Unveiling the Photo- and Thermal-Stability of Cesium Lead Halide Perovskite Nanocrystals
Abstract
Abstract Lead halide perovskites possess unique characteristics that are well‐suited for optoelectronic and energy capture devices, however, concerns about their long‐term stability remain. Limited stability is often linked to the methylammonium cation, and all‐inorganic CsPbX 3 (X=Cl, Br, I) perovskite nanocrystals have been reported with improved stability. In this work, the photostability and thermal stability properties of CsPbX 3 (X=Cl, Br, I) nanocrystals were investigated by means of electron microscopy, X‐ray diffraction, thermogravimetric analysis coupled with FTIR (TGA‐FTIR), ensemble and single particle spectral characterization. CsPbBr 3 was found to be stable under 1‐sun illumination for 16 h in ambient conditions, although single crystal luminescence analysis after illumination using a solar simulator indicates that the luminescence states are changing over time. CsPbBr 3 was also stable to heating to 250 °C. Large CsPbI 3 crystals (34±5 nm) were shown to be the least stable composition under the same conditions as both XRD reflections and Raman bands diminish under irradiation; and with heating the γ (black) phase reverts to the non‐luminescent δ phase. Smaller CsPbI 3 nanocrystals (14±2 nm) purified by a different washing strategy exhibited improved photostability with no evidence of crystal growth but were still thermally unstable. Both CsPbCl 3 and CsPbBr 3 showmore »
- Authors:
-
- Iowa State Univ., Ames, IA (United States). Dept. of Chemistry; Ames Lab., Ames, IA (United States)
- Iowa State Univ., Ames, IA (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1572380
- Alternate Identifier(s):
- OSTI ID: 1567915
- Report Number(s):
- IS-J 10067
Journal ID: ISSN 1439-4235
- Grant/Contract Number:
- DEAC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemPhysChem
- Additional Journal Information:
- Journal Volume: 20; Journal Issue: 20; Journal ID: ISSN 1439-4235
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Boote, Brett W., Andaraarachchi, Himashi P., Rosales, Bryan A., Blome‐Fernández, Rafael, Zhu, Feng, Reichert, Malinda D., Santra, Kalyan, Li, Jingzhe, Petrich, Jacob W., Vela, Javier, and Smith, Emily A. Unveiling the Photo- and Thermal-Stability of Cesium Lead Halide Perovskite Nanocrystals. United States: N. p., 2019.
Web. doi:10.1002/cphc.201900432.
Boote, Brett W., Andaraarachchi, Himashi P., Rosales, Bryan A., Blome‐Fernández, Rafael, Zhu, Feng, Reichert, Malinda D., Santra, Kalyan, Li, Jingzhe, Petrich, Jacob W., Vela, Javier, & Smith, Emily A. Unveiling the Photo- and Thermal-Stability of Cesium Lead Halide Perovskite Nanocrystals. United States. https://doi.org/10.1002/cphc.201900432
Boote, Brett W., Andaraarachchi, Himashi P., Rosales, Bryan A., Blome‐Fernández, Rafael, Zhu, Feng, Reichert, Malinda D., Santra, Kalyan, Li, Jingzhe, Petrich, Jacob W., Vela, Javier, and Smith, Emily A. Thu .
"Unveiling the Photo- and Thermal-Stability of Cesium Lead Halide Perovskite Nanocrystals". United States. https://doi.org/10.1002/cphc.201900432. https://www.osti.gov/servlets/purl/1572380.
