Research: Atmospheres, Vol. 119, Issue 17 https://doi.org/10.1002/2014JD021980	journal	September 2014
Ice nucleation activity of diesel soot particles at cirrus relevant temperature conditions: Effects of hydration, secondary organics coating, soot morphology, and coagulation Kulkarni, Gourihar; China, Swarup; Liu, Shang Geophysical Research Letters, Vol. 43, Issue 7 https://doi.org/10.1002/2016GL068707	journal	April 2016
On the role of ice‐nucleating aerosol in the formation of ice particles in tropical mesoscale convective systems Ladino, Luis A.; Korolev, Alexei; Heckman, Ivan Geophysical Research Letters, Vol. 44, Issue 3 https://doi.org/10.1002/2016GL072455	journal	February 2017
Bounding the role of black carbon in the climate system: A scientific assessment: BLACK CARBON IN THE CLIMATE SYSTEM Bond, T. C.; Doherty, S. J.; Fahey, D. W. Journal of Geophysical Research: Atmospheres, Vol. 118, Issue 11 https://doi.org/10.1002/jgrd.50171	journal	June 2013
Adsorption Study of Porous Structure Development in Carbon Blacks Kruk, Michal; Jaroniec, Mietek; Bereznitski, Yuri Journal of Colloid and Interface Science, Vol. 182, Issue 1 https://doi.org/10.1006/jcis.1996.0461	journal	September 1996
In-situ atomic force microscopy investigation of aerosols exposed to different humidities Köllensperger, G.; Friedbacher, G.; Kotzick, R. Fresenius' Journal of Analytical Chemistry, Vol. 364, Issue 4 https://doi.org/10.1007/s002160051340	journal	June 1999
Carboxylic acids in the troposphere, occurrence, sources, and sinks: A review Chebbi, A.; Carlier, P. Atmospheric Environment, Vol. 30, Issue 24 https://doi.org/10.1016/1352-2310(96)00102-1	journal	December 1996
Ice nucleation on soot particles Gorbunov, B.; Baklanov, A.; Kakutkina, N. Journal of Aerosol Science, Vol. 32, Issue 2 https://doi.org/10.1016/S0021-8502(00)00077-X	journal	February 2001
Low-Molecular-Weight Dicarboxylic Acids in an Urban and Rural Atmosphere Kerminen, Veli-Matti; Ojanen, Christina; Pakkanen, Tuomo Journal of Aerosol Science, Vol. 31, Issue 3 https://doi.org/10.1016/S0021-8502(99)00063-4	journal	March 2000
Pore structure of soot deposits from several combustion sources Rockne, Karl J.; Taghon, Gary L.; Kosson, David S. Chemosphere, Vol. 41, Issue 8 https://doi.org/10.1016/S0045-6535(00)00040-0	journal	October 2000
Elemental composition and morphology of ice-crystal residual particles in cirrus clouds and contrails Petzold, A.; Ström, J.; Ohlsson, S. Atmospheric Research, Vol. 49, Issue 1 https://doi.org/10.1016/S0169-8095(97)00083-5	journal	August 1998
Carbonaceous particle hydration Chughtai, A. R.; Williams, G. R.; Atteya, M. M. O. Atmospheric Environment, Vol. 33, Issue 17 https://doi.org/10.1016/S1352-2310(98)00329-X	journal	August 1999
Aviation and global climate change in the 21st century Lee, David S.; Fahey, David W.; Forster, Piers M. Atmospheric Environment, Vol. 43, Issue 22-23 https://doi.org/10.1016/j.atmosenv.2009.04.024	journal	July 2009
Development of a polarization optical particle counter capable of aerosol type classification Kobayashi, Hiroshi; Hayashi, Masahiko; Shiraishi, Koichi Atmospheric Environment, Vol. 97 https://doi.org/10.1016/j.atmosenv.2014.05.006	journal	November 2014
Review: Particle number size distributions from seven major sources and implications for source apportionment studies Vu, Tuan V.; Delgado-Saborit, Juana Maria; Harrison, Roy M. Atmospheric Environment, Vol. 122 https://doi.org/10.1016/j.atmosenv.2015.09.027	journal	December 2015
Sampling the composition of cirrus ice residuals Cziczo, Daniel J.; Froyd, Karl D. Atmospheric Research, Vol. 142 https://doi.org/10.1016/j.atmosres.2013.06.012	journal	June 2014
