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Title: Thick amorphous complexion formation and extreme thermal stability in ternary nanocrystalline Cu-Zr-Hf alloys

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Publisher's Accepted Manuscript
Journal Name:
Acta Materialia
Additional Journal Information:
Journal Name: Acta Materialia Journal Volume: 179 Journal Issue: C; Journal ID: ISSN 1359-6454
Country of Publication:
United States

Citation Formats

Grigorian, Charlette M., and Rupert, Timothy J. Thick amorphous complexion formation and extreme thermal stability in ternary nanocrystalline Cu-Zr-Hf alloys. United States: N. p., 2019. Web. doi:10.1016/j.actamat.2019.08.031.
Grigorian, Charlette M., & Rupert, Timothy J. Thick amorphous complexion formation and extreme thermal stability in ternary nanocrystalline Cu-Zr-Hf alloys. United States. doi:
Grigorian, Charlette M., and Rupert, Timothy J. Tue . "Thick amorphous complexion formation and extreme thermal stability in ternary nanocrystalline Cu-Zr-Hf alloys". United States. doi:
title = {Thick amorphous complexion formation and extreme thermal stability in ternary nanocrystalline Cu-Zr-Hf alloys},
author = {Grigorian, Charlette M. and Rupert, Timothy J.},
abstractNote = {},
doi = {10.1016/j.actamat.2019.08.031},
journal = {Acta Materialia},
number = C,
volume = 179,
place = {United States},
year = {2019},
month = {10}

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Cited by: 3 works
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Works referenced in this record:

Cu-Zr (Copper-Zirconium)
journal, October 1990

  • Arias, D.; Abriata, J. P.
  • Journal of Phase Equilibria, Vol. 11, Issue 5
  • DOI: 10.1007/BF02898260

Relating Grain Boundary Complexion to Grain Boundary Kinetics II: Silica-Doped Alumina
journal, July 2008

Nanocrystalline Fe–C alloys produced by ball milling of iron and graphite
journal, May 2013

Ultrahigh Strength and High Electrical Conductivity in Copper
journal, April 2004

Stabilization of metallic supercooled liquid and bulk amorphous alloys
journal, January 2000

Atomic Resolution Transmission Electron Microscopy of the Intergranular Structure of a Y 2 O 3 -Containing Silicon Nitride Ceramic
journal, October 2003

Ball Milling-Induced Combustion in Powder Mixtures Containing Titanium, Zirconium, or Hafnium
journal, August 1996

Mitigating grain growth in binary nanocrystalline alloys through solute selection based on thermodynamic stability maps
journal, March 2014

In situ TEM study of grain growth in nanocrystalline copper thin films
journal, March 2010

Calcia partition in phase-separated intergranular glass and interfaces in doped silicon nitride produced by hot isostatic pressing
journal, April 2006

  • Gu, Hui; Cannon, Rowland M.; Tanaka, Isao
  • Materials Science and Engineering: A, Vol. 422, Issue 1-2
  • DOI: 10.1016/j.msea.2006.01.012

Sputtered Hf–Ti nanostructures: A segregation and high-temperature stability study
journal, April 2016

Effect of grain boundary character on segregation-induced structural transitions
journal, April 2016

Zirconium and hafnium separation with molten salt extraction in Sn–Cu–Zr–Hf and Cu–Zr–Hf alloy systems
journal, May 2016

Rietveld texture analysis from synchrotron diffraction images. I. Calibration and basic analysis
journal, January 2014

Alloy effects in nanostructures
journal, January 1993

Equilibrium segregation in a ternary solution: A model for temper embrittlement
journal, December 1975

Amorphous intergranular films as toughening structural features
journal, May 2015

Grain boundary wetting and prewetting in Ni-doped Mo
journal, June 2009

  • Shi, Xiaomeng; Luo, Jian
  • Applied Physics Letters, Vol. 94, Issue 25
  • DOI: 10.1063/1.3155443

Kinetic Instability of Nanocrystalline Aluminum Prepared by Chemical Synthesis; Facile Room-Temperature Grain Growth
journal, October 1998

  • Haber, Joel A.; Buhro, William E.
  • Journal of the American Chemical Society, Vol. 120, Issue 42
  • DOI: 10.1021/ja981972y

A Maximum in the Strength of Nanocrystalline Copper
journal, September 2003

Nanoscale segregation behavior and high-temperature stability of nanocrystalline W–20at.% Ti
journal, July 2014

Manipulating the interfacial structure of nanomaterials to achieve a unique combination of strength and ductility
journal, February 2016