@article{osti_1572380,
title = {Unveiling the Photo- and Thermal-Stability of Cesium Lead Halide Perovskite Nanocrystals},
author = {Boote, Brett W. and Andaraarachchi, Himashi P. and Rosales, Bryan A. and Blome‐Fernández, Rafael and Zhu, Feng and Reichert, Malinda D. and Santra, Kalyan and Li, Jingzhe and Petrich, Jacob W. and Vela, Javier and Smith, Emily A.},
abstractNote = {Abstract Lead halide perovskites possess unique characteristics that are well‐suited for optoelectronic and energy capture devices, however, concerns about their long‐term stability remain. Limited stability is often linked to the methylammonium cation, and all‐inorganic CsPbX 3 (X=Cl, Br, I) perovskite nanocrystals have been reported with improved stability. In this work, the photostability and thermal stability properties of CsPbX 3 (X=Cl, Br, I) nanocrystals were investigated by means of electron microscopy, X‐ray diffraction, thermogravimetric analysis coupled with FTIR (TGA‐FTIR), ensemble and single particle spectral characterization. CsPbBr 3 was found to be stable under 1‐sun illumination for 16 h in ambient conditions, although single crystal luminescence analysis after illumination using a solar simulator indicates that the luminescence states are changing over time. CsPbBr 3 was also stable to heating to 250 °C. Large CsPbI 3 crystals (34±5 nm) were shown to be the least stable composition under the same conditions as both XRD reflections and Raman bands diminish under irradiation; and with heating the γ (black) phase reverts to the non‐luminescent δ phase. Smaller CsPbI 3 nanocrystals (14±2 nm) purified by a different washing strategy exhibited improved photostability with no evidence of crystal growth but were still thermally unstable. Both CsPbCl 3 and CsPbBr 3 show crystal growth under irradiation or heat, likely with a preferential orientation based on XRD patterns. TGA‐FTIR revealed nanocrystal mass loss was only from liberation and subsequent degradation of surface ligands. Encapsulation or other protective strategies should be employed for long‐term stability of these materials under conditions of high irradiance or temperature.},
doi = {10.1002/cphc.201900432},
journal = {ChemPhysChem},
number = 20,
volume = 20,
place = {United States},
year = {Thu Aug 22 00:00:00 EDT 2019},
month = {Thu Aug 22 00:00:00 EDT 2019}
}
Web of Science
Works referenced in this record:
Giant Photoluminescence Blinking of Perovskite Nanocrystals Reveals Single-Trap Control of Luminescence
journal, February 2015
- Tian, Yuxi; Merdasa, Aboma; Peter, Maximilian
- Nano Letters, Vol. 15, Issue 3
Beyond Colloidal Cesium Lead Halide Perovskite Nanocrystals: Analogous Metal Halides and Doping
journal, April 2017
- Swarnkar, Abhishek; Ravi, Vikash Kumar; Nag, Angshuman
- ACS Energy Letters, Vol. 2, Issue 5
Local Polar Fluctuations in Lead Halide Perovskite Crystals
journal, March 2017
- Yaffe, Omer; Guo, Yinsheng; Tan, Liang Z.
- Physical Review Letters, Vol. 118, Issue 13
Quantifying the Thermodynamics of Ligand Binding to CsPbBr 3 Quantum Dots
journal, August 2018
- Smock, Sara R.; Williams, Travis J.; Brutchey, Richard L.
- Angewandte Chemie International Edition, Vol. 57, Issue 36
Light and oxygen induced degradation limits the operational stability of methylammonium lead triiodide perovskite solar cells
journal, January 2016
- Bryant, Daniel; Aristidou, Nicholas; Pont, Sebastian
- Energy & Environmental Science, Vol. 9, Issue 5
Tailored interfaces of unencapsulated perovskite solar cells for >1,000 hour operational stability
journal, January 2018
- Christians, Jeffrey A.; Schulz, Philip; Tinkham, Jonathan S.