Carbon black vs. black carbon and other airborne materials containing elemental carbon: Physical and chemical distinctions Long, Christopher M.; Nascarella, Marc A.; Valberg, Peter A. Environmental Pollution, Vol. 181 https://doi.org/10.1016/j.envpol.2013.06.009	journal	October 2013
Particle analysis by laser mass spectrometry (PALMS) studies of ice nuclei and other low number density particles Cziczo, Daniel J.; Thomson, David S.; Thompson, Thomas L. International Journal of Mass Spectrometry, Vol. 258, Issue 1-3 https://doi.org/10.1016/j.ijms.2006.05.013	journal	December 2006
Soot aggregate restructuring during water processing Ma, Xiaofei; Zangmeister, Christopher D.; Gigault, Julien Journal of Aerosol Science, Vol. 66 https://doi.org/10.1016/j.jaerosci.2013.08.001	journal	December 2013
Morphological characteristics of particles emitted from combustion of different fuels in improved and traditional cookstoves Arora, Pooja; Jain, Suresh Journal of Aerosol Science, Vol. 82 https://doi.org/10.1016/j.jaerosci.2014.12.006	journal	April 2015
New studies on scattering properties of different kinds of soot and carbon-black Francis, Mirvatte; Renard, Jean-Baptiste; Hadamcik, Edith Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 112, Issue 11 https://doi.org/10.1016/j.jqsrt.2011.01.009	journal	July 2011
A TEM study of soot, carbon nanotubes, and related fullerene nanopolyhedra in common fuel-gas combustion sources Murr, L. E.; Soto, K. F. Materials Characterization, Vol. 55, Issue 1 https://doi.org/10.1016/j.matchar.2005.02.008	journal	July 2005
The new carbon black and its role in the United States manufacturing renaissance Hardman, Ned J. Reinforced Plastics, Vol. 61, Issue 3 https://doi.org/10.1016/j.repl.2017.02.002	journal	May 2017
Single-Particle Time-of-Flight Mass Spectrometry Utilizing a Femtosecond Desorption and Ionization Laser Zawadowicz, Maria A.; Abdelmonem, Ahmed; Mohr, Claudia Analytical Chemistry, Vol. 87, Issue 24 https://doi.org/10.1021/acs.analchem.5b03158	journal	November 2015
Investigating the Heterogeneous Ice Nucleation of Sea Spray Aerosols Using Prochlorococcus as a Model Source of Marine Organic Matter Wolf, Martin J.; Coe, Allison; Dove, Lilian A. Environmental Science & Technology, Vol. 53, Issue 3 https://doi.org/10.1021/acs.est.8b05150	journal	December 2018
Effect of the Aerosol-Phase State on Secondary Organic Aerosol Formation from the Reactive Uptake of Isoprene-Derived Epoxydiols (IEPOX) Zhang, Yue; Chen, Yuzhi; Lambe, Andrew T. Environmental Science & Technology Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acs.estlett.8b00044	journal	February 2018
Hydrophobic Ice Confined between Graphene and MoS ₂ Bampoulis, Pantelis; Teernstra, Vincent J.; Lohse, Detlef The Journal of Physical Chemistry C, Vol. 120, Issue 47 https://doi.org/10.1021/acs.jpcc.6b09812	journal	November 2016
Ice Nucleation Activity of Graphene and Graphene Oxides Häusler, Thomas; Gebhardt, Paul; Iglesias, Daniel The Journal of Physical Chemistry C, Vol. 122, Issue 15 https://doi.org/10.1021/acs.jpcc.7b10675	journal	March 2018
Water Confined in Nanocapillaries: Two-Dimensional Bilayer Squarelike Ice and Associated Solid–Liquid–Solid Transition Zhu, Weiduo; Zhu, YinBo; Wang, Lu The Journal of Physical Chemistry C, Vol. 122, Issue 12 https://doi.org/10.1021/acs.jpcc.8b00195	journal	February 2018
Influence of Pore Wall Hydrophobicity on Freezing and Melting of Confined Water Morishige, Kunimitsu The Journal of Physical Chemistry C, Vol. 122, Issue 9 https://doi.org/10.1021/acs.jpcc.8b00538	journal	January 2018