  • Khalajhedayati, Amirhossein; Pan, Zhiliang; Rupert, Timothy J.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10802

Grain boundary complexions
journal, January 2014

Grain size stabilization of nanocrystalline copper at high temperatures by alloying with tantalum
journal, October 2013

Developing grain boundary diagrams for multicomponent alloys
journal, June 2015

Inhibition of grain growth by second-phase particles
journal, December 1988

Complexion: A new concept for kinetic engineering in materials science
journal, October 2007

Changes in the Grain Boundary Character and Energy Distributions Resulting from a Complexion Transition in Ca-Doped Yttria
journal, April 2012

  • Bojarski, Stephanie A.; Ma, Shuailei; Lenthe, William
  • Metallurgical and Materials Transactions A, Vol. 43, Issue 10
  • DOI: 10.1007/s11661-012-1172-y

Unraveling the nature of room temperature grain growth in nanocrystalline materials
journal, September 2008

The Cu-Hf (copper-hafnium) system
journal, February 1988

  • Subramanian, P. R.; Laughlin, D. E.
  • Bulletin of Alloy Phase Diagrams, Vol. 9, Issue 1
  • DOI: 10.1007/BF02877460

Relating Grain-Boundary Complexion to Grain-Boundary Kinetics I: Calcia-Doped Alumina
journal, July 2008

Grain-Growth Kinetics of Nanocrystalline Iron Studied In Situ by Synchrotron Real-Time X-ray Diffraction
journal, March 2000

  • Natter, H.; Schmelzer, M.; Löffler, M. -S
  • The Journal of Physical Chemistry B, Vol. 104, Issue 11
  • DOI: 10.1021/jp991622d

Liquid-like interface complexion: From activated sintering to grain boundary diagrams
journal, October 2008

Enhanced glass forming ability in Zr-based bulk metallic glasses with Hf Addition
journal, May 2012

On the Zener drag
journal, January 1985

Abnormal Grain Growth of Alumina
journal, May 1997

Materials selection rules for amorphous complexion formation in binary metallic alloys
journal, November 2017

Abnormal Grain Growth and Intergranular Amorphous Film Formation in BaTiO 3
journal, February 2007

Effect of Liquid Content on the Abnormal Grain Growth of Alumina
journal, July 2001

Estimation of grain boundary segregation enthalpy and its role in stable nanocrystalline alloy design
journal, August 2013

  • Murdoch, Heather A.; Schuh, Christopher A.
  • Journal of Materials Research, Vol. 28, Issue 16
  • DOI: 10.1557/jmr.2013.211

Grain boundary glassy phase and abnormal grain growth of silicon nitride ceramics
journal, January 2001

Recent Progress in Bulk Glassy Alloys
journal, January 2002

The kinetics of grain growth in nanocrystalline copper
journal, December 1991

Grain boundary complexions in multicomponent alloys: Challenges and opportunities
journal, October 2016

Diffusion Controlled Abnormal Grain Growth in Ceramics
journal, October 2007

On the room-temperature grain growth in nanocrystalline copper
journal, March 1994

Grain growth and strain release in nanocrystalline copper
journal, June 2001

  • Lu, L.; Tao, N. R.; Wang, L. B.
  • Journal of Applied Physics, Vol. 89, Issue 11
  • DOI: 10.1063/1.1367401

Liquid-like grain boundary complexion and sub-eutectic activated sintering in CuO-doped TiO2
journal, May 2017

Atomistic modeling of interfacial segregation and structural transitions in ternary alloys
journal, November 2018

Bulk glass formability for Cu–Hf–Zr–Ag and Cu–Zr–Ag–Si alloys
journal, December 2008

Intergranular glassy films: An overview
journal, April 2006

  • Subramaniam, Anandh; Koch, Christoph T.; Cannon, Rowland M.
  • Materials Science and Engineering: A, Vol. 422, Issue 1-2
  • DOI: 10.1016/j.msea.2006.01.004

Mechanical properties of nanocrystalline materials
journal, May 2006

Segregation-induced grain boundary premelting in nickel-doped tungsten
journal, December 2005

  • Luo, J.; Gupta, V. K.; Yoon, D. H.
  • Applied Physics Letters, Vol. 87, Issue 23
  • DOI: 10.1063/1.2138796

Amorphous complexions enable a new region of high temperature stability in nanocrystalline Ni-W
journal, September 2018

The metallurgy and functional properties of hafnium
journal, August 1992

Overview no. 65
journal, March 1988