- Nature Energy, Vol. 3, Issue 1
Highly Luminescent Phase-Stable CsPbI 3 Perovskite Quantum Dots Achieving Near 100% Absolute Photoluminescence Quantum Yield
journal, September 2017
- Liu, Feng; Zhang, Yaohong; Ding, Chao
- ACS Nano, Vol. 11, Issue 10
Boosting the Photoluminescence of CsPbX 3 (X = Cl, Br, I) Perovskite Nanocrystals Covering a Wide Wavelength Range by Postsynthetic Treatment with Tetrafluoroborate Salts
journal, May 2018
- Ahmed, Tasnim; Seth, Sudipta; Samanta, Anunay
- Chemistry of Materials, Vol. 30, Issue 11
Photoluminescence Temperature Dependence, Dynamics, and Quantum Efficiencies in Mn 2+ -Doped CsPbCl 3 Perovskite Nanocrystals with Varied Dopant Concentration
journal, September 2017
- Yuan, Xi; Ji, Sihang; De Siena, Michael C.
- Chemistry of Materials, Vol. 29, Issue 18
CsPbBr 3 Solar Cells: Controlled Film Growth through Layer-by-Layer Quantum Dot Deposition
journal, November 2017
- Hoffman, Jacob B.; Zaiats, Gary; Wappes, Isaac
- Chemistry of Materials, Vol. 29, Issue 22
Spontaneous Silver Doping and Surface Passivation of CsPbI 3 Perovskite Active Layer Enable Light-Emitting Devices with an External Quantum Efficiency of 11.2%
journal, June 2018
- Lu, Min; Zhang, Xiaoyu; Bai, Xue
- ACS Energy Letters, Vol. 3, Issue 7
Nanorod Suprastructures from a Ternary Graphene Oxide–Polymer–CsPbX 3 Perovskite Nanocrystal Composite That Display High Environmental Stability
journal, October 2017
- Pan, Aizhao; Jurow, Matthew J.; Qiu, Fen
- Nano Letters, Vol. 17, Issue 11
Photoinduced Anion Exchange in Cesium Lead Halide Perovskite Nanocrystals
journal, March 2017
- Parobek, David; Dong, Yitong; Qiao, Tian
- Journal of the American Chemical Society, Vol. 139, Issue 12
The rapid evolution of highly efficient perovskite solar cells
journal, January 2017
- Correa-Baena, Juan-Pablo; Abate, Antonio; Saliba, Michael
- Energy & Environmental Science, Vol. 10, Issue 3
Colloidal Mn-Doped Cesium Lead Halide Perovskite Nanoplatelets
journal, February 2017
- Mir, Wasim J.; Jagadeeswararao, Metikoti; Das, Shyamashis
- ACS Energy Letters, Vol. 2, Issue 3
Enhanced mobility CsPbI 3 quantum dot arrays for record-efficiency, high-voltage photovoltaic cells
journal, October 2017
- Sanehira, Erin M.; Marshall, Ashley R.; Christians, Jeffrey A.
- Science Advances, Vol. 3, Issue 10
Maximizing and stabilizing luminescence from halide perovskites with potassium passivation
journal, March 2018
- Abdi-Jalebi, Mojtaba; Andaji-Garmaroudi, Zahra; Cacovich, Stefania
- Nature, Vol. 555, Issue 7697
High-Temperature Photoluminescence of CsPbX 3 (X = Cl, Br, I) Nanocrystals
journal, March 2017
- Diroll, Benjamin T.; Nedelcu, Georgian; Kovalenko, Maksym V.
- Advanced Functional Materials, Vol. 27, Issue 21
Bright triplet excitons in caesium lead halide perovskites
journal, January 2018
- Becker, Michael A.; Vaxenburg, Roman; Nedelcu, Georgian
- Nature, Vol. 553, Issue 7687
Photophysics of Hybrid Lead Halide Perovskites: The Role of Microstructure
journal, February 2016
- Srimath Kandada, Ajay Ram; Petrozza, Annamaria
- Accounts of Chemical Research, Vol. 49, Issue 3
Efficient and Stable CsPbBr 3 Quantum-Dot Powders Passivated and Encapsulated with a Mixed Silicon Nitride and Silicon Oxide Inorganic Polymer Matrix
journal, March 2018
- Yoon, Hee Chang; Lee, Soyoung; Song, Jae Kyu
- ACS Applied Materials & Interfaces, Vol. 10, Issue 14
Designing of blue, green, and red CsPbX 3 perovskite-codoped flexible films with water resistant property and elimination of anion-exchange for tunable white light emission
journal, January 2017
- Hai, Jun; Li, Hua; Zhao, Yang
- Chemical Communications, Vol. 53, Issue 39
Quantifying the Thermodynamics of Ligand Binding to CsPbBr 3 Quantum Dots
journal, August 2018
- Smock, Sara R.; Williams, Travis J.; Brutchey, Richard L.