Ice Nucleation Properties of Oxidized Carbon Nanomaterials Whale, Thomas F.; Rosillo-Lopez, Martin; Murray, Benjamin J. The Journal of Physical Chemistry Letters, Vol. 6, Issue 15 https://doi.org/10.1021/acs.jpclett.5b01096	journal	July 2015
The Role of Organic Aerosol in Atmospheric Ice Nucleation: A Review Knopf, Daniel A.; Alpert, Peter A.; Wang, Bingbing ACS Earth and Space Chemistry, Vol. 2, Issue 3 https://doi.org/10.1021/acsearthspacechem.7b00120	journal	January 2018
Known and Unexplored Organic Constituents in the Earth's Atmosphere Goldstein, Allen H.; Galbally, Ian E. Environmental Science & Technology, Vol. 41, Issue 5 https://doi.org/10.1021/es072476p	journal	March 2007
Role of OH-Initiated Oxidation of Isoprene in Aging of Combustion Soot Khalizov, Alexei F.; Lin, Yun; Qiu, Chong Environmental Science & Technology, Vol. 47, Issue 5 https://doi.org/10.1021/es3045339	journal	February 2013
Adsorption of Gases in Multimolecular Layers Brunauer, Stephen; Emmett, P. H.; Teller, Edward Journal of the American Chemical Society, Vol. 60, Issue 2, p. 309-319 https://doi.org/10.1021/ja01269a023	journal	February 1938
Heterogeneous Nucleation of Ice on Carbon Surfaces Lupi, Laura; Hudait, Arpa; Molinero, Valeria Journal of the American Chemical Society, Vol. 136, Issue 8 https://doi.org/10.1021/ja411507a	journal	February 2014
Ozonolysis of Mixed Oleic-Acid/Stearic-Acid Particles: Reaction Kinetics and Chemical Morphology Katrib, Y.; Biskos, G.; Buseck, P. R. The Journal of Physical Chemistry A, Vol. 109, Issue 48 https://doi.org/10.1021/jp054714d	journal	December 2005
Dissociative Adsorption of Water at Vacancy Defects in Graphite Cabrera-Sanfelix, Pepa; Darling, George R. The Journal of Physical Chemistry C, Vol. 111, Issue 49 https://doi.org/10.1021/jp076241b	journal	December 2007
Does Hydrophilicity of Carbon Particles Improve Their Ice Nucleation Ability? Lupi, Laura; Molinero, Valeria The Journal of Physical Chemistry A, Vol. 118, Issue 35 https://doi.org/10.1021/jp4118375	journal	February 2014
Chemical Compositions of Black Carbon Particle Cores and Coatings via Soot Particle Aerosol Mass Spectrometry with Photoionization and Electron Ionization Canagaratna, Manjula R.; Massoli, Paola; Browne, Eleanor C. The Journal of Physical Chemistry A, Vol. 119, Issue 19 https://doi.org/10.1021/jp510711u	journal	November 2014
Experimental Study of Water Adsorption on Activated Carbons Salame, Issa I.; Bandosz, Teresa J. Langmuir, Vol. 15, Issue 2 https://doi.org/10.1021/la980492h	journal	January 1999
Ice formation by black carbon particles DeMott, P. J.; Chen, Y.; Kreidenweis, S. M. Geophysical Research Letters, Vol. 26, Issue 16 https://doi.org/10.1029/1999GL900580	journal	August 1999
Soot and sulfate aerosol particles in the remote marine troposphere Pósfai, Mihály; Anderson, James R.; Buseck, Peter R. Journal of Geophysical Research: Atmospheres, Vol. 104, Issue D17 https://doi.org/10.1029/1999JD900208	journal	September 1999
Historical record of carbonaceous particle concentrations from a European high-alpine glacier (Colle Gnifetti, Switzerland) Lavanchy, V. M. H.; Gäggeler, H. W.; Schotterer, U. Journal of Geophysical Research: Atmospheres, Vol. 104, Issue D17 https://doi.org/10.1029/1999JD900408	journal	September 1999
Effect of sulfuric acid coating on heterogeneous ice nucleation by soot aerosol particles Möhler, O. Journal of Geophysical Research, Vol. 110, Issue D11 https://doi.org/10.1029/2004JD005169	journal	January 2005
Laboratory studies of ice formation via deposition mode nucleation onto mineral dust and n-hexane soot samples Kanji, Zamin A.; Abbatt, Jonathan P. D. Journal of Geophysical Research, Vol. 111, Issue D16 https://doi.org/10.1029/2005JD006766	journal	January 2006