- Angewandte Chemie, Vol. 130, Issue 36
Lasing in robust cesium lead halide perovskite nanowires
journal, February 2016
- Eaton, Samuel W.; Lai, Minliang; Gibson, Natalie A.
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 8
Shape Evolution and Single Particle Luminescence of Organometal Halide Perovskite Nanocrystals
journal, February 2015
- Zhu, Feng; Men, Long; Guo, Yijun
- ACS Nano, Vol. 9, Issue 3
Colloidal CsPbX 3 (X = Cl, Br, I) Nanocrystals 2.0: Zwitterionic Capping Ligands for Improved Durability and Stability
journal, February 2018
- Krieg, Franziska; Ochsenbein, Stefan T.; Yakunin, Sergii
- ACS Energy Letters, Vol. 3, Issue 3
Quantitative Phase-Change Thermodynamics and Metastability of Perovskite-Phase Cesium Lead Iodide
journal, March 2017
- Dastidar, Subham; Hawley, Christopher J.; Dillon, Andrew D.
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 6
Coherent Nanotwins and Dynamic Disorder in Cesium Lead Halide Perovskite Nanocrystals
journal, April 2017
- Bertolotti, Federica; Protesescu, Loredana; Kovalenko, Maksym V.
- ACS Nano, Vol. 11, Issue 4
Room-Temperature Synthesis of Mn-Doped Cesium Lead Halide Quantum Dots with High Mn Substitution Ratio
journal, August 2017
- Zhu, Jingrun; Yang, Xiaoling; Zhu, Yihua
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 17
Cesium Lead Chloride/Bromide Perovskite Quantum Dots with Strong Blue Emission Realized via a Nitrate-Induced Selective Surface Defect Elimination Process
journal, December 2018
- Wang, Shixun; Wang, Yu; Zhang, Yu
- The Journal of Physical Chemistry Letters, Vol. 10, Issue 1
Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties
journal, July 2013
- Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G.
- Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038
Quantum dot-induced phase stabilization of -CsPbI3 perovskite for high-efficiency photovoltaics
journal, October 2016
- Swarnkar, A.; Marshall, A. R.; Sanehira, E. M.
- Science, Vol. 354, Issue 6308
Toward Long-Term Stability: Single-Crystal Alloys of Cesium-Containing Mixed Cation and Mixed Halide Perovskite
journal, December 2018
- Chen, Liang; Tan, Yan-Yan; Chen, Zhi-Xin
- Journal of the American Chemical Society, Vol. 141, Issue 4
Highly Dynamic Ligand Binding and Light Absorption Coefficient of Cesium Lead Bromide Perovskite Nanocrystals
journal, January 2016
- De Roo, Jonathan; Ibáñez, Maria; Geiregat, Pieter
- ACS Nano, Vol. 10, Issue 2
All-inorganic cesium lead halide perovskite nanocrystals: synthesis, surface engineering and applications
journal, January 2019
- Yang, Di; Cao, Muhan; Zhong, Qixuan
- Journal of Materials Chemistry C, Vol. 7, Issue 4
Large-Size CH 3 NH 3 PbBr 3 Single Crystal: Growth and In Situ Characterization of the Photophysics Properties
journal, June 2015
- Zhao, Pengjun; Xu, Jinbao; Dong, Xiaoyu
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 13
Polarized Optoelectronics of CsPbX 3 (X = Cl, Br, I) Perovskite Nanoplates with Tunable Size and Thickness
journal, March 2018
- Sheng, Xuexi; Chen, Gaoyu; Wang, Chong
- Advanced Functional Materials, Vol. 28, Issue 19
Photoluminescence Blinking of Single-Crystal Methylammonium Lead Iodide Perovskite Nanorods Induced by Surface Traps
journal, July 2016
- Yuan, Haifeng; Debroye, Elke; Caliandro, Giorgio
- ACS Omega, Vol. 1, Issue 1
Enhancing Luminescence and Photostability of CsPbBr 3 Nanocrystals via Surface Passivation with Silver Complex
journal, May 2018
- Li, Hongbo; Qian, Yang; Xing, Xing
- The Journal of Physical Chemistry C, Vol. 122, Issue 24
Ligand-Mediated Synthesis of Shape-Controlled Cesium Lead Halide Perovskite Nanocrystals via Reprecipitation Process at Room Temperature
journal, February 2016
- Sun, Shibin; Yuan, Dan; Xu, Yuan
- ACS Nano, Vol. 10, Issue 3
Continuous-Wave Lasing in Cesium Lead Bromide Perovskite Nanowires
journal, December 2017
- Evans, Tyler J. S.; Schlaus, Andrew; Fu, Yongping
- Advanced Optical Materials, Vol. 6, Issue 2
All-inorganic cesium lead halide perovskite nanocrystals for photodetector applications
journal, January 2016
- Ramasamy, Parthiban; Lim, Da-Hye; Kim, Bumjin
- Chemical Communications, Vol. 52, Issue 10
Enhanced Luminescence and Stability of Cesium Lead Halide Perovskite CsPbX 3 Nanocrystals by Cu 2+ -Assisted Anion Exchange Reactions
journal, January 2019
- Chen, Yi-Chia; Chou, Hung-Lung; Lin, Jou-Chun
- The Journal of Physical Chemistry C, Vol. 123, Issue 4
Ultrafast terahertz snapshots of excitonic Rydberg states and electronic coherence in an organometal halide perovskite
journal, June 2017
- Luo, Liang; Men, Long; Liu, Zhaoyu
- Nature Communications, Vol. 8, Issue 1
The Degradation and Blinking of Single CsPbI 3 Perovskite Quantum Dots
journal, December 2017
- Yuan, Gangcheng; Ritchie, Cameron; Ritter, Maria
- The Journal of Physical Chemistry C, Vol. 122, Issue 25
All-inorganic cesium lead iodide perovskite solar cells with stabilized efficiency beyond 15%
journal, October 2018
- Wang, Kang; Jin, Zhiwen; Liang, Lei
- Nature Communications, Vol. 9, Issue 1
Picosecond Quantum Cutting Generates Photoluminescence Quantum Yields Over 100% in Ytterbium-Doped CsPbCl 3 Nanocrystals
journal, May 2018
- Milstein, Tyler J.; Kroupa, Daniel M.; Gamelin, Daniel R.
- Nano Letters, Vol. 18, Issue 6
On the crystal structure of colloidally prepared CsPbBr 3 quantum dots
journal, January 2016
- Cottingham, Patrick; Brutchey, Richard L.
- Chemical Communications, Vol. 52, Issue 30
Solution-Phase Synthesis of Cesium Lead Halide Perovskite Microrods for High-Quality Microlasers and Photodetectors
journal, April 2017
- Wang, Shuai; Wang, Kaiyang; Gu, Zhiyuan
- Advanced Optical Materials, Vol. 5, Issue 11
Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals
journal, February 2018
- Akkerman, Quinten A.; Rainò, Gabriele; Kovalenko, Maksym V.