Single-particle mass spectrometry of tropospheric aerosol particles: TROPOSPHERIC AEROSOL PARTICLES Murphy, D. M.; Cziczo, D. J.; Froyd, K. D. Journal of Geophysical Research: Atmospheres, Vol. 111, Issue D23 https://doi.org/10.1029/2006JD007340	journal	September 2006
Ice nucleation behavior of biomass combustion particles at cirrus temperatures DeMott, Paul J.; Petters, Markus D.; Prenni, Anthony J. Journal of Geophysical Research, Vol. 114, Issue D16 https://doi.org/10.1029/2009JD012036	journal	January 2009
Heterogeneous ice nucleation on particles composed of humic-like substances impacted by O ₃ Wang, Bingbing; Knopf, Daniel A. Journal of Geophysical Research, Vol. 116, Issue D3 https://doi.org/10.1029/2010JD014964	journal	January 2011
Ice nucleation and droplet formation by bare and coated soot particles Friedman, Beth; Kulkarni, Gourihar; Beránek, Josef Journal of Geophysical Research, Vol. 116, Issue D17 https://doi.org/10.1029/2011JD015999	journal	January 2011
The potential impact of soot particles from aircraft exhaust on cirrus clouds Jensen, Eric J.; Toon, Owen. B. Geophysical Research Letters, Vol. 24, Issue 3 https://doi.org/10.1029/96GL03235	journal	February 1997
Modeling phase functions for dustlike tropospheric aerosols using a shape mixture of randomly oriented polydisperse spheroids Mishchenko, Michael I.; Travis, Larry D.; Kahn, Ralph A. Journal of Geophysical Research: Atmospheres, Vol. 102, Issue D14 https://doi.org/10.1029/96JD02110	journal	July 1997
Water activity as the determinant for homogeneous ice nucleation in aqueous solutions Koop, Thomas; Luo, Beiping; Tsias, Athanasios Nature, Vol. 406, Issue 6796 https://doi.org/10.1038/35020537	journal	August 2000
Enhanced heterogeneous ice nucleation by special surface geometry Bi, Yuanfei; Cao, Boxiao; Li, Tianshu Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15372	journal	May 2017
In situ detection of biological particles in cloud ice-crystals Pratt, Kerri A.; DeMott, Paul J.; French, Jeffrey R. Nature Geoscience, Vol. 2, Issue 6 https://doi.org/10.1038/ngeo521	journal	May 2009
Soot superaggregates from flaming wildfires and their direct radiative forcing Chakrabarty, Rajan K.; Beres, Nicholas D.; Moosmüller, Hans Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep05508	journal	July 2014
Impact of sequential surface-modification of graphene oxide on ice nucleation Biggs, Caroline I.; Packer, Christopher; Hindmarsh, Steven Physical Chemistry Chemical Physics, Vol. 19, Issue 33 https://doi.org/10.1039/C7CP03219F	journal	January 2017
Measuring rates of reaction in supercooled organic particles with implications for atmospheric aerosol Hearn, John D.; Smith, Geoffrey D. Physical Chemistry Chemical Physics, Vol. 7, Issue 13 https://doi.org/10.1039/b506424d	journal	January 2005
Cloud condensation nuclei and ice nucleation activity of hydrophobic and hydrophilic soot particles Koehler, Kirsten A.; DeMott, Paul J.; Kreidenweis, Sonia M. Physical Chemistry Chemical Physics, Vol. 11, Issue 36 https://doi.org/10.1039/b905334b	journal	January 2009
Ice nucleation by particles immersed in supercooled cloud droplets Murray, B. J.; O'Sullivan, D.; Atkinson, J. D. Chemical Society Reviews, Vol. 41, Issue 19 https://doi.org/10.1039/c2cs35200a	journal	January 2012
Two-step crystal nucleation via capillary condensation Christenson, Hugo K. CrystEngComm, Vol. 15, Issue 11 https://doi.org/10.1039/c3ce26887j	journal	January 2013
The thermodynamics of frost damage to porous solids Everett, D. H. Transactions of the Faraday Society, Vol. 57 https://doi.org/10.1039/tf9615701541	journal	January 1961
Entropy Effect in Ice Crystal Nucleation Fletcher, N. H. The Journal of Chemical Physics, Vol. 30, Issue 6 https://doi.org/10.1063/1.1730221	journal	June 1959
Diameter-dependent hydrophobicity in carbon nanotubes Kyakuno, Haruka; Fukasawa, Mamoru; Ichimura, Ryota The Journal of Chemical Physics, Vol. 145, Issue 6 https://doi.org/10.1063/1.4960609	journal	August 2016
Packing density of rigid aggregates is independent of scale Zangmeister, C. D.; Radney, J. G.; Dockery, L. T. Proceedings of the National Academy of Sciences, Vol. 111, Issue 25 https://doi.org/10.1073/pnas.1403768111	journal	June 2014
Global long-range transport and lung cancer risk from polycyclic aromatic hydrocarbons shielded by coatings of organic aerosol Shrivastava, Manish; Lou, Silja; Zelenyuk, Alla Proceedings of the National Academy of Sciences, Vol. 114, Issue 6 https://doi.org/10.1073/pnas.1618475114	journal	January 2017
Pore condensation and freezing is responsible for ice formation below water saturation for porous particles David, Robert O.; Marcolli, Claudia; Fahrni, Jonas Proceedings of the National Academy of Sciences, Vol. 116, Issue 17 https://doi.org/10.1073/pnas.1813647116	journal	April 2019
Development of an Aerosol Mass Spectrometer for Size and Composition Analysis of Submicron Particles Jayne, John T.; Leard, Danna C.; Zhang, Xuefeng Aerosol Science and Technology, Vol. 33, Issue 1-2 https://doi.org/10.1080/027868200410840	journal	July 2000
Particle Morphology and Density Characterization by Combined Mobility and Aerodynamic Diameter Measurements. Part 1: Theory DeCarlo, Peter; Slowik, Jay; Worsnop, Douglas Aerosol Science and Technology, Vol. 38, Issue 12 https://doi.org/10.1080/02786826.2004.10399461	journal	December 2004
Impact of Particle Generation Method on the Apparent Hygroscopicity of Insoluble Mineral Particles Sullivan, Ryan C.; Moore, Meagan J. K.; Petters, Markus D. Aerosol Science and Technology, Vol. 44, Issue 10 https://doi.org/10.1080/02786826.2010.497514	journal	August 2010
Ns-Soot: A Material-Based Term for Strongly Light-Absorbing Carbonaceous Particles Buseck, Peter R.; Adachi, Kouji; Gelencsér, András Aerosol Science and Technology, Vol. 48, Issue 7 https://doi.org/10.1080/02786826.2014.919374	journal	May 2014
A New Method to Determine the Number Concentrations of Refractory Black Carbon Ice Nucleating Particles Levin, E. J. T.; McMeeking, G. R.; DeMott, P. J. Aerosol Science and Technology, Vol. 48, Issue 12 https://doi.org/10.1080/02786826.2014.977843	journal	October 2014
Morphology of diesel soot residuals from supercooled water droplets and ice crystals: implications for optical properties China, Swarup; Kulkarni, Gourihar; Scarnato, Barbara V. Environmental Research Letters, Vol. 10, Issue 11 https://doi.org/10.1088/1748-9326/10/11/114010	journal	November 2015
The effect of organic coating on the heterogeneous ice nucleation efficiency of mineral dust aerosols Möhler, O.; Benz, S.; Saathoff, H. Environmental Research Letters, Vol. 3, Issue 2 https://doi.org/10.1088/1748-9326/3/2/025007	journal	April 2008
Fast Dynamics of Water Droplets Freezing from the Outside In Wildeman, Sander; Sterl, Sebastian; Sun, Chao Physical Review Letters, Vol. 118, Issue 8 https://doi.org/10.1103/PhysRevLett.118.084101	journal	February 2017
The Freezing Point of Water in Porous Glass Blachere, J. R.; Young, J. E. Journal of the American Ceramic Society, Vol. 55, Issue 6 https://doi.org/10.1111/j.1151-2916.1972.tb11291.x	journal	June 1972
Fine particles in the global troposphere A review Heintzenberg, Jost Tellus B, Vol. 41B, Issue 2 https://doi.org/10.1111/j.1600-0889.1989.tb00132.x	journal	April 1989