- Nature Materials, Vol. 17, Issue 5
In Situ Raman Spectroscopic Studies of Thermal Stability of All-Inorganic Cesium Lead Halide (CsPbX 3 , X = Cl, Br, I) Perovskite Nanocrystals
journal, February 2019
- Liao, Mengling; Shan, Beibei; Li, Ming
- The Journal of Physical Chemistry Letters, Vol. 10, Issue 6
What Is the Best Method to Fit Time-Resolved Data? A Comparison of the Residual Minimization and the Maximum Likelihood Techniques As Applied to Experimental Time-Correlated, Single-Photon Counting Data
journal, February 2016
- Santra, Kalyan; Zhan, Jinchun; Song, Xueyu
- The Journal of Physical Chemistry B, Vol. 120, Issue 9
Quantum Dot Light-Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides (CsPbX 3 )
journal, October 2015
- Song, Jizhong; Li, Jianhai; Li, Xiaoming
- Advanced Materials, Vol. 27, Issue 44
Boosting Tunable Blue Luminescence of Halide Perovskite Nanoplatelets through Postsynthetic Surface Trap Repair
journal, July 2018
- Bohn, Bernhard J.; Tong, Yu; Gramlich, Moritz
- Nano Letters, Vol. 18, Issue 8
Photophysical properties of wavelength-tunable methylammonium lead halide perovskite nanocrystals
journal, January 2017
- Freppon, Daniel J.; Men, Long; Burkhow, Sadie J.
- Journal of Materials Chemistry C, Vol. 5, Issue 1
Generalized colloidal synthesis of high-quality, two-dimensional cesium lead halide perovskite nanosheets and their applications in photodetectors
journal, January 2016
- Lv, Longfei; Xu, Yibing; Fang, Hehai
- Nanoscale, Vol. 8, Issue 28
Controllable emission bands and morphologies of high-quality CsPbX3 perovskite nanocrystals prepared in octane
journal, March 2018
- Ye, Shuai; Zhao, Mengjie; Song, Jun
- Nano Research, Vol. 11, Issue 9
Solution-Phase Synthesis of Cesium Lead Halide Perovskite Nanowires
journal, July 2015
- Zhang, Dandan; Eaton, Samuel W.; Yu, Yi
- Journal of the American Chemical Society, Vol. 137, Issue 29
Enhanced stabilization of inorganic cesium lead triiodide (CsPbI3) perovskite quantum dots with tri-octylphosphine
journal, July 2017
- Lu, Chang; Li, Hui; Kolodziejski, Kathy
- Nano Research, Vol. 11, Issue 2
Exciton-to-Dopant Energy Transfer in Mn-Doped Cesium Lead Halide Perovskite Nanocrystals
journal, November 2016
- Parobek, David; Roman, Benjamin J.; Dong, Yitong
- Nano Letters, Vol. 16, Issue 12
Tuning the Optical Properties of Cesium Lead Halide Perovskite Nanocrystals by Anion Exchange Reactions
journal, August 2015
- Akkerman, Quinten A.; D’Innocenzo, Valerio; Accornero, Sara
- Journal of the American Chemical Society, Vol. 137, Issue 32
Bandgap-Tunable Cesium Lead Halide Perovskites with High Thermal Stability for Efficient Solar Cells
journal, February 2016
- Sutton, Rebecca J.; Eperon, Giles E.; Miranda, Laura
- Advanced Energy Materials, Vol. 6, Issue 8
Fast Anion-Exchange in Highly Luminescent Nanocrystals of Cesium Lead Halide Perovskites (CsPbX 3 , X = Cl, Br, I)
journal, July 2015
- Nedelcu, Georgian; Protesescu, Loredana; Yakunin, Sergii
- Nano Letters, Vol. 15, Issue 8
Room Temperature Single-Photon Emission from Individual Perovskite Quantum Dots
journal, September 2015
- Park, Young-Shin; Guo, Shaojun; Makarov, Nikolay S.