Ice nucleation on flame soot aerosol of different organic carbon content [Ice nucleation on flame soot aerosol of different organic carbon content] Möhler, Ottmar; Linke, Claudia; Saathoff, Harald Meteorologische Zeitschrift, Vol. 14, Issue 4 https://doi.org/10.1127/0941-2948/2005/0055	journal	September 2005
Global Phase Diagram of Water Confined on the Nanometer Scale Kyakuno, Haruka; Matsuda, Kazuyuki; Yahiro, Hitomi Journal of the Physical Society of Japan, Vol. 79, Issue 8 https://doi.org/10.1143/JPSJ.79.083802	journal	August 2010
An Exploratory Study of Ice Nucleation by Soot Aerosols DeMott, Paul J. Journal of Applied Meteorology, Vol. 29, Issue 10 https://doi.org/10.1175/1520-0450(1990)029<1072:AESOIN>2.0.CO;2	journal	October 1990
Ice in the Capillaries of Solid Particles and its Effect on their Nucleating Ability Higuchi, Keiji; Fukuta, Norihiko Journal of the Atmospheric Sciences, Vol. 23, Issue 2 https://doi.org/10.1175/1520-0469(1966)023<0187:IITCOS>2.0.CO;2	journal	March 1966
Freezing Rate Due to Heterogeneous Nucleation Vali, Gabor Journal of the Atmospheric Sciences, Vol. 51, Issue 13 https://doi.org/10.1175/1520-0469(1994)051<1843:FRDTHN>2.0.CO;2	journal	July 1994
Overview of Ice Nucleating Particles Kanji, Zamin A.; Ladino, Luis A.; Wex, Heike Meteorological Monographs, Vol. 58 https://doi.org/10.1175/AMSMONOGRAPHS-D-16-0006.1	journal	January 2017
Measurements of Ice Nucleating Particles and Ice Residuals Cziczo, Daniel J.; Ladino, Luis; Boose, Yvonne Meteorological Monographs, Vol. 58 https://doi.org/10.1175/AMSMONOGRAPHS-D-16-0008.1	journal	January 2017
A Particle-Surface-Area-Based Parameterization of Immersion Freezing on Desert Dust Particles Niemand, Monika; Möhler, Ottmar; Vogel, Bernhard Journal of the Atmospheric Sciences, Vol. 69, Issue 10 https://doi.org/10.1175/JAS-D-11-0249.1	journal	October 2012
Improvements to an Empirical Parameterization of Heterogeneous Ice Nucleation and Its Comparison with Observations Phillips, Vaughan T. J.; Demott, Paul J.; Andronache, Constantin Journal of the Atmospheric Sciences, Vol. 70, Issue 2 https://doi.org/10.1175/JAS-D-12-080.1	journal	February 2013
A New Ice Nucleation Active Site Parameterization for Desert Dust and Soot Ullrich, Romy; Hoose, Corinna; Möhler, Ottmar Journal of the Atmospheric Sciences, Vol. 74, Issue 3 https://doi.org/10.1175/JAS-D-16-0074.1	journal	March 2017
Ice growth in a spherical cavity of a porous medium Vlahou, Ioanna; Worster, M. Grae Journal of Glaciology, Vol. 56, Issue 196 https://doi.org/10.3189/002214310791968494	journal	January 2010
Effect of Thermodenuding on the Structure of Nascent Flame Soot Aggregates Bhandari, Janarjan; China, Swarup; Onasch, Timothy Atmosphere, Vol. 8, Issue 12 https://doi.org/10.3390/atmos8090166	journal	September 2017
A numerical evaluation of global oceanic emissions of α-pinene and isoprene Luo, G.; Yu, F. Atmospheric Chemistry and Physics, Vol. 10, Issue 4 https://doi.org/10.5194/acp-10-2007-2010	journal	January 2010
Studies of propane flame soot acting as heterogeneous ice nuclei in conjunction with single particle soot photometer measurements Crawford, I.; Möhler, O.; Schnaiter, M. Atmospheric Chemistry and Physics, Vol. 11, Issue 18 https://doi.org/10.5194/acp-11-9549-2011	journal	January 2011
Heterogeneous ice nucleation on atmospheric aerosols: a review of results from laboratory experiments Hoose, C.; Möhler, O. Atmospheric Chemistry and Physics, Vol. 12, Issue 20 https://doi.org/10.5194/acp-12-9817-2012	journal	January 2012
Time dependence of immersion freezing: an experimental study on size selected kaolinite particles Welti, A.; Lüönd, F.; Kanji, Z. A. Atmospheric Chemistry and Physics, Vol. 12, Issue 20 https://doi.org/10.5194/acp-12-9893-2012	journal	January 2012
A new method for measuring optical scattering properties of atmospherically relevant dusts using the Cloud and Aerosol Spectrometer with Polarization (CASPOL) Glen, A.; Brooks, S. D. Atmospheric Chemistry and Physics, Vol. 13, Issue 3 https://doi.org/10.5194/acp-13-1345-2013	journal	January 2013
Deposition nucleation viewed as homogeneous or immersion freezing in pores and cavities Marcolli, C. Atmospheric Chemistry and Physics, Vol. 14, Issue 4 https://doi.org/10.5194/acp-14-2071-2014	journal	January 2014
Interpretation of freezing nucleation experiments: singular and stochastic; sites and surfaces Vali, G. Atmospheric Chemistry and Physics, Vol. 14, Issue 11 https://doi.org/10.5194/acp-14-5271-2014	journal	January 2014
Technical Note: A proposal for ice nucleation terminology Vali, G.; DeMott, P. J.; Möhler, O. Atmospheric Chemistry and Physics, Vol. 15, Issue 18 https://doi.org/10.5194/acp-15-10263-2015	journal	January 2015
Black carbon surface oxidation and organic composition of beech-wood soot aerosols Corbin, J. C.; Lohmann, U.; Sierau, B. Atmospheric Chemistry and Physics, Vol. 15, Issue 20 https://doi.org/10.5194/acp-15-11885-2015	journal	January 2015
Pre-activation of ice-nucleating particles by the pore condensation and freezing mechanism Wagner, Robert; Kiselev, Alexei; Möhler, Ottmar Atmospheric Chemistry and Physics, Vol. 16, Issue 4 https://doi.org/10.5194/acp-16-2025-2016	journal	January 2016
A microphysics guide to cirrus clouds – Part 1: Cirrus types Krämer, Martina; Rolf, Christian; Luebke, Anna Atmospheric Chemistry and Physics, Vol. 16, Issue 5 https://doi.org/10.5194/acp-16-3463-2016	journal	January 2016
Phase transition observations and discrimination of small cloud particles by light polarization in expansion chamber experiments Nichman, Leonid; Fuchs, Claudia; Järvinen, Emma Atmospheric Chemistry and Physics, Vol. 16, Issue 5 https://doi.org/10.5194/acp-16-3651-2016	journal	January 2016
The evolution of biomass-burning aerosol size distributions due to coagulation: dependence on fire and meteorological details and parameterization Sakamoto, Kimiko M.; Laing, James R.; Stevens, Robin G. Atmospheric Chemistry and Physics, Vol. 16, Issue 12 https://doi.org/10.5194/acp-16-7709-2016	journal	January 2016
Uncertainty in counting ice nucleating particles with continuous flow diffusion chambers Garimella, Sarvesh; Rothenberg, Daniel A.; Wolf, Martin J. Atmospheric Chemistry and Physics, Vol. 17, Issue 17 https://doi.org/10.5194/acp-17-10855-2017	journal	January 2017
Pre-activation of aerosol particles by ice preserved in pores Marcolli, Claudia Atmospheric Chemistry and Physics, Vol. 17, Issue 3 https://doi.org/10.5194/acp-17-1595-2017	journal	January 2017
Cloud droplet activation of black carbon particles coated with organic compounds of varying solubility Dalirian, Maryam; Ylisirniö, Arttu; Buchholz, Angela Atmospheric Chemistry and Physics, Vol. 18, Issue 16 https://doi.org/10.5194/acp-18-12477-2018	journal	January 2018
Ice nucleation abilities of soot particles determined with the Horizontal Ice Nucleation Chamber Mahrt, Fabian; Marcolli, Claudia; David, Robert O. Atmospheric Chemistry and Physics, Vol. 18, Issue 18 https://doi.org/10.5194/acp-18-13363-2018	journal	January 2018
Composition of ice particle residuals in mixed-phase clouds at Jungfraujoch (Switzerland): enrichment and depletion of particle groups relative to total aerosol Eriksen Hammer, Stine; Mertes, Stephan; Schneider, Johannes Atmospheric Chemistry and Physics, Vol. 18, Issue 19 https://doi.org/10.5194/acp-18-13987-2018	journal	January 2018