- ACS Nano, Vol. 9, Issue 10
Cesium Enhances Long-Term Stability of Lead Bromide Perovskite-Based Solar Cells
journal, December 2015
- Kulbak, Michael; Gupta, Satyajit; Kedem, Nir
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 1
Photophysics of Organic-Inorganic Hybrid Lead Iodide Perovskite Single Crystals
journal, February 2015
- Fang, Hong-Hua; Raissa, Raissa; Abdu-Aguye, Mustapha
- Advanced Functional Materials, Vol. 25, Issue 16
Cesium Lead Halide Perovskites with Improved Stability for Tandem Solar Cells
journal, February 2016
- Beal, Rachel E.; Slotcavage, Daniel J.; Leijtens, Tomas
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 5
Luminescence properties of CsPbBr3 nanocrystals dispersed in a polymer matrix
journal, June 2018
- Demkiv, T. M.; Myagkota, S. V.; Malyi, T.
- Journal of Luminescence, Vol. 198
Two types of luminescence blinking revealed by spectroelectrochemistry of single quantum dots
journal, November 2011
- Galland, Christophe; Ghosh, Yagnaseni; Steinbrück, Andrea
- Nature, Vol. 479, Issue 7372
Doping Lanthanide into Perovskite Nanocrystals: Highly Improved and Expanded Optical Properties
journal, November 2017
- Pan, Gencai; Bai, Xue; Yang, Dongwen
- Nano Letters, Vol. 17, Issue 12
High-Quality In-Plane Aligned CsPbX 3 Perovskite Nanowire Lasers with Composition-Dependent Strong Exciton–Photon Coupling
journal, May 2018
- Wang, Xiaoxia; Shoaib, Muhammad; Wang, Xiao
- ACS Nano, Vol. 12, Issue 6
Highly Luminescent Colloidal Nanoplates of Perovskite Cesium Lead Halide and Their Oriented Assemblies
journal, December 2015
- Bekenstein, Yehonadav; Koscher, Brent A.; Eaton, Samuel W.
- Journal of the American Chemical Society, Vol. 137, Issue 51
Colloidal Nanocrystals of Lead-Free Double-Perovskite (Elpasolite) Semiconductors: Synthesis and Anion Exchange To Access New Materials
journal, January 2018
- Creutz, Sidney E.; Crites, Evan N.; De Siena, Michael C.
- Nano Letters, Vol. 18, Issue 2
Advancements in perovskite solar cells: photophysics behind the photovoltaics
journal, January 2014
- Sum, Tze Chien; Mathews, Nripan
- Energy Environ. Sci., Vol. 7, Issue 8
Pressure Response of Photoluminescence in Cesium Lead Iodide Perovskite Nanocrystals
journal, April 2018
- Beimborn, J. Curtis; Hall, Leah M. G.; Tongying, Pornthip
- The Journal of Physical Chemistry C, Vol. 122, Issue 20
Single Cesium Lead Halide Perovskite Nanocrystals at Low Temperature: Fast Single-Photon Emission, Reduced Blinking, and Exciton Fine Structure
journal, January 2016
- Rainò, Gabriele; Nedelcu, Georgian; Protesescu, Loredana
- ACS Nano, Vol. 10, Issue 2
Nanocrystals of Cesium Lead Halide Perovskites (CsPbX 3 , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut
journal, February 2015
- Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I.
- Nano Letters, Vol. 15, Issue 6
Maximizing and stabilizing luminescence from halide perovskites with potassium passivation
journalarticle, January 2018
- Abdi Jalebi, Mojtaba; Andaji Garmaroudi, Zahra; Cacovich, Stefania
- Springer Nature
Boosting Tunable Blue Luminescence of Halide Perovskite Nanoplatelets through Postsynthetic Surface Trap Repair.
text, January 2018
- Bohn, Bernhard J.; Tong, Yu; Gramlich, Moritz
- Apollo - University of Cambridge Repository
Local polar fluctuations in lead halide perovskite crystals
text, January 2016
- Yaffe, Omer; Guo, Yinsheng; Tan, Liang Z.
- arXiv