Ice-nucleating particle concentrations unaffected by urban air pollution in Beijing, China Chen, Jie; Wu, Zhijun; Augustin-Bauditz, Stefanie Atmospheric Chemistry and Physics, Vol. 18, Issue 5 https://doi.org/10.5194/acp-18-3523-2018	journal	January 2018
Enhanced ice nucleation activity of coal fly ash aerosol particles initiated by ice-filled pores Umo, Nsikanabasi Silas; Wagner, Robert; Ullrich, Romy Atmospheric Chemistry and Physics, Vol. 19, Issue 13 https://doi.org/10.5194/acp-19-8783-2019	journal	January 2019
Oxalic acid as a heterogeneous ice nucleus in the upper troposphere and its indirect aerosol effect Zobrist, B.; Marcolli, C.; Koop, T. Atmospheric Chemistry and Physics, Vol. 6, Issue 10 https://doi.org/10.5194/acp-6-3115-2006	journal	January 2006
Insights into the role of soot aerosols in cirrus cloud formation Kärcher, B.; Möhler, O.; DeMott, P. J. Atmospheric Chemistry and Physics, Vol. 7, Issue 16 https://doi.org/10.5194/acp-7-4203-2007	journal	January 2007
Do atmospheric aerosols form glasses? Zobrist, B.; Marcolli, C.; Pedernera, D. A. Atmospheric Chemistry and Physics, Vol. 8, Issue 17 https://doi.org/10.5194/acp-8-5221-2008	journal	January 2008
Inhibition of ice crystallisation in highly viscous aqueous organic acid droplets Murray, B. J. Atmospheric Chemistry and Physics, Vol. 8, Issue 17 https://doi.org/10.5194/acp-8-5423-2008	journal	January 2008
Studies of heterogeneous freezing by three different desert dust samples Connolly, P. J.; Möhler, O.; Field, P. R. Atmospheric Chemistry and Physics, Vol. 9, Issue 8 https://doi.org/10.5194/acp-9-2805-2009	journal	January 2009
Dry particle generation with a 3-D printed fluidized bed generator Roesch, Michael; Roesch, Carolin; Cziczo, Daniel J. Atmospheric Measurement Techniques, Vol. 10, Issue 6 https://doi.org/10.5194/amt-10-1999-2017	journal	January 2017
Kinetically controlled glass transition measurement of organic aerosol thin films using broadband dielectric spectroscopy Zhang, Yue; Katira, Shachi; Lee, Andrew Atmospheric Measurement Techniques, Vol. 11, Issue 6 https://doi.org/10.5194/amt-11-3479-2018	journal	January 2018
The SPectrometer for Ice Nuclei (SPIN): an instrument to investigate ice nucleation Garimella, Sarvesh; Kristensen, Thomas Bjerring; Ignatius, Karolina Atmospheric Measurement Techniques, Vol. 9, Issue 7 https://doi.org/10.5194/amt-9-2781-2016	journal	January 2016
Accounting for the climate–carbon feedback in emission metrics Gasser, Thomas; Peters, Glen P.; Fuglestvedt, Jan S. Earth System Dynamics, Vol. 8, Issue 2 https://doi.org/10.5194/esd-8-235-2017	journal	January 2017

Similar Records

A biogenic secondary organic aerosol source of cirrus ice nucleating particles

Journal Article · 2020 · Nature Communications · OSTI ID:1778945

Wolf, Martin J.; Zhang, Yue; Zawadowicz, Maria A.; +17 more

Ice Nucleation and Droplet Formation by Bare and Coated Black Carbon Particles

Journal Article · 2011 · Journal of Geophysical Research. D. (Atmospheres), 116:Article No. D17203 · OSTI ID:1036927

Friedman, Beth J; Kulkarni, Gourihar R; Beranek, Josef; +3 more

Quantifying Impacts of Aerosol Mixing State on Nucleation-Scavenging of Black Carbon Aerosol Particles

Journal Article · 2018 · Atmosphere (Basel) · OSTI ID:1501893

Ching, Joseph; West, Matthew; Riemer, Nicole

Title: Laboratory study of the heterogeneous ice nucleation on black-carbon-containing aerosol

Citation Formats

References (120)

Similar Records

Related Subjects